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By C. B. Barmore, B. W. Gandrud, B. M. Bird

"The Bradford mine of the Alabama By-Products Corporation is located in the Warrior coal field of Alabama, in the northern part of Jefferson County, about 25 miles north of Birmingham. The coal mined from the Black Creek bed at this point is not considered to be ideal for coke making by itself but because of its exceptionally low ash content is mixed with the higher-ash coking coals from other beds of the district to control the ash content of coking mixtures. Further reasons for using this coal only as a diluent of the higher-ash opals are that the thinness of the bed renders the production costs relatively high and the reserves are somewhat limited.This paper, which is the fourth of a series on the washability of Alabama coals, Like its predecessors dealing with the Mary Lee beds and the Clark bed,6 contains screen-sizing and float-and-sink tests of a representative sample of the raw coal, and flakiness tests showing the proportions of flaky particles in certain selected sizes. However, inasmuch as the float-and-sink tests of the coarse sizes showed excellent liberation of coal from impurities, crushing tests have not been considered necessary.The data on which this report is based have been obtained in connection with an exhaustive study of coal preparation in Alabama now being conducted by the U. S. Bureau of Mines and the University of Alabama with the cooperation of the different coal operators. As the work progresses other papers will follow containing further data on Alabama coals and giving results obtained in preparing these coals by various methods."

Apr 1, 1931

By Glenn C. Reed

This report is one of a series based upon investigations made and being made within the Missouri River Basin in Montana by engineers of the Bureau of Mines , Albany Branch , Mining Division . These investigations are made primarily to provide preliminary information to the Department of Interior agencies and to others concerned with planning the proposed Federal power development within the Missouri River Basin . The present report has been designed to permit public distribution of factual data obtained . The field investigations were made during the late fall of 1947 and the summer of 1948. Information on mineral occurrences in several areas in Sweet Grass County also are included in this report because of their close proximity to Park County . Practically all known metallic mineral deposits within Park County were investigated ; some nonmetallic mineral deposits also were investigated. The investigations of the metallic mineral deposits in Park County cannot be considered complete ; some long inactive mines and prospects on which little or no information is of record may have been missed . Many of the underground openings , especially at the long inactive properties , no longer are accessible ; consequently , much of the information regarding history their and development necessarily has been obtained from available Federal and State publications .

Feb 1, 1950

By V. E. Edlund

Laboratory batch flotation tests were conducted on copper converter slags to evaluate the relative merits of recovering copper from slow-cooled versus water-quenched slags. Three slags containing 1.6, 5.0, and 6.6 percent copper were used. More than 90 percent of the copper was recovered in a rougher concentrate leaving a 0.2- to 0.3-percent copper tailings when treating slow-cooled slag. Lower recoveries and higher copper tailings ranging from 0,5 to 0.6 percent copper were obtained from quenched slag. Grindability studies were made on the respective heat-treated slags. Quenched slags proved more difficult to grind than slow-cooled slags. Cost studies showed that (1) the cost of slow cooling and crushing off-sets any advantages of higher copper recoveries from slow-cooled slag, and (2) water-quenched slag, which requires no crushing preparatory to grinding, could be treated more economically. Costs based on processing 1,000 tons of slag per day would be $1.85 per ton for quenched slag versus $2.37 per ton for slow-cooled slag.

Jan 1, 1971

By Edmund S. Leaver

The selection of a process for treating a gold ore is governed primarily by the characteristics of the ore under consideration. The form in which the gold occurs, its mode of association with other minerals, and the size and surface condition of the gold particles are important factors which influence materially the choice of procedure for recovering gold. A knowledge of these characteristics may be obtained by microscopic and chemical methods combined with experimental testing. Cyanidation and amalgamation, either alone or in conjunction with flotation and gravity methods, are peculiarly adapted to the treatment of gold ores, especially those of relatively low grade. Gold alloys readily with mercury provided both present clean surfaces. The presence of oils and grease, antimony and arsenic minerals, or soluble sulphides have a harmful effect. Very small, flaky particles of gold frequently are lost in amalgamation because of noncontact with the mercury. Fine gold in pyrite, or gold having rusty or contaminated surfaces, is often lost for the same reason. Grinding or some form of abrasion sometimes removes surface films of iron oxide or substances of a similar nature, and alkalies or other chemicals are used to remove grease. Gold is readily soluble in cyanide solution, and this method of treatment is particularly effective in the recovery of gold from the tailings resulting from other types of concen¬tration procedure. Cyanide solutions must contact the gold to insure recovery, and the porosity of the ore treated and the fineness of grinding required are important governing factors. The use of lime in cyanidation is necessary to protect the cyanide, to precipitate undesirable substances, and to settle slimes. Certain substances in ores are harmful in cyanidation; chief among them are those that combine with cyanide, forming cyanides, and carbon which precipitates gold from solution. Arsenic and antimony are also harmful if present in sufficient quantity. These and other difficulties encountered in cyaniding certain ores often are overcome by roasting prior to leaching. Zinc dust is used almost universally for precipitating precious metals from cyanide solutions. The refining and melting of the product may be accomplished by oxidizing the zinc before melting it in graphite pots with fluxes, although sulphuric acid is now used largely to remove the zinc before melting. Straight cyanidaticn practice is being replaced by flotation as a major process, followed by cyanide leaching of the tailings, but amalgamation is still needed as a primary process for the recovery of coarse gold before either flotation or cyanidation.

Jan 1, 1935

By F. S. Crawford

The average visitor to a large electric-shovel operation may wonder how electric power can be treated as carelessly as apparently it is in open-pit mining, and how the mining company can string it carelessly along the ground in great, black, hoselike cables, whereas the power company, which has learned to respect his deadly agency, keeps power lines far out of reach. This is explained by the fact that this particular kind of application of power to moving machinery requires the use of trailing cable instead of the more permanent type of construction that permits a moving contact, such as a trolley. The cables are designed to insulate fully the enclosed power lines against damage and loss of current; and employees are taught to handle them carefully, although engineers are not satisfied that the trailing cable is foolproof and are seeking constantly to improve methods and equipment to insure greater safety. In some sections they rely mainly on the construction of the cable and perfection of equipment, while in others additional precautions are taken, such as handling the cable with rubber gloves, slings, tongs, or loops. In some sections no temporary repairs are made to cables, while in others such repairs are made and later are vulcanized in the shop. At some operations the cycle of shovel duties is arranged so that cables are very seldom exposed to flying rock fragments while at others this exposure appears to be unavoidable. Methods of fastening the cable to the shovel frame and transporting the loose cable vary. Inspection and care of the cable are important in insuring its safety and durability. A limited amount of information was obtained by field engineers of the United States Bureau of lines from operators in various parts of the United States, as methods of handling electric-shovel operations differ with the districts; practices followed and equipment used in these districts are described in this circular.

Jan 1, 1936

By W. Miola, R. V. Ramaoi

"The MSHA prescribed method for the determination of quartz in airborne respirable-dust samples from underground coal mines is the P-7 method, a combination of /ow-temperature, radio-frequency ashing (LTA) and infra7 red analysis (IR). There is no prescribed procedure for quartz analysis in bulk samples of coal and host rock. Dispersive infrared (IR), Fourier-transform infrared (FTIR) and X-ray diffraction (XRD) methods are most commonly used for the analysis of quartz in powders. Several aspects of the experimental procedures, such as the preparation of the analysis sample from bulk samples, ashing techniques, scanning procedures, peak measurement location, calibration techniques, sample amounts, size consist and data interpretation, affect the results from each of the methods differently. Significant differences in analytical results obtained from X-ray diffraction (XRD) and infrared spectroscopy (IR) on the same samples are reported. All studies point to the need for reliable quartz analysis methods.In a recent research program, a procedure for preparing bulk-coal and host-rock samples for quantitative quartz analysis was developed. Further, the results from X-ray diffractometry and infrared spectroscopy for quartz content on identical samples were compared. Calibrations with pure and mixed standards were used to assess the influence of particle-size distribution, matrix and calibration on the analytical results. In this paper, several issues concerning the measurement of quartz in the samples of coal, host-rock and airborne respirable dust from mines are outlined and quantified. IntroductionThe literature on coal-mine airborne-dust control has identified a need for a better understanding of the sources, mechanisms and amounts of quartz in mine airborne respirable dust (Althouse, 1984; Jankowski, Nesbit and Kissel, 1985; Ramani 1988; Qin, 1988; Bhaskar and Xu, 1990; Bhaskar and Li, 1992; Ramani, Qin and Miola, 1991 ). To understand the quartz content in the source materials, bulk samples of coal and host rock must be analyzed. Establishing an analysis procedure for determining the quartz content in bulk-coal and host-rock samples is necessary for identifying the sources of quartz in mines; for establishing the relationships between the quartz contained in the source and in the airborne dust; and for controlling the content of quartz in the mined product and in the airborne respirable dust."

Dec 1, 1996

Aluminum Production. -By October 1, Aluminum Company of America will restart a 35,000-ton-per-year unit at its aluminum smelter at Rockdale, Tex., restoring that facility to its full capacity of 325,000 tons annually. Primary Ingot Price Increase. -Most U.S. aluminum producers in mid-September were quoting a price of 72 cents per pound for primary aluminum ingot. On September 19, Kaiser Aluminum & Chemical Corp. announced that it would increase the price of primary aluminum ingot 4 cents to 76 cents per pound.

Jan 1, 1980

By V. A. Nieberlein

An extractive process was developed applicable to submarginal titanium deposits containing valuable minor constituents; such as columbium (niobium) and iron. The process consisted of reducing the mineral concentrate with coke at high temperature to form a carbide-suboxide sinter, chlorination in the 400° -500° C. range, and fractional condensation of the chlorides. The chlorination procedure recovered 97, 83, and 87 percent of the titanium from brookite, rutile, and ilmenite sinters, respectively, while simultaneous columbium recoveries on the same materials were 85, 50, and 87 percent.

Jan 1, 1957

By W. T. Benson

Peacetime production of mercury in the United States is controlled by world mercury prices, with significant lags to be expected between price increases or decreases and resultant increased or decreased production. Twenty-four mercury-bearing mines and prospects in widely separated districts in western and central Nevada and one property on the Nevada-Oregon border were examined and sampled. The purpose of the project was to determine if some of the properties warranted more extensive exploration work to obtain information on possible reserves of commercial-and sub-commercial-grade ores. The investigation of mercury deposits in Nevada was sufficiently widespread and indicated several areas of interest in the State that merit further exploration work.

Jan 1, 1956

By Bernard S. Covino

The Bureau of Mines is conducting a study of methods to improve the efficiency of the process used to pickle stainless steels. A review of the literature on pickling of stainless steels showed that the chemistry of several process operations involved in the pickling of stainless steels is not fully understood, and that further research could improve the pickling efficiency. The benefits of this research would be a reduction in the annual loss of several thousands of tons of critical minerals such as nickel and chromium, and a reduction in the amount of solids and spent acid solution that are currently discarded. The conclusion from this review is that further research is needed in four operations that either directly or indirectly influence the pickling process: hot working, annealing, conditioning, and the actual operation of pickling, Laboratory studies of the pickling operation are presently in progress.

Jan 1, 1984

By Donald J. Frendzel

The post-World War II expansion of the Soviet petroleum industry has established the U.S.S.R. as a major oil-producing nation and has led to Russian reentry into the international petroleum trade. The rapid growth of Soviet petroleum production will allow the U.S.S.R. to displace Venezuela as the world's second largest oil-producer in 1960 and to narrow further the gap between Soviet and U.S. crude-oil production. U.S.S.R. crude oil output was only a tenth of U.S. production in 1946, but it will be more than a third at the end of 1960 and more than half in 1965. The Soviet Seven-Year Plan (1959-65) for oil provides for substantial increases in petroleum production, refining, storage, and distribution facilities. Crude oil production and primary distillation capacity are to double, considerable storage capacity is planned, and pipelines for crude oil and petroleum products are to increase threefold. According to the Soviets, the initial phases of this plan (1959 and 1960) have been completed successfully. However, this progress has been achieved with difficulty.

Jan 1, 1961

By E. A. Rowe, G. H. Keith, B. D. Jones

An evaluation of electrowon tungsten powder was made by comparing its characteristics with conventional hydrogen - reduced tungsten powder . Electrowon tungsten powder was investigated with respect to particle size and shape , apparent density , flow rate , compressibility , green strength , and sintering characteristics . In addition , its chemical purity , absolute density , and purification by melting were determined . Significant findings were higher flow rates and better compressibility than hydrogen - reduced tungsten powder . However , the large particle size peculiar to the electrowinning process effectively prevented conventional sintering to a high- density material . The possibility of producing high - density material , using a new technique of hot swaging sheathed sintered - tungsten compacts , was demonstrated by the achievement of densities of 92 percent of theoretical .

Jan 1, 1965

By Michael R. Yenchek

The U.S. Bureau of Mines investigated the operational characteristics of spliced portable power cables. This research had a dual purpose: (1) to determine the thermal and mechanical performance of repaired trailing cables and compare them with undamaged cables and (2) to gauge the impact of long-term, localized heating on the insulating and jacketing materials contained in cable splice kits accepted or approved by the Mine Safety and Health Administration. The ranges of splice joint resistance and tensile breaking strength were determined from laboratory measurements. The choice of crimping tools affected the strength of the splice under tension. Thermal profiles of energized spliced cables were constructed, which showed that spliced conductor joints operated 5 to 20°C hotter than the intact cable at rated currents. Accelerated life tests of thermally aged samples of splice kit insulation and jacket materials confirmed a deficiency in the thermal rating of the insulating tape. The recommendations in this report may be utilized to revise splice kit design, splice kit approval criteria, and trailing cable loading guidelines. Characterizing the thermal operating limits of spliced trailing cables may help to minimize the associated risks from explosions, fires, personnel burns, and shock.

Jan 1, 2010

By Edmund S. Leaver

The selection of a process for treating a gold ore is governed primarily by the characteristics of the ore under consideration. The form in which the gold occurs, its mode of association with other minerals, and the size and surface condition of the gold particles are important factors which influence materially the choice of procedure for recovering gold. A knowledge of these characteristics may be obtained by microscopic and chemical methods combined with experimental testing. Cyanidation and amalgamation, either alone or in conjunction with flotation and gravity methods, are peculiarly adapted to the treatment of gold ores, especially those of relatively low grade. Gold alloys readily with mercury provided both present clean surfaces. The presence of oils and grease, antimony and arsenic minerals, or soluble sulphides have a harmful effect. Very small, flaky particles of gold frequently are lost in amalgamation because of noncontact with the mercury. Fine gold in pyrite, or gold having rusty or contaminated surfaces, is often lost for the same reason. Grinding or some form of abrasion sometimes removes surface films of iron oxide or substances of a similar nature, and alkalies or other chemicals are used to remove grease. Gold is readily soluble in cyanide solution, and this method of treatment is particularly effective in the recovery of gold from the tailings resulting from other types of concentration procedure. Cyanide solutions must contact the gold to insure recovery, and the porosity of the ore treated and the fineness of grinding required are important governing factors. The use of lime in cyanidation is necessary to protect the cyanide, to precipitate undesirable substances, and to settle slimes. Certain substances in ores are harmful in cyanidation; chief among them are those that combine with cyanide, forming cyanides, and carbon which precipitates gold from solution. Arsenic and antimony are also harmful if present in sufficient quantity. These and other difficulties encountered in cyaniding certain ores often are overcome by roasting prior to leaching. Zinc dust is used almost universally for precipitating precious metals from cyanide solutions. The refining and melting of the product may be accomplished by oxidizing the zinc before melting it in graphite pots with fluxes, although sulphuric acid is now used largely to remove the zinc before melting. Straight cyanidation practice is being replaced by flotation as a major process, followed by cyanide leaching of the tailings, but amalgamation is still needed as a primary process for the recovery of coarse gold before either flotation or cyanidation.

Jan 1, 1935

By S. A. Allen

The Eufaula bauxite district of Barbour and Henry Counties in southeast Alabama covers an area approximately 14 miles long, 6 miles wide at the eastern extremity near the Chattahoochee River, and 10 miles wide at the western end near the east fork of the Choctawhatchee River (see figs. 1 and 2). The long axis of this polygon bears a little south of east.

Jan 1, 1949

By S. L. Windes

For a number of years, the Bureau of Mines conducted tests on various types of structures to determine the effect of seismic vibrations emanating from quarry blasting in an effort to determine an index of damage . Associated with these tests , occasional records were made of the characteristics of. the air blast or concussion from the explosions . Although the importance of the air - blast problem was recognized , the equipment was not designed for air -blast measurements , nor was the early research program concerned with the problem . After the ground - vibration tests had been completed , attention was turned to study of the air blast and its effect . The air - blast problem in reference to quarry and mine blasting may be divided conveniently into three phases : (1 ) Determination of the fundamental characteristics of the air blast , such as the pressure - time relationship , speed of propagation, attenuation , and the like ; ( 2) effect of blasting conditions on these air -blast characteristics ; and ( 3) determination of the conditions necessary for damage to structures . The initial step was the development of microphones suitable for recording the anticipated blast pressures. Such microphones were designed and built during 1940 , and described in technical detail for publication ( 2)3/. Briefly, the microphone adopted was a small, plate - diaphragm condenser type . The recording was through special transducer amplifiers with low -frequency response to zero cycles per second and a Duddell - type oscillograph of special design .

Feb 1, 1942

By D. L. Sawyer

The Bureau of Mines studied alumina extraction from uncalcined, kao-linitic clay at temperatures from 1000 to 2500 C using 20-or 27-wt-pct-HCI concentrations and with an acid-to-clay ratio of from 0.8 to 1.4 times stoichiometric. Autogenous digestion pressures ranged from atmospheric pressure to about 900 psia. Extraction of 96 pct of the alumina was obtained by HCI leaching at temperatures and leaching times that varied from 1000 C for 120 h to 2000 C for 15 min. Hydrochloric acid stoichiometry of the reaction A1203'2Si02'2H20 + 6HCI + 2AICl3 + 2Si02 + 5H20 was studied at different temperatures and leaching times in a 750-mL tetrafluoroethylene-polymer-lined autoclave. A combination of high temperature and 20 wt pct excess HCI promoted rapid and almost quantitative extraction of alumina (99 pct in some tests). Additional Bureau data obtained with 35-mL tantalum bombs and leach-ing tests with added fluoride are also provided. At high temperatures, the addition of fluoride did not result in a significant improvement over HCI alone and was deleterious to the filtering properties of the digest residue.

Jan 1, 1985

By A. E. Sands

The Bureau of Mines, S. Department of the Interior) at, its Morgantown., W. Va., station, operating under a cooperative agreement with West Virginia University, is conducting research and development work on the problem of producing synthesis gas from coal. An important part of this work is the study of the gas purification necessary to meet the rigorous standards required to render the gas suitable for use in the Fischer-Tropsch synthesis of liquid fuels. One of the most detrimental impurities is sulfur in all forms, the maximum amount that can be tolerated being one-tenth of a grain per hundred cubic feet. Concentrations as low as this require the use of precise analytical methods to evaluate the performance of processes used for removing sulfur. At the same time the analytical methods should be rapid in order to reveal the failure of purification before damage to the expensive synthesis catalyst results. Although sulfur in unpurified gas is generally present as hydrogen sulfide and as organic sulfur compounds, the latter may be converted to hydrogen sulfide for analytical purposes. Thus a suitable method for the determination of traces of hydrogen sulfide may also be used for the determination of organic sulfur.

Jan 1, 1949

By Michael Hamilton

Mineral resources have been identified at two properties in the Ten takes RARE II area (table 1). Commodities consist of copper and silver. The deposits, in the northwest part of the study area, are hydrothermal and associated with fissure veins that developed along northwest-striking faults within the Precambrian Purcell Lava. In addition to the identified resources, there is high potential for additional copper-silver resources at these properties and moderate potential for copper-silver-lead-zinc-bariun resources at five others (table 2) in the portion of the study area that is underlain by the Purcell. There is no evidence that significant mineralization occurred in strata above or below the Purcell.

Jan 1, 1983

By R. B. Anderson

As a part of a Bureau of Mines program on the conversion of coal to liquid and gaseous fuels, the kinetics of the Fischer-Tropsch synthesis on iron catalysts was investigated. Nitrided catalysts were studied at 21.4 atmospheres using feed gases ranging from 2H2+1CO to 0.25H2+1CO, and at 7.8 to 21.4 atmospheres using 1H2+1CO gas. The overall apparent activation energy increased with increasing carbon monoxide content of the feed gas from 19.5 kcal/mole for 2H2+1CO to 23.7 for 0.7H2+1CO. The rate of synthesis with 1H2+1CO feed increased linearly with operating pressure from 7.8 to 21.4 atmospheres. A semifundamental rate equation of the form [r=a'PH2 0.6pco 0.4- ?r0.5PH200.5] was shown to fit the data satisfactorily. The relative usage of hydrogen to carbon monoxide decreased with increasing conversion, passed a minimum, and then increased. Apparently water is the principal primary product and carbon dioxide is produced by subsequent water-gas shift reaction. In another group of experiments water, carbon dioxide, argon, and methane were added to 1H2+1CO feed to a nitrided iron catalyst. Argon and methane were only diluents. Carbon dioxide was a slight inhibitor and water vapor was a strong inhibitor to the rate of synthesis. Water accelerated the water-gas shift and usually increased methane production. Important factors of catalyst geometry in determining rate were found to be particle size and extent of reduction. Apparently the active portion of the catalyst is confined to a layer of 0.01 to 0.02 cm from the external surface of particles. A special solution was made of differential equations relating re¬action at the catalyst surface to diffusion in pores of the catalyst for spherical particles with an active layer surrounding an inert core. The equation derived expressed the experimental data reasonably well. Diffusivities determined by this equation varied from 3 to 24X10-6 cm2/sec; these values are of the same magnitude as observed for the diffusion of gases in liquid. The appendix presents a group of synthesis experiments at pressures of 21.4 to 103 atmospheres. In this range the rate of synthesis on nitrided iron catalysts increased with pressure to the 0.74 to 0.84 power.

Jan 1, 1964