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By JOSEPH F. CULLEN, Dorsey A. Lyon

In connection with its investigation looking to the prevention of waste and the increase of safety and efficiency in the mineral indus- tries the Bureau of Mines has undertaken a study of the possible uses of the electric furnace in metallurgy. This bulletin presents a com- pilation of such data as seem to be useful for the information of persons who may be interested in the matter. In the application of electricity to metallurgy three kinds of processes are involved, namely, mechanical, thermal, and electrolytic. Under the mechanical application of electricity come those proc- esses of dressing and concentrating ores that are known as either electrostatic or electromagnetic processes. In electrothermic processes the current is used as a source of heat. The fundamental differences between the various types of electric furnace that are at present in commercial use relate to the manner in which the electric current is applied, as may be noted by reference to that part of this report in which the subject is discussed. In electrolytic processes the electric current is used for depositing metals from solutions. The process may be conducted in one of the following ways: (1) The material to be treated may be put into solu- tion and then electrolyzed, the material thus treated forming the electrolyte; (2) the material to be treated may form the anode or be placed in contact with the anode; or (3) the material to be treated may form the cathode or be placed in contact with the cathode. This report treats of electrothermic processes, with the possible exception of those for the reduction of aluminum from its ores. Moreover, of the processes used in the so-called electrochemical in- dustries only those for the reduction of an ore to metal, or to a com- pound of the metal that is of value in itself, or is an aid in metallurgical work, are here discussed.

Jan 1, 1914

By D. S. DeLong, A. Giza, D. G. Fraser, V. A. Robinson, T. B. Whitmoyer, J. E. Sneckenberger

"A cotton dust animal exposure system has been modified to incorporate a microcomputer feedback loop to monitor particle concentrations. The loop's major components are a minature real-time aerosol monitor (miniram) to estimate concentrations and a microcomputer to read the miniram's data and to control a stepper motor that adjusts the amount of dilutant air mixing with respirable cotton dust. Ninety minute trials of this system indicate that the standard deviation of particle concentrations is within 0.68 Mg/m3 of the average concentration, insuring a near constant concentration of respirable dust throughout the exposure.INTRODUCTION Previous workWeyel et al. (1984) have determined that respirable cotton dust can be shaken from bulk cotton samples using acoustical energy. The particle generator designed to utilize this fact operates like a commercially available sonic sifter, but on a much larger scale.While this generator successfully resuspended trapped respirable cotton dust, the generator output concentration decreased exponentially with time. This disadvantage was solved by Frazer et al. (1986) by operating the generator with a sinusoidal voltage near the minimum resonance frequency of the generator. This adjustment enabled the generator to produce respirable cotton dust for six hours or longer.Frazer et al. (1987) utilized the modified acoustical generator to produce a cotton dust animal exposure system. The cotton dust concentrations were estimated by a miniram, a light scattering aerosol Monitor. The system operator used the miniram values to adjust the system's parameters to maintain the desired concentration level.PurposeThe objective of this study was to introduce a computerized feedback loop to the operator controlled cotton dust animal exposure system. The miniram's estimates were analyzed by a microcomputer to determine what adjustments in the flow of dilutant air were necessary to maintain the desired cotton dust concentration. These modifications were intended to improve system performance and ease the system operator's work burden."

Jan 1, 1988

By F. J. Perzak

The Bureau of Mines conducted a flammability study of plastic ventilation ducts. Six rigid 16-in-diam fiberglass-reinforced plastic ducts from five manufacturers were examined using laboratory-scale, large-scale, and full-scale fire tests. The laboratory-scale tests included the American Society for Testing and Materials E162 radiant panel test, the E2863 oxygen index test, and the standardized small-scale flammability test (S3FT) developed by the Mine Safety and Health Administration (MSHA), U.S. Department of Labor, and replicated by the Bureau of Mines. Ten-foot lengths of the same ducts were also subjected to a large-scale vertical fire test, and 20-to 30-ft lengths were tested in a full-scale in-mine fire test at the Bureau's Lake Lynn Laboratory mine. The data from the laboratory-scale radiant panel test and oxygen index test indicated that the ducts were fire-resistant, However, five of the six ducts failed the S3FT and vertical fire tests, and four of the ducts failed the full-scale in-mine tests with flame propagation rates that ranged from 3 to 10 ft/min. The results indicate the need for improved fire-resistant plastic ducts. The good agreement between the S3FT re-sults and the vertical and full-scale tests show that the S3FT provides a good indication of the flammability of fiberglass-reinforced plastic ducting under realistic fire conditions.

Jan 1, 1987

By Jr. Kauffman

The data contained in this report were obtained incidental to the Bureau of Mine's investigation of the lime-soda sinter process as applied to the recovery of alumina from siliceous bauxite, kaolin, and other high aluminous materials. The Bureau of Mines was charged by Congress to investigate processes for the production of aluminum from domestic low-grade ores. The Eastern Experiment Station at College Park, Md., conducted laboratory and pilot-plant investigations of the recover-y of alumina by the lime-soda sinter process. Reports by the College Park staff covering the recovery of alumina from these sources have been published. The lime-soda sinter process involves the sintering of the finely ground siliceous bauxite or clay with limestone and soda ash in a rotary kiln. During the sintering the alumina supposedly reacts with the soda ash to form soluble sodium aluminate and the silica combines with the lime to form the insoluble orthosilicate. In the early stages of the investigation it was considered desirable to know the temperatures at which the phase changes occurred during the sintering operation. The total time involved in the passage of any given portion of the charge through the kiln was 28 minutes. The exposure time of the charge to temperatures above 600° C. (decomposition temperature of kaolinite) was, roughly, half the total. The exposure to the full temperature of the kiln, 1,100° C was only 3 minutes. (Subsequently, the maximum kiln temperature and retention time were increased.)

Jan 1, 1949

By E. D. Gardner

About five minutes after 3 o'clock on Thanksgiving morning, November 24, 1927, smoke was discovered coming up No. 2 shaft of the Magma Copper Co.'s mine at Superior, Pinal County, Arizona. Of the 49 men in the mine at the time, 42 were able to make their way to the outside unassisted, but 7 perished. Six bodies were recovered, and the seventh, that of an Apache Indian cage-tender at No. 2 shaft, is thought to be in the caved section between the 1,600 and 2,250 foot levels A second and independent fire broke, out in No. 1 shift about 2 a.m., November 27, burning .out the shaft timbers from the surface to the 200-foot level and destroying the surface fan and structures. About 20 men were underground fighting the fire in No. 2 shaft, but all were safely withdrawn, aril the fire in No. 1 haft was quickly controlled.

Jan 1, 1928

By T. Christos

The explosive oils, nitroglycerin (NG) and ethylene glycol dinitrate (EGDN), were extracted from dynamites by a halocarbon solvent and were then determined by high-pressure liquid chromatography. Separation was achieved by liquid-liquid chromatography on a column packed with Durapak-Carbowax 400/Corasil II and the eluted NG and EGDN were detected with a double-beam ultraviolet detector.

Jan 1, 1973

By M. F. Chambers

The U.S. Bureau of Mines conducted experiments on electrowinning of neodymium metal by using a molten-metal cathode at 650° C and an electrolyte of 50 mol pct NdCl3 (neodymium chloride) and 50 mol pct KCI (potassium chloride). The molten-metal cathodes were alloys of magnesium and zinc or magnesium and cadmium. Current efficiencies were 90 pct with a Mg-Zn cathode and 80 pct with a Mg-Cd cathode; The Mg-Cd cathode was easily separated from the electrolyte. In contrast, the Mg-Zn cathode tended to mix with the electrolyte, making separation difficult. The cathode metals were separated from the neodymium by distillation at 1,100° C under a vacuum of 10-3 torr. Neodymium metal of 99.9+ purity was recovered from the Mg-Cd alloy cathode after 30 min distillation time. The neodymium recovered from the Mg-Zn system contained almost 2 pct Zn after vacuum distillation. Continuous operation using the Mg-Cd alloy cathode was demonstrated.

Jan 1, 2010

By Oliver Bowles

"Asbestos" is not the name of a distinct mineral species but is rather a commercial term applied to fibrous varieties of several minerals. The origin and significance of names applied to asbestos by early writers are discussed in the section devoted to sources of supply and terms employed in ancient times. VARIETIES The most useful variety of asbestos is chrysotile, a fibrous serpentine the composition of which is expressed by the formula H4Mg3Si209. Chrysotile is characterized by a strength and flexibility that permit the use of the longer fibers for spinning. The bulk of the world production of both long and short fibers, is of this variety.

Jan 1, 1935

By C. W. Schultz

The vapor pressure of manganese in equilibrium with a series of liquid iron-manganese alloys was determined by the carrier gas method over a broad range of alloy composition. From these data the activities of manganese in the iron-manganese system were calculated. The system appears to be ideal.

Jan 1, 1966

By R. Hogg, T. F. Dumm

"It is generally agreed that dust characteristics play a role in the development of Coal Workers' Pneumoconiosis (CWP). Unfortunately, there is a serious lack of information on what the characteristics of mine dust actually are and how they vary among different mining regions, coal seams, etc. This paucity of data can generally be attributed to the serious problems encountered in collecting sufficiently large quantities of dust for conventional analytical procedures.Personal samplers are widely used in coal mines for regulatory and enforcement purposes. Generally, these provide information only on the total (respirable) dust loading in the mine atmosphere and on the mineral matter (primarily quartz) content of the respirable dust. A procedure has been developed by which samples collected with a slightly modified personal sampler can be analyzed for particle size distribution, total mineral matter content and elemental composition, in addition to the standard mass and quartz measurements. These analyses could readily be performed on a routine basis. Shape analysis by Scanning Electron Microscope (SEM) could easily be included if appropriate shape criteria are established. Extension of the procedure to include the determination of complete size/specific gravity (composition) distributions is quite straightforward provided sufficiently large samples (at least 10 mg) can be collected. Typical sample sizes for a personal sampler carried by a miner for one shift range from about 0.5 to 2 mg.The basic procedure was developed and evaluated using synthetic mine dust prepared in the laboratory. Field tests in three working mines in Pennsylvania and West Virginia have confirmed the applicability of the approach to the real world. Particle size distribution measurements on mine dust collected in the modified personal sampler were found to agree closely with the results of simultaneous in situ measurements obtained using cascade impactors."

Mar 1, 1989

Case 1: A driller-helper was pulling a winch cable toward a stack of drill steel when the cable contacted a 12,000-volt power line. The helper was killed, and the driller at the rig controls was severely injured. [ ] Case 2: A crew was preparing to remove a pump from a well when the hoist boom contacted a 4160-volt power line. The hoist operator was electrocuted. [ ]

Jan 1, 2005

By John B. Gayle

The probable inadequacy of physical tests of coke for the purposes for which they are made has been a subject for discussion for many years. However, little has been published in this connection, even though most workers in the field believe that the physical properties of coke are of major importance in its utilization in the steel and allied industries. In fact, the reproducibility of the recognized tests is largely unknown or can only be approximated. This situation occasions many difficulties when attempts are made to judge the coke-production qualities of various coals or coal blends. During World War II the Coke Production Committee, composed of representatives from industry and the Solid Fuels Administration, concluded that study of existing testing methods and possible improvements would be of material assistance in answering questions relating to coke quality. Since that time the Bureau of Mines has taken samples of coke produced in industrial slot-type coke ovens in connection with studies aimed at extending coking-coal reserves by adding to the list of sources known to be suitable for this purpose. Testing procedures on these cokes were arranged so that the data obtained would yield information on (1) the degree of precision of tests commonly used in the industry, (2) the causes of the known poor reproducibility in several of the physical tests, and (3) possible improvements or modifications of existing physical testing procedures.

Jan 1, 1953

By J. R. Ross

The extraction and recovery of nitrate from waste solutions generated in the production of titanium were investigated using solvent extraction techniques. Laboratory studies and continuous tests in a small solvent-extraction system showed that up to 98 percent of the nitrate can be selectively extracted by a solution of tributyl phosphate in kerosine. The extracted nitrate can be recovered as nitric acid, at concentrations suitable for reuse, by stripping the loaded organic with water.

Jan 1, 1973

By S. A. N. Sheya

Many gold-bearing ores in the Western United States also contain small amounts of mercury. The presence of mercury creates potential pollution and health hazards during several steps in gold processing. An investigation was undertaken by the Bureau of Mines to develop techniques for removing mercury from cyanide mill solutions by selective electrowinning to reduce the potential hazards. Sixty-five percent of the mercury was selectively electrowon from synthetic carbon strip solution at applied potentials of 1.00 to 1.50 V when using a mercury-coated platinum or copper plate cathode. Increasing the active surface area by using mercury-coated copper wool resulted in up to % pct of the mercury being electrowon from mill carbon strip solutions that contained 1.9 to 20 ppm Hg, 20 to 345 ppm Au, and 0.35 to 39.5 ppm Ag. About 98 pct of the silver was electrowon with the mercury onto the mercury cathode. Gold extraction ranged between 0 and 20 pet. Results of the investigation showed that choice of cathode material was critical to the success of the process. Selectivity was not achieved using uncoated steel wool cathodes.

Jan 1, 1988

By W. H. Ode, W. A. Selvig

Low-temperature distillation tests at 200°, 350°, and 500° C. were made on a subbituminous coal from Boulder County, Colo., and a subbituminous coal from Weld County Colo., in connection with a survey of carbonizing properties of American coals 4/ and investigations of their chemical and physical properties. 5/ The coal represented by the sample from Weld County was reported to give off combustible volatile matter at unusually low temperatures when placed on a fuel bed. The yields of tar and oil and the composition of the as from this coal, as obtained in the distillation tests, did not confirm this report. These yields and the gas composition of the Weld County coal differed but little from those obtained from the coal from Boulder County. Both coals yielded tar and gas in amounts considered to be normal for coals of their rank.

May 1, 1937

By F. Fraas, J. E. Conley

"The problem of recovering potash from the mineral polyhalite (K2SO4.MgSO4.2CaSO4.2H2O), occurring in large quantities in the salt beds of Texas and New Mexico, has been under investigation at the Nonmetallic Minerals Experiment Station of the U. S. Bureau of Mines continuously since 1928. Most of the results previously obtained have been published in technical journals and in a series of Bureau of Mines Reports of Investigations.The experiments described in the present report were performed to ascertain whether a continuous countercurrent extraction of calcined polyhalite by hot water would yield satisfactory recoveries and concentrations of sium sulphate in the top liquor. Previous investigation by Storch 4 had shown that the rate of solution of uncalcined polyhalite was too slow to be of value in an industrial process, and Storch and Clarke 5 had demonstrated that calcination of the polyhalite greatly, accelerated the rate of solution in hot water, allowing most of the potassium sulphate to be readily extracted."

Sep 1, 1933

By J. M. Kuchta

The chemical and thermal criteria used for predicting the spontaneous combustion hazard are briefly reviewed and data are presented to characterize the gas desorptions and self-heating tendencies of 29 U.S. coals. Closed vessel desorption experiments showed that CO, CO2, and CH4 are the main gases evolved and that the CO, CO/?O2 index, and 02 absorption rate increase with decreasing rank and increasing oxygen content of the coal. In this Bureau of Mines report, the effects of temperature, moisture, and other variables are discussed together with the application of the data to the complex conditions encountered in a mining environment. An important finding is that the presence of CO alone in a mine is not necessarily an indication of a self-heating reaction of the coal. Based upon experiments conducted in an adiabatic-type calorimeter, the self-heating temperatures of lignite and subbituminous coals can be as low as 30° C, whereas the bituminous coals require a temperature of about 60° C or more. The self-heating hazard is greatest when the coals are dried and exposed to a high humidity condition, apparently as a result of the "heat-of-wetting." Generally, the hazard is greatest with the western coals of the United States.

Jan 1, 1980

By E. P. Youngman

This paper presents one of a series of digests of foreign mining legislation and court decisions that is being prepared in advance of a general report relative, to the rights of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of the mining laws of British Guiana has been prepared from the best available sources in Washington and is, released subject to amplification and correction, if necessary, by United States foreign-service officials. INTRODUCTION The sources of information available in the preparation of this paper are the following: 1. The Crown lands ordinance, No. 32 of 1903, September 26, 1903.

Jan 1, 1934

By B. L. Razzaboni, P. Bolsaitis

"The formation of reactive oxygen species resulting from the interaction of silica dust particles with red blood cell membranes was investigated; particularly, the effect of surface hydroxyl (silanol) group concentration on the rate of formation of such reactive oxygen species was investigated. The rate of formation was measured indirectly through the effect of catalase, a hemoprotein peroxidase, on silica-induced hemolysis. It was found that the addition of exogenous catalase to erythrocytes markedly reduces the hemolysis caused by silica particles. Furthermore, the amount of catalase required for deactivation of silica per unit area of particle surface is lower for fumed silica particles and calcined crystalline particles than for uncalcined, crystalline silica, suggesting a correlation between the concentration of OH groups at the silica particle surface and its potential for generation of H2O 2• The addition of albumin, a copper chelator, also decreases hemolysis. These results suggest that the hemolysis caused by silica particles is at least partly related to the formation of H2O2 at the particle surface and its subsequent reaction with Cu+ ions. The relationship between the concentration of surface silanol groups on the silica surface and the amount of catalase required to decrease hemolysis may also provide a method for testing potential fibrogenicity of respirable dusts. IntroductionReactive hydroxyl groups on silica surfaces are known to be cytotoxic and are believed to play a major role in silicosis (1-9). It has been proposed that this cytotoxicity results from hydrogen bonding to cell membranes and a resulting increase in membrane fluidity and permeability (4). Surface hydroxyl groups on silica surfaces have also been shown to interact with carbonyl oxygens in cell membranes (1,5). An extensive study by Nolan et al. (6) of the relationship between the negative surface charge resulting from ionized silanol groups and the hemolytic activity of crystalline a-quartz (Min-U-Sil) has shown a positive correlation between hemolytic activity and the surface concentration of silanol groups. These authors demonstrated that the hydrogen bonding of polyvinyl-N-oxide (PVPNO) with silanol groups, as well as the bonding of metal cations to the ionized sm- groups, results in significant decreases in hemolytic activity. Furthermore, it has been found that the complete removal of surface hydroxyl groups from the surface of respirable silica particles nearly eliminates the hemolytic potential of silica (7), suggesting that hydroxyl groups might be involved in other cytotoxic processes associated with silica-induced lung injury. Reactive oxygen species have been .implicated in cellular damage caused by respirable silica particles. Evidence for the presence .of oxygen radical species (02, OH°, H2O2) generated by silica, especially on freshly formed surfaces, has been produced by various investigators. Kalbanev et al. (8) detected H2O 2 in aqueous suspensions of quartz. Electron spin resonance and spin trapping by Shi et al. (9) confirmed the presence of OH"" radicals in aqueous suspensions of quartz, and Gulumian and van Wyk (10) suggested that both glass and quartz produce hydroxyl radicals in the presence of H2O 2 • Gabor et al. (11) detected the presence of malondialdehydereactive lipid peroxides (i.e., lipid-0°) in cultures of macrophages and respirable silica particles using the thiobarbituric acid (TBA) reaction test. Will (12), however, reported that iron enhances the TBA value of peroxidized lipids, and Scheulen and Kappus (19) found that catalase augmented malondialdehyde formation, thereby increasing the TBA values."

Jan 1, 1990

By John Henderson

If you missed this year?s Texas State Holmes Safety Association meeting, you missed a great one. On January 23 & 24, 2009, we held the meeting that was rescheduled when Hurricane Ike threatened Corpus Christi in September 2008. Sixty-five persons from across the state attended the meeting held at the Holiday Inn Emerald Beach. The weather was 82 degrees, and the sky was clear and perfect for a safety meeting. Evaluations submitted by the attendees gave the presentations, the networking, and even the food top marks. There were eight councils represented; Big Country, Central Texas, Costal Bend, Heart of Texas, Hill Country, North Texas and North Central. Presentations included Workplace Examinations, Emergency Preparedness, Screen Safety, Contractor Responsibilities, Powered Haulage, Supervising for Safety, and Basic Inspections of Slings and Rigging. Mr. Edward Lopez, SC MSHA District Manager, gave the State of the District Address.

Jan 1, 2009