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By C. L. Chaney

Investigations were conducted to develop spectrochemical methods capable of determining 0.01 to 100 micrograms of metals in 50 milliliters of solution. The use of gallium hydroxide (Ga(OH)3) as a carrier-precipitant to concentrate metallic ions is described. A porous-cup graphite electrode is used to collect the precipitate. A specially designed plunger permits the electrode assembly to serve as the sample-containing electrode in the subsequent spec-trographic analysis. Analytical curves are presented for antimony, arsenic, beryllium, and zinc. Sensitivities of detection are given for 13 elements. The techniques were applied to identify impurities separated from tungsten, to determine trace impurities in solutions containing high concentrations of magnesium, cobalt, or nickel, and to identify trace impurities in hydrofluoric acid. Laboratory glassware was a serious source of contamination when low levels of zinc were determined.

Jan 1, 1963

By Chris Nelson

Two pieces of European Union (EU) legislation together establish requirements for protection against risks from vibration at work. The vibration directive1 specifies duties of employers to protect workers from risks from exposure to vibration; the machinery directive2, specifies duties of manufacturers and suppliers regarding the safety of machinery marketed in the EU. This paper discusses both directives and the standardisation programmes that support them. It also addresses the implementation of these requirements in Great Britain. Employers’ duties: the vibration directive This directive requires employers to assess and control risks to health and safety arising from hand-arm vibration (HAV) and whole-body vibration (WBV). Member States were required to implement the directive in national legislation by 6 July 2005. Employers are required to eliminate vibration risk at source, or reduced to a minimum. The duties include: assessing risk and exposure; planning and implementing the necessary risk control measures; providing and maintaining suitable work equipment; providing workers with information and training on risks and their control; and monitoring and reviewing the effectiveness of the risk control programme. Daily exposure exceeding a specified action value triggers a requirement for a programme of technical and organisational measures to minimise vibration exposures and the resulting risk, and the provision of health surveillance. Exposures above a specified limit value are prohibited. When conducting their risk assessments, employers are required to “assess and, if necessary, measure” the vibration exposure of workers, for comparison with the action and limit values. Vibration measurement in the workplace is not expected in all cases and the use of vibration information from equipment manufacturers is specifically mentioned. This provides a link with the machinery directive (see below). Manufacturers’ and suppliers’ duties: The machinery directive The machinery directive, first introduced in 1989, is intended to remove barriers to trade. It puts duties on manufacturers and suppliers who place machinery on the European market to design their products to eliminate or reduce risks to health and safety and to warn the user of any residual risks, providing information required for safe use (for example, operator training, maintenance and selection of consumables). There are specific requirements for minimising risk from vibration in the design and construction of the machine and, in the case of hand-held, hand-

Jan 6, 2006

By John C. Machisak

THE INJURY data and experience at quarries and related plants of the United States are presented in this publication under the following general sections : (A) General injury experience: Tables 1 through 3: Contain current data on the number of injuries, injury-frequency rates, location, accident agency, degree of injury, and related employment data. (B) Injury experience at different kinds of quarries: Tables 4 and 5: Contain current data on number of injuries, injury- frequency rates, location, accident agency, degree of injury, and related employment data. (C) Injury experience by States: Tables 6 through 19: Contain current data on the number of injuries, injury-frequency rates, accident agency, degree of injury, and related employment data.

Jan 1, 1959

By L. C. IlsLey

In the normal operation of mines, the aggregate effect of many seemingly minor op rations may be very important as respects economy and safety. Anion: these operations is the method employed in coupling and uncoupling mine cars. For economic reasons the equipment in mines has not been protected as well as railroad equipment. It is pertinent that haulage accidents rank second in severity among mine accidents, and that manual coupling of cars has been one of the most frequent causes of such accidents. One study4/ revealed that coupling was responsible for about 20 percent of haulage accidents underground. A review of early conditions on steam railroads, which were responsible for the introduction of safer methods of coupling cars, indicates how conditions in might be improved. THE STORY OF RAILROAD COUPLING As any considerable improvement in mine-car coupling probably will follow lines somewhat similar to those that brought order out of chaos for the railroads, it seems appropriate to review briefly the steps taken to improve railroad coupling from the days of link and pin couplings of various types to the adoption of the standard ?M.C.E? automatic coupler.

Jan 1, 1943

By A. W. Kbair, L. D. Gehl

"INTRODUCTION The rock-bit interaction during the cutting process in underground mines has been a matter of great concern to mining operators, researchers and manufacturers, particularly after the passage of strict environmental laws. Coal cutting bears directly on airborne coal dust generation and rock cutting generates frictional sparks which may cause face ignitions, jeopardizing the productivity, safety and economy of the industry. It is imperative to investigate into the factors which have influence on bit we.ar. Hurt and Evans (1981) concluded that the point attack bits have greater ignition potential than the conventional wedge shaped bits, and also worn bits were more responsible for ignition than the new bits. The results of a study (Khair et al., 1992) suggested that after 7% weight loss, the bit should be replaced. The polycrystalline compact diamond (PDC) tipped bits are reported to be cost effective in a study done by USBM (Twin Cities Research Center), and it was stated that the PDC tipped drill bits had 80 to 100 times longer life than the ordinary tungsten carbide (WC) tipped bits.This paper presents the results of the experiments which were conducted utilizing a coal cutting simulator at the laboratory of the Department of Mining Engineering, West Virginia University, USA. The description of the machine and the experimental set-up have been described elsewhere (Khair et al., 1989; Gehi & Khair, 1994), and therefore, will not be discussed here. The rock types which were used in experimen~ are Tennessee sandstone, Berea sandstone and Indiana limestone. The operating parameters include (1) drum speed, (2) water spray pressure and (3) bit type. Besides studying the wear characteristics influenced by the above mentioned variables, the effect of these parameters on the required cutting force, specific energy consumption, acoustic emissions rate and rise in temperature of the bit were also studied. A preliminary study was also done to compare we.ar characteristics of the WC bits with those of the poly-crystalline compact diamond tipped bits."

Dec 1, 1995

By Walter L. Finlay

The Bureau of Mines has developed prototype instruments promising to improve the ability to warn of imminent roof falls. An unusually good opportunity to test these comparatively under natural caving conditions was afforded by the forecasted caving in August 1977 of a mined-out region of the White Pine Mine. The latter's rock strata closely resemble those in many coal mines. The anticipated cave was of the competent-roof/weak-pillar type. It occurred as, and when, predicted. Automated convergence and bed separation gages agreed well with the standard manual convergence gage measurements. A micro seismic gage was found to be insensitive to the fall and may require different test conditions for effectiveness. A roof resistivity unit was tested under a separate Bureau of Mines contract. (No. H02720J7). An unplanned addition showed interesting potential.

Jan 1, 1978

By A. A. Cochran

Bureau of MinesThe Bureau of Mines studied the development of practical methods for recovering manganese from the extensive domestic resources of low-grade ores and open hearth slags. A one-step operation was developed on a laboratory scale in which manganese and iron compounds are treated with chlorine, volatilized, and separated by selective condensation. Manganese recoveries of 90 to nearly 100 percent were obtained from 9 of the most important domestic ores. Analyses of the manganese chloride product indicated that it was suit-able for aqueous electrolysis with little additional purification. A complete, integrated process that provides for the recovery and recycling of chlorine is proposed. This process appears to have distinct advantages over previously proposed manganese recovery processes, and, in sharp contrast to leaching procedures, it is applicable to practically any manganese-bearing material.

Jan 1, 1967

By R. H. Lien

The Bureau of Mines investigated nitrous oxide (N20) stability when used as a solvent for organic removal from metal powder surfaces. Both supercritical and subcritical conditions were studied. This investigation was prompted by the occurrence of a violent reaction when supercritical N20 was being used to deoil a metal powder grinding waste sample that contained 20 to 25 wt pct cutting oil. Tests were conducted to determine the cause of the reaction and to define stability limits. Test data showed that the waste's oil fraction reacted violently with N20 acting as an oxidizer; the metal powder acted as a promoter to reduce the ignition temperature. Although the data were scattered, this temperature appeared to reach a minimum at a certain pressure (dependent on vessel and sample size). The minimum ignition temperature for a 0.64-g sample in a 72-cm3 vessel was 360° C at 200 psig. As the sample size increased, the ignition temperature decreased. For example, when the sample size was increased to 10 g, a reaction occurred at 240° C and 600 psig. Because of the variability of ignition temperature with pressure and sample size, safe operating conditions were not established. Overall, this research showed that extreme caution should be exercised when using N20 in an organic or organic-metal system.

Jan 1, 2011

The objective of this condensed handbook is to provide the inspector with guidance for recognizing hazards from inhalation contaminants in above ground work areas of underground and surface coal mining and processing facilities and evaluating these hazards by collecting samples or making field determinations and interpreting the analytical results. It will be carried with the inspectors during their surveys. The complete handbook should be left in their offices except for Appendix II which lists the compositions of products found in previous surveys. There are several portions of the condensed handbook which should prove most useful to the inspectors. The names and locations of these portions are listed below: Procedure for an Industrial Hygiene Survey (Page 2-1) Survey Check List (Page 2-3) Rules for Determining if Sampling is Required (Page 2-2) List of Most Frequently Encountered Contaminants (Page 2-5) List of Candidate Contaminants and their Sampling Conditions (Page 2-A) Interpretation of Results (Page 3-8) For obtaining information not available from the above mentioned portions of the handbook, the inspector is directed to the Table of Contents, and the Glossary of Terms (Appendix I).

Jan 1, 1975

By C. J. Thompson

This Bureau of Mines study describes the preparation of sulfur compound concentrates boiling from 225° to 400° C, and reports the sulfur types detected in these concentrates by low-voltage mass spectrometry (LVMS). Existing LVMS methods were extended; the procedures described should be generally applicable to high-boiling petroleum distillates and concentrates as a preliminary means of narrowing the number of factions to be considered for more detailed separation and identification studies. The following major sulfur compound constituents of petroleum are indicated by the data: benzothiophenes, dibenzothiophenes, naphthanothiophenes, naphthenobenzothiophenes, and homologs and isomers of these. Cyclic and chain sulfides comprise a significant portion of the gas-oil range sulfur compound types. The presence of some classes of sulfur compounds containing two sulfur atoms per molecule was indicated.

Jan 1, 1966

By Joseph A. Vanous

The inductive communication system was developed under this contract for use in the hoist of deep mines. This program was a four phase program with experimental dual frequency equipment resulting from Phase I, emergency single frequency equipment developed under Phase II, and equipment documentation required under Phase III. An additional emergency system was provided under Phase IV.

Jan 1, 1976

By W. H. Ode, W. A. Selvig

Low-temperature distillation tests at 200°, 350°, and 500° C. were made on a subbituminous coal from Boulder County, Colo., and a subbituminous coal from Weld County Colo., in connection with a survey of carbonizing properties of American coals 4/ and investigations of their chemical and physical properties. 5/ The coal represented by the sample from Weld County was reported to give off combustible volatile matter at unusually low temperatures when placed on a fuel bed. The yields of tar and oil and the composition of the as from this coal, as obtained in the distillation tests, did not confirm this report. These yields and the gas composition of the Weld County coal differed but little from those obtained from the coal from Boulder County. Both coals yielded tar and gas in amounts considered to be normal for coals of their rank.

May 1, 1937

By G. S. Scott

The flammability of trichloroethylene vapors in air has been determined in a 7-inch cyclindrical vessel. Saturated flammable mixtures were formed with air at atmospheric pressure between 30° C (86° F) and 82° C (180° F); the trichloroethylene concentrations at these temperatures are 12.5 (lower) and 90 (upper) volume-percent, respectively. Further study is necessary to assess the effects of different variables on the flammability of this material. INTRODUCTION Trichloroethylene (TCE) (ClHC = CCl2), sold under various trade names (Blacosolv, Perm-A-Clor, Tri, Triad, Triclene, Trivec, Tromex, Vapoclean, Vapoclor, Westrosol, etc.), is an important industrial chemical. A summary of its physical and chemical properties is given in table 1. It is used to degrease metals, leather, and textiles, to extract residual oils from vegetable oil cakes, for dry cleaning, and in soap. It is a powerful solvent for fats, resins, bitumens, rubber, sulfur, and phosphorus. Several explosions in which trichloroethylene was involved prompted an investigation by the Bureau of Mines to determine the conditions under which such accidents can occur.

Jan 1, 1963

By Arthur B. Campbell

This Bureau of Mines report describes a method that utilizes a computer program to evaluate integral Gaussian profiles of atomic concentration versus depth in a solid. The specific use illustrated involves profiling ion- implanted metals using proton-induced X-ray emission (PIXE) analysis and ion sputtering (IS) for sectioning

Jan 1, 1979

Minerals are vital to any industrialized civilization. Annually, the United States uses more than 4 billion tons of new mineral materials, or about 40,000 pounds per person-about half being mineral fuels and the other half being metals and nonmetallics. Stable and economic domestic mining, mineral, metal, and mineral reclamation industries are essential to the economy. The value of United States energy and processed materials of mineral origin exceeds $200 billion annually. Although a number of minerals are imported, especially some designated as "strategic and critical," most U.S. mineral supplies are derived from the domestic mines and processing facilities that you will be seeing, reading about, and visiting as you use this visitor guide. We hope you enjoy your experiences. This pamphlet, a guide to mining and mineral operations that may be observed or visited and some other points of interest relating to minerals, is intended to aid tourists and students who are interested in mining. Some may wish to study our Nation's romantic past; others may plan to enter the minerals industry as a career; still others may have a primary interest in conservation practices. The pamphlet is also intended to aid State and local officials, Chambers of Commerce, and mining firms in answering some of the many questions of tourists and students.

Jan 1, 1976

By G. A. Wancheck

Shear tests were performed on several prepared samples of granular and powdery bulk materials to investigate the following parameters: Particle size and distribution, particle movement, moisture content, consolidation of material, bulk density, void ratio, porosity, volume change, and strain rate. A series of shear tests was performed with weight-percent-ratios of minus 0.185-inch tertiary sand and 1-1/2-by l/2-inch tertiary gravel mixtures, and weight-percent-ratios of minus 200-mesh limestone (rock dust) and minus 200-mesh bituminous float coal dust. A comparison was made for shear test results obtained with rectangular and circular shear cells utilizing the large and small direct shear testers. Specifically, the shear results obtained include the angle of internal friction or shear strength of the tested material under known consolidating pressures, and the kinematic angle of friction or coefficient of friction between the interface of a bulk material and a sample wall material. The experimental procedure, tests, and results are given for each parameter investigated.

Jan 1, 1973

By M. J. Beus, B. Stewart, S. Iverson

Synopsis U.S. Mine Safety and Health Administration (MSHA) accidents statistics have identified ore-pass hazards as a significant safety problem in U.S. underground metal mines. The statistics show that nearly 75% of injuries are directly or indirectly related to pulling or freeing of ore-pass chutes, the use of hand tools in ore passes, fails of broken rock in ore passes and structural failures of chutes or gates and ore-pass walls. Researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) are investigating hazards in and around ore passes in hard rock mines. Risk assessment methods, such as fault-tree analysis, have been employed to identify the most probable causes of orepass failures, define research priorities and analyse the factors that result in malfunctioning and unsafe ore passes. Static and dynamic loads are being measured in a laboratory setting with the use of a reduced-scale orepass mock-up. Field tests are being initiated in mine ore passes to determine static and dynamic loads. Data from the test ore passes are being compared with data from the mine to characterize true system behaviour. Computer modelling with the use of closed-form solutions, finite-element analyses and a newly developed particle flow code predicts static and dynamic leads from the flow and the impact of ore and waste in the ore pass. Preliminary results indicate that dynamic impacts from ore and waste rock might be considerably greater than expected. The total static load is substantially less than is typically used fur the structural design of chute and gate support members. It is suggested that damping factors, normal and shear stiffness and mass frictional characteristics have a significant effect on particle flow and resulting impact loads. This is being verified with the use of results from laboratory tests, field tests and particle flow analyses. Ore passes are vertical or steeply inclined openings in a rock mass through which ore and waste are transported and where they mar also be stored. A typical underground mining system is shown in Fig. 1. The arrows indicate the locations of ore passes and loading pockets and their relative configurations. The control of material flow is potentially one of the most hazardous operations in underground mining. According to MSHA data. most of the ore pass-related accidents in the U.S.A. are associated with the loading-unloading cycle and removal of blockages from ore passes. In particular, attempts to free ore hang-ups have resulted in multiple fatalities. The hazards are obvious; there is uncertainty as to when the ore will break loose and miners are unable to escape falling rock to a safe location. Although ore passes and chutes and gate systems for underground metal and non-metal mines roust meet the requirements specified in the U.S. Code of Federal Regulations (CFR). Parts 57 and 75, recent structural failures of ore-pass linings and gates have underlined the lack of adequate ore-pass design standards available to both MSHA enforcement staff and mine engineers. Because of the importance of an ore pass to the safe operation of a mine design criteria need to be assessed and new guidelines developed. Researchers at the Spokane Research Laboratory of the Nationals Institute for Occupational Safety and Health (NIOSH) are investigating hazards in and around ore passes in hard rock mines and studying design criteria for ore passes. The near-term goal is to conduct laboratory and field experiments and computer modelling to evaluate the ore-pass design criteria currently used. Literature searches, field site

By J. C. Judd

The Bureau of Mines investigated the recovery of vanadium, uranium, and phosphorus from low-grade phosphorite ores and concentrate by leach-ing with H2S04. Samples containing 0.12 to 0.23 pct V20S, 0.009 to 0.012 pct U30S and 18 to 30 pct P20S were treated by batch-agitation leaching, roasting followed by acid leaching, salt-roasting followed by acid leaching, and leaching under pressure. Maximum recoveries using leaching alone ranged from 78 to 98 pct of the V20S and 74 to 88 pct of the U30S-Leaching under pressure resulted in extractions of 88 to 95 pct of the V20S and 84 to 89 pct of the U30S. Leaching following roasting--with or without NaCI--produced extractions of 97 to 99 pct of the V20S and 86 to 91 pct of the U30a. Depending on the technique(s) employed, phosphate extractions ranged from 89 to 99 pct. Solvent extraction laboratory tests were conducted to selectively re-cover vanadium and uranium values from acid leach solutions. An average of 95 pct -of the U30a was recovered using di(2-ethylhexyl) phosphoric acid, plus trioctylphosphinic oxide. Essentially all of the V20S was recovered with octylphenyl acid phosphate plus isodecanol. The phosphate remained in the raffinate.

Jan 1, 1986

By H. E. Perlee

Mathematical expressions are derived for the histories of the pressure, flame radius, mass fraction burned, and burned and unburned gas temperatures associated with a spherical flame propagating concentrically in a spherical vessel. The equations are solved numerically for a 9.5 pct CH4/air mixture using the best available information for the burning velocity, expansion ratio, and specific heat ratio. Calculated histories are in complete accord with experimental measurements. The accuracy of calculated histories is determined relative to errors in the system parameters, and it is found that 10 pct errors in either the burning velocity or the expansion ratio results in a 40-pct error in the pressure history. A 10-pct error in either burned or unburned specific heat ratio results in a 22-pct error &apos;in the pressure history. It was further established that the usual assumption of constant specific heat ratio is unacceptable, but equating the burned and unburned specific heat ratios result in no apparent error in the histories. The cubic law (P = Kt3 + Po) is derived and discussed, and it is found that the law is valid only during the early period (P<2 atm) of flame growth.

Jan 1, 1974

By I. D. Schleicher, L. H. Rorden, F. B. Curry, T. C. Moore

The purpose of this program is to extend electromagnetic (EM) techniques for use in locating miners trapped in mines as deep as 1000 m. A previously developed EM system is considered adequate for use at mines less than 300 m deep where it has a probability of detection of 54%. A system for deep mines must keep underground equipment simple, and use extremely low frequencies (ELF), sensitive receivers, and noise cancellation. The proposed location method, developed by Develco for other applications, is based on vector field measurements from two or more static sensors and computation of source location by iterative techniques. During Phase II, very sensitive search coil sensors were built and used in a separate test to verify the feasibility of atmospheric noise cancellation. A "Breadboard" location system version without cancellation, which is a fieldable test bed to evaluate receiving and location functions, was tested and supplied. Very good results were achieved from the first in-mine test with the transmitter at a depth of 380 m. It is expected the results of this work, and additional evaluation tests in the future, will be used to define the requirements for a prototype operational system.