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By G. M. Kintz, E. H. Denny

Although some engineering colleges recognize the importance of instructing young engineers in industrial safety , the different institutions handle this instruction in various ways . It is believed that a recent industrial safety course , conducted at the Colorado School of Mines through the cooperation of this school and the Bureau of Mines , U. S. Department of Commerce , presents some unusual features that are of interest to other schools and to the mining public .

Sep 1, 1930

By Edward C. Peterson

Recent studies indicate that the United States halt substantial reserves of ilmenite, one of the major titanium minerals. However, the studies showed that sources of rutile, another important source of titanium are limited. This paper summarizes and evaluates results and conclusions reached by the various investigations initiated by the Bureau of Mines and others pertaining to the titanium mineral resources of the Nation. Domestic occurrences of ilmenite that are economically exploitable by present-day beneficiation methods are found in Florida, New Jersey, New York, South Carolina, and Virginia. These deposits are estimated to contain 50.3 million tons of titanium dioxide (TiO2). Occurrences of ilmenite that cannot be processed economically under present technological conditions are found in California, Colorado, Minnesota, Montana, Oklahoma, Oregon, Rhode Island, and Wyoming. These reserves amount to 51.1 million tons of TiO2. Reserves of rutile found in the United States are estimated to be 1.8 to 2.1 million tons of TiO2. Other than occurrences in Florida and South Carolina, rutile is found either in small scattered bodies or in deposits where the mineral cannot be recovered economically by present beneficiation methods.

Jan 1, 1966

By D. Harrington, R. R. Sayers

For several years the writers have been studying various phases of the effect of air conditions in metal mines upon underground workers ; in 1918 a short study was made in certain hot and deep mines and brief reports were issued in the Engineering and Mining Journal ( August , 1920) and in the U. S. Public Health Reports (Vol . 36 , No. 4 , January 28 , 1921 ) . In 1921 a more extended study was made (also in hot and deep metel mines ) with intent to determine the limiting conditions imposed upon underground workers by the physiological effect of various air movements , temperatures , and humidities , with and without work . It is the purpose to publish a series of short papers on this later investigation , each paper to consider one particular phase of the work . The present paper deals with the effect on body temperature and pulse rate in still air as compared with moving air of temperatures from 90 to 100° F . and 100 per cent relative humidity, the subjects at rest .

Apr 1, 1923

By Robert E. Barieau

In the design of plants to separate helium from natural gas , it is necessary to estimate the enthalpies of the various streams at various positions in the process . This Bureau of Mines report surveys the various methods that have been used to determine enthalpies and gives information on the organizations with such capabilities . The minimum information required for developing an enthalpy diagram is presented , and the relative merits of the various methods are discussed . It is concluded that methods that require no mass flow rate or energy measurements are to be preferred .

Jan 1, 1965

By J. M. Singer

Methods are proposed for predicting concentrations of nitrogen oxides and carbon monoxide in the combustion gases of flames, specifically of lean, stoichiometric, and rich propane-air flames. Calculations are based on kinetic and thermodynamic theory. These theoretical data are compared with concentrations observed experimentally downstream of flat grid-type burner flames (approximately 25,000 Btu/hr) that were used to simulate gas appliances such as water and space heaters. Air pollutant concentrations are also computed for (1) flames chemically perturbed by recycling flue gases into the primary fuel-air mixtures; (2) flames thermally perturbed by cooling the burned gases at different rates; and (3) flames perturbed by combination of these two effects. In general, experimental and computed concentrations agree to within a factor of 2 to 7 with the experimental values always being higher than the theoretical. The theoretical analysis indicates that cooling the primary flame by recycling cold flue gases (with and without excess air) reduces the relative emission of nitric oxide and increases emission of carbon monoxide if the flame stoichiometry does not radically change. Cooling rates of about 5,500° to 10,000° R/sec starting at about 3,500° R generally suffice to prevent nitric oxide concentrations in lean flames from increasing much above the initial values at the combustion zone; these same cooling rates do not prevent oxidation of most of the initial carbon monoxide.

Jan 1, 1967

By Clarence A. Wright, JAMES T. NORTON, JAMES G. PARMELEE

The object of this paper is to give to mining companies and to all others who are interested some idea of the possibilities in the treatment, by differential flotation, of lead-zinc ores of the Coeur d'Alene region and other districts. The purpose of these investiga.. tions is not to evolve a differential flotation process that would replace present methods of gravity concentration but rather one that could be applied to the relatively fine material and slime produced in the mills and treated unsuc_pessfully by gravity methods or by flotation. It is expected, of course, that the products to be obtained by differential flotation would be of much better grade than those now produced by flotation in the Coeur d'Alene mills. In view of the fact that it has been difficult to obtain representative samples of flotation feed from the mills, owing to the necessity of shipping the material wet and free from oil or other foreign matter that might be deleterious to the differential separation of the sulphides, the writers have felt justified in running flotation tests with the mill feeds in order to ascertain whether a differential separation of the sulphides could be effected. However, two different lots of flotation feed were tested for differential flotation, and the results of tests of one of these are given in this report. It is hoped that it will be possible later to test out the flotation feed for differential flotation on a large scale in some of the mills. This paper covers part of the investigations carried on by the United States Bureau of Mines in cooperation with the Idaho Bureau of Mines, the University of Idaho, and certain mining companies of the Coeur d'Alene region. Although the results of the tests included in this report are not to be considered final, they indicate possibilities and may suggest others leading to a solution of the problem of separating lead and zinc sulphides by differential flotation in the treatment of certain ores.

Jan 1, 1921

By Jennifer Riefenberg

A family of personal computer programs that calculate the Coal Mine Roof Rating (CMRR) has been developed by the U.S. Bureau of Mines. The CMRR rock mass classification system provides a link between the qualitative geologists' description of coal mine roof and the quantitive mine engineers' needs for mine design roof support selection, and hazard detection. The program CMRR is a user-friendly, interactive program into which raw field data are input. A CMRR is calculated and output along with two graphic displays. The first graphic display is a plan view trap with the CMRR's displayed on a color-coded scale. The second display shows a stratigraphic section of the bolted roof interval and its resultant CMRR. In addition, a Lotus 1-2-3 worksheet, computer file BOM-CMRR.WK3, has been developed for easy storage of field data. The worksheet includes four macros that automatically calculate CMRR's, store field test data in a database format, and print a two-page report of the field data and CMRR parameters. Production of summary port; for analysis of site-specific information are readily generated using Lotus 1-2-3 software. These programs help to facilitate the engineer in utilizing the CMRR in ground control studies.

Jan 1, 1994

By P. L. Sibrell

The U.S. Bureau of Mines has tested cyanide leaching for recovery of palladium (Pd) from spent petroleum processing catalysts. Three different catalyst samples were supplied by a spent-catalyst processor. These catalysts consisted of a zeolite base and contained 0.4 to 0.7 pct Pd. During alkaline cyanide leaching, the catalysts exhibited ion-exchange properties due to their zeolite matrices. Hydrogen ions were released from the zeolite in exchange for sodium ions in solution, resulting in a significant decrease in solution pH. This could present a safety hazard because of the potential for release of toxic hydrogen cyanide gas. A pretreatment step where the catalysts were contacted with a 1.0M sodium hydroxide solution was found to prevent the pH shift from occurring. Following the sodium hydroxide pretreatment, two stages of leaching at 160 °C with solution containing 1 pct sodium cyanide and 0.1[M] sodium hydroxide gave at least 75 and up to 95 pct Pd recovery. The Pd was quantitatively recovered from the leach solution by thermal decomposition in an autoclave at 250°C for 1 h. The Pd content of the precipitate was over 50 pct. Thermal decomposition also decreased the total cyanide content of the barren solution to less than 0.2 mg/L. The catalyst leach residues passed the Federal Toxicity Characteristic Leaching Procedure and the California Waste Extraction Test, indicating that landfill disposal of the leach residues would be acceptable.

Jan 1, 2010

By Donald W. Mitchell, John Nagy

Observations made on coking of coal, deposition of soot, dust transport, flame, violence, and related phenomena following experimental coal-dust explosions are summarized. Data are given on gas explosion pressure, flame length, flame velocity, and variation of these parameters with concentration. Conclusions from these observations are useful in preventing similar occurrences in operating mines and serve as a guide in improving safety.

Dec 1, 1963

By B. W. Madsen

The Bureau of Mines conducted a large-scale (6.4 t), long-term (2,165 days) test to gain a better understanding of the leaching characteristics of chalcopyritic ores. An ore sample containing 0.77 pct Cu was leached in a fiberglass column by downward percolation of acidified ferric sulfate solutions. Three sets of leaching conditions were investigated: (1) ambient temperature leaching, (2) elevated temperature (50° to 60° C) leaching, and (3) elevated temperature leaching after inoculation with thermophilic bacteria. Leaching at ambient temperature resulted in a copper extraction rate of 0.44 pct per 100 days. Increasing the temperature to 50° to 60° C resulted in decreased activity of natural mesophilic bacteria, and the leaching rate decreased to 0.22 pct per 100 days. The pH was lowered from 2.0 to 1.6, and nutrient solutions that contained thermophilic bacteria were added. This procedure resulted in an increase in the ferric-to-ferrous iron ratio and an increase in the copper leaching rate. However, the increased leaching rate was not sustained, and 120 days after inoculation the bacterial activity declined, the ferrous iron content increased, and the copper leaching rate decreased.

Jan 1, 1983

By Dennis A. Hansen

As part of a U.S. Bureau of Mines program to develop a more continuous titanium metal extraction process that uses domestic resources, a study was made to determine the extraction of titanium (Ti) and iron (Fe) from New York rock ilmenite using fluosilicic acid (H2SiF6). The effects of leach temperature, acid concentration, and particle size were investigated for the rate at which Ti and Fe are extracted from the ilmenite. Within the leach time studied, the extraction data fit a shrinking-core model; the rate-controlling step was diffusion of H2SiF6 through an ash layer resulting from a heterogeneous leaching reaction. The rate is linearly dependent on the H2SiF6 concentration and is inversely proportional to the square of the particle diameter. Using 2.6M H2SiF6 at 85°C, 49% of the Ti and 53% of the Fe in 44-to 74-µm New York rock ilmenite were extracted in 3 h.

Jan 1, 2010

By Andrew Allan

[This report describe the first experiment of the Anthracite Research Laboratory, Bureau of Miners, in attempting to reduce underground-mining costs and conserve anthracite as a natural r-source by introducing now minim methods. The work war, dons in cooperation with one of the large anthracite-producing companies. It applies to productive mining, characterized by comparatively low cost, per ton and high production per man, as differentiated from development mining, which is always necessary before the, productive or retreat phase can begin. The system d scribed in this report is believed to be generally applicable to beds pitching 70° to 90° and, under certain conditions, to beds pitching loss than 70°. After development hate been completed, an openings is made, extending the full width of the 9- to 10-foot coal bad and reaching from the haulageway to the vertical limits of the solid coal. Long drill holes (20 to 50 feet) charged with about one stick of permissible explosive riper foot of length are fused to break the coal. Once broken, the coal is loaded onto a shaker conveyor by gravity and thence into mine: cars. The coal is mined retreating in 15- to 20-foot sections that are broken and loaded onto the conveyor through a specially constructed chute. In the Bureau?s experimental work, the height of sections arse ranged from 35 to 60 fact, depending on the geologic extent of the coal bed.]

Jan 1, 1952

By J. W. Town

Recrystallization studies on chrome-bearing spinel materials were made by the Bureau of Mines to determine the effects of certain fluxing agents and cooling rates on the chromium-to-iron ratio of recrystallized spinel. Statistically designed and evaluated tests showed that the ratio of chromium to iron in naturally occurring chrome spinel could be increased from 1.5 to 1 to over 7 to 1 and that the ratio of chromium to iron in the chrome-spinel in a stain-less steel slag could be raised to over 18 to 1. Silica, magnesia, and lime had significant positive effects, while alumina had a significant negative effect. Cooling rates of 200 C per hour in a programmed spiral globar electric furnace were satisfactory for growing crystals of recoverable size.

Jan 1, 1967

By W. H. Coghill, F. D. DeVaney

"Introduction Numerous investigators have studied grinding. Each has contributed his bit to a literature that is difficult to correlate. Too many of the results have been transformed into curves with no many ""inflection points"" and ""counterflexures"" that they obscure the issue.Some of the investigators have neglected the very essence of the problem, namely, the power and the amount of material to which a known amount of work was applied. The purpose of this paper is to show the ease with which results can be interpreted when these quantities are duly recognized. Some grinding tests will be given for illustration.Grinding studies are of two kinds: (1) Study of the character of the ore and (2) study of the performance of the machines. Several ores may be crushed by a given machine, or several machines may be used on a given ore. The illustrations given in this report cover both objectives.Grindability Characteristics When the ores are being studied the information sought is grindability characteristics (grain-size distribution) and the grindability (work required to produce new surface) of a group of ores.When the study is of the machines, several machines are used for a given ore or given types of ores, and the grinding performances of the machines are compared by a grain-size study.Table 1 gives the grindability characteristics and grindability of six substances, one of which is coal. The substances are arranged from left to right in progressing order of tons per horsepower-hour. Curves and graphs are not needed for elucidation. The secret of the ease of interpretation is the order mentioned and the similarity of the sizing analyses. Power records must be complete in grinding studies.The grinding device was a ball, plunger, and mortar called the drop weight.' It may be used to advantage when the amount of material to be tested is too small for the orthodox machines.The upper part of table 1 shows the grindability characteristics by the cumulative-sizing analyses. Note how closely the percentage weights agree for a given sieve size. The lower part shows the grindability in terms defined elsewhere. The present paper should be read in conjunction with that paper."

Jun 1, 1934

By R. N. Love, L. Goldman

"INTRODUCTION When tannin is present in a boiler water, it causes certain difficulties in many analytical testing procedures because of its colloidal action in interfering with the removal of suspended matter by filtration and also because of the color it imparts to the boiler water.For example, in any test for phosphate in boiler water the first step is to filter out of the sample all sludge and suspended solids. Calcium phosphate in the sludge would give high results if not completely removed. If tannin is present in the sample, the sludge and suspended matter tend to pass through the filter paper so that it is difficult to remove it all. It may even be that tannin makes some of the suspended material in the sample completely nonfilterable. If this is true, it would be necessary to destroy or remove the tannin from the sample before filtering to get complete removal of calcium phosphate from the sample. In addition, if the test used is a colorimetric one, the tannin causes interference by its own color.As the calorimetric phosphate test is so convenient for control purposes and the use of tannin for boiler water treatment has become common, it has become necessary to develop suitable methods for employing the colorimetric phosphate test for boiler waters containing tannin. In this paper three different methods for doing this arc described and studied."

Oct 1, 1946

By Joseph L. Buckley

A total of 55 conveyor belt fire tests were conducted in the Bureau of Mines Fire Test Gallery, located at the Factory Mutual (FM) Fire Test Center West Glocester, R.I. The objectives of these tests were to: 1) determine the fire resistance and burning characteristics of various conveyor belt materials under simulated mine conditions; 2) provide essential data for designing a reliable bench-scale conveyor belt fire resistance test; and, 3) determine fire test conditions that will discriminate between low, moderate and high fire resistant materials. Belts, representative of those which mold he found in underground coal mines were examined under n umber of experimental conditions which included; ignition intensity; air flow rate; ratio of belt bright (h2) to overall gallery height (h1); exposure time; and, belt width. It was found that fire propagation could be achieved for some "fire resistant" belts (complying with the present Schedule 2G standard for approval) when exposed to an Ignition source of =6000 Btu/min for a 15-min period at a belt height ratio of 01.66. There appears to be a dependency of flame propagation on air flow rates and belt width, although the tests performed do not provide a quantitative trend. Recommendations are made for additional work to resolve some anomalous date and to fill voids in the rest program.

Jan 1, 1978

By W. H. Ode

An investigation of standard methods for determining ash in low-rank* coals showed that generally 60 to 95 percent of the total sulfur in the coal is retained in the ash as SO3. This large sulfur retention causes a positive error in the determined mount of ash of as much as 6 percentage points for the coals examined, although it usually is 2 to 3 percentage points for lignites and about 1 for subbituminous coals. Unless the sulfur content is low or unless a correction is made for the SO3 retained, the fixed carbon and oxygen have an equivalent negative error when determined by difference; also other inaccurate analytical values occur when the data are calculated on an ash- free bas is. No simple modification of the ashing procedure was found that would reduce the sulfur retention to a point where its effect on the ash determination would not be significant, Therefore, for accurate analytical work on law-rank coals, the SO3 should be deducted from the determined ash to obtain a "corrected" ash value.

Jan 1, 1962

This publication summarizes the in-house and contract research projects programmed for fiscal year 1984 by the Bureau of Mines under its Conservation and Development activity. The document provides a mechanism for interested parties to gain insight into projects of the Bureau's Conservation and Development research program. The objective of the Conservation and Development Program is to provide the technological advances needed to stimulate the mining of domestic deposits containing critical, strategic, and other essential minerals in compliance with existing regulations and at costs sufficiently low to be competitive in world markets. Research efforts are directed toward improving the fundamental understanding of processes and procedures involved in the production of minerals. The overall goals will be accomplished by investigating alternative mining methods to increase domestic production of critical and strategic minerals from low-grade deposits; expanding the technology for the economic and efficient extraction of minerals consistent with cost-effective compliance with environmental regulations; and advancing the technologies needed to insure an adequate supply of coal.

Jan 1, 1984

By H. J. Coleman

Knowledge of the types of naturally occurring sulfur compounds in petroleum is of both theoretical and practical interest to petroleum chemists and geologists. This knowledge has been extended by the identification of 77 sulfur compounds, including 36 thiols, 23 chain sulfides, and 18 cyclic sulfides in a 111° to 150° C boiling range distillate of Wasson, Texas, crude oil. The characterization procedure used in separating and identifying these compounds included isothermal distillation, vacuum fractionation, liquid-solid chromatography (alumina adsorption), chemical treatment, gas-liquid chromatography, microdesulfurization, and infrared analysis. The procedural steps described represent a systematic method of sulfur compound analysis considered applicable for determining the nature and concentration of the sulfur constituents present in any straight-run petroleum distillate of the above-boiling range.

Jan 1, 1966

By McHenry Mosier

This paper describes come mechanical raid electrical signal systems in common use in Metal-mine shafts, together with several distinctive systems that indicate or control the origin of the signal. The latter systems remove the hazard of the movement of the cage from one level in response to signals from another. Previous publications of the Bureau of Mines have covered several meritorious installations One of the best signal systems for deep shafts is at the Homestake mine4/. A successful installation of an induction system in the Lake Superior mining region permits signaling as well as telephoning from cages at rest or in motion5/. El Potosi mine uses a variation of the three-wire electric system6/. A mine in Utah has developed a system of the double trolly-wire type, in which the cage attendant may signal from a moving cage7/. At present no system of the sine-shaft signaling employing radio is available.

Jan 1, 1939