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By Thomas L. Ochs

The stripping of iron-laden solvent with hydrochloric acid in the iron-removal step of the clay-hydrochloric acid process for the extraction of alumina from calcined kaolinitic clay results in a loaded ferric chloride stripping liquor. Treatment of this stripping liquor at boiling with calcined kaolin to form insoluble Fe203(s) and a dilute A1C13 solution was undertaken by the Bureau of Mines to characterize process problems and to aid in sizing of solids-liquid separation equipment. Variables identified as important in the chemical reaction were calcined kaolin particle size, ratio of calcined kaolin to FeC13, and reaction time. These parameters were tested for significance and their interactions investigated. Fine calcined kaolin (-65 mesh) at a greater than 1:1 mole ratio of contained acid-soluble A1203 to Fe203 equivalent of the FeC13 in the stripping liquor required less reaction time than coarser (-16 mesh) material. Solids-liquid separation of the reacted slurries by both settling and filtration requires flocculation.

Jan 1, 2011

By R. V. Ramani

One area of study in the Coal Mine Injury Analysis project was to illustrate and enhance the ability o mine safety management personnel to apply analytical techniques to Injury experience data and to justify requests for funds for safety enhancement actions on a cost/benefit and other quantitative basis. Four volumes of this final project report detail (1) the objectives and scope of the mine safety management research, (2) the results of literature review, and case studies, and (3) models developed for mine safety management. The four volumes are titled as Volume III: Mine Safety Management, Volume IV: Analytical Techniques for Mine Safety Management; Volume V: Mine Safety Management Case Studies and Volume IX: Training Cost Model. In this volume, the application of the quantitative procedures to mine-specific accident/injury experience data is discussed in detail in the form of case studies. The accident data from three mines are analyzed, and recommendations for training are proposed for each of the mines on the basis of this analysis. The procedures to apply cost-benefit analyses are described along with the cost benefit ratios for the training program/policies for the mines.

Jan 1, 1993

By Daniel L. Ng

This Bureau of Mines report describes the results of scanning electron microscopic (SEM) studies of the combustion residues of carbonaceous dust particles resulting from explosions and thermal ignitions in laboratory and full-scale mine tests. The dusts studied varied widely in rank and volatility: Pittsburgh seam bituminous coal (35% volatility), Pocahontas seam bituminous coal (16% volatility), anthracite (7% volatility), graphite, and diamond. The most systematic explosion studies were performed in an 8-L chamber with narrow size distributions of Pittsburgh coal dust with surface mean diameters of 2, 22, and 84 pm. Experiments were conducted mainly in air, with some data obtained in 50% 02. Observations of the bituminous coal explosion residues showed particles with rounded edges, particles with blowholes, and some cenospheres. The lower volatility dust residues showed fewer changes from the original, unburned dust. In addition to the experimental studies, results of SEM observations of residues from a mine explosion disaster are reported. Comparison of such residues with those from the laboratory and experimental mine explosions can help investigators determine the extent of dust participation in the disaster and in identifying the possible ignition sources.

Jan 1, 1983

By A. R. T. Denues

The Explosives Division of the Bureau of Mines, United States Department of the Interior, is investigating cushioned blasting at the Explosives Testing Station, Bruceton, Pa. The general interests of this investigation are practical and relate particularly to safety. The immediate concern is an application of cushioned blasting in coal mining In cushioned blasting, various means are employed to reduce the intensity of the application of energy in an explosive action in a borehole. The primary object is to increase the efficiency of the use of explosives.

Jan 1, 1940

By A. R. T. Denues

The Explosives Division of the Bureau of Mines, United States Department of the Interior, is investigating cushioned blasting at the Explosives Testing Station, Bruceton, Pa. The general interests of this investigation are practical and relate particularly to safety. The immediate concern is an application of cushioned blasting in coal mining. In cushioned blasting, various means are employed to reduce the intensity of the application of energy in an explosive action in a borehole. The primary object is to increase the efficiency of the use of explosives.

Jan 1, 1940

By Kenneth H. Johnston

Records show that waterflooding was tried in Osage County as early as 1934, but it was not economically important until a large unitized flood in the North Burbank field was begun in 1950. Development was rapid and by the end of 1960, there were 70 active water flood projects and 16 active pressure-maintenance projects in the County. The locations and status of the water-flood and pressure-maintenance projects in Osage County on December 31, 1960 are shown in figure 1, and information pertaining to these projects as of July 1, 1960 is given in table 1. For the past several years, Bureau of Mines petroleum engineers have arranged tours of selected waterflooding projects for the spring meeting of the Kansas-Oklahoma Water flood Association. These tours are conducted to demonstrate unique operating methods and new field equipment and to provide additional opportunities for exchanging information. Each of these tours has been supplemented by a published report describing in detail the projects visited. This report has been prepared for distribution during the 1961 spring tour of three waterflooding projects and a pressure-maintenance project in Osage County, Okla. (fig. 2).

Jan 1, 1961

By John R. Bartels

This Bureau of Mines report describes the development of a preliminary design for a novel, protected, cab-shuttle car for use in working seam heights down to 40 in. Because of the severe restrictions imposed by low-coal operation, Mine Safety and Health Administration (MSHA) regulations only require canopy protection on shuttle cars operating in seam heights of 42 in or greater. MSHA routinely grants variances for canopy use in seams 48 in high or less. The design was generated by giving the operator needs equal priority as related to machine performance parameters. Cab-shuttle car concepts that led to the recommended design are described, along with criteria and testing used to evaluate their potential effectiveness.

Jan 1, 1988

By D. E. Traut

A fluidized countercurrent ion-exchange system was developed, operated, and evaluated by the U.S. Department of the Interior, Bureau of Mines. The system consisted of integrated multiple-compartment absorption and elution columns in which the solution flows were continuous except for short periods when resin increments were withdrawn. The exchange of uranyl carbonate between a simulated in situ uranium leach liquor and a strong-base ion-exchange resin together with the subsequent elution with an ammonium chloride solution was studied. The effects of the number of sections, section height, amount of resin withdrawal, solution flow rate, and column diameter were investigated. The kinetic and equilibrium relationships for the absorption and elution steps were also examined. The experimental data indicate a strong interdependence between variables. Solution retention time appears to be a major limiting variable in the absorption process, while resin residence time is the determining factor in the elution process. The column was efficient over a range of conditions, but close control was needed for optimum operation.

Jan 1, 1978

By Kenneth O. Bayard, John D. Sullivan

"This repot continues the series of papers being prepared at the Southwest Experiment Station of the Bureau of Mines in cooperation with the department of mining and metallurgy, University of Arizona, on factors involved in the leaching of ores. A list of previous publications is given in the bibliography at the end of this paper.Four factors are essential to the leaching of any copper-bearing ore: (1) A solution that will attack the copper minerals must get into the body of the ore particles; (2) the copper minerals must be dissolved by the solution; (3) the solution containing the dissolved copper must find its way out of the voids of the rocks into the main solution; and (4) the copper in solution must be recovered by some means of precipitation.This paper considers the third step -- the extraction of the water-soluble copper. From leached ores. The usual commercial practice in leaching copper ores consists of: (1) Crushing the ore to pass through a screen with approximately one-quarter or one-third inch openings; (2) charging the crushed ore into a fat; (3) adding, usually by upward percolation, a solution that will attack the copper minerals; and (4) washing the copper-laden solutions out of the ore with solutions weaker in copper than the pregnant solution, and finally with water. A countercurrent system of leaching and washing is usually employed. In some plants the solutions are circulated during leaching and washing, and in others they are not. In some plants the wash solutions are added by upward percolation, while at Chuquicamata the so-called ""piston-displacement"" method of washing is employed.The following condensed resume of the leaching cycle of the plant of the Inspiration Consolidated Copper Co. is given to present to the reader a picture of the steps involved in a typical leaching cycle. This plant was recently described in detail.4 The ore, crushed to pass openings 11/2 inches in diameter, passes over a screen with ¼-inch openings. The undersize from the screen goes to a Dorr howl classifier that removes the primary slime from the circuit. The overflow from the classifier is treated in a slime-leaching plant. The oversize of the ¼-inch screen passes through rolls, where it is crushed to pass a 3/8-inchscreen. The undersize from the 3/8-inch screen join with the coarse material from the classifier, and the combined products become the feed to the leaching vats. There are 13 concrete lead-lined leaching vats. The complete leaching cycle is 13 days. Eight tanks are under acid-iron content at all times; three are being washed, one tank is being filled, and the one is being excavated. The electrolyzed solution from the tank house, to which amount of new acid has been added, is put on the oldest tank of ore under need This solution travels from tank to tank and finally emerges from the newest ore"

Apr 1, 1931

By C. E. Reistle

The tests reported in this paper were made in the East Texas field in the summer and fall of 1932 as a part of the Bureau of Mines study of the operation of flowing wells and reservoir performance; and to determine, if possible, the minimum reservoir pressure necessary to produce the wells in this field by natural flow through different sizes of flow strings. The minimum reservoir pressure that would be required to maintain natural flow through 2 1/2-inch tubing was determined experimentally for the existing energy conditions in the East Texas field. With the present available data, however, it 'is impossible to predict accurately or to determine by calculation the necessary energy requirements for maintaining the vertical flow of oil and gas mixtures under all conditions. Although some valuable data were obtained which seem to have application to the solution of problems involving vertical flow, this important research of the petroleum industry is so involved that more study of the complicating factors influencing the flow of oil-gas mixtures through vertical pipes is required. Versluys4 has presented a mathematical analysis of the vertical flow of oil and gas mixtures which covers the fundamental theories of the problem-although, as he points cut, there are factors, particularly friction, slippage, and solubility of the gas in the oil that must be mown or determined experimentally before the equations he has developed can be applied to actual

Jan 1, 1933

By R. B. Stotelmeyer

Mineral resources, or a potential for their discovery, occur at 34 localities in the Glacier Peak Wilderness and adjacent areas of the north Cascade Range of Washington (see plate). Eighteen of the mineral deposits are in the established Wilderness, four are in or partly in contiguous RARE II (Roadless Area Review and Evaluation) lands recommended by the Forest Service for addition to the Wilderness (A, D and G6031.), three are in adjacent RARE II lands excluded from wilderness consideration, and nine are in nearby roaded areas excluded from the RARE II inventory. Mineral commodities that might be produced from the Wilderness and recommended additions are gold, silver, copper, lead, zinc, molybdenum, arsenic, cadmium, tungsten, cobalt, limestone (marble), pumice, and volcanic cinders. Mineral production from adjacent lands might include most of these commodities, plus antimony, decorative stone, pyrite, silica, and garnet.

Jan 1, 1982

By William C. McBee

Sulfur concretes have been developed by the Bureau of Mines as construction materials with physical and mechanical properties that suit them for use in acid and salt corrosive environments where conventional concretes fail. Mixture design methods were established for preparing sulfur concretes using different types of aggregates and recently developed mixed-modified sulfur cements Bench-scale testing of the sulfur concretes has shown their potential value. Corrosion resistance, strength, and durability of sulfur concrete are superior to those of conventional materials. Field in situ evaluation tests of the sulfur concretes as replacement for conventional concrete materials are in progress in corrosive areas of 24 commercial chemical, fertilizer, and metallurgical plants.

Jan 1, 1983

By M. A. Schellhardt

In recent years development of instruments and equipment for determining subsurface pressures and temperatures in. gas and oil wells has made it feasible to obtain information that eras not available in the past on many gas-production problems. The material presented in this report illustrates particularly the value of subsurface-temperature data in the study of subsurface leakage from gas wells. An abnormal decline in the shut-in pressure of the Lone Star Gasoline Co. A. Jones No. 1 gas well in the southern part of the Buffalo (Tex.) field was observed during an interval when a negligible volume of gas bras being withdrawn from the reservoir. Wellhead-pressure readings indicated that the shut-in pressure of the well declined from 2,295 pounds per square inch gage on February 3, 1937, to 1,445 on February 12, 1935. Tests conducted by engineers of the Lone Star Gas Co. suggested that the subnormal pressure gaged on February 12, 1938, probably was not caused by a head of liquid in the well.

Jan 1, 1940

By S. J. Aresco

The Bureau of Mines has been active in promoting the purchase of coal for Government use under specifications that define the requirements in terms of heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analyses. To these, when required, are added the ash-softening temperature, the free-swelling index, and the Hardgrove grindability index. Under most of these specification contracts the bidders guarantee the quality of the coal, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled in accordance with instructions 5/ issued by the Bureau of Mines; the samples are analyzed in the Bureau laboratory to determine whether the coal is of the quality guaranteed by the contractor and, if it is not, a price adjustment is made. Analyses of the delivered coal and tipple samples (samples collected at mine tipples as coal is being loaded into railroad cars or trucks) provide valuable data for use in evaluating future bids. In addition, the continuous sampling of coal as delivered is a check on the practical results obtained in burning the coal.

Jan 1, 1962

By L. Nahai

An important objective of the Australian Government's policies on resources development is to encourage further processing of raw materials domestically, to the extent that this is economically feasible and consistent with sound industrial development. This Bureau of Mines report examines the extent to which Australia is able to pursue this policy in terms of its own competitive advantages and the implications of such a policy for the United States. Such factors as the impact of other competing producers and their advantages, expected world demand, and infrastructural problem--which may limit pursuit of this policy to the fullest extent--are discussed. After a broad review of the re-source, economic, social, and environmental factors, the perspective for increased processing is examined for a number of mineral commodities.

Jan 1, 1982

By Basil Dimitriades

The roles of hydrocarbons and nitrogen oxides in smog formation were investigated by the Bureau of Mines. Samples of automobile exhaust with varying HC and NOx levels were irradiated in a smog chamber under conditions that resulted in smog levels similar to those observed in the atmosphere. Results were used to define the patterns that describe the dependence of a number of smog manifestations on HC and on NOx. Using these dependence data and some simplifying assumptions, estimates were made of the ranges within which HC and NOx must lie in order to obtain specified levels of air quality.

Jan 1, 1970

By R. E. Simpson

Beginning in 1972, fully grouted resin bolts were used in underground mines. An estimated 20 million resin bolts will be installed in 1980 owing to their apparent support improvement in most roof-bolt applications. Inorganic cements were tested to replace the resin at a lower cost while retaining the advantages of a grouted bolt. Although other inorganic materials were considered, all but portland and gypsum cements were rejected for reasons of availability, performance, or cost. Portland and gypsum-type cements were tested by the Bureau of Mines to select a fast-hardening, low-cost material that would anchor a roof bolt adequately to meet safety standards. An alpha-gypsum cement, accelerated with potassium sulfate, was selected as the best material because it had adequate pull strength at a desired set time of less than 5 minutes and was readily available.

Jan 1, 1980

By T. M. Barczak

A primary objective of the Bureau of Mines geomechanics research program is to develop a better understanding of support behavior and interaction of supports with the strata so that supports can be more closely engineered to the geological conditions in which they are employed. Four longwall shield supports were instrumented with an eight-transducer instrumentation array to measure leg, canopy capsule, and compression lemniscate link forces from which resultant shield loading was determined. The instrumented supports were monitored over a 4-month period, producing over 75 shield cycles of resultant shield loading. Resultant loading is the true measure of support resistance, providing both roof-to-floor and face-to-waste support reactions as well as the location of the reaction on the shield canopy. Observed roof support reactions were analyzed, with particular emphasis on horizontal shield loading, since it is the least understood design parameter. Average, peak, and change in shield loading during the mining cycle are discussed. Correlations among data parameters are examined, as is the distribution of support loading at the headgate and midface. Conclusions are drawn as to the effectiveness of the shield support at this installation. Recommendations are made for further research needs.

Jan 1, 1987

By Ferron A. Olson

Natural bornite (Cu5FeS4) leached in ferric chloride or in sulfuric or hydrochloric acid solutions with oxygen showed several differences. In ferric chloride 80 of the copper was leached in two stages. The first (30 copper removal) requiring one minute was controlled by mixed kinetics (liquid ferric ion diffusion and chemical surface reaction). The second was controlled by formation of a surface sulfur layer and then diffusion through the sulfur. With oxygen in sulfuric acid reaction was slow and only the first stage was studied. Copper removal had an induction period. The bornite structure disappeared at 12% copper removal (also found with ferric chloride) and covellite formed on the surface with a species inside the particles having an x-ray structure similar to CuFeS2 but with composition Cu3FeS4 (also with ferric chloride). Copper removal was controlled by iron dissolution. Surface iron vacancies filled with Cu+ to give CuS while interior copper dissolution produced Cu3FeS4. Preliminary results with oxygen and hydrochloric acid showed 80% copper removal and sulfur as end products (similar to ferric chloride).

Jan 1, 1982

By William R. Barton

COLUMBIUM (niobium) and tantalum are similar refractory metals with closely related properties and uses and close association in ore deposits. Until recently both metals, particularly columbium, were essentially laboratory curiosities. However, since the beginning of World War II, applied technology, under the impetus of national security requirements, has realized many chemical, electronic, nucleonic, and missile and rocketry applications, where high temperature or corrosive environments require the use of columbium or tantalum. At the same time, advances in these fields have resulted in intensive research on the geological distribution, resources, metallurgy, and properties of these two metals; their alloys and compounds; and the development of a full-fledged columbium-tantalum industry. The future appears to promise continued acceleration in such studies and ever-increasing demand for these elements. The raw material supplies of columbium are abundant, and the extractive metallurgy of columbium is well enough advanced to assure adequate supplies of the element at reasonable prices to meet any projected demands. Although the extractive metallurgy of tantalum is similarly well developed, raw material supplies are so limited that, lacking new ore discoveries, an increase in demand to five times the 1959 level would severely tax ore-production facilities. Approximately 120 tons of tantalum and about one-half as much columbium was produced in 1959. Additional quantities are consumed as compounds or additive alloys such as ferrocolumbium and ferrotantalum columbium (55).3

Jan 1, 1962