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By Vernon C. Davis

"INTRODUCTION This report describes the work done and presents the data obtained from limited diamond drilling at the lead-zinc deposits cf the Belle Eldridge Gold Mines, Inc., in Lawrence County, S. Dak. during the summer and fall of 1943. The work was undertaken in an effort to increase reserves and step-up production of zinc and lead so vitally important to the war program.The geology, topography and existing mine workings were mapped and studied. Subsequently, six vertical core-drill holes were put down from surface sites.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our natural resources to the end that they make the greatest possible contribution to national security and economy. The Mining Division, Lowell B. Moon, chief, conducts preliminary examinations, does the actual investigative work, and prepares the final report. The Metallurgical Division, Oliver C. Ralston, chief, analyzes samples and makes beneficiation tests, if such are necessary.Special acknowledgment is made to John Paul Gries, geologist, South Dakota School of Mines, for mapping and interpretation of geology and topography, logging of cores obtained, and his assistance in guiding the drilling."

Mar 1, 1948

By N. S. Dalal, Xianglin Shi

"Electron spin resonance (ESR) spin trapping experiments have been carried out to investigate the mechanism of sulfite oxidation em¬ploying 5,5-dimethyl-l-pyrroline-1-oxide (DMPO) as a spin trap. The results show that sulfite autoxidation, catalyzed by Mn(II), involves not only the SO-3 radicals but also the •OH radicals. An addition of H2 02 to the sulfite aqueous medium significantly increases the •OH radical formation. This result provides new clues to the chemical mechanism of the sulfite oxidation and the sulfite toxicity.INTRODUCTIONStudies of the oxidation of the sulfite (SO 2-/3) ions under various conditions are of high current interest because excessive exposure to sulfite is toxic and the origin of this toxicity seems to involve sulfite oxidative pathways [1]. An important fact is that human exposure to sulfite is on the increase [1,2]. Some of the increase in the sulfite exposure is linked to the fact that SO2 is a major air pollutant [2] and in aqueous media SO2 exists in equilibrium with SO2-/3. In addition, beverages and foods are common sources of sulfite intake. For example, sulfite is used extensively in the wine industry as an inhibitor of yeasts and bacteria and is present in finished wines in concentrations up to 6 mM [1]. Sulfite is also often added to dehydrated fruits, vegetables and soups, as well as fruit juices and beer [1,3,4]. Because of these, the mean daily intake of sulfite from diet (in the United States) has been estimated to be between 0.0014 and 0.14 mM/kg body weight [1]. At such high levels, sulfite exposure can have toxic effects, such as the induction of an acute asthmatic state [5,6]. Sulfite also appears to have adverse genetic effects [7] and can act as a mutagen or comutagen [8] and a cocarcinogen [5,7-9]."

Jan 1, 1990

By A. W. Khair, L. D. Gehl

"This paper describes the study of bit wear characteristics on three types of rock namely Tennessee sandstone, Berea sandstone and Indiana limestone. High content of quartz with quartz cement in Tennessee sandstone causes removal of material from the bit body and dam2ge to the tip of the bit resulting into excessive weight and height loss as compared to other two types of rock. The drum speed and water spray pressure do not contribute significant effect on bit wear. The polycrystalline compact diamond (PCD) tipped bits are more wear resistant than the ordinary tungsten carbide (WC) tipped bits, but, due to wider body of PCD bits, the wear rate increases particularly at greater depth of cut. INTRODUCTIONThe impact of bit-rock interaction during the cutting process in underground coal mines has always attracted the-interests of mining operators, researchers and the manufacturers. Coal cutting bears directly on airborne coal dust generation which causes ""black lung"" in coal workers. On the other hand, rock cutting generates frictional sparks causing face ignitions. The bit wear not only produces airborne rcspirable coal dust , but also affects the productivity, safety and economy. Hun and Evans (J) concluded that the point attack bits have greater ignition potential than the conventional wedge shaped bits. The results of a study (2) suggested that after 7% of weight loss, the bit should be replaced. In a survey study (3), it was found that the bit consumption of bit had an effect on the productivity and utilization of the continuous miners. The mining industry is yet to receive a solution which could provide them with optimum operating parameters for coal cutting machines in underground C9al mines.The study was, therefore, taken up to determine wear characteristics as influenced by the rock propenies and varying operating parameters. For the purpose of this study, three types of rock, Tennessee sandstone, Berea sandstone and Indiana limestone were used. The machine operating parameters included (i) drum speed, (ii) water spray pressure and (iii) bit type. Besides studying the wear characteristics, the effects of these parameters on the required cutting force, specific energy consumption, acoustic emission generation and bit temperature rise were also studied. Also, the preliminary experiments were performed to compare the bit wear between PCD and WC tipped bits."

Dec 1, 1995

By M. L. Wang, S. R. Short, E. M. Daniloff, E. L. Petsonk, D. M. Mannino, G .. R. Wagner

"Background—It has been suggested that health related job selection is a major cause of the healthy worker effect, and may result in inaccurate estimates of health risks of exposures in the working environment. Improved understanding of self selection, including the role of airway hyperresponsiveness, should improve accuracy in estimating occupational risks.Methods—We evaluated symptoms of the respiratory tract, lung function, occupa¬tional and smoking histories, and airway responsiveness from a cross sectional sur¬vey of 478 underground bituminous coal miners and non-mining controls. Workers with abnormal spirometry were excluded from methacholine testing.Results—Methacholine responsiveness (= 15% decline in forced expiratory volume in one second) was associated in both miners and controls with reduced ventilatory lung function and an increased risk of respiratory symptoms. Miners with the longest duration of work at the coal face had a low prevalence of methacholine responsiveness, compared with miners who had never worked at the coal face (12% v 39%, P < 0.01). Throughout their mining careers, miners who responded to methacholine were consistently less likely to have worked in dusty jobs than miners who did not respond to methacholine.Conclusions—These results provide evidence that workers who are employed in dusty jobs are less likely than their unexposed coworkers to show increased non-specific airway responsiveness, pre-sumably as a result of health related job selection. Surveys of workers in which responsiveness data are unavailable may underestimate the effects of dust exposure on respiratory health."

Dec 1, 1996

By Hillary W. St. Clair

Mining activity began in colonial times with ironmaking operations scattered along the eastern seaboard. Iron furnaces and forges manufactured iron implements from bog iron ores using charcoal from the extensive forests as a fuel. Lead ores were mined in the Mississippi Valley and copper ores in the Lake Superior region. However, the real beginning of the American mining industry did not occur until the 19th century. The history of American mining is organized around three epochal events. The first was the discovery of gold in California in 1848, which marked the beginning of a period of apprenticeship in mining and metallurgical techniques. The second was the discovery of the fabulous Comstock Lode in western Nevada in 1859, which expanded mining throughout the Far West and led to large-scale underground mining and the development of smelting techniques for lead, silver, and copper ores. The third event was the building of a transcontinental rail-road system after the Civil War, which brought about the consolidation of the industry from a large number of independent mines, mills, and smelters into integrated operations run by large corporations. Thus developed the mining industry that today supplies the energy and critical materials for the great-est industrial complex the world has known.

Jan 1, 1977

By Donald E. Redmon

This Bureau of Mines report examines the injury experience in the quarrying industry for the years 1964-65. Twenty-eight tables for each year are presented in which disabling work injuries are summarized by department, source of injury, extent of disability, part of body injured, and nature of injury. Correlative information on employment, worktime, and operating activity is also presented.

Jan 1, 1973

By Charles W. Briggs

The steel foundries of Germany were investigated for the purpose of ascertaining (1) the type and classification of steel structures produced as castings, (2) processing methods, (3) the mechanical properties of carbon and alloy cast steels, (4) the type and character of defective castings, (5) the appearance of castings, (6) research in steel castings, and (7) plant lay-out and equipment.

Jan 1, 1946

By W. B. Berwald

[Accurate ~cusirc::ie t of euusu.rface r,resw rus £Uld tee:: ?er:~t:,res in producin+ oil and as wells is one of tine ast iy,ulortant steps ever t,.s:en to place the rprwctice of retroleum ,-iroduction on an exact scientific basis. i&apos;reerures and teial.or-tures in a -petrolcuia r4:, rvoir. have a rn..r..ed influence over the o:wvement of oil and ~c s both within the. reservoir and t~:rou,=Ii the various-size "flow otrin;;u" of proLucin,; wells to tine surface. Knovrled: ?c of theso fc,.ctgrs form a Laois for cny attei:ant to [.,-~ly eciantific j:cthods to the solution or analysio of mc.nj proble;ae encountered in the production of oil and 1c_c, Without a.ccur:tc mcaaurx,ients of reosures r:.nd tcn::paratuxes within the rocervoit and -well &apos;flo-,r strinL:s" tae aI,licution of w.ny proved enbinecrin and scientific princiy-,loo is on %,]

Jan 1, 1935

By Cheryl Hill, Michael Keane, Pamela Mike, Raghoottma Pandurangi, William Wallace, Mohindar Seebra, Val Vallyathan

"Dipalmitoyl glycerophosphorylcholine (lecithin) dispersed in physiologic saline, a model of the primary component of pulmonary surfactant, is adsorbed by respirable quartz and aluminosilicate dusts. Dust cytotoxicity as measured by erythrocyte bemolysis and pulmonary macrophage enzyme release is suppressed by this adsorption. The degree of suppression of hemolytic potential versus specific adsorption of lecithin from dispersion in saline by respirable quartz and kaolin dusts are compared with dusts' BET specific surface areas to interpret the prophylactic effect of lecithin adsorption. Dust hemolytic potential versus medium pH is presented. Fourier transform infrared spectroscopy and photo-acoustic spectroscopy of lecithin on quartz and of lecithin on kaolin are presented and reviewed with results of studies of the time course of removal of lecithin adsorbed on mineral surfaces by digestion by phospholipase enzyme. Results are discussed in terms of a model of prompt neutralization of respired mineral dusts by pulmonary surfactant, and a gradual re-toxification by digestive processes acting on the adsorbed prophylactic surfactant coating following phagocytosis. INTRODUCTIONQuartz dust of respirable size is well known to cause fibrotic lung disease, but numerous questions persist in the understanding of the initiation and progression of this disease. Our approach concentrates on physical and chemical aspects of mineral dusts early-on in their interactions with living organisms, and we have chosen simplified models to investigate that interaction.In the alveolar ·spaces of the lung, tissue is coated with a surface-active material (pulmonary surfactant), which, among other functions, mechanically stabilizes the lung from collapse by reducing the surface tension of water in the alveolar sacs.1 This surfactant is also the material that is first contacted by a mineral particle that is transported to an alveolus and is impacted there. This surfactant material has been studied extensively. The primary components are known to be proteins (about 11 % in dog lavage fluid), and phospholipids (about 88%).2 Pbosphatidyl cholines constitute roughly 80% of the phospholipid fraction; about 70% of the phosphatidyl choline fraction is dipalmitoyl lecithin (DPL).2 Respirable aluminosilicate particles are capable of adsorbing dipalmitoyl lecithin from dispersion in physiologic saline, a model for a possible initial event occurring upon deposition of a particle in a pulmonary alveolus. As may be seen from Figure 1, the DPL molecule has several fixed charges at neutral pH; a positive charge on the trimethylamine (choline) moiety, and a negative charge on the phosphate group. Also evident are the two fatty acid residues of palmitic acid, which are bonded through ester likages to the glycerol segment of the molecule. The fatty acid moieties of phosphatidyl choline make the molecule inso1uble in aqueous solutions under normal conditions, but a colloidal unit of aggregated molecules called a micelle is usually formed spontaneously above a certain minimum concentration. Small micellar vesicles are generally formed in the laboratory by using ultrasonic agitation or by solvent evaporation methods."

Jan 1, 1990

By R. L. Rough, W. K. Overbey

The Bureau of Mines obtained samples of oil - reservoir rock from wells in Ohio , Pennsylvania , and West Virginia as part of an investigation of the susceptibility of petroleum reservoirs to secondary - recovery techniques . Illustrations and tables showing the geographic and stratigraphic sequence of the cored reservoirs and 40 tables of detailed lithologic descriptions of the reservoirs are presented . Information relevant to geologic surroundings , oilfield history , coring and well logging operations , and reservoir core analyses are referenced throughout the report .

Jun 1, 1970

By O. Llewellyn Jack

From September 1978 to December 1983, ESD Corporation (formerly a Division of FMC Corporation) undertook the development and testing of a bidirectional auger under contract with the U.S. Department of Energy. Underground testing began in August 1981 at Peabody Coal Company&apos;s Marissa Mine near Marissa, Illinois. The auger was developed to increase mine production and coal recovery without increasing land subsidence. It bored 4-foot-diameter by 10-foot-deep holes into pillars on 7-foot centers (each hole recovering 5 tons). All operating during this test was performed by maintenance personnel with the goal of finding ways to increase the machine potential. The maximum excavation rate achieved was 1.4 tons per minute. It was concluded that the concept of drilling short holes to extract coal from underground pillars without surface subsidence was practicable with a wheel mounted auger, but that more power was desirable for this mine, and that the hydraulically driven augering system that provided experimental versatility was not sufficiently reliable for production use.

Jan 1, 1983

By Ralph L. Brown

The chemical properties of the unsaturated members of the aliphatic series of hydrocarbons are such as to render them " made to order" starting points or basic . materials for the synthesis of hundreds of important organic chemicals . The tremendous quantities of these unsaturated compounds that are being produced daily in the various coal carbonization and oil refining processes , and which at present have little value other than that of fuel , render a survey of the identity and ex- tent of occurrence of these compounds important from the viewpoint of economic utilization and resource conservation The increased need of liquid fuel and the relatively early exhaustion of petroleum resources will eventually require every utilization of liquid fuel products obtainable directly or indirectly from coal . Accordingly , the Bureau of Mines took advantage of an opportunity for examining the gaseous unsaturated hydrocarbons found in the gas obtained when a mixture of water- Collection of the material gas tar and coal is distilled in a gas-making retort . for examination was made possible through the courtesy of the Trent Process Corporation , Washington , D.C. , which was at that time carrying on at the Georgetown Gas Works , distillation of " amal gams " prepared from various coals and oils by the Trent process for cleaning coals . Kanawha gas coal ( 70%) and water gas tar ( 30 % ) from the Washington Gas Light plant were used in the " amal gam" being distilled at that time . The results obtained in this examination are presented here .

Feb 2, 1922

By Fei Chen, Lesley J. Gaydos, Laurence M. Demers, Douglas C. Kuhn

The fibrogenic effects of silica in experimental animals and humans has been extensively studied (I 7, 20). However, the pathogenesis and molecular mechanisms underlying lung injury and fibrosis resulting from silica exposure remain to be elucidated. It is well-documented that silica can stimulate monocyte-macrophage lineage cells to produce cytokines and growth factors, including interleukin-I (IL- I) (20), tumor necrosis factor-ex (TNF-cx) (I 7), insulin-like growth factor-I (IGF-1) (4), and transforming growth factor-P (TGF-P) (24). Consequently, it has been suggested that the fibrogenic effect of silica may be mediated by cytokines in the fater stages of silicosis. During the early phase of interaction between silica and the pulmonary alveolar macrophage, several direct and indirect lines of evidence suggest that reactive oxygen intermediates (ROI) may play a pivotal role in silica- induced tissue damage (2I, 22). One of the most important components of and contributors to ROI is nitric oxide (NO) produced from L-arginine and molecular oxygen under the catalytic influence of NO synthase (NOS) (I 9). At present, at least three NOS genes have been cloned: a constitutive neuron NOS, a constitutive endothelial cell NOS and an inducible NOS (iNOS) (16). A number of factors have been shown to differentially induce iNOS gene expression in different cell lines including bacterial cell products and foreign antigens. During inflammation, NO is a double-edged sword in terms of the host immune defense mechanisms and the physiologic response to an inflammatory insult. The macrophage is one of the major cellular sources of NO. During the early phase of acute inflammation, NO produced from the macrophage appears to facilitate the clearance of pathogens and promotes a local relaxation effect on the microcirculation of vascular smooth muscle. When the production of NO is left unattenuated, especially under oxidative stress, direct cytotoxic effects of NO can emerge through the formation of peroxynitrite as a result of a reaction between NO and superoxide (2).

Jan 1, 1998

By Arnold B. Hubbard

This report describes a method of concentrating the insoluble organic material (kerogen) in a rich Colorado oil shale without any apparent alteration of its original chemical form. The method involved treating finely pulverized shale with dilute acetic acid at room temperature to remove the carbonates, which act as a cementing agent for the shale, and cause the shale particles to partly disintegrate into the organic and inorganic components. The acid-treated shale then was centrifuged in different liquid mediums ranging from 1.4 to 1.15 gravity to effect a mechanical separation. From a Colorado oil shale containing 48.0 percent ash, kerogen concentrates containing 43.3 to 8.7 percent ash were obtained. The carbon:hydrogen ratios of the kerogen in the original shale and the different concentrates were essentially the same. The oil:kerogen ratios calculated from Fischer assays of the above samples were essentially the same, regardless of the organic or inorganic contents. This was also true of the assay water:kerogen ratios of the same samples. These data indicate that no significant change occurred in the kerogen during the concentration process.

Jan 1, 1952

By T. L. Iapalucci

To determine the behavior of chlorine in coal combustion, the Bureau of Mines burned 10 chlorine-containing coals, high-, medium-, and low-volatile, in a laboratory-scale pulverized-coal combustor. At carbon-combustion efficiencies of 94 to 98 percent, 1.6 to 7.1 percent of the chlorine or an average of 4 percent of the chlorine in the coal was retained in the ash; the balance, predominantly hydrogen chloride, was evolved in the combustion gas. Sulfur retention in the ash ranged from 2.3 to 10.7 percent or an average of 6.3 percent, Addition of alkali and alkaline earth carbonates to a medium-volatile coal containing 0.27 percent chlorine by preferentially reacting with the chlorine increased the Cl/S atom ratio in the ash, Lithium carbonate addition at 0.43 percent and K2C03 at 1.59 percent increased the C1/S ratio in the ash from 0.2 to 0.6.

Jan 1, 1969

By D. J. Dollhopf

This research was part of an effort to investigate means of reestablishing non¬polluted hydrological systems in areas where surface mining directly impacts shallow ground-water resources. Chemically undesirable overburden material was selectively backfilled with the intent that it would be below the future root zone, be above the reestablished aquifer, and would not be leached as a result of deep percolation. After 2 years the buried material remains above the spoil aquifer and below the maximum rooting depth. Unsaturated water flow from the land surface to the buried material occurred during wet climatological periods. No significant leaching of buried material was observed, however. Overburden sample contamination from drill stem joint grease with Pb, Zn, and Cu additives caused substantial error regarding DTPA extractable trace metals. A grease with teflon and talc additives was recommended for use in future sampling programs. DTPA extractable trace elements in overburden material had no statistical relationship to post-mine ground-water quality. Overburden columns leached with water produced leachates comparable to overburden and spoil ground-water trace metal quality. A depositional model described the Rosebud Coal overburden as a fluvial system with distinct units of sand, silt, and clay, with distinct chemical properties. Physical and chemical characteristics of the model were comparable to the in situ geochemical system, a relationship which may aid in locating overburden materials unsuitable for reclamation.

Jan 1, 1979

By L. A. Haas

S02 reduction with CO was studied in an integral flow reactor at a nominal flow of 0.5 liter per minute. Reactant gas contained 3 percent SO2, 6 percent CO, and the balance He. SO2 conversion was determined for three different types of catalysts. The first consisted of 16 commercial catalysts used for various chemical syntheses. Only the commercial catalysts which contained transition metals in alumina removed more than 30 percent 80a at temperatures below 510° C. Two other types of catalysts were prepared in the laboratory either by pelletizing equal amounts of powdered alumina and transition metal oxides or by impregnating commercial alumina tablets with transition metal ions. Regardless of preparation techniques, Cr and Fe in alumina were the two best catalysts. The observed results suggest that an intermediate (SCO) is formed by the interaction of surface metal sulfides and carbonyls. Alumina then catalyzes the interaction of SCO with S02 to form the end products (sulfur and carbon dioxide). Over 80 percent S02 was removed at 460° C with 2 grams alumina impregnated with 2.5 percent iron.

Jan 1, 1972

By J. S. Browning

The Bureau of Mines investigated the concentration characteristics of high-clay sylvinite ores from potash companies operating in the Permian basin near Carlsbad, N. Mex. These ores, containing 14 to 19 percent K20 and 3 to 5 percent clay slimes, cannot be effectively processed by current commercial flotation methods because of their high clay content. A solution to this problem was shown to be the use of two-stage moderate scrubbing conditions for clay disaggregation and removal as opposed to strenuous attritioning. Bench-scale beneficiation techniques for recovering potash minerals by flotation from the scrubbed material resulted in acceptable product grades and recoveries. By using a coarse grind, emphasis was placed on production of premium granular and coarse products. Flotation results showed that concentrates of 59.6 to 60.4 percent K.0 values can be obtained. Continuous pilot plant beneficiation techniques for recovering potash minerals by flotation resulted in concentrates containing 58.8 to 59.8 percent K20 with recoveries of 69.7 to 81.4 percent of the K20.

Jan 1, 1975

By Richard J. Mainiero, James H. Rowland

When most people think of explosives transport they think of a hazardous operation. We all know that we aren’t allowed to transport explosives through tunnels and are discouraged from traveling through heavily populated areas. Popular opinion suggests that explosives transport is a very risky operation. The authors decided to look into this a little more thoroughly and found just the opposite to be true. While there have been some disastrous world-wide accidents involving the transport of industrial explosives, this is not the case in the U.S. Over the past 10 years, accidents related to the transport of explosives used in mining and construction have resulted in 5 major injuries, 11 minor injuries, and no fatalities. Explosives and ammonium nitrate (AN) transport outside the U.S. has not had such a good record; there have been 4 major explosives or AN transport accidents resulting in a total of more than 300 deaths. Most of these fatalities could have been prevented if the accident site had been evacuated once the explosive or AN cargo began burning. The safe history of explosives and AN transport in the U.S. is due to diligent efforts by government, labor, and industry. However, accidents will become more common and disastrous if we become complacent.

By Raymond B. Ladoo

Toward the end of 1920 , the average grades of ground feldspar offered to the pottery industry were so poor and so generally unsatisfactory that many of the largest consumers decided to take active steps for their own protection . A few of the potters made arrangements to grind their own feldspar , while others asked the Bureau of Mines to make a detailed study of the problem and to suggest methods of improvement . Accordingly such a study was undertaken, the partial results of which are outlined in this preliminary report . The outstanding features of the present feldspar industry which are of interest in this connection are stated below. (1 ) Many grinding companies do not own or control all or even a major part of their sources of crude material , but buy in job lots from many sources . (2 ) There is great need of more adequate engineering and chemical control over mines and mills . ( 3) ~ Out of date , inefficient methods and equipment for mining and grinding are in common use . (4) Little or no cooperation exists between feldspar producers , but on the contrary many feldspar companies are exceedingly secretive . This tends towards (a) preservation of obsolete methods ; ( b ) want of knowledge of the essential features of production , market requirements , and the relation between total milling and consuming capacities of the country; ( c ) inefficient and often mistaken trade practices ; ( d) unprofitable and even ruinous competition in dull periods . (5) The small size of many feldspar deposits precludes maintenance of an efficient organization at each individual mine . ( 6 ) Many of the best deposits of feldspar situated close to railroads are becoming depleted , which results in gradual lowering of grades , and increase in cost for better grades . (7) There is a lack of exact mowledge of the ceramic properties and behaviour of feldspar by some consumers , which results in ( a) purchase of feldspar on the basis of price alone , thus encouraging low production costs at the expense of quality , and ( b) inefficient and expensive cross- hauling of both crude and ground feldspar .

Jan 1, 1922