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By W. W. Adams

"The main purpose in the compilation of accident statistics is to reveal conditions that may result in injury to persons or property so that remedial measures may be applied. For practical reasons it is usually found necessary to restrict inquiry to conditions which actually have caused personal injury, and to omit those which nay, but have not yet, resulted in damage, Fortunately or unfortunately, there is a sufficient number of the former to indicate the existence of hazards so numerous as to require all of the attention which the industry can devote to the subject.Two years ago, the Bureau of 'mines, in cooperation with the National Safety Council, undertook an intensive campaign to obtain more complete and satisfactory information regarding mine accidents than had theretofore been available. Since 1911 the bureau had been receiving annual summaries from all companies operating metal mines, showing, in a general way, the number and causes of accidents that occurred during the preceding year and the number of men employed at the mines. Monthly summaries of fatal accidents at coal mines were received from the state inspectors, showing the number of deaths attributed to each of 22 main causes of accidents, Information for individual coal mines was not furnished.While this information, nation-wide in scope, is indispensable because it epitomizes the progress or retrogression in the industry as a whole, and serves as a background of specialized studies, yet certain classes of acci¬dents, for example, those that are more or less peculiar to specific districts or mines, require an analysis in greater detail than is possible on the sole basis afforded by the annual summaries.The need for more specific information was realized some years ago in the State of Pennsylvania in connection with the administration of the workmen's compensation law, The mining industry is well acquainted with the val¬uable studies of accidents, particularly nonfatal accidents, in the mines of that State being conducted by Mr. Rush N. Hosier."

Sep 1, 1924

By L. B. Pankratz

Low-temperature heat capacities, high-temperature enthalpy increments, and the enthalpy of formation at 298° K were determined calorimetrically for vanadium subnitride (VN0.465). The low-temperature investigation gave S°298.15 = 6.379 ±0.005 cal/deg mole, and a combustion calorimeter investiga¬tion provided ?Hf°298.15 = -31.80 ±0.60 kcal/mole. The two quantities were combined with the high-temperature data to give standard values of enthalpies of formation and free energies of formation above 298° K. These and related thermodynamic functions were tabulated to 1,800° K. Similar data are included in the range of 298° to 1,600° K for the mononitride, VN.

Jan 1, 1971

By W. D. Walker

The trend toward encouragement of worker participation in accident prevention in the coal mines of the United States is not new; however, it has been given added impetus in recent years and is now definitely progressing. It has been found by experience that, although there are many approaches to a mine-safety program that will include the workers themselves as well as their supervisors, no one way is suitable under all circumstances. It requires the concerted efforts of many agencies working along parallel lines toward a common goal. The following seven principal agencies, using somewhat different methods, are listed to illustrate how this problem is approached throughout the coal-mining industry 1. Federal Bureau of Mines. 2. State mining departments (in individual States where coal is produced). 3. Programs conducted by individual mine operators. 4. Programs conducted by mine workers' organizations (unions). 5. Institutes, societies, and other educational organizations. 6. Coal operators' associations (regional and national). 7. Universities, college, and high schools. Each of the seven approaches to safety are discussed briefly, and their methods end contributions, such as publications and other activities, are listed.

Jan 1, 1953

By W. P. Diamond

The Bureau of Mines has been involved in the drilling of vertical, horizontal, and directional coalbed gas drainage boreholes for mine safety since 1964. In that time, boreholes have been drilled in most of the major coal regions of the United States under a wide variety of geologic conditions. Many of the geologic conditions that occur in the coal measures are detrimental to gas drainage; others may be beneficial. Analytical techniques to determine the gas content of coal samples and evaluate regional trends of gas distribution have been developed. Drilling techniques that maximize the acquisition of coalbed gas data and geologic information have been determined. Although some of the geologic factors influencing the placement and potential success of coalbed gas drainage boreholes have been reported in papers on individual projects, a complete, systematic compilation has not previously been available. The objective of this paper is to pro- vide information on specific geologic factors that should be considered prior to, during, and after the drilling of coalbed gas drainage bore-holes. Many of the commonsense considerations that have been learned through many years of Bureau of Mines experience, but have generally not been reported formally, are included for those who may be considering coalbed gas drainage drilling for the first time, or who have not had the opportunity to encounter a substantial number of geologic situations.

Jan 1, 1982

By L. R. Burdick

This paper presents a review of published investigation dealing with the importance of sulfur compounds in the deterioration of materials or providing some basis for estimating the extent of loss shareable to such air pollution. Materials included are cement, stone, metals, paint, leather, paper, sand cloth. The investigations may be divided into two classes, one of the laboratory type in which the sulfur content and the humidity of the air were controlled and the other dealing with the exposure of materials to atmospheres not under control. The first type of work has shown that cement is subject to deterioration by the action of sulfur dioxide gas. The experiments with stone indicate that although limestone takes up sulfur dioxide, from the air, moist sulfur dioxide-air mixtures alone cannot be used for establishing- the comparative weathering- qualities of the different types of stone by accelerated test methods. Laboratory tests indicate that sulfur compounds in the air accelerate the corrosion of iron, steel, zinc, copper, and nickel at normal air temperatures and at certain relative humidities. It has also been indicated that certain types of paint are, affected by high sulfur dioxide concentrations, and that paper is attacked by sulfur dioxide in the atmosphere. The investigations of the second type show the amount or variation of corrosion in different localities and under different types of exposure. The investigations (10) (18)4/ during which sulfur determinations were made indicate that sulfur dioxide is a main controlling factor in the corrosion of iron and steel but according to Quick (18) may not be for some nonferrous metals. In general, the laboratory tests do not Jive definite data on the loss due to sulfur compounds at the concentrations normally found in the air. The data from atmospheric exposures are not complete from the standpoint of the exact effect of the sulfur compounds. Damage to materials so exposed is affected by factors such as other chemical contaminants, humidity, rainfall, solid deposits, and sunlight. A simple scheme has been devised in Great Britain which is considered to provide a measure of the attack of sulfur compound, on building materials (1). Small cylinders coated

Jan 1, 1939

As mine haulage vehicles become larger, the danger to a driver during a fire emergency is increased by the greater height of the cab above ground. Also, property damage due to fires on bigger trucks can be substantial. To solve this problem, the Department of Interior's Bureau of Mines, through two research and development contracts with FMC Corporation, San Jose, California, has developed two reasonably priced, reliable automatic fire sensing and suppression prototype systems for large haulage vehicles. At the onset of the large mobile equipment fire protection contract effort, it was learned that fires were frequently experienced in open-pit mine haulage equipment, especially large trucks. As the size of equipment has grown, so has the hazard presented to an operator forced to leave his truck in a hurry when fire breaks out and his normal path to the ground is blocked by flames. His only recourse is to jump from the cab platform to the ground, and the one-story drop of 10 feet or more can severely injure him. It is with these factors in mind that a program was undertaken to provide a fire detection and extinguishing capability tor the large mobile equipment, especially trucks, used in open pit mines.

Jan 1, 2012

By D. G. Kesterkel

Low-melting thoriurnrbase binary alloys or metal solutions were prepared by two different techniques involving the electrolysis of ThO2 dissolved in fluoride melts. Experiments were performed at 950° to 1,250° C using electrolytes containing ThF4 and various alkali and alkaline earth fluorides. In the first method, electroreduction of ThO2 and deposition of thorium on a nickel or iron cathode formed a molten alloy that dripped off and collected on the bottom of the cell, or in a tungsten cup. An electrocodeposition technique was used to prepare thorium-base alloys or solutions containing nickel, iron, chromium, or manganese. Electrolytic reduction of the component metal oxides and simultaneous deposition of the two metals on a tungsten cathode yielded a liquid alloy product. Complementary experiments were performed on the fused fluoride electrowinning of dendritic thorium from Th02 at 1,075° to 1,200° C in which thorium crystals were recovered and arc-melted into buttons. Major contaminants were aluminum, carbon, copper, iron, oxygen, and silicon, totaling 0.2 percent.

Jan 1, 1966

By Albert E. Long

By the USB of X-ray diffraction methods, scientists have learned how the atoms in a diamond crystal are arranged and how the atoms are tied together by chemical bonds. They have found that, even though the bonds between all atoms of the diamond have equal strength, they are so distributed that there are more bonds in certain layers or directions through the crystals than in others. The unequal distribution of the bonds in certain directions creates planes, within the diamond, of unequal strength and resistance to abrasion. The location and disposition of the directions that are relatively harder than the others were determined by Slawson and Kohn 3/ in 1950. By plotting these directions on stereographic projections they delineated the hard regions on the surface of the diamond, but only those trained in the methods of crystallography can readily interpret their diagrams. The principal purpose of this report is to present information that will help individuals without previous training in crystallography to learn to recognize the special features of the surfaces of diamond crystals that are definite guides to the location of the various hard directions of the stones. A crystallographer trained in using various precise laboratory instruments might consider such rudimentary criteria as rather unscientific, but these simple characteristics of diamond crystals are practical clues which anyone equipped with a magnifying lens can find and recognize. The use of the special faces, points, edges, and growth lines as a gui.de in orienting a diamond will allow it to be placed in a position reasonably close to the optimum. Preliminary results of experimental work conducted by the Bureau of Mines indicate that this is all that is necessary in setting diamond-bit crowns. This experimental work demonstrated that setting bits with the hard vectors of the diamond as cutting points greatly reduces the diamond loss and increases the efficiency of the bit.

Jan 1, 1952

By Benjamin W. Haynes

Materials from phosphate rock mining and processing were analyzed for fluorine and uranium content as part of the Bureau of Mines program to more effectively recover resources from mining and mineral processing reject materials. The analysis of both feed and waste materials generated in the beneficiation and acidulation of phosphate rock was performed to obtain information on the disposition and concentration of these elements in phosphate rock processing streams. Fluorine was determined by a distillation-titration method and by ion chromatography. Uranium was determined by the dibenzoylmethane (DBM) method, the reliability being confirmed by roundrobin analysis of samples within Bureau of Mines research centers. National Bureau of Standards (NBS) Standard Reference Material (SRM) 120b-Phosphate Rock was also analyzed for fluorine and uranium to verify procedures and results. Fluorine values ranged from 0.3 wt-pct in gypsum filter cake to 3.7 wt-pct in phosphate rock concentrate. Uranium ranged from less than 5 µg/g in gypsum filter cake to 200 µg/g in a dried clay slime.

Jan 1, 1981

By K. K. Kelley

Thermodynamics data for silicates have applications in the fields of extractive metallurgy, ceramics, and geochemistry. To facilitate these applications, up-to-date tables of heats and free energies of formation are needed. It is the purpose of this report to supply such tables for anhydrous silicates. During the last 15 years the heats of formation of a substantial number of anhydrous silicates have been reliably determined at or near room temperature. This resulted from the development (first by the Bureau of Mines and later by the Geophysical Laboratory of the Carnegie Institution of Washington, by the Institute of Geology of the University of Helsinki, Finland, and by the Department of Geology of the University of Chicago) of accurate solution calorimeters, employing hydrofluoric acid as the reaction medium. Specific references to work of these laboratories will be made in the next section of this report. Also, entropy data at 298.150 K. and high-temperature heat-content values are available for many of these silicates, mainly owing to work of the Bureau of Mines. Most of these entropy and heat-content data have been compiled in Bureau of Mines Bulletins (13, 15).3

Jan 1, 1962

By Rudolf E. Greuer

This study concerns itself with two topics of the mine ventilation - mine fire interface which, when the work for this study began, did not seem to receive sufficient attention. Section 1: Comments on Spontaneous Combustion of Coal in Mines It is attempted to describe heat generation, heat and oxygen transport, in such a way that existing experimental data for U.S. coals can be used to assess conditions inducive to spontaneous heatings quantitatively. Investigated are, in particular, critical air velocities, minimum sizes of coal accumulations, moisture contents and the influence of mining factors. An extensive, practice oriented literature survey is included. Section 2: The Early Detection of Mine Fires by Assessment. of Mine Gases The suitability of the major constituents of combustion products for an early detection of fires is discussed. The same is done for gas concentration ratios. Since it was felt (at least at the time when this report section was written) that the value of the carbon monoxide/oxygen deficiency ratio was overestimated, the usefulness of monitoring this ratio as compared to monitoring CO concentrations was critically investigated. The state of art concerning instrumentation and organization of fire detection systems is reviewed also.

Jan 1, 2011

By T. L. Joseph

"IntroductionThe efficiency of ore reduction in the blast furnace and fuel requirements depend upon the degree of uniformity with which reducing gases can be distributed through the stock column and upon the permeability of individual pieces of ore and sinter. If the ore is fine, the major problem in reduction is to get the ascending gas stream to the surface of the ore-Hard, dense ores of low permeability, mined in coarse sizes, tend to improve the permeability of the bed, but unless they are crushed to the proper size they reach the hearth unreduced.Surveys by the Bureau of Mines have shown conclusively that the gas distribution in the upper three fourths of the furnace is far from ideal. Furnace lines, top design, and methods of charging are important, but more thorough size preparation of the ore is necessary to eliminate size segregation at the stock line, which inevitably leads to non-uniformities in gas distribution.Because of the quantity of sinter now produced close study of the characteristics which determine its behavior in smelting is warranted. As the use of concentrates increases agglomeration will become more of a necessity. Improvements in the physical character of the ore burden are particularly important to plants using coke of poor physical quality. In addition to aiding reduction, improved physical properties of the ore burden will permit the use of higher blast heats, which is equally important.Reduction Tests on Fine Sizes of SinterPrevious reduction tests on minus 0.742— plus 0.525--inch pieces of commercial sinters revealed large differences in porosity and reducibility. The results have been published in a former report. 3 Although the physical properties of the sinter, particularly porosity, were found to be of major importance in determining the rate of deoxidization, it appeared that certain chemical properties of the sinter appreciably retarded the reduction of sinters high in silica. This was attributed to the presence of fayalite, which has been identified by Schwartz and by Luyken and Kraeber4 as an important constituent of sinter. Although furnace operators and metallurgists have assumed that iron silicate is more difficult to reduce than hematite or magnetite, definite data on the reduction characteristics of this material were not available. Tests were undertaken, therefore, to develop a method for de-termining the amount of iron silicate present in sinters so that its effect upon reduction could be observed."

Jun 1, 1934

By Robert J. Evans

Capital and operating costs were estimated using a wet suppression, fabric filter, and a combination system of the two for hypothetical hard rock stone crushing plants located in central Pennsylvania, operating at 300, 600, and 1,000 tons per hour. Fixed capital expenditure for the dust abatement systems ranged from $49,129 to $249,162. Annual operating costs for the dust abatement systems ranged from $8,394 to $46,606 (0.9 to 3.2 cents per ton). If these dust abatement systems are properly sized, installed, and maintained, efficiencies approaching 95 percent can be expected for reduction in weight of dust particles emitted before control.

Jan 1, 1975

By C. F. Davidson

The Bureau of Mines studied the extraction of lithium from lithium-containing clays by chlorination with hydrogen chloride (HC1). In bench-scale laboratory investigations, HC1-H20 mixtures were used to selectively chlorinate lithium, but not calcium or magnesium, in lithium-containing clays. The addition of calcium carbonate to the clay was found to improve the lithium recovery. Reaction conditions found to affect the lithium recovery were ratio of clay to carbonate, reaction temperature, and HC1 concentration. The best conditions for selective chlorination of the lithium were 2:1 clay-carbonate, 750° C, and 20 wt-pct HC1. The experimental results and trends in lithium extraction are explained using thermodynamic relationships.

Jan 1, 1981

By E. G. King

Many of the rare-earth oxides are now commercially available in pure form and they have a variety of potential technical uses. Thermodynamic data for these oxides, however, are rather sparse. It is one of the functions of the Bureau of Mines to fill the need for this type of information. This report gives the results of low-temperature heat-capacity and high-temperature heat-content measurements by the Bureau of Mines of lanthanum sesquioxide. The entropy at 298.15° K. was evaluated and heat-content and entropy increments above 298.15° K. were obtained to 1,800° K. The results were combined with the known heat of formation at 298.15° K. to derive heats and free energies of formation at higher temperatures. Sufficient information is now available to permit reliable thermodynamic calculations involving lanthanum sesquioxide within the temperature range 298° to 2,000° K.

Jan 1, 1961

By Oliver Bowles

Granites are classed as igneous rooks; they have been formed by the solidification of rook magmas or Solutions from deep within the earth. It is an almost invariable law of nature that mamas which cool quickly form fine-brained or glassy rocks, while those that cool slowly are completely crystallized and are coarser-grained. Granites, being of the latter class, are regarded as having attained their solid form at considerable depth below the surface under conditions of high temperature and pressure. The constituent minerals crystallized out slowly, the crystals interlocking with one another. The great depth of overlying rocks that must have been present when crystallization took place has been removed by erosion over large areas on the surface of the earth in consequence of which granites appear at or near the surface in many localities.

Jan 1, 1930

By T. E. Gray

This report describes the preparation characteristics of the significant coalbeds in Harrison County, W. Va. It is one in a series of Federal Bureau of Mines reports planned to determine coals suitable for the production of metallurgical coke, either as mined or after beneficiation. Over 6.5 million tons of coal was produced in Harrison County, W. Va., in 1958, of which over 3.7 million tons was cleaned mechanically in seven preparation plants. All of the coal cleaned was from the Pittsburgh bed. It has been estimated that more than 1,816 million tons of coal remains in the county in beds 12 inches or more thick. The Pittsburgh and Redstone beds were selected by the Bureau for a study based on current production rates and estimated minable reserves. Sample locations were selected following a study of the literature, conferences with mining engineers and mining company officials in the field, and examination of the available sites. Six samples were collected from the Pittsburgh bed, and three samples came from the Redstone bed, Float-and-sink tests of the samples collected from the Pittsburgh and Redstone beds showed that neither coal could be upgraded to a metallurgical fuel under the standards set up for this study, even after intensive preparation. Finer crushing of the samples moderately increased the yields and slightly reduced both the ash and the sulfur contents in the 1.30-specific-gravity float fractions. Finer crushing slightly decreased the yields in the 1.58-specific-gravity float fractions, whereas it reduced the sulfur content 0.11 percent for the Redstone sample and 0.46 for the Pittsburgh sample.

Jan 1, 1961

By John D. Bardill

This report covers the magnetic surveying done in the Plattsburg area , which was part of a general survey, of magnetite deposits in New York State . Other areas being surveyed are the Star Lake district , St. Lawrence County ; Brewster district , Putnam County; and the Sterling district , Orange County. Reconnaissance indicated an area about 3 miles long and 1,200 feet wide , but detailed surveys have been completed on only a portion of that area . In several districts , surveys of this type have served as a basis in the selection of areas for exploration by diamond drilling by the Bureau of Mines .

Jan 1, 1947

By Robert C. Dyni

The use of techniques and equipment designed to pneumatically place backfill into an underground mine opening through boreholes for subsidence abatement has historically met with limited success, largely due to the inability to directly monitor the placement of the backfill in the opening. The success of a backfilling project cannot be guaranteed if it is not known whether the underground opening has been completely filled with backfill material. To overcome the inability to directly monitor backfill placement, the U.S. Bureau of Mines developed a pneumatic backfilling system that allows for direct viewing of the backfill as it is placed in an underground mine opening. This system utilizes a recently developed pneumatic nozzle coupled with an instrumentation package that allows for real-time observations and measurements of backfill placed in an underground opening through a borehole. The nozzle utilizes a high-velocity airstream to redirect backfill falling through a pipe in the borehole and directly in front of the nozzle; the airstream redirects and propels the backfill horizontally into the .mine opening at over 100 ft/s. The instrumentation package, mounted directly to the nozzle, contains a video camera, high-intensity lamps, laser-rangefinder, electronic compass, and water sensor.

Jan 1, 2010

By R. E. Morgan

[IN COMPILING the table of analyses of this bulletin every available source of information was studied. These sources, as listed at the end of the table, were many and varied, and it believed that the tabulation gives the best general information obtainable. However, its known accuracy and completeness of coverage necessarily fall far short of published data on coals of the United States. A table of world production of coal and lignite, as and published by the Bureau of Mine, of world resources of coals, brown coal, and lignite, as published in the Yearbook of the World Power Conference, 1948, are included for convenience of the reader. The six continental maps at the end of the bulletin show the general location of the principal coal fields.]

Jan 1, 1952