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By Alvin Kaufman

Geothermal plants are competitive with conventional units. A geothermal plant can produce electric energy for 6.70 mills per kwhr, compared with 6.96 mills for coal, 6.74 mills for oil, and 7.04 mills for gas. These costs include fixed and variable charges. Potential for geothermal power exists in the Western United States, Alaska, and possibly Hawaii. Assuming that the current downward trend in cost per kilowatt of coal will cease and that the relative cost of gas and oil, already trending upward, may rise considerably more, geothermal energy will be utilized where available, in producing electric energy. It will be used in California first because it is directly competitive with gas-and oil-fired installations there. A long-term appraisal is difficult because little is known about the sources of geothermal power and the electric generating capacity which the steam fields will support. However, a market for geothermal steam-generated electricity exists within the Western States.

Jan 1, 1964

By Walter W. Kaufman

This report summarizes a study conducted to determine the state of the art of various rock removal systems and their capabilities. The Objective of the study was to determine if currently manufactured equipment can adequately accomplish rock removal in surface mine reclamation applications. Evaluations of state reclamation regulations, with regard to topsoil rock content, were made to determine the rock removal requirements. The major categories of equipment studied are rock pickers and rock rakes. The impact of rock removal implementation on the reclamation operations is discussed in detail.

Jan 1, 1979

By M. M. Wong

The Bureau of Mines, under a cooperative research program with four lead companies, has investigated a nonsmelting process for the production of lead metal. The process, which would eliminate sulfur dioxide generation and minimize particulate lead emissions, involves ferric chloride leaching of galena concentrate to produce lead chloride, followed by molten-salt electrolysis of the lead chloride to yield lead metal and chlorine. This chlorine is used to regenerate ferric chloride in the leaching solution. The process was tested in an experimental unit with a capacity of 500 lb of lead metal per day. The tests were performed in three 10-day and six 5-day campaigns, during a period spanning 28 mo. The study was carried out using a southeastern Missouri lead concentrate. Typical lead recovery was about 98 pct. Process problems related to impurity buildup and control were studied. When copper and silver impurities were removed from the leaching solution, a lead metal purity of 99.999 pct was obtained. Lead-in-air levels and lead-in-blood levels of operating personnel were monitored. The process has potential for producing lead with minimum pollution, but is not ready for commercial utilization. Operation of a prototype commercial electrolytic cell and a full-scale pilot-plant investigation by industry are needed to evaluate the commercial viability of the process.

Jan 1, 1983

By R. D. Leitch, C. A. Taylor

Trinitrotoluene is made by the direct nitration of toluene by a mixture of nitric and sulphuric acids . The exact procedure varies , but the product , where Grade I of TNT is desired , is similar , and consists largely of material that has a melting and setting point of 80.6 °c . The purification consists of draining off the liquid portions , including the acid and liquid nitro compounds . The mass is crushed and washed until the TNT is acid - free . It may still have a low-melting point due to the presence of material of lower nitration. Other isomers also have the same effect . The crystal mass may be washed with a solution of sodium sulphite , thiosulphate , sulphuric acid , or with an organic solvent such as alcohol , benzene , or carbon tetrachloride , Where a very pure product is desired , the TNT is separated by fractional crystallization from solution in organic solvents . The TNT is If it forms In some cases the material is melted during purification . agitated as it cools to prevent solidification in a solid mass . in a solid mass , this is broken up and screened . There has been some question as to the effect of the different methods of purification on the strength and sensitiveness of TNT , although all methods left a product that would give satisfactory tests .

Sep 1, 1923

By Jennifer A. Slatnick

The U.S. Bureau of Mines estimated the potential availability of titanium from 39 mines and deposits in 12 market economy countries. The evaluated properties account for 76 pet of the market economy country demonstrated resources, which total 603 Mt of contained titanium dioxide (Ti02) in the minerals rutile, ilmenite, leucoxene, and anatase, and represent 95 pct of current production. Approximately 250 Mt of contained Ti02 could be economically recovered from evaluated titanium operations at January 1992 market prices. In terms of mineral concentrates, this equals approximately 19 Mt of rutile concentrate, 110 Mt of ilmenite concentrate, 47 Mt of synthetic rutile concentrate (in addition to the ilmenite), and 160 Mt of titanium slag that could be recovered. Over the past decade, the titanium minerals industry has adapted to the changing market. In the 1980's, titanium producers expanded production because of the rising demand for titanium products. Today, the titanium industry is in a state of overcapacity, and byproduct revenues, such as that from zircon, have become essential in keeping operations profitable. The industry has also witnessed a greater dependence on upgraded ilmenite products, such as titanium slag and synthetic rutile, because of the expense of rutile and the lower wastes emitted from these upgraded products. As a result of this dependence on upgraded ilmenite products, South Africa has become a leading titanium producing country and has displaced Australian production.

Jan 1, 1994

By C. E. McElroy

"INTRODUCTION The ventilation of working places in mines by jets of air discharged from fan-pipe lines is an important phase of mine ventilation, whether the primary purpose is to dilute gas or dust concentrations or to provide air-motion cooling effect. Jets of similar nature are very prominent factors in the ventilation of enclosed spaces, such as buildings and ships. The effectiveness of such jets depends on the distribution of the air in the jet streams, a subject on which the little definite information previously available applied to jet discharge into large, open spaces under conditions quite different from those ordinarily associated with fan-pipe discharge in mines.The results of an initial series of experiments on the discharge of air from fan-pipe lines in mine openings have been described. 3/ This report presents the results of a second series of experiments and compares the results of both series with theory and experiment on jet discharge into large, open spaces. The results of this second series confirm and supplement those of the initial series, in which a 10-inch pipe discharged into an 8- by 8-foot develop¬ment end through seven short discharge pieces of different designs. In the present series the same 10-inch line was used, but the discharge was through 10- to 30-foot lengths of 5-inch, 10-inch, and 20-inch-diameter pipes and through a 20-foot length of 29- by 3-inch pipe. Tests were made with the air discharged into a closed drift or development end, as in the previous series (in which case the discharged air returned past the end of the pipe) and into an open drift (in which case the discharged air did not return past the end of the pipe but continued out along the drift). Test conditions corresponded to the discharge of a jet into a channel closed at one end; in one case, the discharge was directed toward the closed end and in the other toward the open end. The former typifies fan-pipe ventilation of development ends and the latter an abrupt increase in the sectional area of an airway. In both the flow had to pass from jet to open air against some resistance.The tests were made in the Mount Weather Testing Adit of the Bureau at Bluemont, Va., on the pipe line installed for ventilating the adit, and extended from late September to mid-November 1940. Preparations were made for directly comparable series of experiments on the injector effect of fan-pipe discharge in an open drift and on free expansion in large, open spaces, but these test programs were .first postponed in favor of other work and finally abandoned until the war is over."

Nov 1, 1943

By Anthony T. Xannacchione, Luis E. Vallejo

At present, there is little knowledge concerning the shear strength of clays containing floating rock particles with concentrations from 0 to 30%. In practice, the effect of rock particles is typically disregarded in shear strength analysis The two primary reasons for this are: 1) a lack of agreement concerning the influence of rock particles on material strength, and 2) the expense and difficulty of testing day-rack mixtures with existing laboratory procedures. These factors have impeded the development of successful slope remediation design techniques far colluviums derived from resistant sedimentary rocks or spoil produced from surface mining. This study reviewed 3 1 technical papers which contain analysis of shear strengths for clay and sands with varying mixtures of rock particles. These technical papers, published over the last 40 years, are comprised of field case studies, laboratory evaluations, and theoretical analysis. Evaluation of this body of knowledge ha shown that the shear strength gradually increases with increasing percentages of floating particles in unsaturated clays.

By Keith A. Heasley, Frank E. Chase, Christopher Mark

Deep cover retreat mining (overburden in excess of 750 ft) is an important emerging issue which will intensify in the future as the more easily mined shallow seam reserves are depleted. Analysis of Mine Safety and Health Administration (MSHA) statistics indicates that deep cover pillar recovery accounts for a disproportionate share of the underground coal mine roof/rib fall fatalities and injuries. Past research has shown that previously recommended Analysis of Retreat Mining Pillar Stability (ARMPS) stability factors (SF’s) may be excessive for deep cover pillar design. The objectives of this study were to evaluate the various methods and strategies by which panels, production pillars and barrier pillars are developed and extracted under deep cover, and to develop appropriate design guidelines. In the course of the research, 29 mines in 7 states were investigated to collect panel design case histories. At each mine site, underground geotechnical data were collected on the pillar line in order to document roof rock, coalbed and floor conditions. The analyses indicated that squeezes were the most likely failure mode where the depth was less than 1,250 ft, but bumps predominated in the deeper cover cases. Immediate roof rock quality, the ARMPS SF’s, and barrier pillar stability factors were all found to be important parameters in determining the outcomes of the case histories. Design guidelines, including suggestions for barrier pillars to isolate active panels from nearby gobs in bump prone ground, are also proposed.

By R. G. Warncke, D. Harrington

"INTRODUCTION The use of black blasting powder as an explosive in coal mines has long been recognized as hazardous and has been responsible for many of the worst disasters in American coal mines. One of the most pressing of the numerous problems confronting the Bureau of Mines, upon its creation in 1910 was to determine methods that would lessen the hazards created by the use of explosives in coal mines. The Bureau continued the study begun by the Technologic Branch of the Geological Survey as to the nature of explosives and made numerous tests to determine types of explosives suitable for blasting in coal mines. The Bureau has tested and approved hundreds of types of explosives and has disseminated information on methods and conditions for use underground to make them permissible as to safety. The Bureau of Mines has encouraged the use of permissible explosives for coal-mine blasting, and its experts both in the laboratory and in the field believe that the use of black blasting powder in any form (granular or pellet) is hazardous in any underground coal mine. Despite the information published at various times and innumerous ways and the general knowledge of the hazards that the use of black blasting powder in any form creates in the blasting of coal, the coal mines in the United States, during 1947 used approximately 34 million pounds of black blasting powder (granular or pellet), or approximately 11.8 percent of the total quantity of explosives used by the coal-mining industry.Many coal mines of the United States, for various and sundry reasons, probably will continue the use of black blasting powder, and this circular has been written for the benefit of such users, not that any suggested method or methods will make the use of this explosive safe, but it has been found that methods and conditions of use of black blasting powder can be improved so as to lessen, though not eliminate, the hazards created by its use."

Mar 1, 1949

By W. J. Wenger

Oil fields in the Powder River Basin of Wyoming have produced 731 million barrels of petroleum through 1959. Production in 1959 was 32 million barrels, the highest production since 1924. The record production was in 1923, when the Basin produced 38 million barrels of oil and the Salt Creek field, then at its peak, produced 35 million barrels. In this report, the characteristics of crude oils found in the Basin are used as a basis for determining the best re-fining uses for the oils and for predicting the characteristics of oils that may be discovered in the Basin in the future. Analyses of 108 oils sampled over a period of 30 years are presented Crude oils of two major types are produced from the Powder River Basin. One has a low sulfur content and occurs in younger formations, and the other has a high sulfur content and occurs in older formations. The oils with low sulfur contents are generally light colored and waxy, and may be either paraffinic or naphthenic. The oils with high sulfur contents are usually dark colored and asphaltic; only their low boiling fractions are paraffinic. Alteration appears to account for the anomalous properties of some oils found at shallow depths. Shapes and slopes of correlation index curves classify the oils into the same two groups as their sulfur contents, with gently sloping curves representing the low-sulfur oils and steep curves representing high-sulfur, asphaltic oils,

Jan 1, 1961

By B. W. Jong

The U.S. Bureau of Mines investigated anhydrous chlorination and caustic-acid leaching processes to recover Ni, Co, Mo, and W from waste hydroprocessing catalysts. In batch laboratory-scale equipment, the chlorination process extracted 61 to 99 pet of the metals. Final recovery was 65 to 99 pct. The caustic-acid leaching process extracted 81 to 98 pct of the metals. Final recovery was 36 to 99 pct. Chlorination processing included roasting, chlorination, hydrolysis of metal chlorides for recovering Mo or W, water leaching of Ni or Co from the spent charge, purification, and solvent extraction or precipitation of Ni or Co from the purified solutions. Caustic-acid leach processing included NaOH leaching, solvent extraction of Mo or W from the NaOH leach liquor, H2S04 leaching of the NaOH leach residue, purification, and solvent extraction or precipitation of Ni or Co from the purified solution. The estimated fixed capital cost for a commercial-scale plant processing 39,000 Ibid of waste Ni-Mo-AI catalyst was $8 million for the chlorination process and $9.6 million for the caustic-acid leaching process. The estimated operating cost was about $0.20 and $0.40 per pound of the waste catalyst, respectively, for the two processes.

Jan 1, 1989

By D. D. Harbuck

To decrease reliance on foreign sources for the strategic and critical metals gallium and germanium, the U.S. Bureau of Mines identified and developed processing technology for two domestic sources of these metals: a Tennessee zinc residue and a Utah ore. Sulfuric acid (H2S04) solutions were used to solubilize gallium and germanium in both sources. Statistically designed experiments showed that the most important parameter for high metal extraction from zinc residue was the H2S04 concentration. At a concentration of 2.9M H2S04, 95 pct of the gallium was extracted, and at a concentration of 0.6M H2S04, 73 pct of the germanium was extracted. Controlled H2S04 concentration was also the key for high metal extractions (97 pct Ga, 87 pct Ge) from the Utah ore. Such control was achieved using a two-stage countercurrent leach circuit. Testing showed that the insoluble germanium in both the residue and ore was tied up with silica. Several methods for overcoming this problem are given. To recover gallium and germanium from the leach solutions, the solvent extractants octylphenyl acid phosphate (OPAP) (for gallium) and LIX 63-OPAP (for germanium) were identified. These extractants were tested in separate, continuous, solvent-extraction circuits yielding a gallium recovery of 94 pct and a germanium recovery of more than 90 pct.

Jan 1, 2010

By F. L. Klinger

CRUDE OIL refining continued to be the foremost industry of Bahrain in 1963. This island, the largest of a group 30 kilometers off the Saudi Arabian coast, is the site of the first petroleum discovery in the Persian Gulf and in the Arabian peninsular region. The island's only oilfield was discovered in 1932; exports of crude began in 1934 and the refinery was built in 1936. Although its crude oil has been less than 1 percent of annual Middle East output in recent years, Bahrain has been an important refining center for many years, processing a substantial portion of Saudi Arabian petroleum as well as all local production. The Bahrain refinery annually accounts for 17 percent 0 the petroleum products produced in the Middle East and 25 percent of the exports. Bahrain's mineral resources consist of oil, gas, and basic construction materials. Petroleum production and refining are the important mineral industries and contribute most of the national income by payments for taxes, wages, and local services including construction and material supply. The petroleum industry has supported a large share of local business and extensive indirect employment, and its early establishment also helped Bahrain to strengthen its position as a trading center in the Persian Gulf. The country's entrepôt trade produces about 20 percent of Government revenue, and Bahrain is somewhat less dependent on the petroleum industry than are the neighboring States to the west.

Jan 1, 1964

By F. P. Haver

The Federal Bureau of Mines investigated aqueous electrolysis as a means for reducing lead chloride prepared by ferric chloride leaching of galena concentrate: NaC1 PbS + 2FeC13 ? PbC12 + 2FeC12 + S°. During electrolysis, metal was produced from solid lead chloride in contact with the cathode rather than from lead in solution. Relatively high current densities--up to 300 amp/ft2--were possible when operating in this way. A very simple cell, having a horizontal lead cathode at the bottom and a vertical graphite anode at the top, was employed. Lead chloride crystals, covering the cathode, were converted to metal powder during electrolysis, and chlorine gas or FeCls was produced at the anode, depending on the electrolyte composition. Electrolytes tried included aqueous solutions of HCI, NaCl, NH4Cl, and FeC12-NaC1. Optimum results (96-pct current efficiency, 0.23 kwhr/lb Pb) were obtained with 20 pct HC1 at 25° C, using a current density of 15 amp/ft2 and an electrode spacing of 1 inch. When the current density was increased, the energy requirement increased also but only to 0.41 kwhr/lb at 150 amp/fr3 and 0.58 kwhr/lb at 300 amp/ft2.

Jan 1, 1978

By John D. Corrick

Three species of chemosynthetic iron- and sulfur-oxidizing autotrophic bacteria have been isolated from the leaching waters of copper mining areas. These species are: The sulfur-oxidizing Thiobacillus concretivorus, the iron-oxidizing Ferrobacillus ferrooxidans, and a sulfur- and iron-oxidizing bacterium closely resembling Thiobacillus ferrooxidans, INTRODUCTION Among several suggested new processes for treating marginal ores in the United States, none is more intriguing than the possibility of extracting metals from low-grade materials by the action of microorganisms One phase of a Federal Bureau of Mines investigation toward developing such a procedure was to isolate and identify specific chemosynthetic iron and sulfur. oxidizing autotrophic bacteria native to certain domestic copper deposits where leaching is practiced. The bacteria or microorganisms considered important to this investigation are those capable of producing solutions of ferric sulfate and sulfuric acid. Solutions of this type are excellent solvents for some copper minerals By establishing the presence of these bacteria at certain copper-leaching areas, strength would be given to a theory that microbial activity is partly responsible for the oxidation that takes place at these areas. Their presence also advances possibilities for controlled use of microbial action in metal extraction processes. Leathen4/ has demonstrated that one of the chemosynthetic iron-oxidizing bacteria, Ferrobacillus ferrooxidans, can oxidize 200 parts per million of ferrous iron to the ferric state in 3 days,

Jan 1, 1961

As part of the Bureau of Mines program to reduce U.S. reliance on foreign suppliers of strategic and critical metals, research was conducted to improve technology for the recovery of critical metals from hardface alloy grinding waste, a form of superalloy scrap. This report describes a hydrometallurgical process that demonstrated on a laboratory scale that 79 pct of the chromium, 97 pct of the cobalt, 99 pct of the manganese, 99 pct of the nickel, and 90 pct of the tungsten could be recovered in chemical form from hardface alloy grinding waste. The process involved deoiling the grinding waste, followed by chloride-based dissolution of the deoiled material. A high-grade calcium tungstate (CaW04) product was recovered from the resultant leach residue by caustic leaching and precipitation. Iron, cobalt, man-ganese, and nickel chlorides were sequentially recovered from the leach liquor by solvent extraction. Amine extractants were used to extract the iron, cobalt, and manganese; decanal oxime was used to extract the nickel. Market-grade cobalt chloride (CoCI2), manganese chloride (MnC12), and nickel chloride (NiCl2) products could be produced directly from the resultant strip liquors. The final raffrnate was a relatively pure chromic chloride (CrCI3) solution that compared favorably with commercial solutions.

Jan 1, 1988

By Lance R. Barron

The U.S. Bureau of Mines (USBM) conducted ground pressure analysis of a wide abutment-type chain pillar in a two-entry gate road of a Western U.S. coal mine with an extremely weak immediate roof. About 15 m of fragile, low-strength mudstone lies between the seam and the lowest competent roof member. Three-and two-entry gate road designs with several pillar sizes and various secondary support systems have been employed to improve tailgate-entry stability, with varying results. This report discusses gate road layout and performance and secondary support effectiveness. The results of the pillar pressure study are compared to pillar loading predicted by a widely used pillar design method and to similar studies in other mines. A stability evaluation of the most recent longwall headgate, using the USBM Analysis of Longwall Pillar Stability (ALPS) method, indicates marginal stability in first-panel mining and instability in second-panel mining. The ALPS method and the USBM Coal Mine Roof Rating system are used to evaluate tailgate-mining stability of the previous gate roads and to determine pillar and entry width and top coal thickness criteria for tailgate stability in future panels.

Jan 1, 2010

By E. R. Spencer, E. R. Bauer

Previous studies and research efforts have shown that noise-induced hearing loss (NIHL) is a problem in the U.S. mining industry. In response, researchers at the National Institute for Occupational Safety and Health (NIOSH) have been conducting a cross-sectional survey of equip­ment noise and worker noise exposures in the mining industry to estimate the potential for NIHL within the mining community. One commodity recently surveyed was the extraction of sand and gravel from surface pits and by dredging. To address the potential for NIHL in the sand and gravel industry, sound levels on and around the dredges and processing equipment were recorded to iden­tify areas of high noise levels. Full-shift worker dosimetry, in conjunction with task observations, was documented to determine the relationship between exposure and source. This paper presents research examining noise on dredges used in several surface mine sand and gravel operations and in the processing facilities. Results indicate that there are areas on the dredges (crane, suction pumps and diesel engines) where sound levels greater than 90 dB(A) are pres­ent. In addition, crushers and screens used in the processing of the sand and gravel also generate sound levels greater than 90 dB(A). Although no surveyed worker exceeded the Mine Safety and Health Administration’s (MSHA’s) permissible exposure level (PEL) of 90 dB(A) eight-hour time-weighted average (TWA8), laborers, mechanics, oilers, helpers, pickers and greasers are the workers most likely to be exposed to hazardous sound levels and to thus develop NIHL over time

By Wm. W. Odell

For a number of years there has been a very appreciable annual,, increase in the production and recovery of natural gas and natural-gas gasoline2 in the United States the latter product being used largely for blending with gasoline from petroleum in the production of motor fuel. On account of the increased amount of oil cracking in the production of gasoline and the accompanying increased percentage of low-boiling constituents in the resulting product, the specifications for the natural gasoline suitable for blending have been altered, that is, the amounts of propane and butane which it can contain have been limited. The result has been that large quantities of the latter materials are wasted because there has been no ready market for thorn in large quantities. Because of this wasteage and because it is probable that large quantities of there and similar materials will be produced in the near future us a result of the more general use of oil cracking processes, a study was made by the Bureau of Mines, under a cooperative agreement with the assistance of the Phillips Petroleum Company, of the suitability of these materials alone or in mixtures for use as gas enricher in the carburetion of water gas for city distribution. This investigation included: (a) A study of the properties of the low boiling members of the paraffin series including pentane with particular reference to their utilization as gases.

Jan 1, 1927

By S. H. Lorain

This paper briefly describes the principal known commercial and near commercial deposits of gold-bearing gravel end the principal placer mining operations of Idaho County, Idaho. It is one of a series of similar papers on western mining districts. The data used in writing this paper were gathered during the summer of 1937. Information concerning gold-bearing gravels was obtained from prospectors and operators, while operators supplied most of the data on mining operations. No attempt was made actually to test the gravels. The principal object of the examination was to indicate placer areas worthy of further investigation by prospective operators.

Jan 1, 1938