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By James S. Browning

Recovery of fine mica from a sample of impounded tailing from the Dixie Mines, Inc., crushing and screening operations, Heflin, Ala., was investigated to determine if plant losses of mica could be reduced while econmically producing a commercially acceptable mica concentrate. Conventional wet-tabling and agglomerate-tabling methods yielded concentrates assaying about 95 percent mica from the tailing that contained 17 percent mica. Products containing about 98 percent mica and accounting for mica recoveries of 86 percent were obtained by flotation, using as reagents sulfuric acid, kerosene, and coco amine acetate (a mixture consisting chiefly of dodecyl and tetradecyl amine acetates). The results of the batch flotation tests were verified by tests in a small continuous flotation pilot plant.

Jan 1, 1963

By P. J. Watson

The objective of this study was to prioritize the potential risks nuisance and biologically active dusts and fumes present in metal and nonmetal mines. This was accomplished by ranking numerical values derived from a matrix formula calculation that took into account dose, mine population, and sampling size. Data used in these calculations were obtained from the Mine Inspection Data Analysis System (MIDAS). The dusts determined to have the highest risk potential were quartz respirable particulates, mine dust, cristobalite respirable particulates, welding fume components, and nuisance respirable dust. Other dusts and fumes that were not ranked in this study, due to small sampling population, but which show a potential risk, include asbestos, talc, hydrogen cyanide, organic compound dusts, arsenic, metal dusts, and metal and nonmetal fumes.

Jan 1, 1987

By G. E. McClelland

As part of its mission to assure an adequate domestic supply of metals essential to the Nation's welfare, the U.S. Department of the Interior, Bureau of Mines, investigated a particle agglomeration technique as a means for improving the flow of leaching solution through heaps of clayey or finely crushed, low-grade, gold-silver ores. Bench-and pilot-scale experiments showed that the percolation rate of cyanide leaching solution was markedly enhanced by mixing the ore with a portland cement binder, moistening the mixture, and mechanically agglomerating and aging the feed prior to heap building and leaching. The rate of gold and silver recovery markedly increased because of the increased, uniform percolation of leaching solution through the agglomerated feed. The use of concentrated cyanide solution instead of water during the agglomeration procedure decreased the leaching time required to obtain maximum recovery. Results of bench-and pilot-scale experiments are discussed.

Jan 1, 1981

By J. M. Stuve

Heat of solution measurements of high-purity neodymium metal and neodymium trichloride (NdCls) in 4.360 molal hydrochloric acid (HCI) were used to determine the standard heat of formation (6EPr) of NdCls? From solution data obtained, the heat of formation of NdCls (c) was computed as -248,970 ±260 cal/mole at 298.150 K.

Jan 1, 1965

By D. E. Redmon

Linear programing provides a mathematical technique by which activities can be planned in such a way that an optimal result is obtained. Routine applications of linear programing require only a knowledge of algebra. However, a complete understanding of the fundamentals of linear programing requires a knowledge of advanced mathematics. The purpose of this publication is clarification of terminology and illustration of applications in comparatively simple mining problems. Two mining situations are considered: Mine stopes from which ore is to be produced at a minimum production cost; also, uranium mines from which ore is transported to one mill, a maximum monetary value is desired. The details of data arrangement for solution by linear programing are described and the solutions are presented. Results of these solutions indicate successful applications of linear programing to mine production scheduling.

Jan 1, 1964

By Wing G. Agnew, John A. Johnson

"INTRODUCTION This paper is one of a series being published by the Bureau of Mines pertaining to an investigation on the use of stemming in metal mines now being conducted at the Mount Weather Testing Adit. Its purpose is to compare the amount of dust and gases produced as a result of blasting charges of dynamite (1) in drill holes, (2) in bombs, and (3) in mud-cap or adobe shots.ACKNOWLEDGMENTSValuable assistance and advice on stemming were given by members of the staff at the Bureau of Mines, as acknowledged in previous publications. 4/TEST PROCEDUREThe results used for comparison in this report are from dust and gas samples taken after blasting (1) four regular test rounds with no stemming, (2) five bomb shots, and (3) two mud-cap or adobe shots.The four rounds were the standard 26-hole test rounds designed to break 4 feet of rock. The procedure for drilling and blasting these rounds is described in Report of Investigations 3509.Before the regular test rounds were blasted, about 1,200 bounds of fine rock was placed on the steel mucking sheets that covered the end of the adit track; the wails, hack, and floor of the adit were washed thoroughly; and the fine rock on the mucking sheets was completely wetted.Each of the 5 bomb shots consisted of 10 sticks of dynamite tied together and hung at midpoint of the adit, 8 feet from the fall."

Dec 1, 1942

By Frank S. Wartman

"The experimental flotation work described in this paper was undertaken to test the conclusions derived from a previous microscopic and chemical study of several samples of converter slag. That study3 resulted in the conclusion that approximately 90 per cent of the copper content of a converter slag wad in either the sulphide or metallic form, and that if the slag were cooled slowly the copper-bearing material would be in particles of such size that they would be freed from silicate and magnetite grains by grinding the slag to pass a 150-mesh sieve. If this were true, it should be possible to separate the copper-bearing grains from slowly cooled, converter slag by the flotation process.Many attempts, of which the author has seen no published account, have been made to treat slags, especially converter slags, by flotation. In every case these trials have been made with chilled slags, in which, as shown in the preceding report, the copper-bearing material is top finely disseminated, to be freed by any reasonable degree of grinding.The flotation tests described in this paper have shown that it is possible to recover by flotation about 30 per cent of the copper content of a converter slag containing 3 per cent copper and to obtain flotation concentrates which have a copper content of 35 per cent.Acknowledgment is made to G. L. Oldright, supervising engineer of the section of nonferrous metallurgy, U. S. Bureau of Mines, for valuable assistance and direction; to W. A. Sloan for chemical analyses; and to Alfred P. Towne for assistance in experimental manipulation."

Apr 1, 1931

By R. G. Sandberg

The Bureau of Mines investigated a hydrometallurgical procedure to recover gold, silver, and byproduct lead from a complex lead-zinc sulfide ore. A ferric chloride (FeCI3) preleach, at 40° C in 6 h, extracted about 50 pct of the zinc and formed insoluble silver and lead chlorides. Subsequent acid thiourea leaching, for 1 to 3 h at 40° C, extracted about 85 pct of the gold and silver. Lead chloride was solubilized from the remaining residue with NaCI brine solution at 55° C in 1 h. Lead metal was recovered from the brine solution in an electrolytic cell with an anion perms elective membrane at a current efficiency of 95 pct and current density of 100 A/m2. Spent FeCl3 leach solution was reoxidized in the anode compartment at a current efficiency between 75 and 95 pct.

Jan 1, 1986

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

D.2 Principal Types of Coating A Sodium Silicate Sodium silicate is a good fire retarder when freshly applied, but it loses its effectiveness if the relative humidity is at all high, thus exposure to a relative humidity exceeding 65 percent causes a serious decrease in the effectiveness after only one month. In fire, sodium silicate swells to a frothy mass (intumescence) which hardens and insulates the wood against heat. This property is destroyed by exposure to moisture. Manufacturers of many of the proprietary paints containing silicates state that their products have overcome this difficulty The reagent may be applied alone, or, better, in a mixture with lime-water and common salt, or with inert fillers such as kaolin or asbestos. B Ammonium Phosphate Strong solutions (25 to 35 percent) of monammonium phosphate or diammonium phosphate give good protection. Two or three coats of hot solution should be applied either with a large flat brush or an ordinary paint spray gun The solution should be applied as hot as possible, as this improved penetration, and it should be the aim of the operator to apply 4 lbs of reagent, i e , one gallon of 33 percent solution to every 100 square feet of surface

Jan 1, 1976

By H. R. Beard

The Federal Bureau of Mines investigated the absorption of radium and thorium from waste uranium leach liquor by clays and other materials. This work was conducted in support of the Bureau's goal of minimizing the environ¬mental conflicts, impacts, and occupational hazards Associated with mining and mineral processing operations. Tailings and soil samples from Wyoming and Utah were contacted with tailings liquors to determine the degree of absorp¬tion. Absorption ranged from 0 to 99 percent for radium and from 0 to 31 per¬cent for thorium. Some samples, which readily absorbed radium, were contacted with various salt solutions that could be present in tailings solutions to determine their effectiveness as desorbents. The desorption of radium ranged from 0.06 to 100 percent. An alpha-spectrometric method was used to determine the radium and thorium, concentrations in the solutions and the solids.

Jan 1, 1979

By H. R. Beard

The Bureau of Mines investigated the absorption of radium and thorium from waste uranium leach liquor by clays and other materials. This work was conducted in support of the Bureau's goal of minimizing the environmental conflicts, impacts, and occupational hazards associated with mining and milling operations. Tailing and soil samples from New Mexico were evaluated for their potential to absorb radium and thorium from tailing liquors. Absorption ranged from 0 to 97 pct for radium and 0 to 60 pct for thorium. Some samples that readily absorbed radium were contacted with various salt solutions that could be present in tailing solutions to determine whether desorption would be a potential problem. The desorption of radium ranged from 0 to 75 pct. An alpha spectrometric method was used to determine the radium and thorium concentrations in the solutions and solids.

Jan 1, 1980

To develop effective noise controls for continuous min-ing machines (CMMs) to reduce worker noise exposure. Background Noise-induced hearing loss (NIHL) is an occupational illness caused by chronic exposure to excessive sound levels. For underground coal mine workers, NIHL continues to be a serious health issue. Analysis of hearing loss data suggests that by retirement age, 70%?90% of U.S. coal mine workers will have a hearing impairment. Operated in the confined spaces of underground mines, large industrial mining equipment often produces sound levels that can be harmful to workers. Of all equipment used in underground coal mining operations, CMMs account for the most noise overexposures. To reduce the occurrence of noise over-exposures, engineering noise controls must be developed for the CMM.

Sep 1, 2008

By John E. Pahlman

An increasing number of gold and silver mining operations are employing cyanide solutions to effectively dissolve silver and gold from finely disseminated ores. Many of these operations use small, packaged processing systems like the State of Maine filter system, which employs zinc precipitation of gold and silver. Solution-clarifying filters in these systems become blinded with calcium carbonate (CaC03) scale and require frequent (every 2 to 10 days) dismantling of the filter units for acid cleaning, This is a hazardous operation as it is not compatible with the alkaline cyanide leach solutions and may result in the evolution of toxic hydrogen cyanide (HCN) gas during cleaning and during any accidental acid spill. The Bureau of Nines has investigated an alternative, nonacidic method of cleaning blinded State of Maine filters that employs ethylene- diamine-tetraacetic-acid (EDTA) type chelating agents to dissolve the scale. In situ cleaning of a 150-st/d State of Maine filters with EDTA- type chelating agents was successfully demonstrated. Greater than 90 pct of the CaC03 scale was removed in about 10 min with circulation of 31 L of 2.5-pct-EDTA solution through the filter unit. The EDTA cleaning method not only eliminates the cyanide hazard in filter cleaning but is advantageous from the standpoint of operating costs and productivity.

Jan 1, 1986

By J. H. Maysilles

The Bureau of Mines is examining a variety of low-grade uranium ores because projections indicate that an appreciable percentage of future U.S. uranium production will be derived from resources containing 0.01 to 0.1 percent U308. One possible source is represented by a granitic material from Wyoming; the available samples contained 0.06 and 0.12 percent U308. Tests were conducted to explore the general leaching characteristics of this potential resource. The material responded to both acidic and alkaline leaching techniques. Conventional acid leaching extracted 93 percent of the uranium in 18 hours; the required acid addition was 50 to 100 pounds of H2S04 per ton of ore, and the oxidant addition was 3 pounds of NaCl03 per ton of ore. The acid consumption continues after maximum uranium recovery has been reached; this effect may complicate heap or in situ leaching with acidic solutions. Some variation in reagent requirements was noted between the two ore samples. Conventional carbonate leaching with strong solutions at 85° C extracted 94 percent of the uranium in 24 hours. These granitic materials also showed some response to dilute carbonate solutions, and the results suggest that the material may be chemically amenable to heap or in situ leaching with dilute carbonate solutions.

Jan 1, 1977

By R. E. Stiles

The modified perchloric--EDTA method devised by the Bureau of Mines for the determination of copper in high-grade samples gives results that are more precise and more accurate than those from the classical sulfuric-iodometric method. Although the perchloric--EDTA method is more costly than the conventional method, the savings in time alone largely offsets this difference. Specifically, the modifications wade in the more conventional procedure comprise (1) use of perchloric acid instead of sulfuric acid for dissolution of copper minerals, (2) precipitation of copper as copper sulfide from dilute perchloric acid solution, (3) wet oxidation and dissolution of the precipitated copper sulfide, (4) use of larger amounts of indicator than those employed in the Schwarzenbach method of titrating low-tenor copper solutions with disodium ethylenedinitri10-tetraacetate and murexide indicator, and (5) use of refrigeration to partially stabilize aqueous solutions of the indicator.

Jan 1, 1966

By Charles L. Kusik

As part of an effort to establish the extent of the domestic chromium supply that could be exploited in case of adverse changes in international chromium production and trading patterns, a two-part study was conducted for the Bureau of Mines, to assess the domestic availability of critical metals in scrap containing significant amounts of chromium. This report describes the part of the study that deals with wrought stainless steels and heat-resisting alloys. Data were collected on types of scrap, sources, quantities, and ultimate disposition, leading to the conclusion that In 1917 about 62,000 tons of contained chromium was unrecycled. Unrecovered obsolete stainless steel scrap accounts for most of these uncollected chromium values. Error margins in the amount of uncollected scrap are estimated to be 10 to 20 percent.

Jan 1, 1980

By P. C. Good

High-purity chromium was prepared in massive form by the electrolysis of chromium trioxide solution at high temperatures. The metal thus obtained, containing 50 to 150 p.p.m. of oxygen, 20 p.p.m. of nitrogen, and traces of metallic impurities, could be hot-worked to rod and sheet and drawn to wire ductile at room temperatures. Optimum concentrations and operating conditions were established for the deposition of chromium from chromic acid baths containing sulfate, fluoride, and silicofluoride ions. Current efficiencies of 13 percent were attained with baths containing sulfate ion, and efficiencies of 40 to 44 percent with baths containing fluoride and silicofluoride ions. Cation exchange resins were used for removing metallic impurities from chromic acid solutions containing sulfate ion; solutions containing fluoride and silicofluoride ions were purified by recrystallization.

Jan 1, 1960

By P. A. Hendricks

This U.S. Bureau of Mines (USBM) report identifies and evaluates factors responsible for metal/nonmetal (M/NM) underground mining accidents involving mobile equipment. Information regarding the occurrence and severity of the accidents, the type of equipment involved, the primary and contributing causes, and preventive measures is included. The goal of this report is to provide information that will aid mine operators and safety managers in the recognition of hazards associated with operating mobile mining equipment in an underground mining environment.

Jan 1, 1994

By C. W. Sill

[In the original Norris and Fay method for determining selenium, selenious acid is reduced by an excess of standard thicsulfate in accordance with the following reaction: H2Se03 + 4Na2S203 + 4HC1 = Na2SeS406 + Na2S406 + 4NaC1 + X20. (1) The excess thiosutfate is then back-titrated with standard iodine solution. The disadvantages of ouch a method are obvious. On an unknown sample, the quantity of thiosutfate required would be difficult to determine; a definite excess is required, but large back titrations would be undesirable. Inasmuch as thiosulfate is decomposed by acid, considerable error may be introduced in this method, the amount depending on the acidity, temperature, concentration of excess thiosulfate, duration of contact between thiosulfate and acid, and other factors, In a critical study of the Norris and Fay method, Coleman and McCrosky3/ show that the method is accurate to less than .1 part per thousand if the excess of this sulfate Is not greater than 5 ml. of 0.1 N solution (in 1.0 ml. of 0.x4 N sulfuric acid) whether the titration is made at 0° or 20°C. A greater excess produced unsatisfactory values at either temperature. Coleman and McCrosky regulated the excess thiosulfate by adding 5-ml. portions of thiosulfate solution followed by the addition of 1 to 3 drops of 2.5 percent potassium iodide in the presence of starch. If a starch-iodine blue color formed locally around the drops of potassium Iodide, the reduction of selenious acid was not complete. On stirring the solution, the local blue color fades and another 5-ml. portion of thiosulfate is added. When addition of potassium iodide fails to produce a local blue color, reduction of selenious acid is complete, and the excess thiosulfate is then back-titrated with standard Iodine solution. The number of equivalents involved in the reduction of selenious acid by either thiosulfate or iodide is the same, and therefore no correction need be made for the potassium iodide. This procedure is much better than the original Norris-Fay titration, but acidity and time would stilt be rather critical factors subject to variation with individual technique. Also, the method still requires the lose of two standard solutions, a rather undesirable factor from the standpoint of routine application.]

Jan 1, 1954

By R. O. Dannenberg

Applicability of the fluosilicate sintering process to recovering beryllium from beryl-spodumene concentrate analyzing 1.4 to 3.7 percent BeO (10 to 30 percent beryl) was investigated. The work was one phase of a Bureau of Mines research program undertaken to assess applicability of conventional processes and to devise new procedures for treating various potential beryllium feed materials. Beryllium recovery of about 70 percent in a product of 99-percent BeO grade was achieved in treating 3D-percent beryl concentrate. The process consisted of (1) sintering a briquetted charge of concentrate, soda ash, and sodium fluosilicate for 3 hours at 750° C.; (2) extracting the soluble beryllium by multiple stages of water leaching; (3) adding caustic to the leach solution and boiling to hydrolyze and precipitate crude beryllium hydroxide; (4) dissolving the crude beryllium hydroxide in sulfuric acid and separating the solution from undissolved silica; (5) sulfidizing the acid beryllium solution to precipitate heavy metal impurities; (6) adding ammonia to the clarified sulfate solution to precipitate beryllium hydroxide; and (7) converting the hydroxide to beryllium oxide (beryllia) by calcining at 900° C. About 60 percent more sodium fluoSilicate was required per unit of beryl than is used industrially in treating 10-to 12-percent BeO concentrate (80 to 90 percent beryl). Recovery decreased, and flux requirements increased, when treating concentrates containing less beryl.

Jan 1, 1963