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By D. B. Dow

This paper on the physical chemistry of oil-field emulsions is the last of a series of three prepared as a result of a study of oil-field emulsions. The first paper3 deals with the factors responsible for the formation of emulsions, find the second4 with methods now utilized for dehydrating oil-field emulsions. A more complete report of the whole investigation is in preparation. The laws governing the formation and resolution of oil-field emulsions fall in that branch of physical chemistry doling with colloids. Much work has been done by the physical chemist on colloids And emulsions, and, although most of this work was on commercial and pharmaceutical emulsions, yet the principles developed apply in a general gray to oil-field emulsions.

Jan 1, 1925

By Larry A. Haas

A major problem encountered in dump leaching operations is the plugging of both the dump and the piping by precipitated iron compounds. Bureau of Mines research to obtain basic data on agitation leaching and dump leaching methods has shown that the addition of organic chelating reagents can significantly enhance the lixiviant permeability through the ore and the concentration of the metal values in the liquor. For example, the addition of 5 giL citric acid (CA) to a conventional sulfuric acid lixiviant almost doubled the fluid flow rate through 5-cm-diameter laboratory columns containing copper ore. After 185 h of per-colation leaching, the metal concentrations with (and without, in parentheses) CA were 1.7 (1.5) giL Cu, 200 (70) ppm Mn, 160 (40) ppm AI, and 6 (3) ppm Co. The enhancement of metal concentrations with chelating reagents such as CA was confirmed by determining the solubil-ity of several metal ions as functions of pH and chelating reagent con-centration. When ferric ions became insoluble at pH values above 3, the concentrations of other ions also decreased. The addition of che-lating reagents kept iron, as well as the other dissolved metals, in solution even at pH values as high as 5. Citric acid was a more effective chelating reagent than gluconic acid, oxalic acid, or sodium lignin sulfonate.

Jan 1, 1985

By Rolland L. Blake

The Bureau of Mines investigated the mineralogy, tonnage, and beneficiating characteristics of oxidized (nonmagnetic) taconite iron resources of the Western Mesabi Range as part of its program to insure adequate future domestic mineral supplies. Magnetic taconite currently provides about 95 pct of Mesabi production, but the large tonnages of oxidized taconite between the magnetic deposits will be needed to help meet future domestic demand for iron ore. Three bulk samples that represent large tonnages from the Western Mesabi Range were selected to determine their mineral composition and liberation by light optical microscopy and to test their beneficiating response. This report describes the mineralogy and liberation characteristics of the three samples of the Biwabik Iron-Formation for 26.5 mi (42.7 kID) from Keewatin to Grand Rapids, MN. (Details of response to beneficia-tion were reported previously.) The samples represent mostly material from the Lower Cherty Member of the Biwabik-Iron Formation, although one sample included some Upper Cherty Member. Minerals of all three samples were quartz (chert), hematite, goethite, and minor to trace amounts of magnetite, iron carbonate, and iron silicates. It was concluded that the oxidized taconites of the Western Mesabi Range represent a subeconomic indicated resource that can be selectively mined and beneficiated as a future large source of iron feed for steelmaking.

Jan 1, 1983

By Will H. Coghill

[The supply of gravel spar and of acid spar is not well balanced. Gravel spar -- 85 per cent flourspar, 5 per cent silica -- gluts the market, whereas acid spar -- 98 per cent fluorspar, 1 per cent silica -- is somewhat scarce. Hence it is desirable to convert some of the gravel spar into acid spar. Knowledge of this condition prompted the Franklin. Fluorsrar Co. at Paducah. Ky., to enter into cooperation with the U. S. Bureau of Mines and the Missouri School of Mines and Metallurgy to improve the methods of fluorspar, milling so that morn acid spar would be available. The fluorspar company detailed Mr. Omar Greeman for the work. During the course of the investigation, while Mr. Greeman was also doing work for a master's degree in the School of Mines? an extensive study was made of gravity concentration of fluorspar ores. Decrepitation by heat treatment was also given a laboratory try-out. A part of tie time was spent on flotation; these notes relate only to the flotation. The results of one of the flotation runs is appended. The test was made in a 500-gram mechanical-agitation machine. The sample was ground to 100-mesh in a pebble mill.]

Jan 1, 1928

Prevent the propagation of a fire and control the spread of smoke and toxic gas in underground mines. Approach A fire door suitable for large openings in underground noncoal mines and providing protection for openings requiring 11/2 hours of fire resistance, a 250°F maximum temperature rise, and high pressure differentials was de-signed, laboratory tested, and in-mine tested. How It Works The door is a double-acting swing type. Its two panels. connected by an overhead linkage, open in opposite directions. Consequently, high pressure differentials across the door have little effect on the force required to open and close the door. The door is constructed of 14-gauge sheet steel skins welded to both sides of a 5-inch-wide steel channel frame. The frame is rein-forced with 5-inch-wide steel channels in a horizontal and diagonal pattern. The voids between the reinforcing members are filled with a ceramic fiber insulation material to limit the surface temperature rise of the unexposed side of the door during a fire. A fire -resistant neoprene-coated fabric is used to seal around the edges of the door panels. The door is opened and closed by an air cylinder, attached to the over-head linkage and operated by lanyards on either side of the door. The door design includes an optional airlock manway for drifts of adequate width.

Jan 1, 1983

By L. M. Irwin

This Bureau of Mines investigation relates the physical properties of copper reverberatory furnace slags to changes in composition, The smelting of upper Michigan copper ore presents some problems that probably differ from those of other copper smelting areas. The study of these problems has, however, provided important data regarding slags in general and therefore will be of value to other operations as well. Conclusions reached from this study were: (1) Slag fluidity and refractive indices varied directly with the iron content and inversely with silica, lime, and alumina, and (2) there was no apparent correlation between slag fluidity and its copper content.

Jan 1, 1962

By B. T. Brady

Recent theoretical, experimental, and field studies conducted by the Bureau of Mines suggest that rock failures may be predicted and, in some instances, controlled. Theoretical studies that were later corroborated by laboratory and field studies predict that a seismic anomaly will precede rock bursts and/or roof falls in mines. The seismic anomaly is predicted to consist of an increase in the number of seismic events occurring in the immediate vicinity where the failure 1s nucleated. This increase will then be followed by a dramatic decrease of seismicity in a broad region that surrounds the location of the impending failure. The dimensions of this region allow a preliminary estimate of the time to failure (measured from the time the seismicity increase began) as well as an estimate of the energy that will be released at the instant of failure. Field observations indicating that this predicted behavior does precede rock bursts and a roof fall are presented in this report. Implications of results to the problem of failure control in mines that experience massive rock failures are discussed.

Jan 1, 1978

This chapter analyses the parameters influencing initial design of communication systems, for new mines and upgrading existing systems. Paragraph 5.2 outlines those variables that must be taken into account during the design stages of a new wired phone system. Recommended features, general requirements, and how they can be implemented are treated in this section. Paragraph 5.3 describes ways of improving or extending the range of trolley carrier phone systems and pager phone systems already installed in the mine. 5.2 New Phone System Design The task of designing an adequate communication, control, and monitoring system for an underground mine must be addressed on a system basis. In addition to insuring that effective voice communication is established, any new system should take into account present and future requirements of remote control and monitoring functions. Chapter 4 illustrated the drastic savings in response time that can be realized when remote control and monitoring are integrated into the overall communication system. The importance of including control and monitoring in the overall design plan for any system cannot be overemphasized. Because each mine is unique, and thus usually has its own special operating characteristics and communication requirements, there is no such thing as "the one best system" to meet the requirements of all mines. The optimum communication, control, and monitoring system for a mine must be one that has been tailored to meet the special requirements of that particular mine. Factors that must be considered during system design include- a. Type of mine and mining methods (low- or high-seam coal, deep hardrock mine, stope caving, longwall, room and pillar, etc.). b. Maximum number of working sections. c. Expected mine growth rate and eventual maximum size. d. Haulage methods (tracked trolley, diesel, belt, etc.). e. Underground power distribution system (dc, ac, or both). f. Features desired (two-way radio paging, private line capability for emergency use, etc.). g. Redundant or backup systems for use during outages of the normal system. Although no two mines are alike, the following items have been established as the main characteristics desired for any underground communication system: 1. Multiple Communication Paths to Outside--the objective here is to give all telephones a second method of communicating with the surface. 2. Audible Emergency Signaling--the communication system provides the main means of alerting miners during emergencies. The system should include means to broadcast distinct audible signals for emergency signaling. Initiation of these signals should probably be controlled from. a central outside point, such as a surface control room. 3. Emergency Override--provisions should be included to permit any conversation to be overridden with emergency communication. 4. Selective Area Page--as mines grow larger it is apparent that the entire telephone system paging mode need not be activated each time a call is initiated. When the general area of a

Jan 1, 1984

A mineral survey of the Rough Hills WSA (Wilderness Study Area) in northeastern Nevada was done by the U.S. Bureau of Mines in 1985 at the request of the Bureau of Land Management. The WSA is comprised of 6,685 acres of mountainous, desert lands within the Elko District of the Bureau of Land Management. The survey entailed investigations of prospects or mineral occurrences to provide information on possible resources within the WSA. No mineral resources were identified in the WSA. The only historical mining activity was for placer gold at the Prunty prospect at the confluence of Copper Creek and the Bruneau River. Total gravel at the prospect is about 6,500 cubic yards; however, the survey showed significant gold values (greater than $0.10 gold per cubic yard) only in the southwestern portion. There, however, the gravel averaged less than $1.00 gold per cubic yard, and only about 3,000 cubic yards are present, a grade and yardage insufficient to be of commercial interest. The occurrence, however, may have value for recreational mining by hobbyists.

Jan 1, 1986

By J. J. Cummins

Green River oil shale previously extracted by benzene was heated at 150°, 200°, 250°, 300°, and 350° C for 0.5 to 360 days to determine the rate at which kerogen degrades to thermal products, the types of thermal products formed, and the effect of prolonged low-temperature heating (preheating) upon subsequent assay yields. Thermal decomposition of kerogen at 150° to 350° C is treated as a first-order reaction. The specific reaction rate for kerogen decomposition increases from 2.2 X 10-4 per day at 150° C to 2.0 X 10-1 per day at 350° C. The calculated kerogen activation energy is 19 kcal. Variations in the rate of formation of individual type components of the pyrolytic products were found. Carbon balances show an increase in the amount of kerogen converted to bitumen and oil (from assay of preheated oil shale) as the temperature of preheating increased from 150° to 350° C. Total product from shale preheated at temperatures of 150° and 200° C gave less than 100 percent of Fischer assay yields while the total products from shale preheated at temperatures of 250° to 350° C gave greater than 100 percent of Fischer assay yields.

Jan 1, 1972

By Howard D. Jacobs

A bulk sample of oxidized taconite taken from the western Mesabi Range was evaluated by the Bureau of Mines using the Bureau-developed selective flocculation-desliming-cationic (or anionic) flotation process. The raw ore sample containing 32.3 pct Fe was treated by both cationic and anionic flotation. Using the cationic system the concentrates averaged. 37.2 wt-pct of the feed and contained 62.8 pct Fe and 4.7 pet Si02 with an iron recovery of 72.3 pet. With the anionic system, concentrates averaged 37.7 wt-pet of the feed and contained 63.0 pct Fe and 5.3 pct 8i02 with an iron recovery of 73.5 pct. A comparison of reagent costs showed that the cationic process cost 144.1 cents per long ton of crude ore and the anionic process 178.7 cents per long ton of crude ore. Reclaimed water comprised 86 pct of the total water requirement for anionic flotation and 88 pct for cationic flotation. The ore used in this study was one of three samples representing about 3.25 billion tons of oxidized taconite containing from 32 to 36 pct feed iron. Previous study had indicated that selective flocculation-desliming-cationic flotation would produce concentrates from the other two samples of 61.7 pct Fe and 5.1 pct Si02 at 67-pct Fe recovery, and 63.5 pct Fe and 4.3 pet Si02 at 8S-pct Fe recovery. By developing a successful treatment for these ores, the Bureau has insured the availability of technology for processing an amount of raw iron ore which, by itself, would supply U.S iron needs for 50 to 75 years at expected consumption rates.

Jan 1, 1981

By Russell. Paul L.

"INTRODUCTION Preliminary reports by Bureau of Mines engineers 3/ and by the Federal Geological Survey 4/ suggested that exploration would discover substantial reserves of minable ore in the Contact mine, Grant County, New Mexico. During February and March 1943, a sampling program was conducted on this property under the direction of the author. This was art of a general survey of the manganese districts of southwestern New Mexico.In its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources, to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as practicable soon as after its conclusion. The Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocer, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. S. Dean, assistant director. With respect to this report, special acknowledgment is due to C. H. Johnson, district engineer for New Mexico, and E. D. Gardner, regional engineer, and his staff, of the Central Region of the Bureau of Mines at the time of this work in 1943; also to Kenworthy, metallurgist at the Rolla. Mo., Laboratory of the Bureau of Mines, for work on beneficietion of the ore, and Sherman K. Neuschel, geologist of the Federal Geological Survey, for assistance in interpreting geological data at the project."

Oct 1, 1946

By Sean Gallagher, John R. Bartels, Dean H. Ambrose

Remote operation of continuous miners has enhanced the health and safety of underground miners in many respects; however, numerous fatal and non-fatal continuous miner struck-by accidents have occurred when using remote controls. In an effort to prevent these injuries, NIOSH researchers at Pittsburgh Research Laboratory examined the workplace relationships between continuous miner operators and various tramming modes of the equipment using motion captured data, predicted operator response times, and field- of- view data to determine causes of operator-machine struck-by events in a virtual mine environment. Factors studied included machine speed, direction of escape, operator facing orientation relative to the machine, work posture, distance from machine, and operator anthropometry. Close proximity to the machine, high machine tramming speeds, a right-facing orientation and operator positioning near the tail all resulted in high risk of being struck. It is hoped that this data will provide an improved rationale for operator positioning for remotely operated continuous miners.

By W. F. Marshall

The effect of engine parameters on exhaust emissions from two diesel engines was studied experimentally. Fuel-injection characteristics and intake air conditions were considered as parameters influencing the emissions. Emphasis was placed on the effect of parameter variations on nitrogen oxide (NOx) emissions, because diesels generally emit very low levels of carbon monoxide (CO) and unburned hydrocarbons. Emissions other than NOx were at lowest levels when the engines were adjusted for best performance. NOx emissions can be diminished somewhat through variation in fuel-injection characteristics, but there generally are penalties in emissions of CO, smoke, and unburned hydrocarbons or in engine performance. Temperature and composition of intake air have a significant effect on NOx emissions. Levels of NOx are reduced by recirculating the exhaust gas or by adding water to the intake air stream. However, the rate of water added or exhaust gas recirculated must be limited to prevent the degradation of engine performance and increased emissions of CO and smoke. At high exhaust recirculation rates, levels of CO and smoke were increased such that it was necessary to derate the engine and also to use a catalytic system for oxidation of CO.

Jan 1, 1971

By Michael Schmitz, John A. Organiscak

ABSTRACT: A method (patent pending) has been developed to determine the quality of environmental cab filtration systems. This method utilizes specially configured filter cartridges to remove carbon dioxide from the ambient air with the environmental cab’s air filtration system. A real-time gas monitor is placed inside an unoccupied cab with the filtration system running to time decay the carbon dioxide to its lowest concentration or equilibrium level. The outside carbon dioxide concentration level can be measured concurrently with another gas monitor or with the same inside cab gas monitor during a representative period before and after the inside sampling is conducted. Cab filtration system leakage is comparatively deduced from the difference between the special cartridge filter efficiency and overall cab efficiency. Laboratory trials have illustrated that desirable high efficiency test filter configurations (greater than 99 % efficiency) can be devised, but have air quantity and test time limitations. These trials also demonstrated that CO2 penetration was reflective of controlled air leaks around a high efficiency filter under equilibrium conditions. This report examines the elements of this patent pending method.

By Fred V. Carrillo

Of the total quantity of secondary copper and zinc that became obsolete in the United States from 19b1 through 1970, more than 11 million tons of copper and 10 million tons of zinc were not recovered. These estimates are based on a study of the flow and recovery of old copper and zinc scrap by consumption end-use. This report describes (1) where copper and zinc are being used; (2) when they become obsolete and available as secondary metal; (3) how they are being collected for recycling; and (4) how much might be recovered from scrap that presently is not being recycled.

Jan 1, 1974

Most laboratory sealant studies were carried out in 2.0 inch I.D. Plexiglas tubes of 9.0 inches height containing 4.0 to 4.5 inches reconstructed soil from an 0-8 or 8-16 inch soil horizon at the Lanse site. (When soil was used from the Kato site, the top soil horizon was approximately 0-4 inches. The 4-8 inch horizon was somewhat comparable to the Lanse 8-16 inch horizon.) A 20 mesh Saran or steel screen was placed over the rubber stopper with a bottom drain to a 100 ml measuring cylinder. In some earlier experiments a 1/2 inch bed of 1/4 inch pea-gravel was then added, but in later experiments this was eliminated as it showed no particular utility. Field soil samples collected by a shovel were stored in sealed containers and sieved through a 4 mesh screen just before use. (Moisture content was typically about 25% for A horizon soil and about 20% for B horizon soil.) The sieved soil minus roots was then added in increments of about 1 1/4 inches. Compaction was effected by dropping a weighted ramrod (1-7/8 inches O.D,) five times from a height of two inches. If about twenty tamps were used or if the soil columns were rapped vigorously while water-logged, compaction was high with no detectable percolation. Freezing such samples would then usually cause very slow percolation, e.g. 1-2 ml/day. Using this as a standard procedure, percolation flows were usually stablized after two to three days to rates of about 100 to 200 ml/hour. Percolate was recycled carefully to minimize disturbance of the soil surface. When percolation flows were about 100 to 200 ml/hour, various additives (sealants) were introduced to the moist column in two to three increments to maintain a slight head. Additive concentrations were usually 2-1/2% with some at 5% in earlier experiments. Typical use of 40 ml of 2-1/2% additive corresponds to 4400 lbs/acre. When no more additive was present as supernatent liquid, water washes of about 15 ml were then used several times followed by special additives as needed. More water washes were then used to maintain a head of about 1/2 inch. Percolate was collected in 100 ml cylinders to measure percolation rates in ml/hr. Turbid percolate was evaporated to determine amount of eluted latex. Percolate was sometimes checked for pH by Pan-pH Indicator Paper9,10 reading in 0.5 units. Surface tension measurements were sometimes made by a DuNouy tensiometer10 in experiments using a surfactant for pretreatment.

Jan 1, 1972

"Health standards in the U.S. are among the highest in the world. Achieving these standards have often had an impact on productivity, slowing output, and raising prices to levels that make it difficult to compete with many foreign industries. The answer to many of these problems lies in the development of new and advanced control techniques. This overview has identified some of the major respirable dust technological hurdles that have been overcome, and provided some insight into current and future approaches underway to remove these obstacles and to provide the United States with the most advanced state-of-the-art mining industry in the world from a respirable dust standpoint. The necessary developmental research is costly and time-consuming. The long-term, high-risk aspects of this effort are being addressed by the Bureau and the Generic Center on Respirable Dust, with support by industry. This should be recognized as one of the principal agents through which the great mineral potential of this Nation can be realized, and our international status as a mining power be assured without compromising the health and welfare of those who ensure it.The problem of more stringent dust standards will continue to grow. To date, approximately 40 pct of the coal mining industry has been placed on more stringent dust standards due to quartz. Control techniques must be improved if mandated levels are to be met. As longwall production increases, dust levels will also increase. In light of the industry trend toward longwall mining, if no new control technology is available, the Federal dust standard will act as a constraint on future output per hour. The Bureau has recently completed a survey of 18 coal preparation plants; 50 pct of these operate at dust levels which exceed 2.0 mg/m3; future work will be directed toward solutions in this area. The 2.0 mg standard for respirable dust is for dust particles which are below 10 pm in diameter. Recent studies have shown that dust in the range between 10 and 25 pm can cause obstructive airway disease. The Bureau is currently determining the extent of exposure to dust in this size range from various mining operations."

Nov 1, 1988

By Homor N. McDonald, G. Dale Coe, Will H. Coghill

"INTRODUCTION Sporadic beneficiation tests have been made on the Birmingham (Ala.) red iron ores for the last 55 years. Now, gravity-concentration plants are in operation, of tables are in use. A major problem, as seen by the present writers, is to obtain a coarser concentrate and add to the recovery without increasing the quantity of slime. The oily practicable solution found so far is to recover, by means of concentration (hydraulic) classifiers, the coarse concentrate normally lost in the table middling and, by a similar method, to recover middling particles from the table tailings The size and shape of the coarse concentrate Particles combine to cause them to report in the table middling rather than in the table concentrate. Similarly, mineral is lost in the tailing. Because of this, the nature of the ore, the deportment jerking table, plant tests on classifiers and tables, and the suitability of small concentration classifiers to treat table zonal middlings are discussed herein.The work was done by the Southern Experiment Station, Bureau of Mines, in cooperation with the University of Alabama, Tuscaloosa, Ala."

Jan 1, 1935

By A. C. Richardson

The mine of the Porter Coal Co. is located at the town of Porter in the northwestern part of Jefferson, County, Ala., about 20 miles west of Birmingham. The operations in this mine are confined to the middle and bottom benches of the Mary Lee bed. The coal from the Porter mine is handpicked and washed before being placed on the market. The handpicked lump coal and the washed egg and nut, coal are sold chiefly as domestic and steam-raising fuel. The coal finer than 1 inch is washed in 2-compartment jigs and utilized in the manufacture of metallurgical coke. The coal company has found that, when coal ranging in size from 1 to 0 inch is washed in jigs, a considerable amount of high-ash material finer than 3/16 inch remains in the washed coal. This paper gives the results of an investigation which was conducted for the purpose of determining the washing characteristics of the through 316-inch raw coal and the extent to which the ash might be reduced by means of coal-washing tables. This investigation has been made in connection with an. extensive study of the coal-washing problems now being conducted by the United States Bureau of Mines and the University of Alabama, with the cooperation of the coal-mining companies of the State.

Jan 1, 1933