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By K. O. Bennington

The thermodynamic properties of two manganese silicates, pyroxmangite and fowlerite (zincian rhodonite), were experimentally determined by the Bureau of Mines. The standard enthalpies of formation were determined by hydrofluoric acid (HF) solution calorimetry, the low-temperature heat capacities by adiabatic calorimetry, and the high-temperature heat capacities by differential scanning calorimetry over the range 322 to 1,372 K. Data for the standard enthalpy of formation (AH298), the derived standard entropy (S298), and the standard Gibbs energy of formation (AGf 298) are as follows: Pyroxmangite [(Mn0.9554Cao,0446)(Si03)J- AHf298 319.668±0.46 kcal/mol AH298 (from oxides)... -7.215±0.11 kcal/mol 5295 23.785±0.048 cal/(mol'K) AGf298 -301.190±7.96 kcal/mol Fowlerite [(Mno.7o3Zno.0884Ca0.2086)(Sio3)]--AHf298 ?... -329.914±0.419 kcal/mol AH298 (from oxides)... -8.400±0.104 kcal/mol 5598 21.949±0.059 cal/(mol-K) AGf298 -310.716±7.99 kcal/mol These experimentally determined values were combined with data from the literature to calculate the Gibbs energies and equilibrium constants of formation over the temperature range of the measurements. Standard enthalpies, Gibbs energies, and equilibrium constants of formation are given as a function of temperature from both the elements and the constituent oxides.

Jan 1, 1987

By M. M. Tilman

The objectives of this research were to determine the practicability of using cobalt as a means of controlling the amount of ferrite in the micro-structures of semiaustenitic stainless steels, and to determine the effects of reduced ferrite content on mechanical properties of these steels. Cobalt additions of up to 3 weight-percent were made to type 17-7 PH2 (AISI 631) stainless steel. Ferrite contents were determined for alloys in the aged condition, and for alloys quenched from the hot working temperature. Ferrite can be completely eliminated from the microstructure of 17-7 PH stainless steel by additions of cobalt, but complete elimination of the ferrite phase results in lower tensile strength, yield strength, and hardness. Tensile properties, hardness, and impact strength were determined for aged material. A subzero temperature treatment before heattreating was necessary to obtain maximum strength in the alloys containing cobalt. Addition of 2 weight-percent cobalt enhances mechanical properties of 17-7 PH stainless steel.

Jan 1, 1968

By Paul M. Tyler

One of the best present-day yardsticks of the material welfare of a nation is its consumption of minerals, The United States, with only 7 percent of the world population, consumes 45 percent of the world wealth, pays the highest real wages, has the shortest working hours, and numbers the largest percentages of home owners among its population, and at the same time its per-capita consumption of minerals is far greater than that of any other nation. In 1937, British India, with roughly twice the population of the United States, used less than 2 percent as much lead, 4 percent as muck zinc, and 13 percent as much copper; even in Europe, which has three times our population and where war preparations have greatly expanded the normal needs of peaceful industries, the aggregate consumption of metals and industrial minerals other than lignite is less than the total for the United States alone. The march of civilization passed from the Stone Age to the Bronze Age before the dawn of history. It may be questioned whether man or monkey first threw stones at an enemy, but only man could have fashioned rough stones into weapons. Eoliths rudely shaped by apelike men are believed by archaeologists to have antedated by hundreds of thousands of years the existence of our own human ancestors. The primitive people that followed the retreating Ice Cap northward in early quaternary period - at least a million years ago - were fairly adept in the shaping of flints and even used a little copper. The Bronze Age, so-called, superseded the Stone Age when, around 8,000 B. C., the news spread that chunk s of natural copper could be pounded into better weapons or cutting implements than ever could be made by chipping stones. The Bronze Age gave place to the Iron Age about 1,000 B, C., and though students of modern history may speak of the Coal Age, the Petroleum Age, and the Automobile Age, and so on, these ages have all been crowded into a brief century and a half. The truth is that we still are in the Iron Age, unless perhaps we choose to call it the Age of Many Metals.

Jan 1, 1940

By H. W. Wainwright

.1. The purification pilot plant and the equipment, solution, and gas cycle used for removing hydrogen sulfide and carbon dioxide are described. 2. As sulfur recovery is necessary in any large Fischer-Tropsch plant, pilot-plant runs were made at 300 p.s.i.g. to study the efficiency of tri-ethanolamine solutions in removing selectively hydrogen sulfide from gases containing varying amounts of carbon dioxide. 3. Aqueous solutions of TEA of 20, 30; 35, and 50 percent were investi¬gated. Data indicate that 30 to 35 percent is the optimum concentration if both selectivity and economy are considered. Slightly better selectivity is obtained with the.20 percent solution, but steam consumption is greater owing to the higher solution rates. Results from our pilot plant runs indicate that a 50 percent solution not only produces an acid gas of lower hydrogen sulfide content but also requires high solution rates to effect hydrogen sulfide purification. 4. Data from 37 runs using TEA are presented in tabular form. In addition, the data are correlated and presented in three sets of curves. By using these curves, it is possible to calculate the compositions of the purified and acid gases for various raw gas mixtures. 5. In cooperation with the Southern Natural Gas Co., investigations were carried out at 300 p.s.i.g. on the simultaneous removal of hydrogen sulfide and carbon dioxide, from gases using various concentrations of diethanolamine. 6. Data from 17 runs employing 20, 30, and 40 percent DEA are reported in both tabular and graphic form. 7. A comparison of the data from one DEA run made at 200 p.s.i.g. with those from the runs operating at 30O p.s.i.g. shows float the absorption capacity of the solution, and, hence, the steam requirements per gallon are about the sage for both pressures. .The only real advantage of the higher pressure is the additional volume of gas that can be treated. 8. The quantity of steam needed to reactivate fouled TEA and DEA solutions increased as the reactivator pressure was increased about 1,0 to 1.1 pounds of steam was required for each gallon of circulating solution when the reactivator was operated at 5 p.s.i.g. 9. A curve is included that shows the effect of the hydrogen sulfide con-centration in a lean 35 percent TEA solution on the hydrogen sulfide content of the purified gas and on steam consumption for reactivation. 10. Both TEA and DEA reduced the organic sulfur content of the raw synthesis gas considerably. Analyses of the lean amine solutions showed a gradual build up of sulfur compounds, indicating that the compounds formed by the amines and organic sulfur do not break down under the ordinary operating conditions of the reactivator. 11. Considerable operating difficulty was encountered in the pilot plant owing to foaming of the amine solutions. Laboratory experiments in which the effectiveness of certain antifoam agents was studied showed Alkaterge C to be most promising for the particular conditions studied.

Jan 1, 1952

By L. R. Burdick

The Smokescope is an instrument recently developed for determining the density of smoke by shade comparison. The instrument is designed so that the smoke is seen adjacent to two shades of gray corresponding to Nos. 2 and 3 on the Ringelmann chart. Data on smoke density are important in the smoke-abatement field. The method that is specified and accepted as standard for smoke-density determination by the majority of city smoke regulations involves comparing the smoke shade with the four shades on the Ringelmann chart as published by the Bureau of Mines.2/ This investigation was made to determine the accuracy and convenience of the Smokescope. It was conducted as a part of the Bureau I s air-pollution work, which includes the study of techniques that will promote smoke abatement. The accuracy of the Smokescope was arbitrarily defined as the difference between the Smokescope determinations and the determinations by the accepted, standard method and was expressed as Smokescope correction. Although the corrections obtained were strictly correct only for the two observers and the Smokescope of the investigation, they indicate what might be expected from any observer who uses a Smokescope with reference shades that duplicate those of the test instrument. The report is devoted largely to the data on Smokescope correction, which were taken from a single stack under controlled smoke conditions. Field work, which was done at various locations with different stacks, is mentioned briefly in connection with the comparison of the convenience of the two methods. The data for estimating Smokescope correction were taken for the three variables that were expected to affect the results, namely, the density of the smoke, the amount of light, and the color of the sky behind the smoke.

Jan 1, 1955

By Robert G. Lundquist

This report summarizes all relevant findings and conclusions regarding capabillty of high-energy projectile impact to operate effectively in an open pit mining environment and to successfully handle secondary breakage and bench scaling problems. A silenced, aimable, mobile projectile launcher was designed and fabricated, utilizing a Government-furnished smooth-bore, 90 mm cannon. The silenced launcher was tested at the contractor's test site prior to shipment to ANAMAX Mining Company's Twin Buttes Mine near Tucson, Arizona. Demonstration tests were conducted at an inactive waste dump in the mine on 39 oversize boulders to determine the relationship between boulder size and projectile energy required for secondary breakage. The high energy projectile impact method (known by the acronym REAM -Rapid Excavation and Mining) was tested on an additional 23 boulders in the working mine and on 31 areas of potentially loose rock high on the pit walls. Most of the secondary breakage tests were successful and acceptable for open-pit mining purposes without producing large amounts of fly rock. Five of the 31 scaling tests were successful with one shot, but most of the remainder required two or more shots, and a few could not be dislodged because they were not as loose as they appeared to be, based on visual examination from a distance. Cost comparisons between the REAM method and conventional methods of secondary breakage and bench scaling are discussed. A film documentary, REAM--Mining Applications of High Energy Projectile Impact, has been produced by the contractor depicting the applications of the silenced cannon.

Jan 1, 1976

By C. P. Mishra

The Bureau of Mines performed a study of the availability of cobalt from market economy countries. The study entailed the detailed analysis of 97 deposits which contain 3.9 billion lb of cobalt at the demonstrated level; in 94 of the deposits cobalt is recovered as a byproduct, and in 3 it is considered the primary product. Since 97 pet of all recoverable cobalt is derived as a byproduct from copper and nickel deposits, the report focused on these two sources. At an assumed market price of $0.89flb for copper, $3.45/lb for nickel, $475/tr 021 for platinum, and $7/lb for cobalt, 1,330 million lb of cobalt at the demonstrated level are potentially available. This total includes 1,105 million lb of cobalt from copper properties, 190 million lb from nickel, 29 million lb from platinum, and 6 million lb from primary cobalt. This analysis indicates that the production cost for 589 million lb of cobalt can be totally covered by the revenues obtained from the other metals produced. The impacts of increases in capital investment and energy costs are also discussed.

Jan 1, 1985

This publication summarizes, for potential contractors and other interested parties, the proposed research, development, and demonstration contract projects programed by the Bureau of Mines for fiscal year 1977 (October 1, 1976-September 30, 1977) under its Advancing Coal Mining Technology program. The objective of these projects is to provide an ordered and sequenced series of advances toward the overall goal of providing the system technology required to increase the productivity of the coal mining process.

Jan 1, 1977

By T. M. Garland

This report presents a more extensive perspective of the calculated profitability of developing and producing crude oil and associated natural gas by primary methods from selected onshore areas of the United States. Estimates were made for cost of drilling, completing, equipping, and producing oil wells at four depths in seven onshore producing areas. A computer program was developed for calculating the discounted cash flow rate of return for the 64 different models in each area resulting from varying the oil-producing rate and production decline rate. The results of these calculations provide data that vividly illustrate the change in rate of return to changes in well depth, initial producing rate, and production decline rate, as well as to variations in development cost and operating expense. Cost per barrel of oil produced in terms of annual cost and total cost is also discussed. Included in the report are explanations of the method of determining costs and the procedure used for profitability analysis. Summaries of all cost estimates and results of profitability analyses are presented in the appendix in tabular form for each of the seven producing areas.

Jan 1, 1972

By Irving Hartmann

As part of the continuing effort by the Bureau of Mines to promote mine safety, research work is being conducted at the Experimental coal mine, Bruceton, Pa., on the prevention of coal-mine explosions and on other mine-safety problems. The principal subjects studied during the past 2 years are briefly described in this paper. Although at present these problems are relevant particularly to the mine layout and to high-speed mining practices in numerous American coal mines, it is hoped that the findings will prove interesting and useful also to our European research colleagues. Some of the investigations treated here will be presented in greater detail in forthcoming Bureau of Mines reports. 1. UNDERGROUND STORAGE OF COAL CUTTINGS The seams in mist American bituminous-coal mines are undercut, shear-cut, or top-cut before blasting. The cuttings arc generally loaded out with the balance of the coal. However, in some mines it is not economical to load and remove cuttings from the mine. This applies especially if the cut section of the seam is of appreciably lower grade than the rest of the coal, or if the cut is made partly into an adjacent stratum that is high in incombustible content. In such mines the cuttings are sometimes stored in random heaps in rooms or other areas, along the ribs of mine entries, or in layers on the floor of rooms or entries.

Jan 1, 1956

By G. S. Scott

The Bureau of Mines is engaged in research to assess the hazards associated with the handling, storage, and use of combustible gases, vapors, and. liquids encountered in mines and in industry. As a part of this general pro-gram, numerous limits of flammability and ignition temperatures are being investigated for a wide variety of combustible materials, and methods are being developed to minimize the explosion hazards of these combustibles. The Bureau receives numerous requests for information on the explosion hazards of specified combustible mixtures under various conditions of use. This information circular has been prepared to assist those who may have similar requests. Destined primarily for the layman with a limited technical knowledge of the subject, it considers rather briefly the numerous factors that enter into the general problem of gaseous explosions and their prevention.

Jan 1, 1951

By Stanton L. Tainter

As a part of a wartime program to aid in the development of known ore bodies and in the discovery of hitherto unknown deposits of strategic minerals, the Bureau of Mines investigated the feasibility of diamond-drilling the Christmas copper deposit, in Gila County, Ariz., to increase the reserves of milling ore. Upon recommendation of the examining engineer, drilling was begun in September 1942, from the bottom (770) level of the mine. One month later, in cooperation with the Bureau, the Federal Geological Survey started geologic mapping of the mine workings. Since extensive and costly development would be required, the War Production Board concluded that ore below the bottom level could not be mined at that time because of the wartime shortages of equipment and man-power. In January 1943, drilling was moved to the 300 and 400 levels to locate reserves readily accessible for continued production of fluxing ore. This drilling, which was under the supervision of L. G. Marshall, was completed in January 1944.

Jan 1, 1948

By Gary P. Sames

Shale roof deterioration in coal mines. caused by ventilation air humidity fluctuations, is a common ground control problem. Shale roof deterioration often results in increased accidents, decreased production, inadequate ventilation, and increasing operating costs in maintaining haulage roads and airways. The results of Bureau of Mines research indicate that air tempering entries are an effective method of controlling deterioration prone shales. Some of the conclusions and recommendations drawn from Bureau research include (1) moisture sensitive shales will react adversely to moisture gains and losses, (2) the majority effect of specific humidity fluctuations can be concentrated in and absorbed by tempering entries, (3) tempering entry panels should be located as near to the main intake as possible, (4) tempering panels should be designed for a conservative recovery and provide a minimum of 20-to 30-min air residence time, (5) ventilation and escapeway requirements must be considered early in panel design, and (6) an efficient support and sealant plan can increase the life expectancy of a tempering panel.

Jan 1, 1985

By G. E. McElroy

[The ventilation of development faces In nines for diluting Gas or dist concentrations and, in hot nines for providing air-motion cooling effect, by fan-pipe units discharging high-velocity steams of air close to the face, is an important phase of mine ventilation. The effectiveness of such units depends largely on the air-flow distribution between the pipe discharge and the face, n subject on which little definite information is available. A study of the air flow from grills into rooms3/ has provided some basic data, but under conditions so different from mine fan-pipe installations in development ends that the data are of doubtful application to mine installations, owing to differences in air-flow conditions.]

Jan 1, 1940

By B. H. Clemmons, C. H. Schack

Extractive metallurgy techniques currently employed to recover silver from primary ores and secondary scrap were reviewed and evaluated to identify and delineate metallurgical problems whose resolution would increase the supply of silver from domestic materials. The survey revealed that practically all primary silver is recovered by froth flotation concentration of various types of ores, followed by smelting and refining of the separate lead, copper, and zinc concentrates. Silver losses during the complex processing are, with rare exception, inconsequential. Furthermore, any silver production gain from base metal ores, which contribute about two-thirds of the total primary silver, is directly dependent on improvement in the market for the base metals. Statistical data on new and old silver scrap are wholly inadequate to make reliable conclusions about scrap processing problems and the possibility of increasing the recovery of silver from the many forms of secondary silverbearing materials. The available information indicates (1) that efficient silver reclamation practices are employed by the larger users of silver, and (2) that recovery of additional secondary silver involves solution of problems of collection rather than of processing. Several possibilities exist for limited increases in silver production from primary ores by improvement in metallurgical practices. Specifically, research is needed to (1) solve the problem of recovering silver from the copper ores of the Copper Range district, Michigan; and (2) devise economically feasible methods for recovery of silver from presently marginal or submarginal ores that because of grade, location, and frequently complex nature cannot presently be exploited by conventional techniques.

Mar 1, 1965

By L. A. Readdy

Pilot Hole "X" was drilled to test the formations through which the ventilation shaft for the proposed U.S.B.M. demonstration oil shale mine would be drilled. The geologic formations encountered in this hole are discussed. Correlation of the geologic horizons encountered in this hole with those encountered in nearby drill holes was accomplished by the use of geophysical logs. Data on the geophysical interpretations are provided. The anticipated geotechnical characteristics of the geologic units encountered in Pilot Hole "X" are described.

Jan 1, 1977

By C. D. Litton

This Bureau of Mines report presents a set of guidelines for determining the distribution of product-of-combustion fire sensors in underground mines. Sensor spacing is defined in terms of sensor alarm threshold, ventilation flow rate, and mine entry dimensions. Sensor spacing guidelines are presented for detection of fires from two primary combustibles, coal and wood, which are common to the majority of underground mines. The guidelines are based on data from full-scale and intermediate-scale fire tests conducted by the Bureau of Mines.

Jan 1, 1983

By W. P. Diamond

The explosion hazard of methane-air mixtures has become an increasingly serious mine planning problem, and an advance assessment of methane gas potential can therefore be essential for a safe and economic mine development program. As part of its coal mine health and safety program, the Bureau of Mines has developed a simple, inexpensive test to measure the methane content of coal samples obtained from exploration cores. The gas content of coal per unit weight as determined by the direct method test can be used as a basis for a preliminary estimate of mine ventilation requirements, and to determine if degasification of the coalbed in advance of mining should be considered. Since the Bureau began measuring the gas content of coal samples in 1972, experience has led to equipment and procedural changes, the most significant of which has been the development of a ball mill for crushing the coal sample to release the residual gas at the end of the desorption test period. This revised procedure replaces the crushing box and graphical methods described in earlier Bureau publications. The results of 583 direct method tests are summarized in tabular form. These results include data on the gas content of 125 coalbeds in 15 States.

Jan 1, 1980

By H. Herbert Hughes

Iceland spar is a variety of calcite ( calcium carbonate ) characterized by its purity , transparency , and perfection of crystalline structure . It takes its name from the country in which it was discovered . The actual demand for it is small , but the supplies of high - grade optical spar are so meager that the search for it has become international in its scope . Iceland spar is a scientific necessity , for without it research precision and technology would be hampered considerably . The earliest students of mineralogy were familiar with calcite , but the transparent variety was not discovered until early in the seventeenth century , when crystals of it were found in the bed of a stream in Iceland . It received little attention until 1669 , when Erasmus Bartholinus first recognized its powers of double refraction . The results of his investigation were published in a book , " Experimenta Crystalli Islandici , " which appeared in 1670. The law governing the action of the rerracted rays was discovered by Christian Huygens eight years later . The polarization of light rays in passing through Iceland spar was discovered in 1809 by Etienne Louis Malus , a French physicist , who published a paper describing the phenomenon . His work was closely followed by that of William Nicol , who in 1828 designed the Nicol prism which is still used as the source of polarized light in most optical instruments .

Jul 1, 1931

By O. Q. Leone

Composite diaphragms were used in the investigation of electrowinning Ti from TiC14 in a fused LiCl-KCI-TiC'2 electrolyte. Composite diaphragms tested were of two general classes--those consisting of two or more solid materials, and those which contained, in addition, a loose material. An electrowinning cell using a flat diaphragm is described. The maximum current density for these diaphragms was 300 amp per ft2. Lower currents permitted longer operation times. The composite diaphragms gave electrode efficiencies that averaged approximately 60 percent, and the electrowon titanium was of good quality--some Brinell hardnesses were as low as 68.

Jan 1, 1972