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By Joseph H. Bilbrey

COBALT is a silvery gray metal which closely resembles nickel in appearance and properties although it is somewhat harder and more brittle. It is rather widely disseminated and is estimated to make up about 0.001 percent of the earth's crust as compared to 0.020 percent for nickel. Cobalt, one of the four ferromagnetic elements, is used for many magnetic applications. It is oxidation resistant, a property which when coupled with its moderately high melting point of 1,495° C., makes it useful in high-temperature applications. Although cobalt had been used by man as a coloring agent for glass and other ceramic products for 4,000 years, it was not isolated as a metal until 1742 and not established as an element until some 40 years later. Early in the 20th century, cobalt began to be used in alloys, and soon these applications displaced ceramics as the major consumer of cobalt. The use of cobalt in alloys gave considerable stimulus to production, and the world output of cobalt increased rapidly, rising from 400 tons in 1920 to 1,400 tons in 1930 and 5,500 tons in 1940. With the advent of the jet plane in the mid 1940's and the consequent increased need for cobalt-bearing high-temperature alloys, cobalt production again increased, reaching 7,900 tons in 1950. The increased demand for cobalt during the Korean war coupled with a large demand for stockpiling caused world production to more than double within the next 10 years, reaching a peak of 17,300 tons in 1959.

Jan 1, 1962

By Rudy J. Matetic

Over-exposure to noise remains a widespread and serious health hazard in the U.S. mining industries despite 25 years of regulation. Every day, 80% of the nation’s miners go to work in an environment where the time weighted average (TWA) noise level exceeds 85 dBA and more than 25% of the miners are exposed to a TWA noise level that exceeds 90 dBA, the permissible exposure limit (PEL). Additionally, MSHA coal noise sample data collected from 2000 to 2002 show that 65% of the equipment whose operators exceeded 100% noise dosage comprise only seven different types of machines; auger miners, bulldozers, continuous miners, front end loaders, roof bolters, shuttle cars (electric), and trucks. In addition, the MSHA data indicate that the roof bolter is third among all the equipment and second among equipment in underground coal whose operators exceed 100% dosage. A research program was implemented to: 1) determine, characterize and to measure sound power levels radiated by a roof bolting machine during differing drilling configurations (thrust, rotational speed, penetration rate, etc.) and utilizing differing types of drilling methods in high compressive strength rock media (>20,000 psi). The research approach characterized the sound power level results from laboratory testing and provided the mining industry with empirical data relative to utilizing differing noise control technologies (drilling configurations and types of drilling methods) in reducing sound power level emissions on a roof bolting machine; 2) distinguish and correlate the empirical data into one, statistically valid, equation, in which, provided the mining industry with a tool to predict overall sound power levels of a roof bolting machine given any type of drilling configuration and drilling method utilized in industry; 3) provided the mining industry with several approaches to predict or determine sound pressure levels in an underground coal mine utilizing laboratory test results from a roof bolting machine and 4) described a method for determining an operators’ noise dosage of a roof bolting machine utilizing predicted or determined sound pressure levels.

Jan 1, 2006

By Isaac A. Zlochower

A number of ignition incidents involving mining and farm equipment have illustrated the surprising danger of drilling, cutting, or otherwise penetrating sealed compartments or frames that are filled with metal scrap for ballast. The presence of chemically-reactive metals (or electrochemically-active pairs), such as zinc in galvanized steel, can produce hydrogen from moisture in the steel scrap, and the resulting pressure, due to the internally-generated hydrogen, can produce an easily-ignited gas jet when the sealed component is penetrated.

By R. W. Van Dolah

The feasibility of formulating cap-sensitive slurry explosives for use in underground mines with potentially flammable gas atmospheres was examined. Formulations containing aluminum metal as sensitizer and sodium chloride to reduce incendivity were prepared; some were cap-sensitive and had adequate air-gap. Flaked aluminum metal rather than the atomized type proved to be the more effective sensitizing agent of the formulations tested for incendivity in the large gallery of the Bureau of Mines, some were found to be suitably nonincendive.

Jan 1, 1968

By E. J. Kloos

Two self-contained breathing apparatus of the closed-circuit compressed-oxygen type were evaluated for performance at 32° to -25° F. Low-temperature effects of oxygen and carbon dioxide concentration, visual properties of the facepiece, and mechanical operation of the apparatus were studied. Although operation varied with the wearer, his breathing rate, the apparatus precooling time, and the temperature, results suggest that general use of currently approved compressed-oxygen closed-circuit breathing apparatus be limited to temperatures above 32° F.

Jan 1, 1968

Develop a new method for coal mint pillar stability evaluation and design based on pillar load measurements. Approach A novel approach to chain pillar stability evaluation and design for longwall coal mining panels has been developed by the Bureau of Mines. The evaluation approach uses an INTEGRITY FACTOR as the criterion for stability. Hydraulic borehole pressure cells developed by the Bureau are used to measure stresses in a pillar for stability evaluation. The results are used to improve the pillar design.

Jan 1, 1989

By J. D. Marchant

Solid-state electrotransport of impurities in cerium, lanthanum, and praseodymium, using a pulsed current, was investigated. The results were compared with those of using a steady current. Impurities that showed appreciable movement with the pulsed current, but not with the steady current, were as follows: Molybdenum and oxygen in cerium, aluminum, iron, and molybdenum in lanthanum. The use of a pulsed current enhances the practical application of solid-state electrotransport to remove a wider variety of impurities from the host metals.

Jan 1, 1971

By S. J. Broderick

[One phase of the general program for utilization of coal-mine waste led to the possibility of making a water softener from the material, as the waste matter contained both coal and clay and it is known that both these substances can be so activated as to exhibit distinct base-exchange properties. The carbonaceous]

Jan 1, 1941

By T. J. Ballard

The Conrad Hill mine vas first opened as a gold mine about 182 and has been operated at various times since then. The Bureau of Mines, as part of the strategic minerals program, mapped and sampled the accessible mine workings. The work failed to reveal appreciable copper values or evidence of additional ore deposits.

Jan 1, 1948

By Roy L. Wilfong

Infrared reference spectra are presented of compounds of importance in lead sulfide flotation research. Included are the spectra of several short chain alkyl xanthates of lead and zinc, the corresponding dixanthogen compounds, and the common oxidation products of lead sulfide and their sodium analogs. The spectra of several frequently used industrial flotation reagent xanthates are also presented. A thorough, well-documented discussion is given of the various corrections made to correct the as recorded absorption band data to near absolute values.

Jan 1, 1974

By J. Bennetts

As part of its mission to develop technology that will help increase the supply of critical and strategic minerals from domestic resources, the Bureau of Mines has investigated methods for beneficiating platinum-group metal ores from the Stillwater complex, Montana. This report presents the result of a bench-scale study employing froth flotation to recover a sulfide concentrate containing platinum-palladium values from a mineralized gabbro. Best results were obtained with a flotation scheme utilizing a mercaptobenzothiazone collector and sulfuric acid. Rougher concentrates containing approximately 11 oz Pt-Pd/ton and 90 pct of the metal values in the ore were obtained. Subsequently, cleaner concentrates containing approximately 26 oz Pt-Pd/ton and between 80 to 85 pct of the Pt-Pd values in the ore were prepared.

Jan 1, 1980

By Eugene H. Skinner

This Bureau of Mines report describes the fieldwork and subsequent analysis to determine physical properties, stress distribution, and several aspects of rock behavior as a necessary evaluation for a typical mine opening. All work was done at a test site on the 3300 level, Crescent mine, Coeur d'Alene mining district, Idaho. Free field stress beyond the influence of the opening was also determined. Conventional overcore technique with the three-component borehole deformation gage developed by the Bureau of Mines was used in three drill holes. Three field verification tests were performed using a gage newly developed by the Spokane Mining Research Center in an approach herein termed "initial deformation method." Use of this method validated that aspect of overcore theory which predicts that similar deformation effect occurs in the wall rock around the perimeter of an opening in rock under stress. Also described are all drilling procedures and performances. Physical property determinations were made on rock samples obtained from the three overcore drill holes. Twelve physical properties with a total of [532] values were obtained at various drill hole orientations and depths. Exhaustive statistical tests were utilized in the analysis of these physical properties. Further elaborated are statistical inferences based on these analyses. Extensive analysis and interpretation of Crescent mine geology are also described.

Jan 1, 1974

By J. A. Kosek

Work has been conducted under Bureau of Mines Contract Number HO 357078 to develop instruments for detecting CO, NO and NO2 in a mine atmosphere, using fuel cell technology. The approach has been to optimize the fuel cell sensor configuration for the specific detection of CO, NO and NO2 in the presence of other mine gases utilizing recent advances in catalyst, electrode and solid polymer electrolyte membrane technology. Para-metric testing has been conducted on three electrode sensor cells to define performance and life characteristics as a function of temperature, feed flow and applied sensor voltage. Extended life testing has been performed on sensor cell configurations exhibiting favorable characteristics. Reliable, efficient gas sampling and electronic control circuitry has been fabricated for use with the sensor cells, and integrated into devices to meet the performance and design specifications for portable, battery-powered, hand held direct indicating gas detectors for use underground. Twenty of the production-type, direct indicating CO detectors have been tested and delivered to the Bureau of Mines under the present contract. Three prototype diffusion head CO monitors have also been delivered for evaluation under the pre-sent contract. The gas sampling pump and related parts have been replaced by a diffusion tube assembly in which CO reaches the sensing electrode surface by diffusion alone. In addition, delivery will be made of ten direct-indicating nitric oxide detectors and ten direct-indicating nitrogen dioxide detectors. These instruments are very similar in design to the direct indicating CO detector.

Jan 1, 1979

An underground mine disaster is an accident of major proportions that takes a significant toll in human lives. A disaster usually disrupts the normal functioning of a mine and may result in entrapment of miners whose normal egress from the mine is cut off. A disaster often necessitates a rescue operation and a means of keeping the trapped miners alive while they await rescue. Explosion, fire, inundation of water or toxic gases, and collapse of a major portion of a mine are among the causes of mine disasters. Miners threatened by such an occurence must either bring the situation under control (e.g., by extinguishing a fire) or remove themselves from the danger. If control is unsuccessful, they must retreat to a place of safety. Four different activities may be involved: evacuation, escape, survival, and rescue. Evacuation is the orderly exit of people from the mine using previously identified escapeways and following a previously determined evacuation plan. Miners whose normal evacuation routes are blocked may be able to find alternative exit routes and escape by their own efforts. For those who cannot, the issue becomes survival while waiting to be rescued. The survival period may last for many days while rescue efforts are mounted from outside the mine.

Jan 1, 1981

By I. Liebman

The Bureau of Mines conducted research to develop triggered barrier systems for protection against gas explosions that can occur in underground coal mines during the use of continuous miners. Several extinguishing agents were tested in barriers at a simulated mine face. Water, powered by pressurized nitrogen, was found to be efficient in stopping fully developed gas explosions, but it had little effect against the explosion during its incipient stage. Hybrid combinations of currently known extinguishants, however, were successful against incipient explosions. Three hybrids that were developed and tested consisted of Halon 1301, combined with either an aqueous foam solution, water, or a dry chemical powder. The three hybrids were found to be more efficient than any constituent alone. Results of the tests point to a synergism between the hybrid components, and indicate that the Halon aids in dispersing its constituent and also converts the aqueous foam solution into a stable fine foam and the water into fine drops.

Jan 1, 1978

By James Gibbs

In order to provide an initial approach to the deposits of oil shale, nahcolite, and dawsonite in the central area of the Piceance Creek Basin in northwestern Colorado, the U.S.B.M. and associated contractor personnel drilled and cased a 96-inch ID shaft to a depth of 2,371 feet. The shaft was constructed using "big hole" drilling techniques and succeeded in giving access to previously inaccessible deposits of the above minerals. This report documents the construction from its beginning in January 1977 to its completion in January 1978. Procedures used and problems encountered are discussed in derail.

Jan 1, 1978

By Russell J. Miller

A high-pressure intensifier system was designed, constructed and field tested as part of a program to determining the feasibility of applying high-pressure water jets on conventional mechanical rock excavation equipment to increase advance rates. Also developed were a high-volume swivel, capable of transferring the high-pressure water to a rotating cutterhead and manifold system for locating and protecting the jets on the cutterhead. Field tests were conducted in a granite quarry near Skykomish, WA, approximately 90 miles east of Seattle. The concept of improving excavation rates by using water jets to assist mechanical cutting was proven to be successful, with an average increase in excavation mete of 50 to 60%. For some tests, the excavation rate was more than doubled. Machine torque requirements were reduced approximately 25% when the water jets were used. It was suggested this was due to reduced cutterhead friction in the presence of the water jets. A comprehensive economic analysis was undertaken as part of a concurrent study to determine the degree of cost benefits attainable from increased advance rates. Very significant savings were seen to be possible. It was concluded that the basic concept of combining a water jet capability with a mechanical excavating machine is definitely possible.

Jan 1, 1976

The general nature of the special constructional features that are required to provide safety from explosion hazards on machines approved as permissible by the Bureau of Mines is fairly well known to mining men who are at all interested in safety. These requirements are outlined in the schedules, under the provisions of which the investigations of such machines are conducted. Also, the method of conducting inspections and. tests of such machines has been described in Bureau of Mines Bulletin 305, Inspection and Testing of Mine Type Electrical Equipment for Permissibility, published in 1929. A more detailed knowledge of the special safety features of a particular machine is often useful and sometimes essential for inspectors, safety engineers, maintenance men, and engineers in selecting machines for a particular application. Three bulletins that give information of this nature have been published by the bureau, viz., Bulletin 313, Permissible Storage-Battery Locomotives and Power Trucks. Bulletin 343, Permissible Coal-Handling Equipment. Bulletin 382, Permissible Coal-Cutting Equipment.

Jan 1, 1937

By Diane Schwegler-Berry, Vincent Castranova, Chang-geng Moe, Jane Y. C. Ma, Mark D. Moore, Joseph K. H. Ma, Carl J. Malanga, Ji-Hee Kane

"Effects of Bisbenzylisoquinoline Alkaloids on Alveolar Macrophages: Correlation between Binding Affinity. Inhibitory Potency and Antifibrotic Potential. CASTRANOVA, V., KANG, J-H., MA. J. K. H., Mo, C-H., MALANGA, L. J., MOORE M. D., SCHWEGLER-BERRY, D.. AND MA. J. Y. C. (1991). Toxicol. Appl. Pharmacol 108, 242-252. The Chinese have conducted extensive studies concerning the medicinal properties of plant products. In this investigation the ability of three bisbenzylisoquinoline alkaloids to inhibit particle-induced activation of alveolar macrophages was evaluated and this inhibitory potential was correlated with the ability of those drugs to bind to membrane components. Tetrandrine. i.e.. an herbal medicine used as an antifibrotic agent in China, was a potent inhibitor of particle-stimulated oxygen consumption, superoxide release, and hydrogen peroxide secretion by alveolar macrophages. Tetrandrine also exhibited substantial binding affinity for membrane lipids and alveolar macrophages. In contrast, tubocurine, an analogue with little antifibrotic potential, exhibited low binding affinity and had little effect on macrophage activation. Methoxyadiantifoline, an alkaloid of unknown antifibrotic potential, exhibited inhibitory and binding properties similar to those of tetrandrine. The data indicate that a strong relationship exists between the antifibrotic potential of these alkaloids and their ability to bind to alveolar macrophages and inhibit particle-induced activation of these phagocytes. These drugs should serve as useful probes to evaluate the role of alveolar macrophages in pulmonary fibrosis. © 1991 Academic Press, Inc.Chronic silicosis is a fibrotic disease resulting from occupational exposure to silica dust. It is manifested initially by an increase in the quantity of pulmonary surfactant (Dethloff et al., 1986). However, in later stages it is characterized by an increase in collagen formation and the development of concentric hyalinized nodular lesions in the lung (Ziskind et al., 1976). Although mechanisms for the progression of silicosis have not yet been completely defined, activation of alveolar macrophages by respirable silica particles is believed to play an important role in the etiology of this disease. Studies from our laboratory have shown that both in vitro and in vivo silica exposures result in a stimulation of macrophage release of reactive products capable of damaging the lung parenchyma (Castranova et al., 1990; Goodman et al., 1990). In addition, exposure of al¬veolar macrophages to silica results in the release of fibrogenic factors which enhance the proliferation of fibroblasts and the synthesis of collagen by these pneumocytes (Leibovich and Ross, 1976; Bitterman et al., 1982, 1983).The bisbenzylisoquinoline alkaloids, which represent the largest group among the iso-quinoline compounds isolated from the plant kingdom, are known to exhibit a broad rangeof pharmacological activities. Tetrandrine, for example, an alkaloid isolated from the root of Stephania tetrandra, has been tested for its antitumor, antihypertensive, and antisilicotic effects (Kupchan and Atland, 1973; Zeng et al., 1985; Yu et al., 1983). It is currently used in China as a treatment for angina, hypertension, and silica-induced pulmonary fibrosis (Li et al., 1981). Several related bisbenzylisoquinoline alkaloids such as methoxyadiantifoline and tubocurine have also been evaluated for medicinal effects. Methoxyadiantifoline has been shown to exhibit effects on the cardiovascular system similar to those reported for tetrandrine (Jia et al., 1988). However, to date, the antifibrotic activity of methoxyadiantifoline has not been evaluated. In contrast to tetrandrine, tubocurine, a structural analogue of this drug, has been reported to be relatively ineffective against fibrosis (Mo et al., 1982)."

Mar 1, 1992

By Robert L. Lagace

This final report documents the work dune by Arthur D. Little, Inc. (ADL) on behalf of the U.S. Bureau of Mines, Pittsburgh Mining and Safety Research Center (PMSRC), on Contract H0122026 (which began in August of 1971). Under this contract ADL provided technical assistance to the Bureau on a task basis on virtually all aspects of the Bureau's programs related to present and planned emergency and operational communications and miner location systems for underground coal mines. The work consisted of independent investigations, analyses, experiments, breadboard and prototype hardware development, workshops and technology transfer seminars on mine communications, and on-going evaluations and guidance related to the Bureau's contracted programs on electromagnetic noise, mine communications systems, and trapped miner location. This final report documents the work in two volumes, Volume I, "Emergency and Operational Mine Communications," and Volume II, "Seismic Detection and Location of Isolated Miners." The Tables of Contents of both Volumes are included in each Volume. Phase I of the contract was devoted to performing an in-depth assessment of electromagnetic noise measurements taken by several contractors and other investigators, and then defining a new noise measurement program and instrumentation system tailored to obtain the necessary but missing noise data. These data are required for use in the design of new emergency and operational communication systems. This work, and the follow-on coordination and guidance activities of ADL on this noise measurement program in subsequent phases of the contract, are treated in Part One of Volume I.

Jan 1, 1974