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By S. C. Schaefer

Thermodynamic properties of indium oxide (In203) have been studied with a high-temperature galvanic cell employing stabilized zirconia electrolytes. In the temperature range 790° to 1,230° K the free-energy change for the cell reaction 21n(1) + 3Cu20(c) = In203(c) + 6Cu(c) together with the standard free energy of formation of cuprous oxide gives the standard free energy of formation of indium oxide from the elements as ?Gf° = -218.78 + 75.34 X 10-3T ±0.7 kcal/mole. A third-law analysis yields the standard enthalpy of formation: ?Hf°298.15 = -221.5 kcal/mole.

Jan 1, 1971

By R. B. Anderson

SULFUR poisoning of iron catalysts in the Fischer-Tropsch synthesis was investigated at the Bureau of Mines, because synthesis gas produced from coal contains sulfur compounds. Tests of two typical iron catalysts with synthesis gas containing known concentrations of H2S were made to determine catalyst life as a function of sulfur concentration to ascertain the type of gas purification required. Fixed beds of activated steel turnings and a fused iron oxide catalyst were investigated in sulfur poisoning tests at 21.4 atmospheres with IH2+100 gas containing 6.9, 23, or 69 mg S as H2S per cubic meter (0.3, 1.0, and 3.0 gr per 100 cu. ft.). In tests of reduced catalysts at constant temperatures, more than 80 percent of the activity was lost when 0.5 mg S/g Fe was introduced. Poisoning of nitrided or carbided fused iron oxide catalysts to a given extent required more than twice as much sulfur than for the corresponding reduced catalyst. When the synthesis temperature was increased to compensate for loss in activity, tests of the fused iron oxide catalysts at constant productivity could be continued for 19 to 98 days. The tests were terminated by clogging of the reactor, presumably caused by carbon deposition. One objective of the present work was to determine if synthesis gas, purified by the Bureau of Mines' hot-potassium carbonate process for removing H2S, OOS, and CO2, is suitable for synthesis on iron catalysts. The sulfur content of the gas purified by tills process is in the range of concentrations used in the present work. In constant-productivity tests of nitrided fused iron oxide catalysts with synthesis gas containing 6.9 mg S/m3, catalyst lives are nearly long enough for serious consideration of tills mode of operation. However, factors relating to selectivity and stability of the catalyst indicate that this type of operation is impractical for a commercial process. On this basis additional gas purification, such as iron oxide boxes following a hot potassium carbonate scrubber, is desirable.

Jan 1, 1965

By M. K. Larson, J. K. Whyatt, F. M. Jenkins

The U.S. Bureau of Mines conducted an overcore stress measurement on the 5300 level of the Lucky Friday Mine, Mullan, ID, to investigate the stress regime around an experimental stope in a rock-burst-prone mine. The result indicated a stress field with unexpected magnitude and orientation [F . 135 MPa (19,600 psi) oriented S 80E1W]. An unusual amount of rock-burst activity was encountered during subsequent excavation. A careful review of the overcore data suggested the overcore strain measurements were valid. Moreover, concentrated rock-burst activity suggested that the measured stress field did exist, but was localized and therefore did not represent the far-field in situ stress field.

Jan 1, 1995

By L. D. Wyant

That natural gas-gasoline can be used to advantage as a refrigerant is suggested by the fact that the "make" tanks and other parts of the equipment of gasoline plants frequently become coated with frost. The experiments reported in this paper confirm this assumption and indicate that volatile gasoline can be use used to advantage in many refrigerating plants. The Bureau of Mines is making a study of wax distillates in order to find out why satisfactory lubricating oils and waxes can be made easily from certain crude oils and only with difficulty from others. In the commercial distillation of crude petroleum it is customary to separate the distillates into the following groups: (A) Gasolines and naphthas, (B) Kerosenes, (C) Gas oil, and (D) Wax distillate (consisting mostly of light lubricating oil together with small amounts of paraffin Wax).

Jan 1, 1923

By R. W. Smith

The Bureau of Mines has been engaged in a systematic evaluation of the thermodynamic properties of combustion gases. These studies were designed to provide basic thermodynamic information of high accuracy, facilitating the theoretical study of flame and combustion phenomena.4 This report is the fifth of a series5/ presenting results of the study for particular fuel-oxidant systems. These calculations have as their objective the constant pressure flame temperature of acetylene-air for a range of pressures.

Jan 1, 1954

By C. M. Mason

Bureau of Mines studies were made on the sensitivity of several ammonium nitrate-fuel oil (AN-FO) mixtures to bullet impact. The experimental work was done with one military rifle and two high-velocity sporting rifles with a variety of ammunition. For the three rifles used, the order of efficiency in initiating detonation in AN-FO mixtures was 220 Swift >300 Weatherby Magnum >30-&apos;06. The velocity of the bullet was found to be a decisive factor in the initiation. The sensitivity of various materials studied increased as follows: Clay-coated prills with 4 percent oil <fresh surfactant-coated prills with 4 or 6 percent oil <surfactant-coated prills with 4 or 6 percent oil and aged 270 days <crushed prills with 6 percent oil <very low-density, surfactant-coated prills (micronized), with 4 percent oil.

Jan 1, 1963

By James W. Ballard

The facts are generally accepted that an atmosphere containing large quantities of any dust is objectionable to breathe and that some dusts are more dangerous than others. Therefore, knowledge of the composition of dusts is important in evaluating the hazard entailed on exposure. At present, free silica, of which quartz is the most abundant form, is considered one of the most significant dusts, from the standpoint of pneumoconiosis, and one State5/ has established permissible limits of air dustiness on the basis of the free-silica content of rock. The amount of free silica in materials used for rock dusting also has been limited.6/ Determination of free silica or quartz, therefore, is important.

Jan 1, 1940

By D. Harrington

Near the close of the nineteenth century electricity was introduced underground, and the mining industry automatically was confronted with another potential source of fatalities and injuries to mine workers. Electricity has become an increasingly vital factor in the production of goal, particularly in recent years, because of the greatly extended mechanization that has taken place underground. The enlarged use of electrical equipment for cutting, loading, and hauling coal unquestionably increased the potentiality of shock and explosion hazards underground. Electricity may be used in coal mines with minimum danger if electric equipment and power-carrying wires are chosen properly and installed and kept protected by proper safeguards; on the other hand, if vigilance is relaxed in the slightest degree accidents may result. Electrical accidents are caused chiefly by direct contact with electrical equipment or power-carrying wires, by ignition of explosive gas or dust, and by fires of electrical origin. Electricity now ranks fourth as a cause of coal-mine fatalities, not including deaths from explosions or fires of electrical origin.

Jan 1, 1936

By Ronald H. Church, Walter E. Pittman, J. T. McLendon

In its role of providing technical assistance to the mining industry, the Bureau of Mines&apos; Tuscaloosa Research Center has conducted research to develop trapped miner location systems which would aid in locating miners trapped by underground mining disasters. Efforts to produce electromagnetic systems for the location of trapped miners underground and to communicate with them were surveyed, from the 1920&apos;s to 1981. Theoretical studies of through-the-earth electromagnetic transmissions are described as well as studies of the electrical characteristics of various rocks, minerals, and soil. Several trapped miner location systems are reviewed including the Westinghouse systems, the DEVELCO system, and an automated three-dimensional location system, and the phase difference of arrival technique. Tangential research, relevant to trapped miner location systems is described. A comprehensive bibliography covering all aspects of trapped miner, through-the-earth electromagnetic location and communications systems is appended.

By Leonard Obert

A triaxial procedure is described for measuring the modulus of elasticity and Possion's ratio of stress relief cores , that is , the concentric hole cores obtained by the overcoring technique . The elastic constant determinations can be made at stress levels comparable with those encountered in underground mining . The results from tests on an aluminum alloy calibration specimen and four rock specimens are included .

Jan 1, 1964

By Timothy J. Rohrbacher

This report presents a U.S. Bureau of Mines study that incorporates coal mining factors, coal recovery factors, and economic factors into the definition of an economically recoverable coal resource. The relationship between these factors to the Energy Information Administration&apos;s estimate of U.S. coal resources-the "Demonstrated Reserve Base"-is discussed. The Matewan 7-1/2 minute quadrangle in eastern Kentucky was selected as the initial study area. Results indicate that of the original 1,193 million tons of resource in the quadrangle, only 89 million tons (7.5%) are economically recoverable at a cost of $25 per ton or less. At the current production rate of 5.3 million tons per year, this represents only 16.8 years of remaining reserves.

Jan 1, 1993

By A. B. Hooker

Gassy mines require daily inspections with methane detectors to test for the presence of methane. Although in many manes it may be sufficient to know that there is no methane present or that its percentage is below a certain amount, it is desirable and often necessary to determine definitely the percentage of methane at the working faces and in the various air currents. The Bureau of Mines recognizes two general types of portable methane detectors, namely; 1. Methane detectors by which the presence of methane may be detected and its approximate percentage estimated.

Jan 1, 1929

By Seth C. Schaefer

As part of the Bureau of Mines, U.S. Department of the Interior, effort to provide thermodynamic data for the advancement of minerals technology, the Gibbs energy of formation of sphalerite (zinc sulfide) was investigated with a high-temperature galvanic cell employing stabilized zirconia as the electrolyte. In the temperature range 948 to 1,210 K, potential measurements were obtained for the cell Pt, ZnS + ZnO, S02 = 1 atm // Zr02 // Cu20 + Cu, Pt, with the overall cell reaction ZnS(c) + 3 Cu20(c) = ZnO(c) + 6 Cu(c) + S02(g). (1) These results, combined with the best available values of ?Gf° for ZnO, S02, and Cu20 from the literature, give the Gibbs energy of formation of zinc sulfide for the reaction Zn(l,v) + 1/2 S2(g) = ZnS© (2) ?Gf° = -64.223 + 24.02 X 10-3T ± 0.650 kcal/mole (3) (948-1,180 K; standard states - pure liquid zinc and S2 gas at 1 atm), and ?Gf° = -92.720 + 48.17 X 10-3 ± 0.650 kcal/mole (1,180-1,210 K; standard states - pure zinc vapor and S2 gas at 1 atm). A third law analysis yields for the formation reaction Zn(1) + 1/2 S2(g) = ZnS(c), (5) a standard enthalpy of formation as follows: ?Hf298.15 = -63.64 ± 0.700 kcal/mole.

Jan 1, 1978

By T. SPOLAN, G. W. Jones, R. E. Kennedy

Information relative to the explosibility of acetylene at elevated pressures and means of handling acetylene safely under these conditions is of considerable interest at present. American practice limits the pressure at which acetylene may be generated and distributed to poiIits of' use. The pressure in portable acetylene generators is 15 pounds per square inch gage. Tests made by the Bureau of Mines have shown that 15 pounds per square inch gage is too high to prevent explosiofiS of gaseous acetylene in the absence of air; in fact, dry acetylene gai can be exploded at pressures greater than 5.9 pounds per square inch gage. The Bureau has been interested in the explosibility of acetylene for many years because of its continued: use for illumination in many metal mines and its general use in cutting 1illd~--eldifigoperations in the mining maus-try.

Dec 1, 1948

By S. J. Davenport

[The tremendous increase in mine mechanization since 1929 has increased markedly the application of electric power in and about the coal mines of the United States. Cutting, drilling, and leading machines have replaced hand-mining methods in nary mines. As a result, expansion of the gathering haulage has necessitated introduction of extensive feeder, trolley, grid other power wires. (1)3/ In spite of this vast mechanization the fatality rate from electric shock has been on the decline. However, there are still too many accidents, and efforts to eliminate electrical hazards cannot be relaxed. It is hoped that an acquaintance with the physiological aspects of electrical accidents will make workers end management aware of the lurking dangers of this very common and extremely dangerous form of energy.]

Jan 1, 1951

By E. L. Garton

The Bureau of Mines for a number of years bas been conducting an investigation of crude petroleum from producing fields in the United States and the Western Hemisphere and has published a series of reports on these fields. Analyses of crude-oil samples from many oil fields of Oklahoma are given in Bulletin 2915. Analyses of 21 representative crude oils from various producing zones of the Oklahoma City field are given in this report. A close study of the analyses reveals very few differences in the general characteristics and chemical properties of these oils.

Jan 1, 1932

By Peter K. Mathison

The U.S. Bureau of Mines has developed a hydrologic monitoring system for in situ leaching operations. This system records and displays flow and pressure information from sensors located in leachant injection and recovery wells. Continuous monitoring of hydrologic conditions is important during leaching operations because hydrologic factors such as aquifer permeability, solution injection rates, injection pressure, and solution recovery rates interact and change over time. This hydrologic monitoring system has been tested in an underground setting at the Cyprus Casa Grande copper mine. The system consists of hardware and computer software components and includes two Bureau-developed software applications. This publication describes the implementation of the hydrologic monitoring system and the software developed at the Bureau in support of in situ leaching research.

Jan 1, 1994

By Elizabeth A. Johnson

The vaporization thermodynamics of the aluminum-silicon carbides Al4SiC4 and Al8SiC7 were studied by the Bureau of Mines over the temperature range of approximately 1,500 to 1,700 K. Vapor pressures were measured by a Knudsen effusion-mass spectrometry technique in which powdered samples were effused from graphite crucibles through small orifices. For each compound, a total of six orifice diameters was tested to verify equilibrium within the cell. Aluminum, mass number 27, was the only vapor species detected over the range 4 to 200 amu. Experimental results are based on the following equations for incongruent decomposition: A14SiC4(cr) - 4A1(g) + SiC(a,hex) + 3C(gr); Al8SiC7(cr) - 8A1(g) + SiC(a,hex) + 6C(gr). The observed vapor pressure-temperature relationships determined with a cell orifice area of 2.0 x 10-3 cm2 for Al4SiC4 and 1.81 x 10-3 cm2 for A18SiC7 are the following: Log P - (-18,682/T) + 12.476, for Al4SiC4 (1,550 to 1,643 K) and Log P = (-19,308/T) + 12.421, for Al8SiC7 (1,526 to 1,784 K), with P in pascals and T in kelvins. Third-law analysis of the data provided the following heats of formation: A14SiC4 ?H at 298.15 K - -50.0 kcal/mol and A18SiC7 ?H at 298.15 K - -92.1 kcal/mol.

Jan 1, 2011

By Alan R. Buehler

The Bureau of Mines conducted a mineral investigation of the 32,270-hectare Cache Peak study area in 1992; the area had been proposed as wilderness. Bureau personnel examined and sampled prospect workings; 50 rock and placer samples were taken during the investigation. The study area is centered about 25 km southeast of Challis, Idaho, in the Challis National Forest. According to May, 1993, Bureau of Land Management mining claim records there were no current mining claims located inside the study area. Up to 100 claims may have been located in the study area in the past. Gold, silver, copper, lead, zinc: Significant analyses, poor exposure precludes resource estimate. Limestone: More than I billion tonnes may be chemically suitable for a variety of uses, markets too distant to favor mining. Dolomite: More than 1 billion tonnes may be chemically suitable for producing magnesium metal, markets too distant to favor mining. Sand and Gravel: Several million m3, but markets and transportation costs do not favor mining. Chalcedonic nodules: Two localities in the study area may be of interest to hobbyists who cut and polish stone. There is no reported past production from the study area.

Jan 1, 1993

By Wesley A. Grosh

The Allah Cooper mine, in Louisa County, Va., formerly was a producer of lead and zinc. It was believed that the critical shortage of leach and zinc and the fact that some ore had been produced at this mine justified exploration of it. A preliminary examination was made on April 30, 1943, by J. E. Hill, a Bureau of Mines Engineer. Diamond drilling was done on the property from November 30 to December 18, 1943, to determine whether the sulfide body extended to depth. One hole drilled to a depth of 650 feet and located so as to cut the Allah Cooper ore shoot about 150 feet below the lowest known mine workings failed to disclose sulfide vein at that depth.

Jan 1, 1949