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By Irving Hartmann, John Nagy, Donald Mitchell

"SUMMARY AND CONCLUSIONThe test data indicate that water infusion of the Pittsburgh coal seam does not reduce the amount of fine dust produced during mining operations to the extent reported elsewhere. Wide variations in the amounts of dust collected in the air current were noted in duplicate samples and repetitive tests. Changes in depth and location of the infusion holes and amount of water injected and addition of a wetting agent to the water had little effect on the amount of dust liberated.Water was forced readily into the coal. Some water flowed out along the cleats, but an appreciable amount remained in the seam. Little or no water pene¬trated the coal seam above the upper infusion holes.The average dust concentration (with and without infusion) in the return air, 40 feet outby the working face, was 25 million particles per cubic foot during undercutting, 20 million during drilling, 75 million during shot firing, and 20 million during hand loading. At the working face the average concentration was 3 to 6 times higher. The concentrations were measured at an airflow of 1,600 cubic feet per minute (c.f.m.) at the face.On the basis of this short investigation, no final conclusions can be made on the effectiveness of water infusion in reducing the amount of fine dust liberated during mining in the Pittsburgh coal seam. However, the data indicate that dust reduction resulting from infusion would be small.INTRODUCTIONThe production of fine coal dust is an inherent part of nearly every phase of mining. The use of large, high-speed continuous-mining machines and other mechanical equipment has increased dust production. In addition, in coal seams that have been subjected to high pressures for a long period, and particularly in dry and friable seams, some very fine dust is in the seam before mining. Much effort has been devoted to allaying and collecting at its source the fine coal dust released during mining. One of the comparatively recent techniques that has been developed for this purpose is infusion of water or other liquids into the coal seam. This method consists of injecting water under pressure into a coal seam to neutralize the fine dust released during mining. The water generally is introduced through bore holes in the face before undercutting."

Jul 1, 1957

By N. S. Dalal, X. Shi, V. Vallyathan

"Correlated spectroscopic and cytotoxicity measurements were made on newly crushed silica to find whether the fracture-induced, silicon related (Si-0· or Si· type) free radicals play a direct role in the mechanism of hemolysis by silica particles. The free radical content of the silica particles was controlled through the radical decay, thermal annealing, and boiling processes, and was followed with electron spin resonance spectroscopy. Portions of the same sample were evaluated for their hemolytic potential, employing sheep erthyrocyte and optical absorption techniques. The results indicate little, if any, correlation between the amount of the silicon-based radicals and the hemolytic potential of the fresh dusts, but these or related radical sites might be contributors to silica cytoxicity and fibrogenicity via peroxidative pathways .INTRODUCTIONIn an earlier convnunication (1.) from our laboratory it was reported that mechanical crushing of coal and quartz under normal air atmosphere generates free rad;cals on the particle surfaces, and that these radicals decay with time, hence pointing to a higher toxicity of fresh dusts in relationship to pneumoconiosis and silicosis. More recently Fubin; et al.(2) have also reported the detection by electron spin resonance (ESR) of the formation of SiO· and Si·-type of radicals from quartz particles crushed under atmospheric conditions. In agreement with earlier ESR studies on single crystals of quartz crushed under high vacuum (10-10 torr) (3) and subsequent exposure to air (3), and to other gases (4), these radicals were identified (2) as being formed by the hemolytic cleavage of the Si-0-Si bonds and the reactions of the Si· and SiO· ,radical with atmosphere. Fubin; et al. (2) also suggested that these radicals might be involved in the mechanism of the fibrotic action by silica, either by transforming the particle surface into a selective oxidating agent or as an initiator of a sequence of reactions leading to fibrosis. Earlier Gabor and Anea (5) had reported that lipid peroxidation caused by free radicals on the silica surface might be involved in the red blood cell membrane damage. Thus far, however, no parallel cytotoxicity, fibrogenicity, and free radical studies on a given Quartz dust sample have been reported, except for some earlier work from our laboratory (1,6,7). We now present more recent results obtained from parallel cytotoxicity, fibrogenicity, and free radical measurements on a freshly made quartz dust. The dust’s free radical content was measured using ESR spectroscopy while its cytotoxicity poteni1al was estimated via hemolysis. Hemolysis was employed as the tox1c1ty test because it 1s a widely used method for estimating the potential of a dust for disrupting the cell membrane (8). The f1brotic potential was followed.by measuring the dust-induced lipid perox1dat1on. us1ng linole1c ac1d as a model lipid. As discussed below, the results obtained suggest new clues.to the mechanism of the Quartz-related cytotoxicity and fibrogenicity."

Jan 1, 1988

By C. S. Allbright

This report gives the results of analyzing three groups of crude shale oils by the Bureau of Mines procedure:4/ (1) Oils produced by standard Fischer assay determinations on oil shales from Brazil (Paraiba Valley) and the United States (Colorado); (2) oils produced from Brazilian shale by different retorting methods; and (3) oils from high-temperature retorting of Colorado oil shale in the Entrained Solids retort. It is the second in a series presenting data obtained by analyzing crude shale oils from various sources. The series furnishes information on the general characteristics and compositions of a wide variety of shale oils. Use of a standard analytical method on all samples facilitates comparison of different oils. The 18 oil samples analyzed in this project comprised 3 from assays of Brazilian and Colorado oil shales in the Fischer retort, 9 obtained by processing Brazilian shale in various other units, and 6 from entrained solids retorting of Colorado shale at 1,000° to 1,500° F. The crude oils from Brazilian shale contained about half as much nitrogen as the Colorado oils. Properties of the Fischer assay oils from Colorado shales agreed with some data that relate grade of the oil shale with properties of the crude oil from the Fischer assay. Comparison of results from Fischer assays of oils from the foreign and domestic shales shows that the oil from Brazilian shale contains more low-boiling material and less residuum than either of the two from Colorado shale. This fact is reflected in lower specific gravity, viscosity, and carbon-residue values for the Brazilian oil. Retorting Brazilian shale in the Entrained Solids unit at 1,120° F. produced an oil whose boiling range was generally lower than the boiling ranges of oils obtained by processing in three other retorts at conventional temperatures. The quality of crude oils from high-temperature retorting of Colorado shale in the Entrained Solids process varies with retorting temperature. As the temperature is raised within the range 1,000° to 1,500° F., the amount of the naphtha fraction in the crude oil increases to about 35 percent and the aromaticity to 98 percent.

Jan 1, 1956

By W. P. Yant

A previous report of the Bureau of Mines dealt with the toxicity of dichlorodifluoromethane, a new refrigerant that has a remarkably low toxicity. Continued research by the Frigidaire Corporation and toxicological experiments performed in the Laboratory of Applied Physiology of the University of Cincinnati revealed another organic fluoride, dichlorotetrafluoroethane, whose toxicity also appeared to be of a very low order and whose physical and chemical properties make it suitable for refrigeration purposes. In addition to low toxicity, safety in its use is further enhanced by its physical properties, which permit the design of equipment that operates at comparatively low pressures and hence mitigates the dangers and problems of leakage. The investigation described in this report was performed by the Bureau of Mines at the request and with the cooperation of the Frigidaire Corporation.

Jan 1, 1932

By M. R. Geer, H. F. Yancey

Fuel requirements of the Pacific Northwest have been increased greatly by the war . To the normal peacetime demands for fuel have been added the requirements of new industrial and metallurgical plants engaged in war production , the increased demand arising from expansion of existing industrial establishments , increased amounts of railroad fuel required to handle wartime traffic , and increased quantities of domestic fuel required by the influx of war workers . In the face of these augmented demands for fuel shipments of fuel oil have been curtailed , wood fuel which normally is an important factor in both industrial and domestic markets of the area is less abundant , and the production of coal in Washington has decreased sharply . The fuel requirements of the region have been met so far by shipping large tonnages of coal into the Pacific Northwest from Utah , Wyoming , Montana , and Colorado ; the quantity received from these States and Canada in 1943 amounted to 2,688,9124/ tons , 175 percent of the Washington production . or The proximity of the Washington coal mines to large centers of war production has resulted in widespread migration of miners to employment in shipyards and aircraft plants ; the ensuing shortage of miners largely accounts for the decreased production of coal in the State . Hence , strip mining , which requires relatively few workers and a shorter time for development , offers an attractive means of alleviating the local coal shortage and obviating the necessity of shipping coal from the producing areas of the Rocky Mountain States to the Pacific.coast . So urgent has been the necessity for augmenting local coal production that any coal property that promises to be amenable to strip mining , even though the coal may be inferior in quality , has warranted examination . Even low- grade coals that cannot compete in the normal market can be used locally , thus releasing better coals for shipment to critical centers. of consumption ... One such deposit of low- rank fuel examined by the Bureau of Mines is in western Lewis County , about 9 miles east of Toledo , Wash . The coal is lignitic and on the as - received basis has a heating value of 6,000 to 6,500 B.t.u. per pound . The property is of interest primarily because the physical conditions favor operation by stripping and offer opportunities for low- cost production with very low manpower requirement .

Jan 1, 1945

By Robert W. Geehan

A preliminary examination of the Dayton iron deposit was made in 1941 and 1942 by Paul E. Pesonen and O. H. Metzger, engineers of the Bureau of Nines. Trenching and sampling were recommended, to be followed by core drilling if favorable results were obtained. The Bureau of Mines conducted a project at the property from June to December 1942. The deposit is in sec. 6, T. 17 N., R. 23 E.; sec. 31, T. 18 N., R. 23 E.; sec. 36, T. 18 N., R. 22 E.; and sec. 1, T. 17 N., R. 22 E., M. D. B. & M., about 15 miles west of Lahontan Reservoir in Lyon and Storey Counties, Nev. It lies at an altitude of about 4,500 feet north of the Carson Plains, in the foothill section of mountains that rise to about 7,000 feet to the north of the property. The deposit may be reached by driving 12.5 miles northeast of Dayton over U. S. Highway 50, thence northerly 2.7 miles over a dirt road to the property. The climate is hot and dry in summer, with occasional thunderstorms some of cloudburst variety, and frequent high winds. Winters are usually moderate, with light snowfall and some subfreezing temperature.

Jan 1, 1949

By David F. Smith, F. A. Hartgen

"Incidental to a cooperative investigation with the Carnegie Institute of Technology and the International Combustion Engineering Corporation on the burning characteristics of a powdered coal and the powdered semi-coke therefrom, the U. S. Bureau of :alas has determined the relative temperatures at which rapid self-heating occurs in these two fuels. Determinations were made on various screen sizes of the two fuels. Chemical analyses on different sizes were made in the bureau's Coal Analysis Laboratory, of which H. M. Cooper is in charge. The true densities were determined b the method given in Bureau of Mines Technical Paper 8.4The apparatus used in the determination of the temperatures for rapid self-heating was similar to that used by Wheeler A 10-gram sample of the fuel was placed upon a screen in a glass tube enclosed in a vertical electric furnace. The tube was surrounded with sand. One thermocouple -as imbedded in the sand and another in the fuel. Measurements of the temperatures were obtained at regular intervals with a recording potentiometer, as the furnace temperature was uniformly raised. Dry air was passed down through the fuel samples at a uniform rate of 123 c. c. per minute; the temperature of the air was substantially that of the furnace."

Oct 1, 1929

By A. C. Fieldner

In preparing this paper, an attempt was made to obtain results of plant-scale carbonization tests on washed and unwashed coal from the same mine. A letter. in which the following questions were asked was sent to some 50 coke-oven superintendents and others who might be interested; "What is the influence of washing coal on: (1) The chemical and physical properties of coke, as for example, the size the amount of breeze, the fracture, strength, cell-structure, etc. (2) The quantity and quality of gas and by-products. (3) The capacity of the ovens. (4) The composition of the coal. "Your general opinion, as well as any specific data or results of tests, on this important subject will be arc greatly appreciated."

Jan 1, 1930

By R. Karl Zipf, Z. T. Bieniawski

"Fracture mechanics plays an important role in studies of geologic materials such as rock and coal. Yet fracture data are scarce for rock and most limited or unreliable for coal. A testing system was developed which can apply mixed mode loads to a crack tip in many rocks and geologic materials. It is possible to subject the test specimen to pure mode I, various mixed modes and a nearly pure mode II fracture load. The system is currently used to study the mechanics of fine fragment formation in various coals. Experimental measurements include KI and KII' fracture velocity and acoustic emission.INTRODUCTIONA major research program at The Pennsylvania State University is directed to understanding the fundamental mechanics of fine fragment formation in various coals. The program represents an effort to reduce the incidence of coal workers pneumoconiosis (black lung) in coal miners. The principal source of the respirable coal fragments is the cutting operation which forms and liberates the particles by a fracture process. Present understanding of the mechanics of the events which form and liberate these particles is meager (Cook, 1982).Current knowledge of the fundamental mechanisms of coal dust generation and entrainment in terms of the underlying fracture mechanics is critically needed to improve and possibly control the processes involved. Whether the cutting operation is done with a 'continuous miner' cutting machine, a plow or a longwall shearer, it is fundamentally a problem of mixed-mode crack propagation. When a cutting tool interacts with coal, it causes numerous cracks to propagate through the intact material. Numerous larger fragments are broken free, but another quantity of undesirable fine fragments is also created. The formation of these respirable fragments may be a direct result of the crack propagation process; hence, a thorough understanding of the fracture mechanics of coal is required to minimize production of the unwanted fine fragments.In most rock engineering applications, the rock material properties are of secondary importance to the rock mass properties; however, for rock fragmentation and rock cutting problems, it is rock material properties such as fracture toughness which are of prime interest (Bieniawski, 1980). Several rock cutting and rock failure theories have been proposed, but it is only very recently that fracture mechanics concepts have been successfully applied to the study of rock cutting mechanics. All cutting models seek to predict the cutting forces and the cutter geometry necessary to cause rock breakage and chip formation given some fundamental mechanical properties ~f the rock. Such models have wide applications in drilling, tunnel boring and mining problems. Nelson et al., (1985, 1986) has provided a very useful correlation between the laboratory measured fracture mechanics properties of rock and the performance of the disk cutters on tunnel boring machines."

Jan 1, 1989

By G. E. McElroy, D. Harrington

The use of shall electrically- driven fans , in conjunction with air- pipe of various diameters is becoming of increasing importance for the ventilation of working places in metal mines through which the general ventilating currents can not be coursed . It will probably continue to increase in importance since the concept that air motion is the most important factor in maintaining comfort in hot ( above 80° F . ) working places is more generally accepted , and as the inefficiency and greater expense of attempting to ventilate such places with compressed air is recognized . Managers of large properties can afford to experiment with fan- pipe installations until types are found that meet their conditions , but managers of shall properties , unless forced to it by extreme conditions , prefer to wait until they can obtain data sufficient to guarantee at least a measure of success from such installations . At present , such data , even in part , are available to only a few (mainly fan manufacturer's representatives , consulting ventilation engineers , and ventilatin engineers employed by large companies ) , and important recent developments are mostly of a confidential nature . One large metal - mining company cooperated with a fan manufacturer in some extensive experimental work on small blowers and found that instead of using stock fans , considerable power economy could be effected and equal quantities of air delivered by use of or 2/3 width fans with small motors rather than using stock fans and larger motors ; it was also found advisable to adopt certain sizes of tubing for certain lengths of run . In fact , many important facts were ascertained in this study , and it is now promised that they will soon be given to the public . It is true that a certain amount of data on industrial installations are available , but such data are only in part applicable to metal -mine conditions , because , until recently , little attention has been given to ventilation in metalmines , and the conditions encountered usually require a greater length of pipe , a more temporary type of construction , and closer attention to temperature control than the ordinary run of industrial installations demands ..

Feb 1, 1922

By M. J. Ferrante

High-temperature enthalpy and X-ray powder diffraction studies were con-ducted on aluminum sulfide (Al2S3) as part of the Bureau of Mines effort to provide new data for the advancement of mineral technology consistent with environmental preservation and energy conservation. Relative enthalpies were measured with a copper-block calorimeter from 298.15 to 879 K. Tabulated values are listed for heat capacity, entropy, Gibbs energy functions, and relative enthalpies between 298.15 and 900 K. Enthalpies were also given in the form of an equation and combined with published data to calculate standard enthalpies of formation and Gibbs energies of formation for reactions of crystalline aluminum with crystalline, liquid, and gaseous diatomic sulfur. The hexagonal, rhombohedral, and cubic phases of Al2S3 were identified by X-ray powder diffraction studies, and the indexed powder diffraction patterns of these phases are given. The hexagonal phase was stable to about 852 K and was partially converted to the rhombohedral form at 879 K.

Jan 1, 1981

By T. A. Henrie, E. K. Kleespies

Carbon reduction of rutile and ilmenite in nitrogen and ammonia atmospheres was studied as a method of preparing titanium nitride . Ammonia was a better nitriding agent than nitrogen . The contact between the solid reactants , carbon and rutile , was a prime factor in nitrogen atmospheres and was of lesser import in dissociated ammonia . The reduction process for conversion of rutile to the nitride required carbon . The nitriding of ilmenite- carbon mixtures produced titanium nitride and elemental iron .

Jan 1, 1964

By J. P. Bennett

The Bureau of Mines investigated the dimensional changes of ceramic materials exposed to acid environments to evaluate construction materials for emerging technology in chemical and metallurgical processes. Six commercial ceramic materials (two red shale, two fireclay, one silica, and one silicon carbide (SiC» were exposed to H20, 20 and 30 wt pct HCl, 40 and 60 wt pct HN03, and 10 and 50 wt pct H2S04 at temperatures from 50° to 90° C for 300 days. Linear expansions ranged from a low of -0.02 pct for the silica to a high of 0.45 pct for the red shale. A general ranking of the volume expansion of the materials tested, (from high to low), is as follows: high-porosity red shale A and fireclay B » low-porosity red shale B and fireclay A > silicon carbide and silica. A general ranking (largest to smallest) of the effect of exposure environments is HCl > H2S04, HN03 > H20. An autoclave test method was evaluated. Data obtained from 8-to 24-h exposures were compared with data obtained from the 300-day exposures. The relative expansion trends were similar, indicating that this method could be used as an accelerated test.

Jan 1, 1988

By Robert E. Barieau

General expressions for evaluating practically all the thermodynamic properties of a fluid from a single equation of state are derived. Most of the formulas are expressed in terms of the compressibility factor, with this factor being an explicit function of the temperature and the molal density. Similar expressions are given using reduced variables.

Jan 1, 1967

By Warren Howes, A. B. Campbell, W. H. Ode

"INTRODUCTION The mines in the eastern part of the now active region of the Tri-State zinc district of Missouri, Kansas, and Oklahoma have unusually acid water, which during periods of moderate or no rainfall is used in the mills to replace losses from evaporation, seepage, and tailings disposal. Its use has caused difficulties by corrosion of equipment and by interference with flotation.The growing importance of flotation, which requires good water, and the increasing troubles caused by the corrosion of the milling equipment have prompted the Mississippi Valley Experiment Station of the United States Bureau of Mines, in cooperation with the Missouri School of Mines and Metallurgy, Rolla, Mo., to investigate the action of the waters on flotation and to undertake to develop means of obviating their harmful effects.The work was under the immediate direction of W. T. Schrenk, consulting chemist, United States Bureau of Mines, and professor of chemistry, Missouri School of Mines and Metallurgy, and Will H. Coghill, supervising engineer of the ore dressing section of the United States Bureau of Mines.ORIGIN OF ACID MINE WATERSRain water, carrying oxygen and carbon dioxide in solution, finds its way into the pores and crevices of the earth's crust and percolates downward through the rocks. This water and its dissolved gases exert a solvent action on many minerals, the extent of which depends upon the nature of the associated minerals.The iron sulphides are the chief sources of the 'trouble with sulphates and sulphuric acid because they oxidize so freely and contain more sulphur than is required to satisfy the iron when ferrous sulphate is formed. Galena and sphalerite may oxidize to sulphates without liberating acid. A few of the common reactions occurring in the Tri-State mine waters may be illustrated by the following equations:"

Mar 1, 1932

By Robert J. Timko, R. Lincoln Derick

This U.S. Bureau of Mines study examined spontaneous heating episodes in coal mine pillars in an active underground coal mine. The information obtained from these incidents was then analyzed to learn which sampling methods provided the earliest indication of pillar heating. The objective of this study was to discover if the location of future events of pillar spontaneous heating could be inferred from the available information. The spontaneous heating-prone area in this evaluation involved pillars located just in by the mine portals. Several detection methods were used to determine gas levels outside as well as inside the affected pillars. It was hoped that, by incorporating external and internal sampling methods into an organized program, locations undergoing spontaneous heating could be determined more readily. This study found that by drilling small-diameter boreholes into the pillars, then obtaining gas samples from the affected pillars, the ability to locate early spontaneous heating episodes was improved. However, the ability to accurately predict future spontaneous heating events remains in question.

Jan 1, 1995

By F. E. Brantley, D. M. Yergensen, D. A. Martin

Fluidized - bed roasting was investigated as a means of decomposing gypsum and gypsum mixtures to produce a gas rich in sulfur dioxide and a lime or portland cement residue . Ninety- eight percent desulfurization of gypsum in a 10 - inch fluidized- bed reactor took 1.5 hours at an operating temperature between 1,200 ° and 1,225 ° C. A cement- type residue was obtained but had to be refired at 1,450 ° C before mortar prepared from it met the physical specifications for cement .

Jan 1, 1963

By Robert H. Mattes

The Lake Lynn Laboratory is a multipurpose mining research laboratory operated by the Bureau of Mines and located in Fairchance, Pa, It consists of both surface and underground facilities. The initial focus of the facility, scheduled for full operation in fall 1982, will be on the problems of fires and explosions in mines. The initial experimental explosion was fired on March 3, 1982. The intent of this document is to provide the reader with detailed information on the physical capabilities of the Lake Lynn Laboratory. Subsequent publications will focus on the capabilities of Lake Lynn as compared with those of other similar facilities worldwide, and a comparison of initial explosion test results realized at Lake Lynn and comparable results from the Bruceton Experimental Mines.

Jan 1, 1983

By H. G. Lucas

A feeder screw supplied at constant pressure by a hopper-orifice arrangement was developed for feeding solids in size ranges up to several hundred micrometers at constant flow rates. Performance of the feeder was evaluated by measuring the flow rates obtained with 3-to 7-micrometer coal ash, 70 percent through 200-mesh coal, and minus 325-plus 400-mesh coal ash. Constant feed rates within a few percent of set values were achieved for half-hour periods for the larger particles and for 5-minute periods for the finer particles. Suggestions are given for feedstock preparation and feeder operation for optimum performance.

Jan 1, 1974

By M. A. Schellhardt

"INTRODUCTION The augmented demands for natural gas in many parts of the United States as a result of war have increased the need for information regarding the producing characteristics of natural-gas and gas-condensate-type wells capable of delivering large volumes of gas, as such information is important to the formulation of conservative and efficient operative and recovery practices.,For many years, the capacity of natural-gas wells to produce gas has received studied consideration by Bureau of Mines' engineers, and three reports 3/ on gaging gas-well capacities have been published. In Report of Investigations 2929, Pierce and Rawlins point out that for accurate gaging, the actual pressures at the face of the sand in the well and the relationship between such pressures and the rates of flow of gas through the sand must be determined. Their report describes a method of attacking the problem of determining the actual pressures at the sand by means of observations of pressures and volumes at the wellhead.In Report of Investigations 2930, Pierce and Rawlins explain how the fundamental relation"

Aug 1, 1944