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By L. B. Berger

Studies showing the effect of mixing hot exhaust gases with tie intake air of a four-stroke-cycle Diesel engine are described. The results indicate a marked increase in carbon monoxide in tip exhaust gases, a decrease in oxides of nitrogen, and no significant effect on aldehydes. The increase in carbon monoxide was greater at higher fuel-air ratios and was caused partly by the increase in fuel-air ratio end partly by the decrease in oxygen concentration resulting when exhaust has was added. The application of these results to the use of Diesel engines underground is considered.

Jan 1, 1940

By W. L. Cornell

The Missouri Pb ores are the only domestic Co resource being mined and processed for other metals; therefore, they present a viable short-term opportunity for Co production. Lead, zinc, and copper concentrates are produced from the ore. The Cu concentrate can contain up to 30 pct Co and the Pb concentrate up to 15 pct Co. Since Co is detrimental to the processing of the Zn concentrate; the remainder of the Co is rejected to the tailings. The tailings can contain as much as 50 pet Co originally present in the mined ore. Researchers at the U.S. Bureau of Mines have successfully tested on a continuous basis a process that recovers a bulk sulfide concentrate from mill tailings. The concentrate contains up to one-half of the Co and from 50 to 90 pct of the Pb, Zn, and Cu. Concentrate weight represents 10 pet or less of the total tailings.

Jan 1, 1989

By Richard J. Mainiero

The Bureau of Mines has developed a prototype nonincendive explosive rock-breaker charge that can be fired unconfined in underground bituminous coal mines without the danger of igniting a flammable atmosphere that might be present. At present, unconfined shooting in underground coal mines is prohibited, but there are situations where the use of such shots would yield an overall improvement in safety. The charge consists of 1-1/2 lb of permissible water gel explosive in the form of a short cylinder 7 inches in diameter and 7/8 inches high, surrounded by a 1 1/2-inch-thick layer of damp salt, and encased in latex rubber reinforced with cheese cloth. The latex rubber housing provides a charge package that is strong enough to resist rough handling yet is pliable enough to conform to an irregular stone surface. A charge of this shape was found to be more effective at breaking rock than charges with lined or unlined cavities. Incendivity tests in a gallery have shown that the prototype charge will not ignite a flammable methane-air atmosphere when fired. Rock- breaking tests made with limestone boulders indicate that the charge will satisfactorily break stone slabs weighing 1 to 2 tons, and that two or more charges might be effective for slabs weighing up to 10 tons. In cooperation with the Mine Safety and Health Administration (MSHA), a test protocol for the certification of these charges as "permissible" for use in flammable atmospheres is being developed.

Jan 1, 1982

By D. W. Frommer

As one phase of a general problem of recovering sulfide slimes, mineral-dressing research was conducted on flotation tailing from the St. Joseph Lead Co., Bonne Terre, Mo., mill to recover a significant portion of the residual, finely divided galena. Production of a high-grade concentrate was not part of the immediate objective. Only a reasonable ratio of concentration of lead sulfide slime was sought, since the problem of upgrading by mechanical or extractive processes would be considered in the later stages of this study. The results show that, from a feed material averaging 0.20 percent lead (about 70 percent finer than 400-mesh), a recovery of up to 45 percent could be effected by flotation in rougher concentrate analyzing up to 6.5 percent Pb. These results were obtained by using larger quantities of various xanthates and sodium sulfide than used customarily in mills. Sodium sulfide, which is ordinarily detrimental to flotation of galena, was beneficial in this case.

Jan 1, 1959

By Van E. Shaw, D. J. Bauer

Conversion of euxenite concentrate to sulfates with sulfuric acid and solvent extraction of the yttrium- rare - earth mixture with EHPA were studied to determine extraction and separation characteristics . Digestion with 3.5 pounds of 96 percent sulfuric acid per pound of concentrate at 336 ° C for 4 hours resulted in an easily handled product with a yield in excess of 98 per- A thorium- free product was obtained by calcining the sulfated material for 3.5 hours at 650 ° C prior to leaching with water . Di ( 2 - ethylhexyl ) phosphoric acid solvent is an effective extractant with preference for cerium ( IV ) and heavy - group rare - earth elements including yttrium . Separation of complex rare - earth mixtures into light- and heavy - group fractions is feasible , and these fractions can be further processed to isolate ytterbium , neodymium , and dysprosium by changing processing conditions to obtain separation factors greater than two between these and adjacent elements .

Jan 1, 1965

By L. E. Schultze

The Bureau of Mines devised a technique to recover a Zn-Pb concen-trate from a geothermal brine. More than 99 pct of the Zn and Ph was precipitated by treating the brine with H2S and controlling the pH with lime. Recycle of the sulfide precipitates increased crystal size and resulted in easily filterable products. A typical sulfide precipitate contained 53 pct ZnS, 8 pet PbS, 24 pct MnS, and 15 pct FeS. Addition of sulfide as FeS or CaS was not effective in precipitating Zn and Pb, but Zn in the brine was selectively removed with a strongly basic ion-exchange resin. A proposed flowsheet for metals recovery is discussed.

Jan 1, 1985

By Robert F. Droullard

The Bureau of Mines has investigated techniques of using gross alpha or beta detectors to continuously measure working levels. Both methods measure radioactive particulates collected on a filter paper using a constant airflow. Inherent-error studies indicate a value of about ±3 percent for the gross alpha method and about ±8 percent for the beta method in typical mine atmospheres. However, the beta method avoids problems associated with alpha detectors and is therefore more useful. Applications of these continuous working-level detectors include work area monitoring of exposure levels in underground openings, such as mines and caves, and calibrating personal dosimeters exposed over extended time intervals.

Jan 1, 1977

By Bernard J. Steblay

Two instruments have been constructed that extend microseismic data collection and processing capability for Bureau of Mines research in rock burst, coal bounce and outburst, and roof fall monitoring. The first instrument is a 13-channel tape-triggering system. This system allows better utilization of instrumentation tape recorders by collecting data digitally, turning the tape on only when valid data are present, and increasing the dynamic range of the recorder by using digital data. A digital-to-analog converter is used to provide analog output of the recorded digital data. The instrument records a much larger time slice of transient events than do current commercial devices. The second instrument is a microseismic energy measurement device. This device uses recent developments In integrated circuits to overcome the dynamic range and accuracy limitations of previous instruments. The analog signal is converted to a digital one, and then high-speed multiplication techniques are used to square the amplitude value in real time and integrate it.

Jan 1, 1983

By R. H. Church, William E. Webb, Walter E. Pittman, James R. Boyle

As part of the Bureau of Mines health and safety research program, a short-range locator system, capable of locating miners who have become trapped following a mine accident, has been devised, The system consists of a lightweight, low-power radio transmitter incorporated into a miner's cap lamp battery and a directional receiver carried by rescuers. Prototype transmitters have been constructed, and the propagation of their signals has been investigated, The detectability of the signal in underground coal mines has also been investigated, This research indicates that a short-range location system would serve as an economical and practical means of locating miners from within the mine following an accident,

Jan 1, 1984

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) spin trapping methodology has been used to study the reactions of manganese dusts with glutathione, employing a-{4-pyridyl-1-oxide)·N-tert-butyl-nitrone (PBN) and 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as spin traps. The results show evidence for the glutathionyl radical formation in the reactions of both MnO2 and manganese (Ill) acetate with glutathione. Based on these experimental observations, we hypothesise that the mechanism of neurotoxic effects of manganese might be due to the fact that the generation of glutathionyl radicals depletes the glutathione pool and reduces the glutathione shield against free radical products of dopamine metabolism and manganese induced reactive oxygenated species. IntroductionExposure to manganese compounds often occurs as the result of foundries and mining operations (1. 2). Other significant sources of environmental manganese include coal-fired power plants and burning of residual and crude oil (3, 4). Lately gasoline combustion has also started to contribute since manganese (methyl cyclopentadienyl manganese tricarbonyl. 0. 125 g/gallon) is being used instead of lead as an antiknock ingredient in automobile fuels (5. 6). Although manganese is an essential element in certain biological processes it is toxic in excessive amounts. The manganese toxicity is mainly associated with the nervous system (7-9). Symptoms frequently observed in manganese poisoning or manganism are disorientation, memory loss, anxiety, compulsive laughing and crying, mask-like faces, akincsia rigidity and tremor (10). In spite of numerous investigations to understand the mechanism of manganese induced injury. it has not been possible to localize the initial chemical lesion responsible for altered physiology and ultimate cell death. This may perhaps he the reason for failure in developing a successful therapy for manganese intoxication."

Jan 1, 1990

By Karl-Heinz Frohne

This report presents the findings of a study of a portion of the Clover-Rush Run oilfield located in Roane County, W. Va. The study was made to investigate the possibilities of secondary oil recovery in the Big Injun sandstone underlying the William Kaufman lease. Reservoir properties, original reserves, and primary oil recovery are also presented. The investigation is based on a core analysis and related laboratory tests, well records, field production data, and subsurface information from the Kaufman property. A theoretical primary oil recovery of 9.7 percent of original oil in place is predicted for the reservoir. A waterflood performance prediction of a hypothetical pilot area was made by use of a computer. The prediction showed that, based on laboratory oil water relative permeability curves, the water-injection time needed to initiate oil production is excessive and that the stabilized water-injection and corresponding oil-production rates are very low. This precludes waterflooding the reservoir on an economic basis. A prediction for secondary oil recovery by gas injection was attempted but could not be completed because essential reservoir data were not available. In July 1965, the lease operator initiated, and is currently conducting, a gas-injection program, but there had been no increase in oil production up to November 1966.

Jan 1, 1967

By John W. Cole

As part of a general preliminary investigation of lead-zinc deposits in Stevens County, Wash., the Electric Point and Gladstone mines on Gladstone Mountain, in the Northport Mining District, were examined by R. M. Gammell, an engineer of the Bureau of Mines, in June 1946. A trenching and sampling program was executed later the same year under' the supervision of Miro Mihelich and the author. This report presents the factual data obtained from the trenching and sampling operations.

Jan 1, 1949

By Arnold B. Hubbard

This report presents a hydrogenolysis study undertaken to obtain information on the constitution of the kerogen or organic material in Colorado oil shale and to determine some of the properties of the hydrogenolysis products. The high yield of hydrogenolysis products was separated, so far as possible, into type compounds; a number were identified. The results thus obtained were used as a basis for proposing the possible existence of certain structures in kerogen. To the authors' knowledge, few or no hydrogenolysis studies have been made of Colorado oil-shale kerogen by others. However, this method has been used in studying the constitution of coal. In general, the coal studies involved treating pulverized coal at different temperatures and hydrogen pressures with different catalysts. In some instances different solvents were used during the treatments.

Jan 1, 1959

By R. B. Fisher

This report gives the results of mineralogical research on the Nicaro (Cuba) nickel ores and plant products. These studies were made under a cooperative agreement with the General Services Administration (GSA) of the U. S. Government. The purpose of the investigation was to obtain fundamental data that would be useful to other GSA contractors concerned with the Nicaro ores in their research on reduction roasting, leaching, and other phases of the project; and to the metallurgical staff of the Nicaro plant in Cuba. The overall objective of the combined research was to provide data to accomplish metallurgical improvement in the operations of the U.S. Government-owned plant at Nicaro, Oriente Province, Cuba. Particular emphasis is placed on improving the recovery of nickel from the ores and on the possibility of recovering other valuable constituents, especially cobalt. This study presents the physical and chemical characteristics, mineral associations, differential thermal analyses in controlled atmospheres, and X-ray studies of the ores and plant products. The nickel ores, serpentine and laterite, were from the Ramona-Lama Mulo and Ramona ore deposits. Serpentine ore consisted of serpentine-group minerals, basic iron oxide, magnetic iron oxides, chromite, olivine, enstatite, anthophyllite, cryptocrystalline quartz, wad, and a trace of calcite. This ore contained 1.6 percent nickel, 0.05 percent cobalt, 0.86 percent chromium, and 17.4 percent iron. Laterite are was composed principally of goethite with some altered serpentine, quartz, chromite, wad, magnetite, maghemite, and hematite. It carried 1.3 percent nickel, 0.11 percent cobalt, 1.9 percent chromium, and 48.4 percent iron.

Jan 1, 1959

By W. R. Reed

A computer model named the "Dynamic Component Program" (DCP) was specifically designed for predicting the dispersion off dust from haul trucks at surface mines. Validation of the DCP was completed by comparing its results with the results of the 1SC3 model and with actual dust measurements taken front two operating mine sires. Comparisons of the field measurements, predictions of the ISC3 model and the predictions of the DCP demonstrate that the results from the DCP represent, on average, an 85% improvement truer the ISC3 dust dispersion model results.

Jan 1, 2008

By Forrest T. Moyer

In 1969, the number of fatal injuries in the coal mining industry was lower than in any previous year and the number of nonfatal injuries was lower than in any preceding year except 1968. Fatal injuries in 1969 totaled 203 with frequency rates of 0.85 per million man-hours of worktime and 0.36 per million tons of coal These rates were new annual lows. Nonfatal injuries totaled 9,917 with frequency rates of 41.76 per million man-hours and 17.42 per million tons. The severity rate for fatal and nonfatal injuries combined was 7,359 days lost or charged per million man-hours. The average severity was 173 days lost or charged per injury. These statistics represent the injury experience of an average of 133,302 employees per day working an average of 225 days in 5,955 coal mines for a total of 237-5 million man-hours worked and a coal output of 565 2 million tons

Jan 1, 1973

By James D. Noll, M. Eileen Birch

A monitoring method for diesel particulate matter was published as Method 5040 by the National Institute for Occupational Safety and Health (NIOSH). Organic and elemental carbon are determined by the method, but elemental carbon (EC) is a better exposure measure. The US Mine Safety and Health Administration (MSHA) proposed use of NIOSH 5040 for compliance determinations in metal and nonmetal mines. MSHA also published a rule making for coalmines, but no exposure standard was provided. A standard based on particulate carbon is not considered practical because of coal dust interference. Interference may not be a problem if an appropriate size-selective sampler and EC exposure standard are employed. Sub micrometer dust concentrations found in previous surveys of nondieselized, underground coal mines were relatively low. If a large fraction of the sub micrometer dust is organic and mineral matter, sub micrometer EC concentrations would be much lower than sub micrometer mass concentrations. Laboratory and ?eld results reported here in indicate the amount of EC contributed by sub micrometer coal dust is minor. In a laboratory test, a sub micrometer EC concentration of 31µg m 3 was found when sampling are spirable coal dust concentration over three times the US compliance limit (2mg m3). Laboratory results are consistent with surveys of nondieselized coal mines, where EC results ranged from below the method limit of detection to 18µg m 3 when size-selective samplers were used to collect dust fraction shaving particle diameters below 1.5µm sub micrometer EC concentrations were ?7µg m3. In dieselized mines, sub micrometer EC concentrations are much higher.

By W. J. Fullerton

This paper is one of a series being prepared by the U. S. Bureau of Mines describing mining and milling methods and costs at cement-plant quarries throughout the United States, end deals directly with methods and costs at the quarry and mill of the North American Cement Corporation at Catskill, N. Y. The process of manufacturing cement is described only as far as the final grinding of the raw materials. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent local operating expenditures only and not total production costs. It is recognized that publication of total production costs may in many instances cause embarrassment to individual producers, as well as to the industry as a Whole. On the other hand, operating costs are essential to the technical discussion and study of methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding; of the scone of the cost tabulations may ensue.

Jan 1, 1931

By Virgil A. Marple, Susanne V. Hering

"5.1 IntroductionTraditional impactors do not offer much size resolution for submicrometer particles; typically their finest size cut is around 0.4 µ.m. Yet for many aerosol applications it is useful to be able to size segregate aerosols in the size range below 0.4 µ.m. Diesel emissions, welding fumes, cigarette smokes and photochemically generated smog aerosols typically exhibit mass median diameters between 0.1 and 0.6 µ.m. When sampling these aerosols with a traditional impactor, fifty percent or more of the aerosol mass can penetrate the final impactor stage. Allhough the material can still be collected on a backup filter, the filter gives no size resolution. As a result, the investigator has no size information on a substantial portion of the sample. One needs a sampler that size-segregates the majority of the aerosol mass. A lower size cut of 0.1 µ.m or less is required for most combustion smokes and smog aerosol s.To obtain smaller cutpoints two types of impactors have been developed, namely low-pressure impactors and micro-orifice impactors. Both instruments can provide cutpoints as small as 0.05 µ.m. Low-pressure impactors were introduced more than twenty years ago (Stem et al., 1962), and a variety of these samplers are in use today. Micro-orifice impactors have been developed at the University of Minnesota within the last five years (Marple et al., 1981 ). To date theirs are the only examples of these instruments in use.5.2 Operating PrinciplesThe low-pressure and micro-orifice impactors use two different approaches to achieve their very small particle-size cuts. Low pressure impactors resemble ordinary impactors, but are operated at reduced pressures of 5-40 kPa (0.05 - 0.4 atm). They take advantage of the decreased aerodynamic drag on particles that occurs when the mean free path in the air is as large or larger than the particle diameter. Micro-orifice impactors operate at near atmospheric pressure, but employ very small orifices, 40 µ.m to 200 µ.m in diameter. The streamlines of the air impinging upon the impaction plate have correspondingly smaller radii of curvature; the air is accelerated more quickly, making it more difficult for the particles to follow. The basic operating principles for both types of impactors are evident from the particle Stokes number, defined as:"

Mar 1, 1989

By Frank Ruskey

This report describes a computer program devised by the Bureau of Mines to model coal-mining situations where one or more panels encounter oil or gas wells. The program seeks in several hundred trials to evade the wells if possible or to minimize their influence by shifting or skewing the mine plan and/or adjusting the centerline dimensions of the entryways. Upon completion of computations, the program sorts the hundreds of models which have been tested, and lists the 10 best with their associated parameters. It also draws a mine plan of the best configuration, showing the entryways and crosscuts along with the "lost" coal remaining in the barrier pillars surrounding the various wells.

Jan 1, 1972