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By Otto Ruhl

"INTRODUCTION With the conclusion of the war and the ensuing readjustment of industry to peacetime conditions, the Bureau of Mines recognized that definite and complete figures on the reserves of zinc and lead ores in the Tri-State District would be needed for an evaluation of the problem of reconversion. In October 1945 its engineers began examination of all the mines and pros¬pects in the Tri-State area and assembling of the basic data for a complete detailed estimate of the reserves of the field. Six to twelve months will be required to complete the report with the personnel available; therefore, it has been deemed advisable to provide as much data as possible for imme¬diate use. Accordingly, a confidential report prepared in January 1944 for the use of and in cooperation with the War Production Board has been brought up to date to form the basis of this preliminary estimate of reserves.The 1944 report has been revised by first subtracting from the reserves then set up for each mill group the amounts mined and milled by those properties for 1944 and 10 months of 1945, with November and December estimated. These production statistics were taken from the monthly reports of the Metal Economics Division of the Bureau of Mines. The remaining reserves were then adjusted by additions of tonnages of new reserves disclosed by developments during the years 1944 and 1945. Such additions were based upon the data furnished by various operators, upon estimates supplied by the Federal Geological Survey District Office at Miami, Okla., and upon estimates of the engineers of the Bureau of Mines Joplin field office.It is apparent from the work so far accomplished in the detailed exami¬nations now under way that the final estimate of reserves will probably be somewhat greater and will differ to a certain degree from these preliminary totals, not only as to the tonnages of ere but also as to grades and distribution by areas. This is due to the fact that all the factors of development, exploration, and geology are being considered in the present examination and report for each individual mine and prospect, whereas the previous reports covered only the immediate development factors surrounding each mill group then in active operation or projected for operation at some early date in accordance with the possible needs for war production."

Aug 1, 1946

By A. J. Barry

Two methods of testing anchorages of headed expansion-type mine roof bolts were investigated by the Federal Bureau of Mines to determine whether they are acceptable for general use. In both methods a load was applied to a tightened bolt with a hydraulic jack. A total of 80 tests, 40 using each method, was conducted in 4 test areas in 3 commercial coal mines. Electric resistance strain gages were used in all tests to indicate true bolt load as the bolt was tightened and when an additional load was applied with the hydraulic jack. The results indicate that: 1. The relationship between the true bolt load and the jack load will vary according to the test method until the two loads become equal. The bolt load-jack load relationship below this point can be determined only with strain gages. 2. The point at which the two loads become equal can be estimated by noting the load when the hardened washer becomes loose in one method, and when the bearing plate becomes loose from the roof in the other. It also can be approximated for either method of testing by noting the load when the first abrupt change in the slope of the jack load-bolt displacement curve occurs. 3. The anchorage characteristics of the test bolt can be determined from the data obtained from either method by examining the slope of the jack load-bolt displacement curve above the point at which the true bolt load is equal to the jack load.

Jan 1, 1960

By D. E. Kirby

In the preparation of beryllium-copper alloys by fused-salt electrolysis, beryllium was electrowon from beryllium oxide dissolved in fluoride electrolytes and deposited on copper cathodes. At 880° to 1,030° C, deposition was on solid cathodes. Beryllium deposited on the copper, forming a liquid alloy that dripped from the cathode. Dripping alloys containing 3 to 4 weight-percent beryllium were produced with as high as 90 percent cathode current efficiency, by electrolysis at 910°.C. To prepare alloys of higher beryllium content, attempts were made at depositing beryllium on liquid copper cathodes. These efforts were generally unsuccessful, although alloys containing as much as 12 percent beryllium were prepared by this method. At temperatures of 1,100° to 1,300° C, requisite to maintaining beryllium-copper compositions as liquids, the beryllium reacted with cell structures.

Jan 1, 1972

By G. V. Sullivan

This report describes an investigation by the Bureau of Mines of flotation techniques for the recovery of chromite from fine-grained disseminated ores. Reported work on the concentration of chromiferous materials shows that flotation has been applied almost exclusively to slime-free pulps. Therefore, chromium recoveries that could be obtained by flotation were related to the amount of slime rejected. However, results of recent studies by the Bureau of Mines showed that des liming is not a requisite to selective concentration of chromite. Laboratory-scale tests on seven ore types from the more important chromium-bearing areas of the Pacific Northwest showed flotation to be technically feasible for treatment of all but one of the samples. Concentrate grades were affected more by the composition of the chromite mineral than by the grade or character of the ore. Test results from three of the samples showed that, without prior desliming of the pulp, 78 to 91 percent of the chromium could be recovered in concentrates of 90 percent or more chromite; two samples responded to similar treatment, resulting in concentrates of more than 80 percent chromite with recoveries of 85 and 89 percent chromium. One sample of mill products, subjected to severe weathering, required removal of the primary slime to obtain a concentrate of 65 percent chromite with only 75 percent chromium recovery.

Jan 1, 1960

By Joan C. Biordi

In this research by the Bureau of Mines, slightly lean CH4-O2-Ar flames at 0.042 atm with and without small amounts of the inhibitor CF3Br were probed using molecular beam and mass spectrometric techniques. Ratios of product concentrations to reactant concentrations were formed and compared with the equilibrium constant for seven reactions--(l) H+O2 = OH+O, (2) O+H2 = OH+H, (3) OH+H2 = H2O+H, (4) OH+OH = H2O+O, (5) CO+OH = CO2+H, (6) Br+HBr = Br2+H, and (7) H+HBr =H2+Br--to determine to what extent they may be considered balanced in various regions of the flame. With the possible exception of reaction 4, none of the reactions are completely balanced until maximum flame temperature is reached. Once the reactions become equilibrated, their balance is maintained as the temperature and radical concentrations falloff in the secondary reaction zone. Reaction 7, in inhibited flames, is balanced at relatively low temperatures, comparable to reaction 4. Reaction 6 was found not to balance in either the secondary or primary reaction zones. Radical decay in the secondary reaction zone was analyzed using the pool-decay concept. The important recombination reactions were judged to be H+OH+M~H2O+M, and H+O2+M?HO2+M. A rate coefficient of 2x1016 cm6 mole-2 sec-1 is calculated for M = the burnt gas mixture of Ar, HaO, CO2, and 5x1015 cm6 mole-a sec-1 is calculated for M = Ar (both for T = 1,750±150 K).

Jan 1, 1977

By K. K. Kershner

Important contributions can be made to conservation of natural resources by recovering mineral values from primary and secondary metallurgical slimes and flue dusts. This applies particularly to ultrafine mineral particles that escape recovery by conventional mineral dressing. In the interest of economy and conservation the Bureau of Mines is investigating fundamental properties of ultrafine mineral values in slimes as a means of developing new or improved methods of mineral recovery. The work described in this progress report was carried on in the Bureau's laboratories at Rolla, Mo., from 1951 to 1953. The mineral material used as a subject for study was tin-ore slimes. DESCRIPTION OF TIN SLIMES The tin slimes consist principally of quartz, with appreciable quantities of tourmaline and sericite mica and small amounts of cassiterite, pyrite, hematite, and arsenopyrite. The tin content is approximately 0.5 percent.

Jan 1, 1954

By J. C. Edwards

Fire experiments were conducted in the Safety Research Coal Mine (SRCM) at the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, with coal, diesel-fuel, electrical-cable, conveyor-belt, and metal-cutting fire sources to determine the response of fire sensors to products-of-combustion (POC). Metal oxide semiconductor (MOS) and smoke fire sensors demonstrated an earlier fire detection capability than a CO sensor. This capability was of particular significance for a conveyor-belt fire in which the optical visibility was reduced to 1.52 m with an increase in CO of less than 2 ppm at a distance of 148 m from the fire. Application of a neural-network program to the sensor responses from each type of fire source resulted in correct classifications of coal, diesel-fuel, cable, belt, and metal-cutting combustion with a mean of 96% of the test data correctly classified.

Jan 1, 2000

By J. C. Edwards

Fire experiments were conducted in the Safety Research Coal Mine (SRCM) at the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, with coal, diesel-fuel, electrical-cable, conveyor-belt, and metal-cutting fire sources to determine the response of fire sensors to products-of-combustion (POC). Metal oxide semiconductor (MOS) and smoke fire sensors demonstrated an earlier fire detection capability than a CO sensor. This capability was of particular significance for a conveyor-belt fire in which the optical visibility was reduced to 1.52 m with an increase in CO of less than 2 ppm at a distance of 148 m from the fire. Application of a neural-network program to the sensor responses from each type of fire source resulted in correct classifications of coal, diesel-fuel, cable, belt, and metal-cutting combustion with a mean of 96% of the test data correctly classified.

Jan 1, 2000

By James S. Browning

The Bureau of Mines conducted laboratory and small-scale continuous tests of kyanite ore from Georgia to determine the technical feasibility of recovering commercial-grade kyanite concentrates by flotation. The research indicated that combinations of sulfuric acid and petroleum sulfonate may be used effectively for flotation of kyanite from quartzite-kyanite ore. Over 87 percent of the kyanite was recovered in a concentrate analyzing 55.8 percent A1203 and 5.3 percent acid-soluble Fe203. Subsequent treatment of the flotation concentrate by high-intensity wet magnetic separation reduced the acid-soluble Fe203 to 0.8 percent and increased the alumina content to 57.6 percent, with a recovery of 82.7 percent of the total alumina in the ore.

Jan 1, 1970

By Paul Hopkins

The following methods have been selected from a large number tried while assaying several hundred samples of placer concentrates. It is thought that some of these methods may be useful to those who are required to assay similar products containing large quantities of metallic articles, such as jeweler's sweepings. No great difficulties will be encountered in assaying black sand from beaches or river bars. Such samples require care in grinding and sifting so that no oversize particles of gold or platinum are lost. It is also necessary to have sufficient silica in the flux to form a fluid slag with the excess of iron, magnesium, or chromium which such samples contain. It is much more difficult to assay black sands, or concentrates, produced in large-scale placer-mining operations. These products are usually much harder and more abrasive than the beach black sands. They also contain numerous metallic particles resulting mainly from wear on the mining machinery. These particles consist chiefly of iron or steel but also contain lead, copper, and alloys such as babbitt, solder, brass, ferrosilicon, etc. Fairly large particles of gold are often found. Some samples will contain as much as 10 percent of such metallic particles. It is not feasible to remove the particles of iron with a magnet and discard them, as they invariably contain gold, sometimes a considerable amount. This gold is attached to the iron particles by rust or wedged into cavities. Scraps of sheet iron are often found which have become tightly folded or rolled and contain gold or amalgam within the folds.

Jan 1, 1934

Effective in the 1987 Minerals Yearbook, the following changes have been made: "Asphalt" has been deleted; "Greenland" is included in the "Potash" chapter; "Meerschaum" is included in the "Clays" chapter; and "Staurolite" is included in the "Abrasive Materials" chapter. QUARTZ CRYSTAL Cultured quartz crystal production increased significantly in 198?, following 2 years of reduced production. Consumption of domestic lascas as feedstock for cultured quartz crystal increased. Imports of lascas from Brazil also increased. Although no lascas was mined in the United States during the year, the domestic producer supplied material to consumers from company stockpiles. Specimen-quality natural quartz was very much in demand; quartz crystal for this application is discussed in the Gem Stone chapter.

Jan 1, 1989

By M. C. Chapman, P. L. Swanson, A. T. Iannacchione

The National Institute for Occupational Safety and Health (NIOSH) evaluated microseismic activity from three field sites to compare and contrast the characteristics of microseismic emissions from very different geologic, stress, and mining environments. Recently, NIOSH has embarked on a research program to evaluate the use of microseismic monitoring information to identify roof fall failure processes and to assess its potential to warn of unstable roof conditions. Large roof instabilities, such as roof falls and certain roof caving events, have proven difficult to anticipate representing an increased risk to miners working in these inherently hazardous areas. When local failure processes are better understood, appropriate control measures can be engineered to mitigate these hazards. This study used microseismic emissions to help identify three local rock failure processes. It was also shown that analysis of microseismic emissions can aid in assessing the degree of instability associated with these local rock failure processes.

By Richard F. Link, George W. Gladfelter, George S. Koch

Contour maps, useful in mineral industries, for example, in analysis of trends in mineralization, may be constructed through statistical methods of regression analysis programed for an electronic computer, For many applica­tions, the resulting maps are more useful and objective than conventional contour maps that are necessarily subjective because they are drawn by hand methods. In principle, an equation is found that fits a quadratic surface to observed elevations of points referred to a datum plane, The quadratic sur­face, represented by a contour map may take the form of a ridge, valley, dome, or basin, Once an equation has been derived, its coefficients may be used to construct a contour map--showing lines of equal value that are derived from the original observed data points by the averaging process of fitting the quadratic surface. Methods employed are illustrated by an example analysis, based on data from a large vein of the Fresnillo mine, Zacatecas, Mexico. Computer programs to implement the methods are described in an appendix,

Jan 1, 1964

By C. B. Manula, R. L. Sanford, R. A. Rivell

A central requirement for using simulation models is the need for retrospect testing to validate experimental conclusions. Acceptance of a model by managers and safety practitioners is more likely to depend on its tested performance in-the field rather than on the underlying logic or the validity aspects of the model itself. It is here that simulation bridges the gap between theory and useful design procedures. The original version of the rail haulage sub-assembly was success¬fully tested in the field (Sanford, 1969). However, the case studies that were described here involved single-stage haulage and restricted jobtypes from UGMHS. Since this report together with Volume VI (Production Subsystem) describes extensive changes and modifications to the rail haulage sub-assembly and UGMHS, field tests were necessary to verify both the rail model and the linking concepts to the Produc¬tion Sub-system. Mine Description The candidate mine selected for model verification works the 6 1/2 foot Pittsburgh seam. Shaft openings are used for manways and ventilation and a dual compartment slope for materials handling. In the bottom half of the slope, a hoist with track handles supplies and equipment. In the upper half, a 42 inch belt conveyor travelling at 450 fpm moves coal from a rotary dump to the surface. The immediate roof is shale with the first 12 inches taken during development mining. About 4500 raw tons are produced daily from seven face units and one spare working three shifts. At seven of the sections,

Jan 1, 1974

By V. Castranova, K. Van Dyke

"I. INTRODUCTIONA mechanism which is present in leukocytes and capable of releasing histamine from rabbit platelets was first described by Barbaro and Zvaitler in I966. A soluble mediator between rabbit leukocytes and platelets was also detected by Siraganian and Osier in 1971. This factor was isolated and characterized in 1971 by Benveniste et al. and named platelet activating factor i PAF). It was shown to be released from rabbit basophils through an antigen - IgE-dependent mechanism. The presence of PAF in human leukocytes' and its aggregation and releasing effects on human platelets were also demonstrated. Chemical analysis has shown that PAF is a glycerophospholipid with a choline polar head group. an ester-linked acyl chain at the second carbon and a nonester link at the first carbon.' The structure of the mediator was found to be 1-O-alky1-2-acetyl-sn-glyceryl-3-phosphoryl choline and it has been chemically synthesized.""' A variable portion exists in the alkyl group attached to the first carbon which can have a variety of molecular sizes such as C and C (where Cu is more abundant). Recent work by Pinckard et al."" has shown that there are at least five variations of the alkyl group.PAF has been shown to have a broad range of biological effects. Release of PAF from alveolar macrophages may be important in asthma, allergy, and shock states. In a rabbit model of antigen IgE anaphylaxsis. PAF can induce all of the effects of antigen challenge and. therefore is presumed to be a key mediator in production of anaphylaxsis. In addition to aggregating and degranulating platelets it is a potent chemoattractant."" and causes contraction of guinea pig ileum contraction of lung tissue and enhanced capillary permeability PAF has important effects in the kidney and is also known as the renal hypotensive factor proposed by Blank et al. who found the structure of PAF independently of Benveniste et al.' In producing these responses. PAF acts by a receptor-like mechanism. In platelets. PAF selectively desensitizes itself but not thrombin or collagen. In smooth muscle tissues a similar phenomenon occurs with anaphylatoxin or other stimuli.In vivo. PAF probably acts in concert with other agents in producing its various biological effects. It causes platelets to release histamine serotonin and RCS (rabbit-contractile substance formed from prostaglandins PPG2, PGH2 and TXA2) which contracts rabbit aorta. PAF can cause cells to release SRS-A and leukotriene B."

Jan 1, 1989

By W. A. Haley

The purpose of this investigation was to develop and improve mining methods for mining thin coal beds, to increase productivity, and to increase the recovery of coal. German coal planers and a modified longwall system of mining were introduced into American mines and are bringing about increased productivity and better recovery as compared with the conventional methods displaced. Since the first installation, 4 additional planers have been purchased by coal companies and over 1-1/2 mil¬lion tons of coal has been mined by them, using the modified longwall mining method. INTRODUCTION Except from 1932 to 1934, the growth of mechanical loading in underground bituminous-coal and lignite mines in the United States has increased steadily. The amount of coal loaded mechanically in underground mines has increased from 0.3 percent in 1923 to 79.6 percent of the total underground production in 1953.3/ The use of new and improved mining machines and auxiliary equipment, together with new techniques in mining methods, usually has resulted in increased productivity.

Jan 1, 1957

By N. S. Dalal, X. Shi

"The oxidation of NADPH by vanadate(V) in the presence of glutathione reductase showed typical enzymatic kinetics. The oxidation was inhibited by N-ethylmaleimide, a glutathione reductase inhibitor. Superoxide dismutase had no significant effect on the oxidation, indicating non-involvment of the superoxide radical. The vanadate(V) reduction was found to be a one-electron transfer process. These results suggest a new pathway for vanadate(V) metabolism and a new function of glutathione reductase. Compounds of vanadium(V), such as NaV03 , exert potent toxic effects on a wide variety of biological systems (1-3). Despite intense current activity, however, the biochemical mechanism of vanadate(V) toxicity is still not well understood (1- 14). It is believed that one of the important pathways involves the oxidation (by vanadate(V)) of NAD(P)H (15, 16), but, to our knowledge, there has been no report of the identification of any vanadate(V) reductase. With a view to finding if there exists any vanadate(V) reductase, we have investigated the oxidation of NADPH by vanadate(V) in the presence of glutathione reductase. Glutathione reductase (GSSG-R)2 was selected because our previous studies have shown (17) that GSSG-R can act as a reductase for chromate(VI), which is isoelectronic with vanadate(V). We find that GSSG-R does indeed function as a NADPH-dependent vanadate(V) reductase, thus pointing to a new pathway for the metabolism of vanadate(V), as well as to this property for GSSG-R. MATERIALS AND METHODSSodium metavanadate (NaV03 ), henceforth vanadate, was purchased from Aldrich and its solution was always freshly prepared. The GSSG·R used was from bovine intestinal mucosa and was purchased from Sigma. The oxidation of NADPH was followed photometrically as the decrease in absorbance at 340 nm. The spin trap, 5,5-dimethyl- pyrroline-N-oxide (DMPO), was purchased from Aldrich and used without further purification, since very weak or no spin adduct signal was obtained from the purchased sample when used alone.ESR spectra were obtained at X-band (9.7 GHz) using a Bruker ER200 ESR spectrometer. The magnetic field was calibrated with a self-tracking NMR gaussmeter (Bruker, Model ER035A) and the microwave frequency was measured with a digital frequency counter (Hewlett-Packard, Model 5340A). An ASPECT 2000 computer was used for data storage and analysis. The concentrations given in the figure legends are the final concentrations. All experiments were carried out in the phosphate buffer solution (pH 7.2) and at room temperature."

Jan 1, 1990

In the past, mine management has been concerned with removing water from active mining sections primarily because it hampered the movement of mining equipment and aggravated the working condition of the miners. Pumping water to sumps and gravity drainage by ditching have proven successful in mines for minimizing section down time due to water influx. However, with the advent of more strict pollution laws the mining engineer must now be concerned with keeping water out of the section and also with preventing it from causing pollution. A review of the handbooks and textbooks used in the mining engineering curricula reveals that little has been written concerning acid mine water prevention or control in underground coal mines. Additionally, the review of the curricula of mining schools indicates they are not teaching the engineering students the necessary techniques of mine water management as they relate to the abatement of mine water pollution.

Jan 1, 1970

By R. A. Guereca

The Bureau of Mines conducted an analysis to determine criteria for steady-state, laminar flow boundary conditions for a coiled-tube gas viscosimeter by comparing experimental data from a thick-walled, stainless steel capillary in a horizontal, straight-tube condition, with similar data taken after the same capillary was formed into a helix. Overlapping volumetric f10wrates and pressure drops are covered for both configurations at pressure levels of 28, 225, and 1,000 psia at 3000 K. Friction factor, Reynolds number, and Dean number correlation plots show conditions where the coi1ed-tube flow deviates from straight-tube flow. The coiled-tube data indicate departure from Poiseui11e steady-state laminar flow at a Reynolds number close to 390 and a Dean number of about 15. Below these conditions and consistent with the data reported, Dean's circulation appears negligible. For the particular coil used, a conservative upper limit of 10 is chosen for the Dean number corresponding to an upper limit of about 250 for the Reynolds number.

Jan 1, 1967

By Ralph L. Brown

As a preliminary step in a recent study4 of the phenols present in a low-temperature tar, the writers prepared the hydroxyacetic derivatives of the simpler available members of the phenol series in order to obtain material to assist in fixing the identity of similar derivatives obtained from the phenols of the tar. When comparing the melting points of the pure derivatives we had made with those given in the literature we were unable to find the characteristics of one of the xylenol derivatives which we had prepared--namely the 1, 3 dimethyl-2-phenoxyacetic acid, In the belief that the compound does not appear in the literature we are presenting these notes on its preparation and its melting point. The hydroxyacetic derivatives are easily prepared and in good yield, and are useful in studying mixtures of phenols. The 1, 3 dimethyl-2-phenoxyacetic acid makes the fifth of the six isomeric derivatives to be reported in the literature. Gluud and Breuer report the preparation of the 1, 3, 4, the 1, 4, 2, and the 1, 2, 4 derivatives. A fourth isomer-¬the symmentrical 1, 3, 5--has been reported by Schutz6, although no record of it occurs in the indexes. The remaining derivative--the 1, 2, 8-has not, been found and it is now being synthesized in the Organic Chemistry Laboratory of the. Pittsburgh Experiment Station. It is true, however, that from a phenolic fraction boiling 215.9 to 2180 isolated from natural petroleum, Tanaka and Kobayashi7 obtained a hydroxyacetic derivative melting at 103.3°. They state that this is the 1, 2, dime ethyl-3-phenoxyacetic acid but present no evidence for the assertion. The known derivatives are summarized in Table 1 following;

Jan 1, 1929