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By Bernard Lewis

This report on the research and technical studies conducted by the Explosives Branch of the Bureau of Mines covers the 2-year period July 1, 1946, to June 30, 1948. A report for the fiscal year 1947 was omitted because of the large amount of work still in an unfinished state. The material presented herein is based largely upon more comprehensive reports prepared under the authorship of members of the branch staff.

Jan 1, 1949

By R. M. Santmyers

The chief compounds of boron are borax and boric acid, both of which have important applications in industry. At present the United States furnishes more than half of the world's requirements of borate materials, practically all from California. Nearly the entire production of borax in this country is under the control of four companies: The American Potash and Chemical Corporation, the Pacific Coast Borax Co., the West End Chemical Co., and the Western Borax Co.

Jan 1, 1931

By L. A. Readdy

Pilot Hole "X" was drilled to test the formations through which the ventilation shaft for the proposed U.S.B.M. demonstration oil shale mine will be drilled. The history of the drilling of Pilot Hole "XI' is presented. This historical summary provides the details of method used during the drilling of this hole. Problems encountered during drilling are discussed. The quantities of drilling mud and other materials used to drill the hole are documented.

Jan 1, 1977

By Ruth F. Brinkley

This circular describes the activities and publications of the Bureau of Mines, Explosives Research Laboratory4 for the fiscal year 1960 (July 1, 1959 -June 30, 1960). Part 1 describes briefly the principal projects that were active during the report period, and presents some data not scheduled for publication elsewhere in the near future. Certain of the results are only preliminary and should be regarded as tentative, pending the findings of the completed investigation. Publications that appeared during the report period are listed and described briefly in part 2. In general, the research activities reported in these publications antedate fiscal year 1960. The published material relating to activities that are still current is indicated by references in part 1.

Jan 1, 1962

By Gordon R. Sima, John L. Bennett, Roger L. King

Electric shocks are a serious problem in the mining environment. Because of extremely wide ranging use of electrically powered equipment in the mining industry, the hazard to personnel due to electrical shock and related injuries are not restricted to any single area but cover the entire spectrum of mining activity. Electrical accidents, resulting in personal injury, due to im- proper or complete lack of grounding of electrically operated mining machines, form a significant percentage of the overall electrical accident picture. The object of this paper is to describe methods of detection of unsafe electrical conditions with respect to the grounding of electrically operated mining equipment. It also includes a discussion of prototype instruments which effectively monitor the condition of the grounding safety devices currently in use on mining equipment and warn of dangerous conditions as soon as they appear. The paper is based on work accomplished under USBM Contract Number 50357115. The contract was initiated under the Pittsburgh Mining and Safety Research Center Program. It was administered under the technical direction of PM and SRC with Mr. Roger L. King as the Technical Project Officer. Mr. Daniel B. Dawkins was the Contract Administrator for the Bureau of Mines.

By H. William Zeller, T. E. Westpha1

The U.S. Bureau of Mimes evaluated the effects of two iron-based fuel additives on diesel particulate matter (DPM) emissions. The 5.6-L, six-cylinder test engine is typical of engines used in underground mines. One additive, ferrous picrate, did not measurably affect exhaust emissions. This report is mainly about a ferrocene-based additive that reduced DPM between 4 and 45 pct, depending on engine operating conditions. The report concludes that the DPM reductions were caused by the catalytic oxidation properties of a ferric oxide coating that developed inside the engine's combustion chamber. The ferric oxide coating also decreased gas-phase hydrocarbons and O, but it increased CO, and NO,. The increase in NO,, of about 12 pct, is considered the only adverse effect of the ferrocene-based fuel additive. The results suggest that the effectiveness of ferrocene was partially offset by increased sulfates because of the high-sulfur fuel used. Recommendations for continuing fuel additive research are presented.

Jan 1, 1992

By B. J. Moore

This publication contains analyses and related source data for 675 natural gas samples from wells and pipelines in 24 States and 5 foreign countries. The samples obtained and analyzed during calendar year 1980 are included in tables 1-4. Those samples included in tables 5-7 were collected during the years 1960 through 1979. However, permission to publish the analyses of those samples was not given until the past year when the operators were again contacted to seek release of the information. All of these samples were collected as a part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted in the United States by the Bureau of Mines since 1917. In late 1965, the survey was expanded to include foreign gasfields. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4862 and 576. The results of the investigation of the occurrences of helium are published annually to make the information available as soon as possible to the gas industry and the general public. Twenty-two previous publications have presented the results of 12,152 gas analyses made prior to 1980. The first three, Bulletins 486,' 576,5 and 617,6 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1980. The other

Jan 1, 1981

By K. L. Paciorek

The aim of the present study is to determine on a gram per gram basis the toxic products of the thermal oxidative degradations of selected compositions. Four families of materials were investigated under the subject contract namely polyvinyl chloride and neoprene compositions, rigid urethane foams I and woods. Three methods were employed to conduct the thermal oxidative degradations: a sealed system (quiescent environment) I a stagnation burner arrangement (dynamic environment) I and a flow-through apparatus (dynamic I but less severe than stagnation burner conditions). The majority of tests were conducted using the first two systems; only limited experiments were carried out employing the third decomposition procedure. All decomposition was done at temperatures of 370 -4000C I the higher temperature being used in the stagnation burner. It has to be stressed that the nature of the products and the relative product concentration are temperature dependent. Thermogravimetric and differential thermal analyses were performed to supplement and extend the above delineated studies and to explore the feasibility of using these analyses as a method for material differentiation.

Jan 1, 1973

By R. J. O'Dea

"The United States hat large reserves of titaniferous iron ores that are a potential future source of both iron and titanium. Although it is not now economically feasible to recover iron and titanium metals from these ores, they may become important in times of stress and, in some instances, already have served as a source of pigment-quality titania.The iron- and titanium-bearing constituents of the ores considered in this report are not completely separable from each other by ore-dressing methods, and chemical (or smelting) procedures must be employed. It is im¬portant, therefore, that information be available concerting their reactivities. The most important titanium-bearing constituent is ilmenite (FeTiO3), the thermodynamic properties of which were discussed in a previous publication.3/ The results of thermodynamic studies showed that both hydrogen and carbon monoxide are relatively ineffective reducing agents for the iron in limonite. On the other hand, carbon theoretically is effective at tempera¬tures above 8510C., at which. point the combined equilibrium pressures of CO and CO2 from the reactionsFeTiO3 + C = Fe+ TiO + COand200 = C+ CO2reach 1 atmosphere.This report gives results of small-scale tests of selective reduction by carbon of the iron in titaniferous iron ores, both with and without addition of sodium carbonate. It is shown that the bulk of the iron may be reduced and separated without serious reduction or loss of titanium. Three Wyoming ores, Iron Mountain, Shanton, and Taylor, wore studied. The principal factors investigated were temperature, time, carbon:ore ratio, particle size, and sodium carbon ore ratio.Two methods of investigation were employed. In the first, intimate mixtures of ore and carbon were roasted and the reduced iron and titanium evaluated by leaching with dilute sulfuric acid and analyzing the leach solution (and, in some instances, the dried residues).Twenty grams of ore were mixed thoroughly with carbon and tamped into an alundum thimble having a loosely fitting cover. The thimble and contents were placed in a test-tube end porcelain tube and heated to the desired temperature in a Globar tube furnace. The open end of the porcelain tube was connected to a bubbler containing sulfuric acid, in a manner that permitted complete shut-off of the tube when desired. This allowed removal of the tube from the furnace at the end of the roast period without exposure of the contents to the atmosphere."

Jun 1, 1946

By Gary Choate

The work presented in this report represents the background activity which led to the fabrication and testing of a greenhorn and crowd limit switch system for electric shovels. The program began With a literature search and manufacturers product review to gather material as a basis for concept generation. Visits to three open pit mines provided information from operation and maintenance managers which was useful in preparing design concepts. These concepts were evaluated through laboratory tests and engineering analysis to select a final design concept. The resultant greenhorn is four separate shock absorbing pads each enclosed in a housing which bolts to the end of a dipper handle adaptor. The plungers impact against stops mounted to the saddle block. The crowd limit control is a nonmechanical device which senses the location of the dipper and makes appropriate commands to the crowd motor to insure against impacting the greenhorns. The electronic crowd limit control is redundant and indicates malfunction modes. The greenhorn prevents shovel damage in the unlikely event of impact.

Jan 1, 1983

A working understanding of present coal mine communications equipment and its usage is an essential prerequisite to the determination of future communications systems needs. As a means of gaining this understanding, a field survey program was planned and implemented. The plan formulated called for obtaining both qualitative and quantitative data from three main areas of interest: the types, physical condition, and performance characteristics of equipment presently used in the sample of mines to be visited; the relationship present communications has to safety and productivity; and the practical, future communications needs as de- rived through interviews with present mine management. In compliance with the original plan, the type and physical condition of equipment in use was found through at-mine interviews of personnel responsible for installation and maintenance. Further evaluation was made through the review of equipment instruction books and maintenance manuals and through in-mine inspection of communications equipment and signal distribution networks. The performance characteristics were determined through listening to conversations and noise levels and by talk-testing from randomly selected stations throughout each mine. System operation was evaluated by asking communication system users their opinions and by noting any difficulties personnel had using the systems. Plans in the second area of interest--that of relating communications to mining operations-- were to observe mining operations and usage of communications; to gain insight through interviews with mine management, from mine superintendents to section foreman; and to look for correlation between communications, production, and safety. Lastly the communication systems needs and requirements were determined from first hand interviews of mine personnel, from the analysis that lead to the individual reports on the eight mines, and from an overview of all of the mines studied. The latter was done to find commonality between the needs of the individual mines such that system requirements having the greatest universal value could be derived, thus lowering per-mine cost of equipment through economics of scale. Armed with tape recorders, backgrounds in communications technology, and with an interview questionnaire that was improved as experience was gained, engineers visited the eight mines to obtain the raw data from which the needs and requirements could be developed through analysis. During the first part of the program two days were spent at each mine so that interviews and tours could be completed, and so that full eight hour shift phone usage recordings could be obtained for statistical analysis. One day visits were sufficient for those trips where tape recordings were not made. During the later trips less attention was given to the statistical nature of communications, and more to how communications relates to the total mining operation.

Nov 15, 1974

By R. W. Nash

This report describes the design and operation of a digital instrumentation package for the Bureau of Mines improved torsion pendulum, a scientific instrument that measures the vibration damping of metallic materials. The new design eliminates manual analog-to-digital conversion, reduces the data acquisition time, and increases the precision of the measurements. The digital output can be coupled directly to a micro-processor or computer to produce the final data in real time.

Jan 1, 1983

By Donald S. Colby

CARBON-BLACK shipments, which had declined in the latter art of 1953, remained low in 1954 until after settlement of the labor strike that occurred in the rubber industry in July and August. The production of new model automobiles in the last quarter of the year spurred the demand for rubber tires and consequently the demand for carbon black. Total shipments of 1,498 million pounds for the year were 4 percent below 1953.

Jan 1, 1958

By Rita D. Sylvester

"This compilation lists and summarizes publications by Bureau authors published in the regular Bureau of Mines series, in scientific, technical, or trade journals, or in other media; those available from the Bureau of Mines are indicated. Patents issued to Bureau personnel are also listed, and instructions are given on how to apply for permission to use them. One of the outstanding features of this Special Publication is an exhausive subject and author index. IntroductionThe Bureau of Mines was established in the public interest to conduct inquiries and scientific and technologic investigations concerning mining and the preparation, treatment and utilization of mineral substances; to promote health and safety in the mineral industries; to conserve material resources and present their waste; to further economic development; to increase efficiency in the mining, metallurgical, quarrying, and other mineral industries; and to inquire into the economic conditions affecting those industries, The organic act of the Bureau, as amended by Congress and approved February 25, 1913, made it the province and duty of the Bureau to ""disseminate information concerning these subjects in such manner as will best carry out the purposes of this Act.""In accordance with this directive, the Bureau reports the findings of its research and investigations in its own series of publications and also in articles that appear in scientific, technical, and trade journals; in proceedings of conventions and seminar's; in reference books; and in other non-Bureau publications. The number of these reports, the wide range of subjects they cover, and the variety of mediums in which they appear make the kind of list and index presented in this special publication both necessary and valuable. This issue describes reports and articles published during the period January 1, 1970, to December 31, 1974. It supplements the 50-year list of Bureau publications issued from July 1, 1910, to January 1, 1960;2 the 50-year list of articles by Bureau authors published outside the Bureau from July 1, 1910, to January 1, 1960;3 and the 5-year lists of Bureau publications and articles from January I, 1960, to December 31, 1964,4 and from January I, 1965, to December 31, 1969.5 It includes all the material in the four annual lists of Bureau publications and articles from January 1, 1970, to December 31, 1973."

Jan 1, 1975

By Robert L. Lagace

[Suuple Iheorctrccil models are I'M lllolalcd to cltaraclerl/c medium frequency (MF) radio vase pi opaiation in undcrgiounli room arid pillar coal mines fur the purpose of predleiln the most lavolable operating fIegtucncics,md nr,ixunum communic;IIIoil ranges for pottahIe rldu)s with I top antennas. I or conductul IrCC areas, at hree layer propaeaIion IltodcI wit II a Iiallsmissloil IIIIi- lhlllllIIal'u11 lot the plupa!edti ii unlstallt Iris been dcvcloped ;md verified experimentally. 1 lie mode u1 propaCaUetl lakes Ills form of i parallel plane (0,t)) TIM lransnussu)nhne 1% PC of mode with the electric held vertical and the magnetic held hoti/cntal t itliin a planar coal scam in which the tunnels Can he ignored and which 1s hounded above and below hp richer conductivity rock. 1lie model lilt the data best river the 200 io 1000 kH/ frequency hand and exhibits a rc;;lon of optlnrul1l Pelffelntance, with respect Io maxnluiulg radio Communication range, between 300 and 100 klf/. Maximum cunununlcatrorl ranges are sliongls dependent oil the sigiial alleilliatroil sale, ant) Illelclulc on the electrical conductivltles of the coal seam and surrounding ruck. These ranges v;ny tutu about ,,5 Io 100 nleleis Ill a high Iuss scam such as the Ilelllit No. fl to about .100 to 400 meters in a low loss seam such as the Pittsburgh foil portable intrinsically safe radios. The ieslllls die haled on the comparison oftheorc' and experiment for eleven n n. ill sesen coal seams. V OT ate is dice: a conductor such as a power Cable, is present a model has been developed for the coupling of loop antennas to a low loss Coaxial TEM ti;u?smisslon line mode in which the cable acts as the inner conducl,lr and the rock above and below acts as the outer conductor. The electuc and md' nctic Itelds for till` (node are apprlixitllatcly transverse to the cahlC and fall oil expontially with distance in the transverse plane. The principle of reciprocity is used to simplify the analysis. More expelitnental data arc needed to help resolve discrepancies between the theory and the limited data available to date.]

Jan 1, 1980

By C. W. Sill

[In the original Norris and Fay method for determining selenium, selenious acid is reduced by an excess of standard thicsulfate in accordance with the following reaction: H2Se03 + 4Na2S203 + 4HC1 = Na2SeS406 + Na2S406 + 4NaC1 + X20. (1) The excess thiosutfate is then back-titrated with standard iodine solution. The disadvantages of ouch a method are obvious. On an unknown sample, the quantity of thiosutfate required would be difficult to determine; a definite excess is required, but large back titrations would be undesirable. Inasmuch as thiosulfate is decomposed by acid, considerable error may be introduced in this method, the amount depending on the acidity, temperature, concentration of excess thiosulfate, duration of contact between thiosulfate and acid, and other factors, In a critical study of the Norris and Fay method, Coleman and McCrosky3/ show that the method is accurate to less than .1 part per thousand if the excess of this sulfate Is not greater than 5 ml. of 0.1 N solution (in 1.0 ml. of 0.x4 N sulfuric acid) whether the titration is made at 0° or 20°C. A greater excess produced unsatisfactory values at either temperature. Coleman and McCrosky regulated the excess thiosulfate by adding 5-ml. portions of thiosulfate solution followed by the addition of 1 to 3 drops of 2.5 percent potassium iodide in the presence of starch. If a starch-iodine blue color formed locally around the drops of potassium Iodide, the reduction of selenious acid was not complete. On stirring the solution, the local blue color fades and another 5-ml. portion of thiosulfate is added. When addition of potassium iodide fails to produce a local blue color, reduction of selenious acid is complete, and the excess thiosulfate is then back-titrated with standard Iodine solution. The number of equivalents involved in the reduction of selenious acid by either thiosulfate or iodide is the same, and therefore no correction need be made for the potassium iodide. This procedure is much better than the original Norris-Fay titration, but acidity and time would stilt be rather critical factors subject to variation with individual technique. Also, the method still requires the lose of two standard solutions, a rather undesirable factor from the standpoint of routine application.]

Jan 1, 1954

By A. B. Hooker, R. A. Kearns

Material used for flame safety lamp gauzes should possess the following qualities: (1) mechanical strength, (2) resistance to corrosion under service con- ditions, (3) a relatively high thermal conductivity, (4) a melting point above the ignition temperature of mine gas. Heretofore, three metals have been used for flame lamp gauzes, namely: steel, brass and copper. While each of these has the requisite qualities to some extent, none of them is an ideal gauze material. Copper gauzes lack mechanical strength, especiall, after they have been heated; brass and copper both have comparatively low melting points so that before the gas ignition is reached the gauze metal is attacked and oxidized under the action of the heat. Steel corrodes readily in damp atmos- pheres and if the lamp stands unused under these conditions for some time, the gauzes become unfit for service. Tests of these three materials have shown that steel offers the highest degree of safety. Manel metal, the natural alloy of nickel and copper, is practically noncor- rodible. Its relting point is approximately the same as that of steel. From time to time it has been suggested that this alloy might be a better gauze material than steel, since gauzes made of Monel metal should have all of the good qualities that steel gauzes possess and, in addition, would not corrode appreciably in ordinary mine atmospheres. One advocate of this use for Monel metal, the International Nickel Co., through their development engineer, Mr. Robert J. McKay, cooperated with the Interior Department, Bureau of ines, to the extent of supplying twelve sets of 30 mesh, Monel-metal gauzes for tests. Those gauzes were made up by the same lamp manufactur- er ho rade the steel gauzes used in the previous investigation. Being made by the same processes as the steel gauzes, these Manel-metal gauzes were needlessly given the same anti-rust coating that is always applied to steel gauzes to prevent any corrosion before the gauzes are used. In previous tests the Bureau of Mines had collected data as to the behavior of steel gauzes. In determining the value of Monel metal as a gauze material, it was planned to obtain similar data with Monel-metal gauzes, and thus make a direct comparison with the steel gauzes. In addition, steel and Monel-metal gauzes

Apr 1, 1923

Significantly increase the amount of fresh air that sweeps the face in front of a continuous mining ma-chine, in order to prevent methane gas buildup. Approach Water sprays are mounted along the sides of a continuous miner and behind the cutter head to help push ventilating air along the required path, and prevent its short circuiting. How It Works A continuous miner is fitted with two sets of water sprays, one of which is used at a time. The set of sprays shown in the diagram, helps move the ventilating air forward along the left side of the miner and across the cutter drum from left to right. That air is then drawn into the exhaust air passageway located along

Jan 1, 1978

By James E. Hill

Tremendous improvements in mining technology have been witnessed during the past 100 years. For example, before 1860 all blastholes were drilled manually and blasting was done with low-energy black-powder. During the 1860's both the pneumatic rock drill and high-energy dynamite were introduced, ushering in an era of mining mechanization that has steadily progressed since that time. Today, with the rapid implementation of the latest advances in communication science, mining technology is moving into a new era that goes beyond mechanization as such. Transistors, transducers, scanners, telemetry, and the like, all terms largely derived from the new communication sciences, add up to what is popularly know as automation-the communication of machine with machine. Automation is now playing an important role in selected parts of the mining process, such as hoisting, hydraulic roof supports, and underground surface locomotive haulage and belt conveyor systems. But this year marked the first attempt to auto-mate the total mining process with the commencement of production at the British National Coal Boards Bevercotes mine. If this full-scale experiment proves successful, it could lead towards other fully automated mines in both Britain and other parts of the world. This decade, there-fore, could be considered the one that provided the foundation for the mines of the future.

Jan 1, 1966

By Joan C. Biordi

[Composition profiles for atomic, radical, and stable species, as well as temperature and area expansion ratio profiles, have been determined for a nearly stoichiometric CH4-02-Ar flame and one to which 0.3 percent CF5Br inhibitor had been added. Net reaction rate profiles were calculated for all the observed species. For the normal flame, these and the mole fraction profiles gave rate coefficient information about the elementary reactions in the methane flame, for example, CH. + 0 4- H2CO 0 H, k4 = 1.05 X 1014CM3 mole-1sec-1 for 1,550§T 0,725' K; CO + OH 4 C02 + H, k6= 4.7 X 1011 for 1,350{T X1,750° K. Comparison between the inhibited and normal flame showed that A] and [CH3] were significantly reduced at the lower temperatures in the inhibited flame even though in the hot gas region the [E] [OH!, and [0] were essentially the same in both flames. The CF3Br disappears very early in the flame, relative to the fuel, and the reaction primarily responsible for its disappearance is H v CF3Br 4 HBr + CF3, where k7 is found to be 2.2 X 1014 exp(-9460/RT) for 700-1,550° K. Reaction of the inhibitor with methyl radicals provides for the relatively small amounts of CH3Br observed, but CH3 + Br2 - CHs Br + Br must also occur. The HBr formed reacts rapidly with H atoms to form H2 and Br, but the reaction is soon "balanced" in the flame as may be demonstrated by calculation of the equilibrium constant at various temperatures. The fluoro-carbon fragment produced in reaction (7) also reacts rapidly, in part with methyl radicals to give the observed elimination product CH2CF2 Later in the flame, above -1,400' K, F2CO is formed from the reaction CH2CF2 + 0 P F2CO + CH2 and k., -1.5 X 1013 at 1,600° K. The rather slow decay of carbonyl fluoride is attributed to reaction with H atoms according to the sequence F2CO I H - HF + FCO and FCO + H HF + CO.]

Jan 1, 1975