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By K. D. Luxbacher

Understanding methane emissions in underground coal mines is critical for a safe and productive mine. In addition to reasonable estimation of initial coalbed reservoir parameters, it is also crucial that changes in effective stress due to mining and pore pressure reduction are taken into account due to their effects on porosity and permeability. Primary parameters for estimation of emissions or modeling of the mining environment for this purpose are porosity and permeability which can change dramatically as a result of stress redistribution associated with mining and gas desorption from a large coal volume. These parameters affect the emission rates and ventilation requirements, as well as water inflow into the working environment. Stopping leakage, on the other hand, is a secondary stress dependent factor in estimation of emissions, as convergence of the roof and floor strata, compromising the integrity of the stopping, may result in leakage, making prediction of ventilation requirements difficult. This paper aims to examine the effects of porosity and permeability changes of the coal seam on methane emissions in an underground continuous miner section. The models were developed and executed in a dynamic fashion to simulate an advancing section. Through this process, the changes of effective stress in coal, particularly their change paths, on porosity and permeability were incorporated into the models and methane emissions, concentrations, air requirements, water inflow and possible leakage from the stoppings were investigated using a conventional coalbed methane reservoir model.

Jan 1, 2009

By R. W. Stahl

Coal mining has been revolutionized by the continuous miner. This machine has replaced, or has combined into 1, 3 former operations: Cutting, blasting, and loading. During the 25-year period before this machine was introduced, advances had been made in transportation, but the actual "coal getting" remained virtually the same. As frequently occurs, the multiple-purpose continuous miner introduced a new hazard--more rapid liberation of methane. The coal output formerly obtained from 10 to 20 working places might now be obtained from 1. It is true that circulation of air was generally increased; but the bulk of this machine virtually precludes continuous flow of air across the face, where gas may accumulate. Apprehension about this possible hazard led the Bureau of Mines to test face atmospheres during operation; and Report of Investigations 5288, Methane Buildup During Cutting and Continuous Mining Operations (published in 1956), presents proof that real danger may be present in many otherwise well ventilated mines.

Jan 1, 1958

By B. B. Letson, D. F. Smith, T. E. Gardner, A. R. Taylor

Low- temperature heat capacities of strontium chloride (7° - 300° K) and strontium fluoride ( 11 ° - 300 ° K) were measured with an adiabatic calorimeter . Smooth values of heat capacity , entropy , enthalpy function , and free - energy function were calculated from the heat - capacity data . The smooth values are reported at 10 ° K intervals and at 273.15 ° and 298.15 ° K.

Jan 1, 1963

By Steven R. Munts

In 1985, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied 8,445 acres of the 20,650-acre Tunnison Mountain Wilderness Study Area in order to evaluate its identified mi nerd 1 resources. The study area is located in Lassen County, CA, about 8 miles northeast from Susanville. No mineral resources were identified in the study area based on literature, field observations, and sample results. No mines were operating in or near the study area in 1985, and no mines, prospects, or claims have been located in or within 1 mi le of the study area. The study area is underlain by Pliocene and Pleistocene volcanic units composed of basalt, andesite, rhyolite, and some pyroclastics. No metallic and only nonmetallic commodities are present in the study area. These included stone and sand and gravel. Although substantial volumes of basalt and andesite (stone) occur within the study area, no identified resources of these commodities were delineated. Sand and gravel is not economic because of small occurrence size and lack of local markets.

Jan 1, 1987

By D. M. Soboroff

Etchants containing hexavalent chromium and sulfuric acid are used in a variety of surface-finishing operations. When the resultant spent solutions are discarded, substantial quantities of chromium are lost and pollution prob¬lems are created. To minimize the undesirable environmental effects while improving metal and minerals recycling technology, the Bureau of Mines is conducting research on a method for the economic inplant recycling of these waste etchants. Trivalent chromium, produced when the etchant reacts with a sub¬strate, is oxidized in the anode chamber of a diaphragm cell; other metals, dissolved during the etching operation, are transferred to the catholyte. When waste brass etchants are treated in this manner, all of the trivalent chromium is oxidized and more than 40 percent of the copper and zinc is removed. Similar copper removal and chromium oxidation are achieved with waste printed circuit board etchants and rinse waters from plastic etching operations. The electrical energy needed to regenerate 1 kg sodium dichromate is less than 9 kwhr. Regenerated brass etchants evaluated by two companies equaled or exceeded the performance of fresh etchants.

Jan 1, 1979

By C. J. Wilhelm, John M. Devine

"Hydrogen aulphide associated with natural as was noted as early as at Point Albino, Canada. 4 The presence of this impurity was recognized also in other of the earlier oil and gas fields, although the occurrence ma by no means common. However, in recent years, with the development of the producing zones of west Texas and the Texas Panhandle the production of ""sour"" crude has increased greatly and hydrogen sulphide has proved a generally troublesome factor-frequently a major problem—in the drilling and operation of any wells in those areas.The problems arising from the drilling and producing of oil or gas wells in hydrogen-sulphide areas, fall under two general divisions: safety problems and corrosion problems. Mention is made of a third division which is closely related to the other two, that of treating--or the development of processes for the removal of hydrogen sulphide. From the standpoint of safety and health hazards, hydrogen sulphide in the petroleum industry has been discussed in a number of publications. 5 Likewise, the problem of hydrogen-sulphide corrosion of production equipment has been given considerable attention in the literature.6"

Sep 1, 1931

By A. R. Rule

This report describes preliminary studies by the Bureau of Mines to develop a procedure for extracting the fluorine from low-grade fluorspar ores in which the CaF2 particles are finely locked in the calcite matrix. A combination of flotation beneficiation and pyrohydrolysis is applied to recover and to liberate the fluorine. Flotation of a finely locked high-calcite fluorspar ore containing only 11.7 pct CaF2 recovered over 92 pct of the fluorspar at a grade of 51 to 52 pct CaF2. Pyrohydrolysis of the flotation concentrate liberated nearly 90 pct of the fluorine as aqueous HF. By this procedure over 80 pct of the fluorine contained in the original ore was extracted.

Jan 1, 1974

By J. W. Eckerd

The crushing of chestnut-size (1-5/8 by 13/16 inch) Pennsylvania anthracite in four commercial crushers (impact) jaw) hammer-mill) and gyratory types) was studied by the Bureau of Mines to determine which could produce the largest proportions of buckwheat Nos. 1 and 2 sizes (9/16 by 3/16 inch). Single pass dry and wet crushing techniques and the effect of stage crushing were evaluated. Calculations were made to show the effect of closed-circuit reduction on production rates and yield of the various sizes. The data show that the gyratory crushers produced the greatest percentage of the desired sizes. A ring-type hammer mill produced the greatest tonnage of buckwheat No.1 and rice (14.9 tons per hr.) during dry grinding tests) but the yield of these sizes was only about 55 percent) as compared with 62 to 70 percent for the gyratory crushers. The impact and jaw crushers produced the smallest amount of buckwheat and rice and the largest quantity of oversize material.

Jan 1, 1960

This manual provides instructions for installing, operating, and maintaining a protective canopy on the Joy Mfg. Co. loader. These instructions are based upon two actual install .at ions: one made in a mine on loader, model 14BU10-11AH, and one in the factory on model 14BU10- 11AH. The parts list and engineering drawings for the protective canopy are included at the end of the manual. And a discussion of some alternative design concepts is also included. The manual can also be used for retrofitting other loaders with similar protective canopies. Skilled mechanics can determine if the instructions herein would be applicable to the other loaders and can determine any necessary modifications if they are not.

Jan 1, 1973

To provide cooler air to miners working in hot areas of mines, particularly new deep hardrock mines. Approach Air supplied to hot working areas of mines is cooled by passing it through a series of water sprays. How It Works Water nozzles mounted inside a section of ventilation tubing release cooling sprays of water into the air being blown through the tube. The prototype of the water spray cooler consists of six evenly spaced water sprays located inside a 10-ft. long section of 16-inch-diameter fiberglass ventilation tubing. See diagram. This section of rigid tubing is installed into one of the positive pressure ventilation tubing lines that conduct fresh air into working stopes. The intake manifold to the six water sprays is connected to the mine?s cool water line, and the water valve on the manifold is opened. Warm ventilation air being supplied to the stope passes through the water sprays, and is cooled by the lower temperature water.

Jan 1, 1979

By James R. Aggson

This Bureau of Mines report presents a finite element analysis of roof stresses associated with a 4-foot-high by 18-foot-wide underground coal mine entry. This analysis starts with known loading conditions determined in an underground coal mine in West Virginia and is extended to other possible underground loading conditions. The roof failures predicted by the finite element analysis under known loading conditions correlate well with the roof failures observed underground. The most probable failure modes are identified for the various loading conditions considered. Various failure preventive measures are discussed.

Jan 1, 1979

By W. L. Cornell

The Missouri lead ores are the only domestic sources of cobalt presently being mined and processed for other materials. They represent the best short-term solution for meeting up to 13 pct of the Nation's strategic and critical cobalt needs from domestic sources. Presently, the cobalt is lost as an impurity in the copper, lead, and zinc concentrates and in the mill tailings because the technology to recover it with minium impact on present production does not exist. This paper presents results of research, built upon earlier Bureau of Mines laboratory research, to enumerate the problems encountered in cobalt recovery from the copper concentrate under actual mill conditions; to present alternative solutions to these problems; and finally, to describe the best available technology for cobalt recovery within the imposed constraints. Mineralogical analyses showed the cobalt present as a distinct mineral phase, predominately siegenite, amenable to a physical separation method such as froth flotation. Flotation was chosen for recovery because of easy adaptation by the mills. Unit processes of grinding, conditioning, and flotation were studied individually and in concert, and a series of continuous tests were run based on the parameters developed to obtain engineering data for subsequent economic analysis. Overall cobalt grades of 3.00 wt pct at a recovery of 64.0 pct were achieved.

Jan 1, 1987

By F. H. Gunnell, W. C. Dunham

"INTRODUCTION The Treasure Hill mines, situated in Dry Canyon, Ophir mining district, Tooele County, Utah, together with several other properties in the district, examined were examined by Frank L. Wideman, an engineer, the Bureau of Mines, in September 1942.In April 1945, development drilling was started on the Treasure Hill mines, which are operated under lease from the Madison Mines Co. The project was continued in 1946 and terminated in 1947.While the Bureau of Mines project was in progress, the Morgan and Fullion tunnel workings were surveyed by Bureau engineers.ACKNOWKEDGEMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy, It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual investigative perk, and prepares the final report. The Branch, O. C. Ralston, chief, analyzes samples and performs beneficiation tests. The work here described was under the direct supervision of Paul T. Allsman, chief, Salt Lake City Division, Mining Branch."

Jan 1, 1948

By Ann G. Kim, Thomas R. Justin, John F. Miller

The U.S. Bureau of Mines applied its mine fire diagnostic method to an abandoned anthracite mine fire site in Carbondale, Lackawanna County, PA. The technique to locate fires in abandoned coal mines and coal refuse piles includes the determination of hydrocarbon concentrations in mine gases, the imposition of an underground gas flow direction, and use of a surface mapping method, to define heated and cold zones in underground coal strata. The heated zones at Carbondale were characterized by elevated methane concentrations. The results of 25 communication tests were analyzed to define 2 large (approximately 100 by 250 ft) and 5 small, isolated heated zones. An approximate correlation existed between the location of the heated zones and areas of anomalous snow melt. The correlation between the results of the diagnostic test and subsurface temperatures was not significant.

Jan 1, 1992

By Mark Sanders

This report compares a proposed 10/60 "piggyback" 02 generating self-rescue unit to the standard CO self-rescue unit with respect to work task interference. A simulated low seam coal mine was constructed and subjects performed locomotion, shoveling, cart pushing, and timbering tasks with the 10/60 or self-rescuer attached to their belts. Task completion time was longer on all tasks when wearing the 10/60 unit, although only locomotion was statistically significant. The 10/60 unit was bumped over 100% more often than the standard self-rescuer. Implications for design of the proposed 10/60 container are: 1) unit?s container must be extra durable to withstand the added abuse it is likely to receive by low coal miners; and 2) extra consideration must be given to preventing the device from slipping on the belt while working, especially in low coal.

Jan 1, 1980

By Joseph E. Matta, John C. LaScola, Fred N. Kissell

The Bureau of Mines investigated coal storage silos to determine how gassy coal must be for methane accumulations in a silo to become hazardous and where such accumulations are likely to occur. Methane concentrations were measured in the open space above the stored coal pile, in the pile, and in the reclaiming area. No methane layering was found in closed-top silos. Reclaiming areas were as gassy as the top part of the silos. Coal samples were collected from the conveyors entering the silos in order to assess the gassiness of the coal. No simple correlation was found between the gassiness of the coal stored and the measured methane concentrations. However, at mines where the average 24-hour gas emission from the conveyor belt samples was 14 ft3/ton or more, fans or open tops were used. It appears that a large fraction of the methane released during storage remains in the void space between the coal particles.

Jan 1, 1981

By Frank J. Wiebelt, Spangler Ricker

"INTRODUCTION Bauxite, in Appalachian Alabama, occurs in the Rock Run and Goshen Valley districts in Cherokee County; in Nences Creek Valley near Jacksonville; near Anniston in Calhoun County; north of Fort Payne in DeKalb County; near Ashville in St. Clair County; and near Talladega in Talladega County.In February 1942, Preston E. Cloud, Jr., assistant geologist, Federal Geological Survey, began a study of these bauxite deposits and the geology relating thereto.The Bureau of Mines established field headquarters at Piedmont, Calhoun County, in July 1942. Mineral agreements covering a total of 11,097 acres were executed with 15 landowners in the Rock Run district; 38 in the Goshen Valley district, covering 7,575.5 acres; and 3 in the Nances Creek Valley district, covering 988.5 acres. Drilling was done on.the properties of 9 land¬owners in the Rock Run district, and on the property of 1 landowner each in the Goshen Valley and the Nances Creek districts. Drilling began October 26, 1942, and ceased on May 17, 1943.Power drilling was supplemented by a labor crew that drilled hand-auger holes in shallow deposits and sampled .old shafts, mines, and mine dumps.In all, 222 holes for a total of 13,250 feet were drilled. Of these toles, 88 penetrated bauxite but too low in grade to constitute ore."

Mar 1, 1948

By J. G. Donaldson

Cobalt-tungsten binary deposits were formed in laboratory experiments by hydrogen reduction of the anhydrous mixed vapors of cobaltous chloride and tungsten hexachloride. The materials were sublimed in seperately heated zones of reaction tube and were transported in a stream of purified helium into the deposition section of the tube where the chloride gases were reduced to metal by a countercurrent flow of hydrogen. Heattreating of the near stoichiometric binary metallic deposits converted nearly all to the intermetallic compound Co3W, however, small quantities of both cobalt and tungsten remained. Mechanical tests showed that the tensile strength of heat-treated 75 percent cobalt-25 percent tungsten deposits was twice as high as that of similarly treated deposits of cobalt.

Jan 1, 1965

By J. E. Doo1ey

To process and use the heavy ends of petroleum effectively, the development of suitable separation and characterization procedures not currently available was required. A systematic procedure was developed by the Bureau of Mines using such techniques as isothermal and molecular distillation, chemical treatment, silica-alumina gel chromatography, gel permeation chromatography, and spectrometry. Using these techniques, the Bureau achieved a detailed separation and characterization of a 370° to 535° C distillate from Gach Saran, Iran, crude oil. Such a systematic procedure and the semiquantitative data resulting therefrom should be of value in selecting feedstocks and in optimizing petroleum processing operations.

Jan 1, 1973

Provide an environmentally compatible means of producing lead from galena concentrates that replaces the current high-temperature pyrometallurgical primary lead smelting process and supplies pure lead metal within present and proposed Environmental Protection Agency (FPA) and Occupational Safety and Health Administration (OSHA) lead emission standards. Approach The U.S. Bureau of Mines developed an energy efficient and pollution-free leach-electrowinning method for use in recovering pure lead metal and byproducts from lead sulfide concentrates.

Jan 1, 1989