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By Nadia C. Miller

In situ stope leaching is an innovative mining system that reduces the surface impacts of conventional underground mining. As in any leaching operation, stope leaching requires hydrologic site characterization and control of leaching solutions. Several tracer tests, using sodium chloride (NaCl) in various concentrations, were conducted by the U.S. Bureau of Mines (USBM) in an underground experimental stope to simulate a leaching environment. The tests were conducted in fractured crystalline rock that was partially water-saturated. As tests progressed, the surrounding fractures became more saturated. A predominant flow direction away from the stope was found during testing. Testing procedures, results, and a remediation plan for in situ leaching based on field observations are presented in this report.

Jan 1, 2010

By F. H. Gibson

An investigation was made by the Federal Bureau of Mines of methods for determining phosphorus in coal, coal ash, and coke ash. Several of these methods are being considered for international standardization. As might be expected, methods and proposals from other countries for determining phosphorus differ considerably from those accepted an standard in the United States. Some of the methods differ fundamentally in principle from the American Society for Testing Materials (ASTM) standard used in the United States; others differ only in details of procedure. Because the Bureau considered that certain of the proposed methods might offer advantages in obtaining increased accuracy and precision or in decreasing the time required for making analyses, these methods were investigated, and the results compared with those obtained by the ASTM method. The methods investigated may be grouped into three types--volumetric, colorimetric, and gravimetric. All were about equally accurate and may be used alternatively. From a practical viewpoint, when only a limited number of analyses are made intermittently, the gravimetric procedure probably is the most suitable because no special apparatus or standard solutions are required. The volumetric methods are more rapid when more analyses are made. For mass production, the colorimetric methods, although requiring a suitable photometer or spectrophotometer, are more suitable because a large throughput should be feasible.

Jan 1, 1961

By Lynn L. Rethi, Barbara Fotta

Recent employment figures (taken from the Mine Safety and Health Administration's database) indicate that the number of independent contractor' employees working in the coal mining industry has doubled over the past ten years. As their numbers increase, they become a more visible segment of the industry. [ ] Increased exposure to mining hazards has also brought an increase in the number of fatalities involving independent contractor workers. One gauge that is traditionally used to evaluate the overall safety of an entity is the "number of fatalities." Over the five-year period from 1985-89, 27 independent contractor employees were fatally injured while working on coal mine property. This number increased to 45 fatalities during the subsequent five-year period from 1990-94. Nearly half of these fatalities (47%) were due to accidents involving powered haulage (See Table); 13% were electrical accidents; and 9% were machinery accidents. Combined, these three accident classifications accounted for 69% of all coal nine independent contractor fatalities. Information taken from fatality data is an important piece of the safety puzzle; however, other variables need to he examined in order to better define contributing factors associated with accidents. More specifically, information on trends in fatal and nonfatal accident and injury data is necessary before deciding what approach should be used to improve safety. In order to implement appropriate safety strategies, it is important for safety practitioners to examine all available lost time accident and injury information. The following coal industry data sites specific and present trends of independent contractor employees working in underground locations at coal mines, surface areas of underground coal mines, surface coal mines, and preparation plants. The data compares employment and accidents for time periods at the beginning and the end of a ten-year span from 1985 to 1994. Because the number of incidents involving independent contractors in certain accident categories during any one year may be small, three-year totals are used; the first three years (1985-87) of the ten-year period are compared with the last three years (1992-94). [ ]

By Eugene Frey

"INTRODUCTION The Iron Mountain deposits were examined in the summer of 1943 by engineers of the Bureau of Lanes, and a diamond-drilling project was set up under the Strategic Minerals Program. Actual drilling operations, under the supervision of a Bureau engineer, commenced November 9, 1943, and were completed on November 1, 1944. When the Bureau began detailed exploration of the Iron Mountain deposits, the Federal Geological Survey participated. Dr. I. W. Newhouse, of the Survey, and Dr. A. F. Hagner, of the Wyoming Geological Survey, were assigned to the investigation.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director.With respect to this report, acknowledgment is made to S. R. Zirrmerley and F. T. Allsman, Bureau of Mines, Salt Lake City, Utah, who supervised the work of this project."

Nov 1, 1946

By John R. Zelonka

Models made by encasing strain-gage networks in epoxy are described and evaluated. With this technique relatively complex models can be constructed in which any number of gages can be located and alined precisely. Although the gages are an integral part of the model matrix, they create no important mechanical or thermal stresses. Model construction techniques and experimental data proved reproducible and reliable. In addition, the sGlution obtained with these models to the problem of the state of stress around a circular hole in a plate subject to a plane stress condition was in agreement with theoretical, photoelastic, and finite-element solutions.

Jan 1, 1970

By Jean J. Tancous

Chromium recovery from wet-blue offal trimmings and shavings can be done with substantial chemical cost gains by incineration at 600° C for 5 hr. Pretreating the offal with 0.5 M Na2C03 and air-drying prior to incineration produce Cr04 .By simply incinerating the offal, without pretreatment, an ash containing water insoluble Cr203 was produced. The Cr203 in the ash was purified by leaching with water. Chromium and crude protein were efficiently extracted from offal using 5 pct Na103, 5 pct H2S04, and 3 pct NaCl at 40° C. This procedure was effective but expensive. Satisfactory leather as to odor, appearance and shrinkage temperature was made from chromium recovered from wet-blue offal by incineration and by extraction. Chromium conservation is possible by recycling chromium liquors and by precipitating chromium from spent tanning liquors prior to combining these liquors with other tannery wastes. Combining chromium liquors with other wastes introduces contaminants that make chromium recovery and reuse difficult. Leaching sludges with H2SO4 produced marginal chemical cost gains. Leather tanned with these solutions had satisfactory shrinkage temperature but the sludge odors and iron contamination were objectionable.

Jan 1, 1979

By J. A. Woolf, E. S. Leaver, N. K. Karchmer

"In the cyanidation of silver ore, the need of oxygen is well recognized. Various methods have been introduced for supplying the oxygen. In usual practice, air is the source of oxygen and the methods of application are mechanical.This article gives the results of touts made to show the rate of dissolution of silver from each of the common silver minerals in cyanide solution, under conditions similar to those used in the practical recovery of silver from its ores. The effect of oxygen in aiding the dissolution of the silver from each mineral is also shown by a comparison of the methods of supplying the oxygen. Oxidation by preliminary roasting (500°C.) of each mineral sample gives the maximum extraction of the silver by treatment with cyanide.Each silver mineral5 used in these experiments was as pure as could be obtained from the mineral dealer. In their natural occurrence, silver minerals are not usually free from mineral impurities. They are usually closely associated with other minerals often forming, a complex mixture. The form of crystallization, the proportions, and properties of the diluent that incases or has been dispersed with the silver mineral may decidedly affect the dissolution rate of the silver from each mineral. While the following results should aid in the cyanidation of silver ores, each ore should be studied from the basis of the form and condition of the silver that is to be recovered.All the tests reported in this article were made on synthetic samples, prepared by mixing the particular silver mineral with clean sea sand. Each mineral was ground in an agate mortar to pass 100-mesh before mixing with the sand which had previously been ground in a porcelain pebble mill to 100-mesh. Such proportions of each mineral and the sand were used as to give a head assay of approximately 20 ounces of silver per ton to the synthetic sample.Agitation was carried on in stoppered bottles approximately one-third full of pulp, method apparently supplied all the atmospheric oxygen that would be taken up by the solution under usual conditions, because tests conducted in open bottles did not show increased recovery,"

Jan 1, 1931

By D. K. Ingram, G. L. Mowrey, T. R. Rehak

Problem: Blasting is a hazardous component of surface mining. Serious injuries and fatalities result from improper judgement or practice during rock blasting. This paper describes several fatal injury case studies, analyzes causative factors, and emphasizes preventive measures. Method: This study examines publications by MSHA, USGS, and other authors. The primary source of information was MSHA’s injury-related publications. Results: During the 21-yearperiod from 1978 to 1998, the mean yearly explosive-related injuries (fatal and nonfatal) for surface coal mines was 8.86 (95% CI: 6.38 -11.33), and for surface metal/nonmetal mines 10.76(95% CI: 8.39 - 13.14). Flyrock and lack of blast area security accounted for 68.2% of these injuries. This paper reviews several case studies of fatal injuries. Case studies indicate that the causative factors for fatal injuries are primarily personal and task-related and to some extent environmental. A reduction in the annual injuries in surface coal mines was observed during the ten-year period of 1989 - 1998 [5.80 (95% CI: 2.71 - 8.89) compared to the previous ten-year period of 1979 - 1988 [10.90 (95% CI: 7.77 - 14.14)]. However, such reduction was not noticed in the metal/nonmetal sector, i.e., 9.30 (95% CI: 6.84 - 11.76) for the period 1989-1998compared with 11.00 (95% CI: 7.11 - 14.89) for the period 1979-1988. Discussion: A multifaceted injury prevention approach consisting of behavioral/educational, administrative/regulatory, and engineering interventions merits consideration. Impact on industry: The mining community, especially the blasters, will find useful information on causative factors and preventive measures to mitigate injuries due to flyrock and lack of blast area security in surface blasting. Discussion of case studies during safety meetings will help to mitigate fatal injuries and derive important payoffs in terms of lower risks and costs of injuries.

By S. R. Borrowman

This investigation by the Bureau of Mines was undertaken to develop information on the extractive metallurgy of thorite ores because potential ore bodies of this mineral have been found recently in Colorado, Idaho, and Montana. Basic information on thorite ore treatment that would be useful in appraising the potential of these and other domestic thorium resources was developed. The work was done mainly on thorite ore containing 3.87 percent ThO2 from the Powderhorn district, Colo., and on a composite sample containing 0.52 percent ThO2 from the Wet Mountains district, Colo. Limited tests of d corroborative nature subsequently were made on a sample containing 2.30 percent ThO2 from the Lemhi Pass area on the Idaho-Montana border.

Jan 1, 1962

By Ivette E. Torres

Table 8 provides data for the estimated value of world export trade of all mineral commodities from 1980 through 1991. It also provides a breakdown of the total into mineral fuels and non fuel minerals. These data have been developed from UN export trade data presented in table 9. The percent distribution and growth of the value of world export by major commodity groups are presented in tables 9, 10, and 11, respectively. In terms of industrial minerals (nonmetals), data in tables 10 and 11 include crude industrial minerals only, while table 8 includes an estimate for other industrial minerals. The 1991 estimates that appeared in the 1991 issues of this publication have been revised. It is typical for this section to review the year prior to the year of review because of the unavailability of data at the time of publication. The aggregated value of export trade in mineral commodities for 1992 was not available at the time of publication. The total value of nonfuel and fuel mineral exports for 1991 was about $616 billion in current (1991) dollars. The value of mineral fuel export trade accounted for about 53 % of the total mineral export trade. In 1980, the contribution of mineral fuel to the value of mineral commodity export trade had been almost 68%. The 1991 world mineral commodity export trade represents a 5.3% decrease (table 8) from that of 1990. The largest decrease was attributed to the decrease of export trade of fuel minerals (5%). The value of non fuel mineral export trade decreased by 4 %. Because the value export trade of all commodities increased by 1.2 %, the share of mineral commodities decreased from 19.2 % to 17.9 % of the total.

Jan 1, 1994

By Florence L. Feicht, H. H. Schrenk, Carlton E. Brown

This report describes the dropping - mercury electrode , its use in analysis , and the procedure of the Health Division of the Bureau of Mines in determining lead , cadmium , and zinc . The dropping - mercury electrode or polarograph is an electrolytic device , one electrode of which consists of mercury issuing in small drops from a capillary tube . Such electrodes have been in existence for more than 50 years, but they were not used for analytical purposes until about 1922.6/ Developments since have been rapid , especially in Czechoslovakia , Germany , Italy, and Japan and more recently in the United States . A recent bibliography / contains references to, 825 articles issued from 1903 through 1940. In 1939 Kolthoff and Lingane presented the first comprehensive critical review, in English , of the device and its use in analysis . They have recently issued a book on the same subject. Similar information also is included in a recent book10/ by Kolthoff and Laitinen . Much of the information in this and the two following sections on this device and its use in analysis was obtained from these three publications . The use of the dropping - mercury electrode in analysis is based upon the fact that the kind and amount of electro - reducible and electro - oxidizable constituents in solution can be determined from the current -voltage relationships revealed by this electrode or electrolytic device .

May 1, 1942

By Carl Rampacek

The conversion of dilute sulfur dioxide gas into sulfuric acid by autoxidation in mechanical cells of the flotation or gas absorber types was investigated. Bench-scale tests were made with sulfur dioxide-air mixtures to determine the influence of several factors on autoxidation of sulfur dioxide, using iron and manganese salts as catalysts. The laboratory investigation subsequently was extended to pilot plant acid-making tests, using a modified turbomixer gas absorber having a 12-inch-diameter impeller. Sulfur dioxide gas was produced for the tests by roasting pyrite in a fluidized-bed reactor. In the better tests, made with manganese sulfate as the catalyst, the equivalent of 1,000 pounds of anhydrous H2SO4 was produced per 24 hours as a 10-percent solution; power consumption was 0.2 kwhr per pound of equivalent anhydrous acid synthesized. The batch and continuous tests demonstrated the technical feasibility of producing dilute sulfuric acid by autoxidation of sulfur dioxide gas in mechanical cells when converting pyrite roaster or waste smelter gases.

Jan 1, 1963

By G. E. McElroy

"while investigating the presence of heavy strata gases* in certain mines of the East Tintic mining district of Utah, a small, local body of light, very hot gas of high-nitrogen composition was noted in one of the mines. Observations and analyses indicate that this light gas was resulting from very rapid oxidation of finely disseminated pyrite, in lead-silver sulphide ore. The gas was actually mine air which had lost a large proportion of its oxygen content by reaction with the pyrite. This body of gas was hanging in a local high spot about 5 by 5 by 5 feet in size, caused by caving, at the end of a crosscut. Fifty feet from this spot, an air current of 6000 cubic feet per minute was entering the 5 by 7 foot cross-cat from a raise from below.On account of the vapor contained in the gas, the bottom level of the gas could be plainly seen and was practically a horizontal plane, but of slightly wavy appearance, coinciding with the point where an acetylene light was extinguished. This body of gas was visited on three occasions and samples obtained by means of evacaated bulbs and by water displacement. The temperature of the gas was ap¬proximately 175 degrees P. on all three occasions, so that sampling required thick gloves and quick action. Air three feet below the vapor line had a temperature of only 120 degrees F., and a relative humidity of 27 per cent. The stratification of the air and gas mixtures was so sharply defined that the sampler could hold his head a few inches below the vapor level for an appreciable period of time without any noticeable effect other than that due to the high temperature. At one foot below vapor level, it was 135 degrees F., and the relative humidity was 30 per cent. When a candle and an acetylene light were raised into the gas from below, the candle flame was extinguished at a point two inches lower than the acetylene flume, indicating a drop in oxygen content from about 16 per cent to 12 per cent (oxygen content of normal dry air 20.05 per cent) in the distance of two inches."

Sep 1, 1921

Roof bolting is a slow, expensive, and absolutely necessary mining activity. Roof-bolting activities also account for the largest percentage of lost-time injuries in underground coal mines. Dull bits result in the application of excessive force, which bends drill steel; and changing starter and finisher steel was the most significant source of injuries associated with roof bolting. The tungsten carbide (WC) roof-bolt drill bits currently used in American, Canadian, and Australian coal mines are capable of drilling only one or two 4-ft holes and then they are resharpened once or twice to drill another one or two holes. Often, in medium-hard rock formations (sandstone), as many as 20 to 30 bits may be required to drill a single 4-ft hole. Objective To compare the performance, longevity, and cost of newly developed polycrystalline diamond compact (PDC) roof-bolt drill bits against WC bits. Research and Background Diamonds for industrial use have been scarce throughout history and continuous attempts have been made to produce synthetic diamonds. The first synthetic diamonds were manufactured in 1953. Economically produced synthetic diamonds are 1 to 10 µm in size, but in this size range, they are totally unsuitable for industrial applications. In 1972, General Electric Co. developed a process to sinter the artificially developed, minuscule diamond particles into usable products. In this process, several layers of diamond-particles-and cobalt mixture are overlaid on WC substrates and sintered at 2,350° F and 1,000,000 psi. The final product is known as PDC. Today, PDC's are available in many shapes, but their size is limited to 3/4 in, or less, in length or diameter, because pressures greater than 1,000,000 psi are required to manufacture larger PDC's. At present, diamond and PDC arc the hardest and strongest commercial materials available for wear surfaces. The PDC used in this study had a hardness 3.61 times greater than that of WC.

Jan 1, 1992

To provide an engineering solution to wood crib design and deployment strategies that will ensure safety for underground coal mine workers. This is accomplished by preserving necessary ground control requirements while minimizing support costs or by developing new support strategies to enhance ground support in difficult conditions. A secondary objective is to be able to quantify wood crib support performance to define support requirements for alternative support systems. These objectives have been achieved through a simple-to-use computer program called the wood crib performance model (wcpm).

Jan 1, 1997

By E. G. Baglin

As part of an effort to decrease U.S. dependence on imports of critical and strategic metals, the Bureau of Mines investigated three leaching methods for extracting the base metals and recovering platinum-group metals (PGM) from matte prepared from Stillwater Complex flotation concentrates. Because of a limited supply of natural material, synthetic matte of composition similar to matte prepared from natural concentrates was used to devise the extraction sequences. The validity of the sequences was verified with matte prepared from Stillwater concentrates. In two-stage matte leaching, first-stage H2S04 leaching extracted 99 pct of the nickel and iron from the matte but negligible amounts of copper and PGM. Second-stage oxidative leaching with Fe2(S04)3 or FeC13 solubilized more than 98 pct of the copper and no precious metals. Sequential leaching, in which acid and oxidizing lixiviants were added sequentially to the matte without an intervening filtration step, extracted 99 pct of the Fe, Ni, and Cu. A roasting-leaching technique, in which the residue from first-stage leaching was roasted between 360° and 500° C before a second leaching with H2S04, solubilized 98 pct of the copper. The three leaching methods yielded high-grade PGM residues containing more than 98 pct of the PGM in the matte.

Jan 1, 1982

By S. C. Termes

The Bureau of Mines has used Fourier transform infrared spectroscopy (FT-1R) to study in situ reactions of aqueous solutions of potassium ethylxanthate with CU(II)-and Pb(II)-activated sphalerite plates, in which the plates were both the infrared-transparent windows and the reacting surfaces. A copper (I) ethylxanthate formed predominantly with Cu(II)-activated sphalerite, regardless of the activation time. The products formed on Pb(II)-activated sphalerite depended on the activation times; a short activation time (30 min) yielded a lead ethylxanthate-like product, but a long activation time (90 min) yielded a considerable amount of dixanthogen.

Jan 1, 1986

By A. L. Engel

This investigation was undertaken to assess the feasibility of processing an extensive deposit of iron ore near Palisades, Eureka County, Nev., previously penalized for high phosphorus content. The experiments described indicate a satisfactory accomplishment of objective. Chemical treatment will permit a high-phosphorus iron ore to be used. Leaching with acid solution effectively lowers the phosphorus content with a [gligible] loss of iron. The use of hydrochloric acid is preferred because [ ] does not contaminate the ore and the cost is lower. Minus-1/2-inch ore was satisfactorily leached in 24 hours, minus-1/4-inch ore, in 8 hours, and minus-10-mesh ore, in 3 hours. About 40 pounds of acid per ton of ore was consumed in each instance.

Jan 1, 1959

By Raymond L. Lowrie

Coal deposits in the Boulder-Weld County coalfield in Colorado are analyzed in relation to economic factors governing the growth, stability, and competitive potential of the coal industry. Recoverable reserves, estimated to be 571 million tons, are discussed in detail, particularly those in the Erie and Frederick Quadrangles. Geology of the coal measures, quantity and quality of water resources, and chemical and physical properties of the coal are described. Coal production factors, including mining techniques and equipment, labor requirements, transportation facilities and rates, and markets, are considered for coal's position in competition with alternate fuels. Growth of the fuels market, through increasing thermal-electric power generation in the Denver Metropolitan Area, will stimulate coal production in Colorado. Reserves of the contiguous Boulder-Weld coalfield, if mined in a sustained, year-round, high-tonnage operation, could be used to supply much of that fuel demand.

Jan 1, 1966

By Sean Gallagher, Rhys Llewellyn, Jay Mattos

This paper contains the results of an examination of accident, injury, employment, and production information reported to the U.S. Department of Labor's Mine Safety and Health Administration (MSHA) and provides information on some of the measures longwall mine operators are using to prevent accidents In all industries, technological advances play a key role in determining those who will survive as competitive participants in an increasingly global marketplace. While mining is among the most basic of industries, technological change is neither unfamiliar nor unwelcome to miners. Historically, technological advances in mining, particularly coal mining, have tracked closely with fluctuations in demand. In the early 1900's, coal accounted for more than three quarters of all the fuel consumed in the U.S. To meet this tremendous demand, underground cuffing machines were introduced, resulting in faster, more efficient coal extraction. Transporting coal to the surface, however, remained labor intensive. In the 1920's, nearly all underground coal was still being hand loaded. Demand for coal then declined as the price of oil, natural gas, and electricity became competitive. In the late 1930's and throughout the duration of World War II, coal demand and production was high. By 1940, more than half the coal mined was being mechanically conveyed to the surface. In 1948, the continuous mining method was introduced in the U.S., further accelerating the extraction process. By the 1950's and 1960's, however, coal production again declined as railroads converted to diesel fuel and gas and oil provided a larger share of the home heating market. Underground coal mines required even more mechanization to remain competitive as an energy source. The first longwall system was introduced in 1960. By 1995, longwalls were producing more than 189 million tons of clean coal annually, surpassing continuous mining production for the second straight year. The mining of coal and other materials has not come without a huge loss of life and considerable human suffering. More than 103,000 workers died from injuries in U.S. mines in the last 85 years. Between two and three thousand miners died each year from the turn of the century until 1931, many from underground fires and explosions. The U.S. has witnessed a tremendous drop in fatalities in underground coal mines. Credit for that is due to safety inspections and enforcement activities, better safety awareness and practices among management and labor, improved ventilation, the use of safer equipment, and increased mechanization which removed many miners from the hazards at the face and also reduced the size of the mining work force. There is little doubt that longwall mining has greatly increased underground coal mine productivity. The degree to which longwall mining has contributed to a safer work environment for underground miners is more difficult to ascertain.