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By Charles L. Kusik

As part of an effort to establish processes that could be exploited in case of adverse changes in international chromium production and trading patterns, this study was sponsored by the Federal Emergency Management Agency (formerly the Federal Preparedness Agency) through the Bureau of Mines, to experimentally determine the feasibility of recovering chromium from critical scrap metals containing significant quantities of this element. Based on a conceptual pyrometallurgical chromium recovery flowsheet developed at Arthur D. Little, Inc., the experimental program described in this report demonstrated key process steps for the recovery of chromium as ferrochromium in a batch process. The process involves oxidation of chromium into a slag phase, subsequent separation of the slag phase from the remaining metal, followed by reduction of chromium from the slag phase to produce ferrochromium.

Jan 1, 1981

By H. Polat, Q. Hu, M. Polat, S. Chander

"The electrostatic charge on spray droplets of ionic surfactant solutions and coal particles was measured and the results were correlated with the dust collection efficiency. When various surfactant were added, the magnitude of the droplet charge increased significantly and it was observed to be a function of surfactant type and concentration. The concentration of maximum droplet charge coincided with surfactant concentration where maximum collection efficiency was observed for these surfactants. Particles of coal also carried substantial amount of charge magnitude of which seemed to be a function of coal rank.Based on the results presented in this paper, it was concluded that ionic surfactant primarily act as a strong electrostatic charge inducer for droplets. Due to interactions between these highly charged droplets and naturally charged particles, the efficiency of droplet-particle collisions play a primary role when compared to the wetting and engulfment phenomenon which could only follow a successful collision. INTRODUCTIONWater spray are widely used to suppress airborne dust in mine atmospheres (Walton and Woolcock, 1960; Kobrick, 1970; Hamilton, 1974; Jayaraman et al., 1986). Several investigators have considered the use of surfactants to enhance the effectiveness of water sprays especially for difficult to wet particles such as those of coal (Glanville and Wightman, 1979). The capture of dust particles by water droplets involves droplet-particle collisions, adhesion of particles to droplets, and engulfment of particles into droplets. Surfactants affect these sub processes through their influence on droplet charge, surface tension, and wetting. The last two mechanism have been thoroughly studied in recent years (Walker et al., 1952; Cohen and Rosen, 1981; Glenville and Haley, 1982; Chander et al., 1988; 1991). However, little attention has been paid to the role of electrical charge on particles and droplets on the collision and adhesion of spray droplets and dust particles."

Nov 1, 1995

By G. F. Kuncir

The time-cost-risk analysis described herein was performed as part of an evaluation of the Advancing Oil Shale Mining Technology Program performed by The Aerospace Corporation. The objectives of this analysis are to assess the feasibility of the program relative' to time and cost constraints, and to determine the probabilities of achieving various technological goals. A combination of standard program planning and analysis techniques were used to achieve these objectives. These included a critical path analysis, a resource allocation analysis, and a risk analysis.

Jan 1, 1977

By Van E. Shaw

Bastnaesite is a natural rare-earth fluorcarbonate of the cerium group that affords an abundant and high-grade source of the lighter rare-earth elements. A simple and efficient method has been developed by the Bureau of Mines for extracting rare-earth compounds from this mineral. Digesting of a flotation concentrate with sulfuric acid converts the rare-earth compounds from fluorcarbonates to sulfates. Action of the acid releases gaseous com-pounds of fluorine and silicon, leaving the sulfated material free of these elements; carbon dioxide from carbonate decomposition is eliminated at the same time. Calcining the sulfated material at 1,200° F. renders the gangue constituents insoluble, whereas the rare-earth sulfates are left in water-soluble form. Leaching with water yields a solution of pure rare-earth sulfates. Bastnaesite could become prominent as a source of cerium-group rare-earth elements. It is rich in the light rare-earth elements and comparatively easy to process; reserves of the mineral are extensive enough to supply a greatly expanded market for many years.

Jan 1, 1959

By E. R. Cole

Bench-scale research at the Bureau of Mines has resulted in the successful development of a combination electrorefining-electrowinning method for recycling all the lead in scrap batteries. The method reduces energy consumption and eliminates toxic emissions, in contrast to present pyrometallurgical smelting, and the lead produced is pure enough for use in maintenance-free batteries. Anodes cast from molten lead scrap were electrorefined in 1-and 2-liter plastic cells using an electrolyte composition of 70 g/l Pb and 90 g/l free H2SiF6 (fluosilicic acid). Both reagent-grade and waste H2SiF6 were used. Cathode starting sheets were made from refined lead. Aloes, and later bone gelatin, and calcium lignin sulfonate addition agents were employed. The sludge remaining after separation of the lead metal was treated in a two-step leaching operation to solubilize the lead for recovery by electrowinning. Conditions for electrowinning were essentially the same as for electro-refining, except that insoluble Pb02-Ti (lead dioxide-coated titanium) anodes were used. The best results for both electrorefining and electrowinning were obtained with a current density of 170 amp/m2 and a cell temperature of 25° to 35° C. Cathode purity ranged from about 99.9 to 99.99+ pct Pb. Maximum energy consumption after 3 days, for electrorefining and electrowinning, was 90 and 700 kwhr per metric ton of refined lead, respectively.

Jan 1, 1981

By R. E. Lindstrom

Electrooxidation techniques were investigated on a bench scale by the Bureau of Mines to determine the applicability of the process for extracting molybdenum and rhenium from low-grade molybdenite concentrates. Parameters affecting the extraction, such as pulp density, power consumption, reagent requirements for pH control, and electrolytic cell configuration, were studied. Molybdenum and rhenium extractions of 98 to 99 percent were achieved from several concentrates containing 4.76 to 28.6 percent molybdenum and 180 ppm to 1,000 ppm rhenium. Optimum results were obtained by maintaining pH values between 5.5 and 7.0 during electrolysis and allowing the final pH to rise to about 8.2. Reagent consumption was 4 to 6 pounds of sodium carbonate per pound of molybdenum extracted. The power consumption declined from a range of 12 to 25 kilowatt hours per pound of molybdenum extracted with immersion electrodes to 9.7 kilowatt hours with a bipolar flow-through cell; however, molybdenum extraction was independent of cell configuration.

Jan 1, 1973

By Martin H. Stanczyk

Two methods of recovering zinc from zinc ammonia complex solutions were investigated. One method studied was distillation of the ammonia from the solutions to recover a basic zinc sulfate, which after calcining to zinc oxide was reduced to metallic zinc using hydrogen at 900° C. The second method tested was electrolysis. The tests were made of synthetic and leach solutions analyzing about 80, 100, and 115 gpl (grams per liter) of Zn, NH3, and SO4, respectively. The leach solutions were prepared by oxidation leaching of a sphalerite flotation concentrate, assaying 55 pct zinc at elevated temperature and pressure. The distillation method recovered about 98 pct of the zinc in a product analyzing 97 pct zinc. Ammonia losses incurred during the leaching and distillation operations were about 0.1 lb per lb (pound per pound) of metallic zinc produced. Electrolysis of the solutions at a cathode current density of 25 amp per sq ft (ampere per square foot) yielded zinc deposits assaying in excess of 99.9 pct zinc. About 1.5 kwhr (kilowatt-hour) of power were consumed per pound of zinc deposited; the current efficiency was 72 pct. Other electrodeposition tests revealed that small amounts of ferric iron in the cell liquor were deleterious to electrolysis unless about 5 lb of glue per ton of zinc were present in the electrolyte. The use of glue and vigorous agitation of the electrolyte gave smooth zinc deposits from solutions containing as much as 0.1 gpl iron.

Jan 1, 1962

By P. M. Brown

The Bureau of Mines is investigating a dewatering technique for coal-clay waste that uses a flocculant, polyethylene oxide (PEO). This flocculant forms strong stable flocs that can be dewatered on a static screen. A field test unit (FTU) using this technique was operated at approximately 400 gal/min, using a waste stream from the flotation circuit of a coal preparation plant. Consolidated coal-clay material con-taining 55 to 60 pct solids was produced when the flotation circuit slurries of 2.7 to 8 pct solids were treated with 0.1 to 0.3 Ib PEO per ton of solids. The FTU was also operated at 64.5 and 87.5 gal/min using a portion of the underflow slurry from the preparation plant's thickener. Consolidated coal-clay material containing 55 to 60 pct solids was produced when the thickener underflow slurries of 19 to 24 pct solids were treated with 0.08 to 0.2 Ib PEO per ton of solids. PED-treated materials continued to dewater when placed in a pit.

Jan 1, 1983

By A. M. Stubbs

The Bureau of Mines has devised a procedure to selectively extract and recover chromic oxide (Cr203) from waste high-temperature shift catalysts that contain approximately 6 pct Cr and 62 pct Fe, both in oxide form. The Bureau's procedure consists of roasting the waste catalyst with sodium hydroxide (NaOH) or sodium carbonate (Na2C03) followed by water leaching. The chromium from the leach liquor was recovered utilizing an oxidation-reduction reaction with pH adjustment to form a hydrous chromic oxide (Crp3oXHp) precipitate. The roast-leach procedure produced chromium extractions greater than 89.7 pct, with product recovery in excess of 99 pct from the leach liquor. The costs of the NaOH and Na2C03 roast processes, including sizing and equipment-related recommendations, were determined by the Bureau's Office of Process Evaluation. The economic evaluation indicates that producing a Crp3 product, at the present time, is not competitive with the present-day cost of imported chromites. The estimated average operating cost for both processes was $5.44/1b of recovered Cr203 concentrate. However, this procedure offers a potential alternative to the disposal of this waste through landfiIl.

Jan 1, 1988

By R. Havens, B. K. Shilber

"INTRODUCTION In the course of the investigation of the occurrence of manganese deposits in the western United States, ore-dressing tests were made on three samples procured by Bureau of Mines engineers from two properties in southeastern Juah County, Utah, each of which is known by the name Black Jack. To avoid confusion, the tests will be described under the names of the owners Kendall-Duvall and the Empire Mines.None of the samples were amenable to ore dressing for the production of high-grade manganese sinter.Ores from the Kendall-Duvall deposit represent an interesting metallurgical phase of low-grade manganese occurrence, as the occurrence of manganese as silicate (braunite) automatically governs the extent to which they can be beneficiated by mechanical methods of treatment. As less than 50 percent of the total manganese was recoverable by complex methods of treatment in a 40- percent-manganese sinter, attempts were made to recover most of the manganese in a low-calcite, intermediate-grade product that might be acceptable for subsequent metallurgical treatment. By selective flotation of calcite and manganese, up to 68 percent recoveries were obtained in plus 20-percent manganese products..No encouragement can be given for successful ore-dressing of Empire ores as represented by samples received for testing, as no products were obtained that would meet minimum marketing specifications. Empire ore contained only 1 percent lime and might be high enough in grade (19 percent manganese) for direct hydrometallurgical treatment."

Nov 1, 1947

The Appalachian Mountains divide Pennsylvania into two distinct coal regions, bituminous and anthracite. The western region of the the state, where the majority of bituminous mines are located, is characterized by mountains and gently rolling hills. Bituminous coal seams underlie about 12,000 square miles in 28 counties. The anthracite coal region, located in the northeast, covers approximately 3,300 square miles. This area contains more than 20 different coal beds that vary in thickness from a few inches to 50 or 60 feet. The anthracite region is characterized by steeply pitching seams that require highly specialized mining techniques and present unique challenges for solving problems such as the mine subsidence associated with abandoned underground anthracite mines. For more than a century, coal has played a major role in the economic and industrial development of Pennsylvania, particularly the steel industry. Estimated bituminous reserves total 23 billion tons, or 5.3 percent of U.S. reserves, and anthracite reserves total 7.1 billion tons, or 97 percent of U.S. anthracite reserves. Pennsylvania received conditional approval of its regulatory program July 31, 1982. Pennsylvania's Abandoned Mine Land Program was approved on the same date.

Jan 1, 1992

By H. D. Jacobs

The Bureau of Mines developed a concentration method to upgrade and utilize marginal natural or direct-shipping iron ores and fine-grained lean iron ores. Presently these ores receive little beneficiation and accordingly have low iron-silica (Fe-Si02) ratios. Ore samples were roasted with equal weights of solid reductant at 1,100° C for 1 hour to metallize the iron and for an additional hour at 1,200° C to promote grain growth. Concentration was effected by crushing and screening techniques and/or wet magnetic separation. Sized concentrates (minus 4 plus 35 mesh) derived from crushing-screening processes contained from 80 to 85 percent iron that was 90 percent metallized. Iron-silica ratios as high as 12:1 and iron recoveries from 75 to 94 percent were obtained. The sized concentrates were judged suitable for use as blast furnace feed. Minus 200-mesh metallized concentrates derived from roasted minus I-inch plus 8-mesh ore fractions and magnetically concentrated contained 90 percent Fe and 4 percent or less Si02, chemically qualifying them as feed for electric furnaces. Roasting minus 8-mesh ore with hydrogen, then magnetically concentrating it, produced iron concentrates containing 57 percent to 67 percent Fe and 3.6 percent to 8.4 percent Si02. The concentrates having Fe-Si02 ratios ranging from 8:1 to 12:1 were considered adequate for use as blast furnace feed. Overall iron recoveries for the 12 ores tested ranged from 56 percent to 94 percent with an average iron recovery of 86 percent.

Jan 1, 1969

By E. V. Cilento, K. A. DiGregorlo, R. C. Lantz

A kinetic model was developed to describe the production of superoxide (02) by single pulmonary alveolar macrophages (PAM). Model predictions were compared to experimental results obtained from single rat PAM. The O2 - was quantified by measuring the reduction of nitroblue tetrazolium (NBT) to a diformazan precipitate (NBTH2) from video-recorded images of individual cells. The kinetic model considered three reactions: (1) the production of extracellular 0 - from the reduction of oxygen by NADPH oxidase using intracellular NADPH as the substrate, (2) the subsequent dismutation of o2- to from O2 , and (3) the reaction of o2- and NBT. NBT specificity for o2- was analyzed by comparing results in the presence and absence of superoxide dismutase (SOD) which catalyzes the dismutation of o2- to H2o2. Measured PAM heterogeneity was accounted for by varying the concentration of intracellular NADPH, its rate of depletion, and the concentration of intracellular NADPH oxidase in the kinetic model. Model predictions compared favorably with experimental results except when SOD was present. This discrepancy may be due to diffusional limitations since NBT is a relatively small molecule (818 MW) compared to SOD (34000 MW). In addition, the cell surface is both ruffled and negatively charged, which may introduce steric hindrances and/or electrostatic effects since SOD is also negatively charged.

Jan 1, 1988

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

A computer model of an existing mine ventilation system can be executed using data developed from ventilation survey results. This model can then be used to analyze and evaluate proposed modifications to the system. The acquisition of field measurements during a ventilation survey and the corresponding development of this information into computer input data have been discussed in detail in the preceding chapters. In this chapter, the data are used in computer-oriented analysis of the mine ventilation system. The PSU/MVS was selected for use because of its advanced capabilities. MINE DESCRIPTION The mine chosen for this application is located in Western Pennsylvania. The Pittsburgh coal seam, having an average height of 5-1/4 to 6-1/2 ft, is mined under approximately 300 to 500 ft of cover. The mine preparation plant and shipping facilities are located at the seam outcrop along a river; mining has progressed from the outcrop to an area about 10 miles from the pit mouth so that there are extensive worked-out areas through which access is maintained to the current mining area. Coal haulage is by conveyor to an underground transfer point, located four miles from the pit mouth, and then by high speed rail haulage to the preparation plant. The rail haulage link is scheduled for replacement by a conveyor in the near future. Mining at the present time is limited to the room and pillar method using continuous miners. Longwall mining had been attempted in the past with only limited success; as a result, several panels originally laid out for longwall mining are currently being extracted by room and pillar work. The

Jan 1, 1977

By Lloyd A. Morley, Robert Stefanko

This report was prepared by The Pennsylvania State University, College of Earth and Mineral Sciences, ' Department of Mineral Engineering, University Park, Pennsylvania, under USBM Grant No. GO-133077. The grant was initiated under the Coal Mine Health and Safety Research Program. It was administered under the technical direction of the Pittsburgh Mining and Safety Research Center with Mr. G. J. Conroy acting as the technical project officer. Mr. J. A. Herickes was the grant administrator for the Bureau of Mines. This report is a summary of the work recently completed as part of this grant during the period 19 June, 1973 to 17 June, 1975. This report was submitted by the authors on 18 July, 1974. This technical report has been reviewed and approved.

Jan 1, 1974

By Kay E. Goldberg

The Bureau of Mines conducted a study to develop and evaluate a training workshop for mine safety training personnel. The workshop was based on the Instructional Development Institute (IDI) which has been used for nearly ten years to train educators and administrators in the application of a nine-step model for defining, developing, and evaluating instruction. The Mining Instructional Development Institute (MIDI) was developed by investigators at the University of Southern California as a two-phase project. Phase I involved the modification of the six-day IDI program (including audiovisual presentations, workbooks, games, and exercises) for use by mine safety trainers as a workshop lasting three and one-half days. Phase II involved the evaluation and validation of the prototype MIDI workshop by means of a two-stage jury of experts and a prototype field trial. On the basis of data collected in the validation process it was determined that the institute provided an effective and useful method of instruction in mine safety training and that the institute would be especially valuable for mine safety training administrators and supervisors.

Jan 1, 1980

By E. V. Cilento, K. A. DiGregorio, R. C. Lantz

Pulmonary inflammation is accompanied by increased microvascular permeability and leakage of plasma into alveolar spaces. Serum has been shown to affect superoxide (O2-) production from pulmonary alveolar macrophages (PAM) in vitro, and in some cases serum has been shown to be necessary for stimulation of PAM. An electro-optical method was used to measure O2- production from single PAM by measuring the reduction of nitroblue tetrazolium (NBT) to a diformazan precipitate (NBTH2) from videorecorded images of individual cells. PAM were stimulated by their initial attachment to culture dishes independent of serum. The addition of 2% serum to the culture medium increased NBTH2 production during attachment, whereas concentrations of 5 and 10% serum had no additional effect. In contrast, PAM incubated for 2 hrs could not be stimulated by phorbol myristate acetate (PMA) or zymosan particles to produce O2- unless serum was present during the incubation and/or stimulation; however, NBTH production was similar in all cases of serum addition. Also2, serum alone did not stimulate adherent PAM indicating that serum is necessary but not sufficient for stimulation of attached. PAM. These results suggest that changes in microcirculatory permeability may have a pronounced effect on superoxide production by PAM and that serum may help regulate or condition these cells during inflammation of the lung. (Supported by USBOM Gll35142.)

Jan 1, 1988

By D. G. Foot

The Bureau of Mines investigated two methods for recovering potash from carnallite ore in continuous 100-lb/h flotation units. In the insoluble-slimes flotation procedure, insoluble slimes were removed by flotation prior to potash flotation. In the direct flotation method, insoluble slimes were depressed and the potash floated directly without prior removal of the insoluble slimes. Seventy-three percent of the potash in the ore was recovered in a leached final KCl product contain-ing 59.1 pet K20 using the insoluble-slimes flotation method. The direct flotation method recovered 74.5 pct of the potash in a final product containing 60.2 pet K20. The rate of return on the investment was calculated at 13 pct for the insoluble-slimes flotation method and 15 pct for the direct flotation method, based on a Bureau economic evaluation.

Jan 1, 1984

By D. W. Bridges, S. R. Borrowman

Thorium and yttrium oxides were recovered from siliceous ores of the Powderhorn , Colo . , area . Processing comprised ( 1 ) acid curing and subsequent ( 2 ) acid baking , ( 3 ) leaching , and ( 4) solvent extraction of thorium , using a primary alkylamine , and yttrium , using di - 2 - ethylhexyl phosphoric acid . About 95 pct of the contained thorium and yttrium was recovered from ore containing 1.2 pct Th02 and 0.5 pct Y₂ 03. The thoria product was 99 pct Tho ; the yttria product was 77 pct Y₂ 03. A 150 - to - 1 concentration ratio was effected on the latter , but some contaminating lanthanon - group oxides remained .

Jan 1, 1964

By W. P. Stroud

In this U.S. Bureau of Mines report, the conditions required for the direct reconstruction of a tomogram from observed line integrals are examined. Because of the limited access to the working faces in coal mines, the special case of access to only two opposite faces is emphasized. Classical matrix methods were used for small dimensional (2 by 2, 3 by 3, and 4 by 4) applications to determine the limitations and the requirements for a solution. The results for large (n by n) grids were then inferred and generalized from those of the smaller grids and matrices. Limited access tomography is found to be appropriate for in-seam hazard detection from seismic and microwave data, but it is shown that additional data must be added to obtain a direct solution.

Jan 1, 2010