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By G. R. Hopkins

A fifth successive record in fuel efficiency was established by the petroleum-refining industry in 1937, when the average heat requirement per barrel of crude oil run to stills was 554,000 B. t. u. compared with 597,000 B. t. u. in 1936. These amounts represent roughly the heat obtainable from a tenth of a barrel of fuel oil (see fig. 1). Innumerable factors can influence heat consumption at refineries, but only a few are important enough to be subject to statistical measurement. Foremost of these is the ratio of runs to capacity, it being generally recognized that because the fuel demands for other than stills are comparatively inelastic, total heat requirements do not increase in direct proportion to crude runs. Thus, in 1937, crude runs of 1,183,440,000 barrels were 11 percent higher than in 1930; the average operating ratio was 83 percent compared with 79 percent in 1936; but the total heat requirement increased only 4 percent, or from 638,149 billion B. t. u. in 1936 to 663,966 billion B. t. u. in 1937.

Jan 1, 1938

By V. Vallyathan, Xianglin Shi, N. S. Dalai

While Cr(VI) is a known carcinogen, the underlying biochemical mechanism is still not fully understood (1). In a pioneering study Jennette (2) utilized electron spin resonance (ESR) spectroscopy to demonstrate that a long-lived Cr(V) species is generated during the reduction of Cr(VI) by microsomes in the presence of NADPH. Later Wetterhahn and co-workers (3, 4) showed that incubation of chromate with isolated rat liver mitochondria causes the reduction of Cr(VI), as well as the formation of a Cr(V) species. Analogous Cr(V) species have also been detected in the reduction of Cr(VI) by other cellular systems such as Hanserulla polymorphared (5) and blood cells (6, 7). All these as well as other studies (8-12) have suggested that this Cr(V) species plays a significant role in the mechanism of Cr(VI) toxicity. Thus far, however, the chemical structure of this dominant Cr(V) species formed in cellular systems has not been identified, and this observation provided an impetus for the present investigation. Another reason for undertaking this study was that some recent reports (10-16) suggest that hydroxyl ('OH) radicals may also play an important role in the mechanism of Cr(VI) toxicity. In particular, it has been shown that OH radicals are formed in reactions between Cr(V) species and H2O2 (13-16), and that the radical yield depends on the chemical structure of the Cr(V) species (15). For example, while Cr(V)-diol complexes efficiently generate OH radicals, another Cr(V) species, the tetraperoxochromate (CrO3/8) ion, does not (15). Thus in the present study, we focused our attention on the following: (a) structural identification of the Cr(V) species generated in the reduction of Cr(VI) by subcellular as well as cellular systems, using microsomes, mitochondria, and Escherichia coli; (b) possible detection of OH radical in the same systems since there is no earlier report of chromium-mediated generation of 'OH radicals in a cellular system; (c) possible involvement of molecular oxygen in chromium-related OH radical generation since a recent report (17) indicated that Cr(VI) mutagenesis is strongly oxygen dependent; and (d) elucidation of the mechanism of OH radical formation in these systems.

Mar 1, 1992

By Manuel Gomez

Areal distributions for ash, total sulfur, and sulfur forms were developed for the top 12 inches, the middle section, the bottom 8 inches, and the total seam of Pittsburgh coal in southwestern Pennsylvania. The sulfur and ash exhibit an apparent high local variability. As a general rule, both the sulfur and ash show high concentrations in the top 12 inches and in the bottom 8 inches of the seam relative to the concentrations observed in the middle section of the seam. The high-low sulfur and ash concentrations in the top 12 inches of the seam are not coincident with the high-low sulfur and ash concentrations in either the middle section or the bottom 8 inches of the seam. With respect to sulfur and ash, it is suggested that the top and bottom sections of the Pittsburgh coal may reflect both a syngenetic and epigenetic origin. Present data support the belief that paleotopography controlled Pittsburgh seam deposition. Evidence is presented to show that channels were cut at various times into the semilithified sediments that buried the Pittsburgh seam. In this channeling process, portions of the Pittsburgh coal may have been eroded away. Following channel development, the lower part of the Pittsburgh sandstone filled the complex system of braided channels to produce the "want areas" encountered in present mining operations. In localized areas of the Pittsburgh seam, impingement of Pittsburgh sandstone may be responsible for the lateral displacement of the coal. Information of this type becomes important in the assessment of exploration data, in the development of a quality control system for mine output, and in mine life planning.

Jan 1, 1974

By Richard J. Mainiero, James H. Rowland III, Marcia L. Harris

This paper reviews the potential hazards posed by the toxic fumes produced by detonating explosives in surface mining and construction operations. Blasting operations produce both toxic and nontoxic gaseous products; the toxic being mainly carbon monoxide (CO) and the oxides of nitrogen (NOx). The quantity of toxic gases produced by an explosive is affected by formulation, confinement, age of the explosive, and contamination of the explosive with water or drill cuttings, among others. Techniques to protect workers and the public from the potential hazards of explosive-related toxic fumes are discussed. These include: • Minimizing the quantity of toxic fumes produced. • Determining where the fumes may go so workers and neighbors can be moved out of harm’s way. • Preventing the fumes from moving towards workers and neighbors. • Monitoring the air near workers and neighbors so they can be relocated if fumes appear. • Ventilating structures or confined spaces until CO falls below a hazardous concentration.

By J. R. Thoenen, Hugh D. Pallister

"INTRODUCTION The Stone Hill Copper project resulted from the recommendations made in the war minerals report on this deposit by engineers of the Bureau of Mines 4/ and a similar report of the Geological Survey. 5/ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of domestic mineral resources to the end that they make the greatest possible contribution to the national security and economy. The Mining Division, Lowell E. Moon, chief, conducts preliminary examinations, does the actual investi¬gative work, and prepares the final report. The Metallurgical Division, Oliver C. Ralston, chief, analyzes samples and makes beneficiation tests.This report was prepared under the supervision of Paul M. Tyler, former regional engineer, Eastern Region, and is based on the examination and investigation of the deposit by Hugh D. Pallister, mining engineer, made under the immediate supervision of Richard W. Smith, former District Engineer for Alabama and Mississippi.The report was rewritten and prepared for publication by J. R. Thoenen, chief, Tuscaloosa Branch, Mining Division.LOCATION AND ACCESSIBILITYThe Store Hill copper mine is about• 12 miles south of Heflin, the oounty seat of Cleburne County, Ala. Heflin, a town with a population of approximately 1,700, is the nearest shipping point for freight and express. It is on the Southern Railway, between Birmingham and Atlanta. A rural mail route passes within quarter of a mile of the mine. Paved reads from Heflin lead to Atlanta, Birmingham, and Montgomery. The country Toads leading from Heflin are well-maintained but are practically inaccessible during inclement weather. The road crossing the property within a hundred yards of the mine needs grading and repairing (see fig. 1)."

Apr 1, 1948

By R. W. Stahl

Gas accumulation and dust suspension are the major safety hazards in coal stockpiling and reclaiming operations. This report presents a schedule of safety precautions and plant design features devised by the Bureau of Mines to reduce danger from these and other sources.

Jan 1, 1965

By William W. Adams

The stone-quarrying industry of the United States, including such related operations as rock crushing, rock dressing, and the manufacture of cement and lime, reported a larger volume of employment in 1934 than in 1933. Reports from the operating companies to the United States Bureau of Mines showed an increase in the number of men employed, number of man-days of employment, and total number of man-hours of labor performed during the year. Moreover, the average worker had a longer period of employment during 1934, the gain amounting to 11 percent over 1933. The increase in employment was accompanied by no increase in accidents for the industry as a whole; in fact, the accident rate for 1934 was a fraction lower than the rate for 1933. In some branches of the industry the frequency of accidents increased, but these increases were more than offset by reductions in rates for other branches. Reports for 1934 were received from 1,403 active plants. The working force averaged 64,331 men for 204 days per man, and the total period of employment for all of the men was 95,258,880 man-hours. Each employee averaged 1,481 hours of work during the year. The total number of hours of labor represented a gain of more than 8 percent, and the average working time per employee showed a gain of 62 hours per man.

Jan 1, 1936

By Geo. Adams Roalfe

THIS PAPER is one of a series being pre¬pared for and published by the United States Bureau of Mines describing, methods of mining and crushing and the costs of operation at commercial crushed-stone plants throughout the country. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total costs. It is recognized that publication of total costs might in many instances cause embarrassment to individual operators, as well as to the industry as a whole. On the other hand, operating, costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. Acknowledgments The author wishes to acknowledge the [ ]

Jan 1, 1932

By T. J. Williams

Researchers at the U.S. Bureau of Mines monitored rock mass response to mining of an experimental underhand longwall stope in Hecla Mining Co.'s LUCKY Friday Mine, Mullan, ID. This stope design, the Lucky Friday underhand longwall (LFUL), was proposed as a means of controlling rock bursting while also allowing increased mechanization of mining operations. Instruments were specifically manufactured to monitor three geomechanical factors (backfill performance, ramp stability, and rock mass response) that directly affect the success of stope design. Despite considerable difficulties with instrument installation and survival in the harsh mine environment, especially within the stope fill, sufficient information was collected to suggest that the LFUL method was successful in achieving project goals. This conclusion, in addition to favorable economic and operational evidence, led the mine to adopt the method throughout the mine. Indeed, this study and mining experience suggest that underhand longwall mining could be considered a feasible mining method for rock-burst-prone ground throughout the Coeur d'Alene District. Further Reports of Investigations (RI) in this series present in-depth analyses of the effects of backfill on rock bursting and calibration of a stope numerical model.

Jan 1, 2010

By J. E. Tiffany

Some of the gases produced by permissible explosives on detonation are poisonous, and the probable hazard involved by the inhalation of carbon monoxide in the past has been evaluated from results of tests in the Bichel Gage. Tests have now been made in the Experimental Coal Mine of the Bureau of Mines at Bruceton, Pa., to determine the composition of the gases obtained under actual mining conditions for the purpose of comparing these, results with those found by the Bichel gage tests. Two permissible explosives were procured for these tests, one that produces a relatively low quantity of poisonous gases in the Bichel gage (24.8 liters per 1-1/2 pounds of explosive) and another that produces a relatively high quantity of poisonous gases (94.6 liters per 1-1/2 pounds). The first of these is designated by the Bureau of Mines as a class A4/ explosive and the other is designated a class B explosive. In comparison with Bichel-gage tests, the shooting of permissible explosives in a coal shot hole resulted in a large reduction in the quantity of carbon monoxide, the principal poisonous gas, which; in the mine tests, was only 22 percent of that found in Bichel-gage tests: The quantity of carbon monoxide from the class B explosive in Bichel-gage tests was 3.8 times larger than that from the class A explosive; in the coalmine tests the ratio was 4:1. The concentrations of carbon monoxide in the mine tests, as determined by analysis of the atmosphere in an enclosed space resulting from shooting 1-1/2-pound and 3-pound charges of the class A explosive, were 0.03 and 0.06 percent, respectively, and the concentrations from 1-1/2-pound and 3-pound charges of the class B explosive were 0.10 and 0.24 percent.

Jan 1, 1950

By D. L. Bickel

This report presents a Bureau of Mines study intended to determine if horizontal stress trends exist and if the stresses can be projected for improved mine design in a selected coalfield. The horizontal stresses were determined in three mines in the Yampa Coalfield and one mine in the adjacent Danforth Hills Coalfield of northwestern Colorado. Stresses were determined from stress-relief measurements using a three-component borehole deformation gauge and overcoring techniques developed by the Bureau. A least-squares method of calculating the average rock stress components in the horizontal plane was performed. Physical properties of the rock from the test sites are also included. For the Yampa Coalfield, the maximum horizontal compressive stress in the floor ranged from 363 to 1,956 psi, and the maximum horizontal compressive stress in the roof ranged from 235 to 875 psi. For the Dan-forth Hills Coalfield, the maximum horizontal compressive stress in the floor ranged from 360 to 1,494 psi, and the maximum horizontal compres-sive stress in the roof was 1,033 psi. Results indicated a trend of low horizontal stresses in the Yampa Coalfield that have not impacted ground control conditions in mines less than 1,000 ft deep.

Jan 1, 1988

By J. R. Welty

High-temperature thermodynamic data have, in recent years, become increasingly important for the extractive metallurgist. The extraction of metals from their ores previously was based on trial and error methods, involving hours of testing and often costly equipment fabrication. Using thermodynamic data it is frequently possible to predict the feasibility of a proposed metallurgical process as well as the optimum operating conditions for the process with reasonable accuracy. Such predictions can save consider-able tim~ and expense. Widespread use of thermodynamic analyses has been handicapped by lack of dependable experimental data. Investigators, notably K. K. Kelley (4)4. have devoted many years to determining and compiling such data. These investigators, although prolific in their production of thermodynamic values, have been unable to meet all the needs of industry and other branches of science. This becomes obvious when one considers the aeronautical and nuclear fields, in which previously unimportant, therefore uninvestigated, substances have become of prime importance.

Jan 1, 1962

By R. V. Ramani, W. Miola

"A relationship exists between the quartz contents in the underground coal nine airborne dust samples and those in the coal and host rocks that are mined [17, 18, 19] The prescribed method for quartz analysis in respirable airborne coal dust samples is the MSHA P-7 method. Accurate quartz analysis procedures are needed for bulk samples in order to predict the potential quartz content in airborne nine dust, which in turn will aid the design of quartz dust control procedures during mining. thereby reducing the airborne quartz dust in underground atmospheres. The requirements of this method are that the amount of quartz is the sample be less than 250ug, and the total sample weight less than 2,500 ug. Unlike with airborne dust samples, there are no limitations to the available mass of bulk samples. However, these are no standard procedures for the preparation of bulk samples for scanning or prescribed methods for quartz analysis. The NIOSH and MSHA methods are certified for roped* dust and the acceptance of these methods for bulk samples assumes that the bulk samples will be reduced to the conditions specified for respirable dust samples. An alternative method is X-ray diffraction, which provides higher average quartz values than those obtained from P-7 method for the same samples.An investigation was carried out to determine the optimal procedure for preparing the bulk samples for the IR and XRD analyses. In this paper, the investigations on the effects of calibration, particle sizes, matrix composition, interferrous, and behavior of the filter substances on IR, XRD and FTIR results are presented. The error introduced by the presence of kaolinite and a new sample asking procedure to reduce it are discussed. The problems experienced with conventional sample holders for scanning were eliminated with the design and development of a new hollow sample holder. Quantitative comparison of quartz determinations by IR, XRD and MR methods on coal, roof and floor rocks, and airborne dust samples are presented. The important factors affecting the results of quartz analysis methods are: 1) bulk sample preparation for obtaining representative and homogeneous analysis samples: 2) particle size distributions of the analysis samples and calibration standards; 3) qualitative matrix composition of the analysis sample; 4) matching calibration standards to analysis sample; 5) substrates for sample deposition during analysis sample preparation; 6) procedures for analysis sample mounting; 7) selection of proper portions of she response profile for insanity measurement; and 8) interferences of spurious phases with the critical analyses. The recommendations of this study are important to enable comparisons and interpretations of analysis and research results."

Nov 1, 1995

By Wm .. W. Odell

There is outlined below the essential facts brought out in an investigation into the causes for emulsion difficulties as experienced at many water gas plants . The investigation was conducted under a cooperative agreement between the University of Illinois Engineering Experiment Station , the Illinois State Geological Survey , and the U. S. Bureau of Mines . Funds of the Illinois Gas Association were used to defray a part of the costs . Active assistance was rendered by the Peoples Gas Light and Coke Company , of Chicago , who furnished a laboratory at Chicago for conducting the experiments , and loaned the services of Mr. E. A. Thiele to help with the laboratory work . A full report on the results of this work will be published by the Bureau of Mines later but it is believed desirable to bring the principal results now to the attention of the industry . In almost every gas plant where carbureted water gas is made , some difficulty is experienced , at one time or another , in separating the tar fran the water that condenses from the gas . The fact that annoyance from this source is ever present in some plants , and seldom present in others , leads to the belief that certain operating variables have considerable to do with the formation of difficulty separable tarwater emulsions . Accordingly , when samples of tar were collected for laboratory study , the operating conditions and methods were simultaneously observed and recorded.

Mar 1, 1922

By R. V. Ramani, J. M. Mutmansky, P. C. Luna, V. A. Marple, Honglin He, B. A. Olson

The development of a sampling instrument for the assessment of an underground coal miner’s exposure to airborne respirable coal mine dust on a continuous and real-time basis has been long identified as essential for timely initiation of control actions. A respirable dust dosimeter (RDD) which operates on the principle of increasing pressure across a filter media with increasing dust mass on the filter has been developed by the National Institute for Occupational Safety and Health. Comparisons of the performance of the RDD with an U.S. approved gravimetric respirable dust sampler (GRD) have shown that the RDD may meet the requirements for measuring miners’ exposures on a cumulative, near real-time basis such as mid-shift and end of shift exposures. Recently, the performances of the RDD and GRD were compared by conducting side-by-side area sampling experiments in a controlled experimental environment in the laboratory and in underground coal mines under normal operating conditions. In this paper, the results from the in-mine study are presented and discussed. The experimental design for the in-mine study included two mines in different coal seams in different geographic coal regions. To ensure a wide range of concentrations, the experiments were conducted in a continuous miner section in Mine 1, and a longwall face in Mine 2. Airborne dust sampling was conducted for four different shifts at each mine. In each shift, two samples of different exposure durations were collected from two different locations. Each sample consisted of the readings of three dosimeters and the exposed filters from the three paired GRD samplers. As a result, a total of 96 comparative samples were obtained, 48 for each mine. The data were analyzed for the precision of the RDD and GRD measurements and for the relationships between the differential pressure of the RDD and the mass of dust on the paired GRD filter. The analyses indicate that, on the average, the RDD and the GRD track the airborne respirable dust concentrations well, exhibiting both a high correlation between the two measurements and a reliable predictive relationship of one from the other. Details of the experimental design, data analyses procedures, results, conclusions and recommendations of the underground experiments are presented in this paper.

By A. J. Barry

An apparatus and procedure have been developed for testing the anchorage effectiveness of slotted-type bolts. The apparatus consists of: (1) A hydrualic Jack assembly for loading the bolt and (2) a device (extensometer or cathetometer) for measuring displacement of the bolt as it is loaded. This apparatus and procedure permit measurment of anchor slip for loads up to the yield load of the bolt. Two representative makes of slotted-type bolts (a total of 94 bolts) were tested in typical sandstone and shale mine roof. Analysis of the test results showed that (1) anchorage capacities up to the yield load of the bolts can be developed in either rock type; (2) the shape of the slotted end of the bolt affects the ease with which the bolt can be driven; (3) all bolts for which the driving distance was more than 1.25 inches produced satisfactory anchorage in both rock types (thus, driving distance can be used as a criterion for satisfactory anchorage); (4) for the group of bolts that was satisfactorily anchored the anchor slip was unaffected by the type of bolt but was considerably larger in shale than in sandstone; and (5) the bolt expansion, that is, the amount the wedge expands the prongs in excess of the diameter of the hole, can also be employed as a criterion for satisfactory anchorage. Although the bolt-expansion and driving-distance results do not differ appreciably, the latter is recommended because it is easier to determine.

Jan 1, 1954

By Kyei-Sing Kwong

The U.S. Bureau of Mines investigated the synthesis of advanced ceramics (SiC+AlN, SiAlON, SiC+A1203, and Si3N4+AlN) from natural clays (kaolin, halloysite, or montmorillonite) by an intercalation and heat treatment method. This process includes the steps of refining a clay, intercalating organic chemicals into its layered structure, drying the intercalated mixture, firing the treated structure at certain temperature ranges in controlled atmospheres to form desired compounds, and grinding the loosely agglomerated structure. Focus of this research is to economically process advanced ceramic structures from abundant natural resources. The advanced ceramic phases produced in this simple treatment are homogeneously distributed at the nanostructure level, and may potentially lead to cost effective manufacturing processes. The intercalation of clay was confirmed by X-ray and BET analyses. The evolution of chemical compositions during carbonization reactions and carbothermal reduction was investigated. The characteristics of refined clays and synthesized powders were studied. Advanced ceramic composites/solid solution have been produced from intercalated clays, without the presence of other compounds.

Jan 1, 2010

By Kathleen M. Kowalski

In emergency management, the effects of stress on the performance of emergency personnel, typically have been ignored or regarded as too enigmatic to quantify. This paper discusses the concept of Critical Incident Stress in responders to emergencies. It presents the rationale for considering stress as a significant factor in the management of emergencies. It is proposed that Critical Incident Stress Debriefing in a disaster can improve the effectiveness of response teams on site, their turnaround time on site, and post-disaster time off the job. Critical Incident Stress intervention also can mitigate potential deleterious emotional effects associated with emergency work. This paper, prepared by a U.S. Bureau of Mines researcher, offers some ideas to the mining industry in general, to mine rescue team trainers, and to developers of program simulations on the specific issue of how people, time, materials and space may be factored into a plan for emergency management. The impact of stress on emergency workers is, presented as a missing component in present emergency management models.

Underground coal mining continues to evolve in the U.S., and more reserves are being mined under deeper cover, with worse roof, or with interactions from previous workings. At the same time, the mining community is responding to higher safety standards and intense competitive pressures. The need for effective ground control design has never been greater. Ground control safety issues that have been addressed by recent the National Institute for Occupational Safety and Health (NIOSH) research include: Improving roof support performance; Maintaining safe tailgate escapeways from longwalls; Optimizing pillar design for retreat mining; Controlling multiple seam interactions; Predicting roof conditions during extended cuts, and; Preventing massive pillar collapses. As funding from both government and the private sector has diminished, the emphasis in research has focused on providing the mining community with practical techniques for improved ground control design. Many projects have successfully employed empirical methods that emphasize the statistical analysis of case histories from underground mines. Other projects have employed numerical models and large-scale laboratory testing of roof support elements. Using these data, NIOSH has developed an entire toolbox of computer programs that have been effectively transferred to the mining community.

By R. L. Grant

The principal official test performed by the Bureau of Mines to determine the permissibility of coal-mine explosives, commonly referred to as the gallery test, has been in use at the Bruceton station for many years (2, 16).4/ In this test the explosive under study is loaded into the borehole of a steel cannon and fired into a flammable mixture of natural gas and air or natural gas, air, and coal dust. To meet the requirements for permissibility, the explosive must not ignite the gas mixture under the conditions of the test. There is little doubt that these tests have succeeded in the main objective, namely, to screen the relatively safe from the relatively hazardous explosives. It has been generally conceded that adoption of permissible explosives by the coal-mining industry in the United States has substantially reduced the frequency of disastrous underground explosions caused by blasting. In recent years, however, research workers planning programs for improving the safety of coal-mine explosives have felt the growing need of a more quantitative method for measuring the incendivity of explosives based on a better understanding of the role of the important variables in the gallery tests, Accordingly, it was decided to apply certain statistical methods and techniques to the gallery test to develop it into a more precise tool for evaluating permissible explosives. One of the first and more important methods applied for this purpose was the up-and-down technique (6,7,17), It was demonstrated (14,15) that the weight of the explosive charge directly affects the ignition probability of the natural gas-air atmosphere and that the curve of ignition probability versus charge weight is a cumulative normal curve. Following these experiments, a program, still in progress, was set up to study how the addition of sodium chloride to various permissible-type ex-plosives affects their incendivity. This program resulted in 3,294 shots,

Jan 1, 1961