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By G. F. Livingston, F. K. Shelton, J. C. Stahl, R. E. Churchward

"INTRODUCTION An investigation of the metallurgy of cobalt from domestic ores has been in progress since February 1940 and has resulted in the formation of a hydrometallurgleal process for the production of electrolytic cobalt metal. Previous reports of these investigations have been given by F. K. Shelton; 7/ and Ruth E. Churchwrd, F. K. Shelton, and G. Knickerbocker. 8/ Briefly, the process, as applied to ores containing cobalt oxide, consists of leaching with H2SO3 or, preferably, with H2SO3 and H2SO4, to dissolve the cobalt. The cobalt solution passes through one or more purification stages to remove iron and elements of the copper group, and cobalt carbonate is precipitated under carefully controlled pH conditions. The cobalt carbonate is dissolved in on acid electrolyte containing sulfuric acid, boric acid, and sodium fluoride. The electrolyte then proceeds to electrolytic cells where cobalt is plated as a metal and sulfuric acid is regenerated.The present paper contains the results of several investigations signed to give a more complete chemical and engineering understanding of different unit processes involved in the electrowinning of colbat. Some work has been done to broaden the process to include arseniferrous cobalt ores as well as the oxide ores upon which the investigation was initiated. Most of the data presented herein have been obtained since the release of the previous reports; any changes suggested heroin that conflict with recommendations in earlier reports are based on more complete data and usually are preferable."

Nov 1, 1945

By J. D. Davis

THE carbonizing properties of one medium- and and five low-volatile coals from West Virginia and one high-volatile A and two medium-volatile coals from Pennsylvania were determined by 800° and 900° C. BM-AGA carbonization tests and expansion tests in the sole-heated oven. Plastic properties of the coals and the yields and quality of their cokes and other carbonization products were determined. The low-volatile coals comprised a mine and a coke-plant sample of Pocahontas No. 6-bed coal from the. Black Eagle No. 1 mine, Wyoming County, W. Va.; a mine sample of Pocahontas No. 6 bed from the Louisville mine, Mercer County, W. Va. ; Davy Sewell bed was sampled at the Twin Branch mine, McDowell County, W. Va.; and Fire Creek bed was sampled at the Dunedin No. 1 mine, Raleigh County, W. Va. The medium-volatile coals were from the Fire Creek bed, Laurel Creek mine, Greenbrier County, W. Va.; Lower Kittanning bed, Springfield No. 4 mine, Cambria County, Pa.; and Upper Kittanning bed, Springfield No. 6 mine, Clearfield County, Pa. The high-volatile A coal represented the Upper and Lower Freeport beds, Kent Nos. 1 and 2 mines, Indiana County, Pa. In addition to the coals listed, high-volatile A coal from the Pittsburgh bed, Warden mine, Allegheny County, Pa., a standard blending coal, was used in blends in this investigation.

Jan 1, 1950

By W. W. Adams

The year 1937 was signalized by increased employment in the metal-and nonmetal-mining 4 industry of the United States. Measured by the number of men working, there was a 17-percent gain in employment compared with 1936. In total number of man-hours worked at all mines, the gain was slightly over 18 percent. Hazards connected with mining resulted in more accidents to the workers than in 1936, but the increase in number of accidents caused only a slight rise in the accident rate because of the much larger increase in the number of man-hours worked. In fact, the fatality rate per million man-hours of exposure was lower in 1937 than in 1936, but the rate for nonfatal injuries increased slightly.

Jan 1, 1940

By A. W. Fahrenwald

The purpose of screening is to separate a crushed or natural product into one or more products in which size of grain is constant, or within certain size limits. The ore dresser finds need for this operation in the laboratory, in the study of ore-dressing processes, and for various purposes in the plants. In the plant, for example, screens are employed in closed circuit with crushing devices such as rolls, and sometimes are used in closed circuit with ball mills. Screens are generally used to prepare jig feed where a sized feed is wanted. For any given sieve opening there is in any feed a certain percentage of grains that will pass through the sieve meshes only with difficulty and under favorable conditions. For example, cylindrical grains of length greater than the maximum dimension of the sieve mesh and of diameter less than the sieve opening pass the sieve only when the long axis of the grain is normal or nearly normal to the sieve. Whether such grains should actually be in the through's or the oversize of a screening operation--considered from the point of view of the subsequent treatment of the grains--can not be said. The grains that pass the sieve opening in a screening process only under-favorable conditions have been named "difficult" grains by R. K. Warner.4 In many ore-dressing flow-sheets it probably matters little whether these difficult grains show up in the screen through's or oversize. The main objection to them is that they are sieve-blinding.

Jan 1, 1929

By N. A. Eilertsen

The Aroostook manganese-bearing deposits lie within a rectangle 30 miles wide and 70 miles long. Over 40 different deposits have been discovered in this area, but they have not been mined because the ores are difficult to treat. In 1949, the Maple Mountain area was selected for detailed investigation by the Bureau of Mines, because study by the State of Maine and the Federal Geological Survey indicated that it was the most promising in Aroostook County for developing a large tonnage of reserves. Investigation by the Bureau of Mines disclosed that all of the reported deposits of the central district were located on the limbs of a syncline underlying a pear-shaped area of 283 acres between the crests of Maple Mountain and Hovey Mountain. The ore area has been outlined by trenching and drilling along three sides of the perimeter, while the remaining side is defined by a fault. The area has a length of 6,300 feet and a maximum width of 3,100 feet. Diamond-drill holes have intersected the deposit as deep as 1,550 feet below surface, but additional deep drilling would be required to determine the intensity of folding or warping at depth. The Maple Mountain-Hovey Mountain deposit lies in the slates of Ordovician age and is classified into three zones, of which the upper, averaging about 57 feet thick, is designated manganiferous purple and red slate. The central zone, also averaging about 57 feet thick and containing the highest manganese content, is manganiferous, banded hematite. The lower zone is manganiferous, interbedded hematitic and green slate with an average width of about 33 feet. Manganese minerals occur with hematite in all three units. Trenching on the northwestern slope of Hovey Mountain uncovered other disconnected deposits of manganiferous rocks of earlier age than the ore of the syncline. The general strike of these deposits, which range from 15 feet to 75 feet in thickness, is southwest a length of 5,000 feet. They dip steeply southeast. The ore of the syncline is predominantly deep, hematitic red, inclining to red-dish black, fine-grained, dense, and thinly laminated. It is hard and siliceous. Hematite has, in places, been altered to magnetite. Because of the fine-grained texture of the ore, the manganese-mineral constituents are difficult to determine. Of the manganese silicates present, braunite is the most readily identified. Manganese carbonates and oxides are found also.

Jan 1, 1952

During the period 1979 thru 1982, Multi Mineral Corporation conducted a mining I research program at the United States Department of the Interior's Bureau of Mines Oil Shale Mining Environmental Research Facility in the Central Piceance Creek Basin, Rio Blanco County, Colorado. The program consisted of mining, environmental and geotechnical research data and, the results are described in this report.

Jan 1, 1983

By Martin Hertzberg

The concept of limit burning velocities, formulated in an earlier Bureau of Mines report (RI 8127), is applied to the problem of flame propagation through tubes of finite size. The limit burning velocity for conductive-convective wall-loss quenching (process b) is (Su)b = [aPe,] where the proper choice of critical Peclet constant, Pe, is determined mainly by the ratio of contact-perimeter loss area to flame-zone cross sectional area. This ratio of loss area to propagation area relates to the shape of the flame front and its control by buoyancy and by boundary conditions. The comparison of (Su)b with previously defined limit velocities for systems mixed by natural convection allows one to assess the influence of tube dimensions and boundary constraints on the "true" or earthly limits for the three directions of propagation. The flame quenching caused by inert powders is shown to be similarly described in terms of a limit burning velocity, (Su)?b. The tube's surface-to-volume ratio (~1/ro) is simply replaced by the powder's surface area per unit volume of the flammable mixture. Thermal loss quenching by these "internal walls" occurs at a critical Peclet constant somewhat higher than that observed for tubes, and the problem is complicated by the finite heat capacities of the powders and particle lag effects in the flame front.

Jan 1, 1980

By M. L. Skow

Large tonnages of the manganese ores found in Aroostook County, Maine, are refractory to conventional mineral-dressing techniques and to the common chemical- extraction procedures. The Maple Mountain-Hovey Mountain ores are typical of this type. Because the most promising method of recovering the manganese from these ores has been a chloridizing roast in which the ground ore is in contact with gaseous hydrogen chloride, preliminary batch tests were made with a fluidized bed. On the basis of these tests, it was concluded that fluidization, with careful control of operating conditions, could be employed for this cloridization and warrants further study. Selective volatilization of the iron at 600° C. was unsuccessful. An operating temperature of approximately 950° C. was necessary for a practicable rate of volatilization of manganese chloride. Hydrogen chloride contents of 10 to 100 percent of the fluidized gas gave essentially equivalent manganese recoveries with an 80- minute retention time, For shorter periods reaction was more complete with the higher hydrogen chloride concentrations. At the 80-minute retention period the lower hydrogen chloride concentrations volatilized somewhat less iron and also improved the physical operation of the process. Fluidization gave results superior to comparable tests on chloridization in a fixed bed.

Jan 1, 1956

By McHenry Mosier

This progress report on a national survey of the use of detachable bits in metal mines covers 10 mines. It presents comparative costs for drilling with conventional and detachable bits, describes the reconditioning of drill steel, and gives various data on rock drilling at these particular mines. Reports to follow will include similar data on drilling at other metal mines in the United States. ACKNOWLEDGMENTS This report is based on costs and data developed and furnished by the operators of the mines visited. The author is greatly indebted to the officials and staff members at these mines for their cooperation and assistance.

Jan 1, 1936

By J. W. Miller

An investigation was begun by the Bureau of Mines in 1948 to determine the preparation characteristics of American coals. Results of the investigation were planned to be reported on a county basis and from the data developed, to determine: (a) Which coals either as mined or after beneficiation by conventional preparation are suitable chemically under present standards for producing metallurgical coke. (b) Which coals require special and more intensive treatment in preparation than is now practiced. (c) Which coals cannot be considered potential sources of metallurgical coke regardless of preparation. This report is one in a county series that describes the preparation characteristics of the coals of Mingo County, W. Va.

Jan 1, 1956

By E. L. Singleton

This Bureau of Mines investigation was initiated to study and establish some of the chemical and physical characteristics of the condensed Mno-Si02 system. To prevent oxidation of the manganous ion, I atmosphere of purified helium was used in the furnaces. Solidus-liquidus curves and invariant points were established from melting-point determinations and were supplemented from data obtained by the static-quenching method. Experimental findings and data are for the intermediate compounds of tephroite and rhodonite with their respective eutectics represented at 25.5 and 37.2 weight-percent silica. Tephroite melts congruently at 1,347° C., and rhodonite melts incongruently at 1,286° 8.. A metastable transformation was determined to exist at the 1,347° C. isotherm, the congruent melting point of tephroite. A composite X-ray-diffraction pattern was formulated for synthetic rhodonite. This investigation contributes fundamental data leading toward a better understanding of the more complex slag systems.

Jan 1, 1962

By Irving Hartmann, John Nagy

"The pressures produced by dust explosions are frequently so great and are developed so rapidly that widespread destruction of manufacturing equipment and buildings results. Experimental data on maximum pressures and rates of pressure rise produced in a closed vessel by numerous metal powders and by dusts used in the plastics industry were published in two previous Bureau of Mines papers.4/5/One means for reducing structural damage is provision in the enclosing walls and/or roof of rapidly opening explosion-relieving devices or relief vents through which the pressure of an incipient dust explosion can be quickly dissipated. The vents can be simply unrestricted or free openings: hinged or pivoted sash which swing outward at a predetermined internal pressure; fixed sash, with light wall anchorages; scored glass panes; light wall panels; monitors or skylights; poppet-type vent closures; paper, metal foil, or other diaphragms that burst at low pressures; pull-out diaphragms, or other similar arrangements.The use of pressure-relief vents is recommended in the dust-explosion codes of the rational Fire Protection Association,6/ and recently a special committee on explosion venting has been organized. However, technical data on which the design and distribution of relief vents can be based are meager. An experimental study on venting grain-dust and cornstarch explosions was made by the Bureau of Chemistry and Soils, United States Department of Agriculture.7/ Tests on cork fines, cinnamon, starch, barley dust, and a phenolic plastic were made in a laboratory-scale (0.1-cubic-foot) apparatus by the engineering department of the Factory Insurance Association.8/ A study on the venting of explosions of acetone-air mixtures was made by the Bureau of Mines.9/The object of the present investigation is to extend the limited knowledge on the effectiveness of pressure-relief vents of different types, shapes, and sizes. The aim is to determine the venting requirements in equipment and structures of various dimensions and shapes for dusts of widely different explosive properties. On the basis of such accumulated information, together with theoretical considerations, it is hoped that ultimately it will be possible to recommend correct venting for most operations in which a dust-explosion hazard exists."

May 1, 1946

By R. F. Linfield

Figure 1-1 shows the basic transmitter design concepts used for the pulse system, the half-wave CW system, and the full-wave CW system. The antenna current waveform is also shown for each transmitter for typical operating frequencies and antennas. The switches shown in Figure 1-i were actually implemented using solid state devices. In all three systems the signaling format may be interrupted to conserve power and thereby extend battery life. Frequency accuracy and stability is achieved using a tuning fork oscillator in the transmitters and tuning fork filters in the receivers for all three systems. This provides the narrow reception bandwidths needed to enhance signal detectability. All three systems also use frequency assignment for identification purposes. The location schemes employed are likewise identical, each being based on detecting the null (signal minimum) of the horizontal magnetic field on the surface. Since these systems are basically similar, the primary purpose is to select the system which gives the maximum signal detectability on the surface from a manpack transmitter operating in the mine. Both the pulse and half-wave C W systems use a d. c. pulse to energize the loop antenna. However, with the pulse system, this pulse duration is short compared to the pulse repetition rate (prf), whereas with the half-wave C W system the pulse duration equals one-half the period of the switching frequency. In the pulse system, energy from the battery is stored in a capacitor so that during the switching interval the internal resistance of the power source can be considered almost negligible. Both transmitters must drive a loop antenna which is a reactive load having inductance, L, and resistance, Ra.

Jan 1, 1973

By C. A. Herbert

This paper sets forth the hazards of accumulations of explosive mixtures of methane and air due to inadequate ventilation, the causes of which are discussed as follows: 1. Lack of well-maintained air courses. 2. Air losses due to leaky stoppings, trap doors, and overcasts. 3. Faulty mining methods. 4. Poor supervision. A modified plan of room-and-pillar panel mine development is suggested, which, it is believed, will eliminate many off the hazards of gas accumulations inherent in the present method of mine development. It is also suggested that some water-proofing agent be used on the roof of permanent air-course entries in conjunction with roof bolting to eliminate the detrimental effect of the moisture-laden atmosphere during summer and thus prevent serious roof falls.

Jan 1, 1953

By Theodore L. Turner, Joseph H. Swift

A study on a small laboratory scale was made of the use of ammoniacalammonium carbonate for batch leaching Mn from low- grade manganiferous materials ( 6 to 16 pct Mn) obtained from deposits in the southern district of Aroostook County , Maine . These materials were partially reduced at 500 ° to 700 ° C with H₂ or CO and then leached with solutions of NH and CO₂ dissolved in water . Extraction of 80 to 90 pct of the Mn was obtained from some sample materials , but 10 to 34 pct of the iron was also extracted . Material from the Littleton Ridge deposit contained manganese intimately associated with Fe , a condition which contributed to difficulties in obtaining a commercially acceptable product . Extensive investigations of the leach and reduction processes with various mixtures of H₂ and water vapor , and CO and CO₂ , failed to disclose a set of conditions for selectively leaching the manganese . Finely divided metallic Fe was probably produced during the reduction steps so that Fe was leached with the Mn in the subsequent extractions .

Jan 1, 1964

By John J. Sammarco

This U.S. Bureau of Mines report describes the research effort and results for a computer-assisted appendage control system of a Joy 14CM continuous mining machine. The cutter head (shear), gathering head, conveyor, and stabilizer jack are the appendages. Positional control of each appendage is accomplished by specifying the desired position to the appendage control computer, which uses appendage position sensor data. Appendage movement is actuated until the desired position is attained as determined by control algorithms. A description of the sensors, mechanical and electrical interfaces, data acquisition and control (DAC) system, experimental method to determine appendage response characteristics (range of motion, start and stop delay times, and movement rates), and their application to the position control loop algorithms are presented. Also, the test results for the shear in an unloaded (free space) and loaded (cutting) condition of the shear are presented.

Jan 1, 1991

By R. R. Trengove

This paper is one of a series published by the Bureau of Mines on mining methods and operation practices. It describes the open-pit mining method and operations of the Kaiser Steel Corp. Eagle Mountain iron-ore mine, which is in the extreme southeastern part of California 175 miles east of Los Angeles in Riverside County. Nearest town to the mine is Indio, which is 60 miles away by an excellent highway (fig. 1). Elevations at the deposit vary from 1,400 to 3,000 feet. Figure 2 is a plan map of the Eagle Mountain iron mine. Kaiser Steel Corp. built a model camp at the mine, with all modern conveniences (fig. 3). The camp, comprising 145 homes, dormitories, mess hall, commissary, post office, and recreational facilities for 600 people, is at 1,390-foot elevation. The area has winter-resort weather between October and May, with occasional drops of temperature to 25° at night. From June to September temperatures sometimes rise to 1200 during the day. Rainfall is scant, approximately 2 inches a year, the majority of which comes as cloudbursts during the summer months.

Jan 1, 1956

By Wm. F. Netzeband

The purpose of this paper is to present to the operators, in other districts a detailed description of the ruining method used and the results obtained to exploiting one of the zinc-lead deposits of the Kansas-Oklahoma-Missouri district. No. 1. mine is located in the heart of the town of Picher in the extreme northeast corner of Oklahoma. HISTORY The first prospect drilling was done at No. 1 mine late in-1914, and shaft sinking was started early in 1915. Sufficient ore was developed to start construction of the mill in April, 1016, Production begin in August, 1916, and the mine s been producing, except for short periods, to the present time. The property was originally a 40-acre tract, but additional properties have been consolidated with the original one until the mine now covers 200 acres.

Jan 1, 1929

By J. H. Jacobs

In late 1946, research was begun at the Bureau of Mines Electrometallurgical Laboratory at Boulder City, Nev., to determine the possibility of electrowinning manganese from chloride electrolytes on a continuous basis. All phases of electrodeposition were investigated on a small scale it the laboratory, and the results were reported by Jacobs and Churchward. These results indicated that a chloride process had certain possible advantages over the sulfate process that made it worthwhile to continue the investigation on a semi-pilot-plant basis, and this paper reports the results of this work. Research and development work on a process for electrowinning manganese from low-grade ores has been carried on intermittently by the Bureau of Mines since 1936. A process was developed, using sulfate electrolyte, that has been extensively described in the literature.

Jan 1, 1951

By R. D. Van Zant

The method for smelting zinc in horizontal retorts developed several centuries ago is still in use. This process consists essentially of the reduction of zinc oxide by carbon at 1,200° to 1,400° C. in a fire-clay retort. The reaction is highly endothermic, and a high radiation loss occurs in transferring the heat of reaction through the fire-clay walls. In recent years, silicon carbide retorts with much better heat-transfer characteristics than fire clay have been supplanting the old retorts. The practical impossibility of recovering the carbon monoxide formed in the reduction causes a large loss of fuel. Intermittent smelting is done in small retorts that are manually charged and discharged, and the furnace crews must be specially trained if efficient results are to be obtained. During the past 20 years several processes have been introduced that have substantially improved the horizontal-retort process. One of these, developed by the New Jersey Zinc Co., consists of a continuous process in which a briquetted mixture of zinc sinter, reducing agent, and binder is coked at 750° to 900° C. and charged into a vertical silicon carbide retort. A supply of displacement air or exhaust combustion gas is introduced at the base of the retort at an appropriate pressure in order to keep the zinc vapor from condensing on the cooled residue in the lower part of the retort. Any .oxidizing constituents in the displacement gas are converted to carbon monoxide by reaction with the carbon in the charge. The spent residue is continuously removed at the bottom of tl1e retort. The chief advantages of this process are said to be increased output per man-day, improved working conditions, high recovery of zinc, increased thermal efficiency, and long retort life.

Jan 1, 1950