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By Sam S. Taylor

Subsurface disposal of oil-field brines was practiced in Oklahoma on a limited scale as early as 1925. The technique of subsurface injection has been improved immensely and has been applied with varying success in many oil-producing areas in Oklahoma, and elsewhere. This method of disposal, however, is only one of several methods available to operators of oil-producing properties, but, in contrast with usual methods of handling brines on the surface it eliminates the damaging effect of mineralized water on fresh-water supplies, vegetation, and aquatic and other animal life. Other methods of brine disposal approved by regulatory agencies in some States include (1) impounding in impervious ponds and solar evaporation, (2) controlled diversion into surface waters, and (3) recovery of the mineral salts of the brine. In most States where oil is produced regulatory bodies authorize the use of one or more of these methods of brine disposal. In Oklahoma, for example, the .Oklahoma Planning and Resources Board of the Conservation Commission has been authorized4/ to adopt whatever methods or means may be necessary to prevent contamination by mineralization of all potable waters within the State.

Jan 1, 1942

By W. H. Oppelt

The Federal Bureau of Mines investigated combustion of lignite in domes-tic heating equipment to obtain information on equipment performance and to evaluate testing procedures. Three types of domestic heating equipment were tested, ranging from a hand-tilled, magazine-type space heater to a ram-type overfeed stoker. Lignite was readily burned in each of the three units under various test conditions. Burnoff rates determined by adding weighed charges to the magazine were found to be in error because of shrinkage of the lignite when only a portion of the magazine capacity was consumed during a test. More reliable burnoff rates could be determined by carbon-nitrogen balances. A hand-fired magazine-type space heater (Booker heater) was operated without the furnace attachment at efficiencies to 75 pct. One test series was run with minimum supervision under conditions encountered in actual household operation. No mechanical trouble was encountered.

Jan 1, 1960

By R. V. Holmes

The properties of the Colorado Copper Co. in Sinbad Valley, Mesa and Montrose Counties, Colo., were rehabilitated and sampled by the Bureau of Mines in October, November, and December 1942. The several deposits were reexamined in March and April 1945 to obtain information disclosed by company work after December 1942. The development program included surface trenching, rehabilitation of several edits, and channel sampling of the exposures. Assay determinations wore made on 204 samples from the surface and underground workings. The results are given in the appendix. Several copper deposits in the Sinbad Valley area are similar in origin. The host rocks are sedimentary and mice in age from Pennsylvanian to Cretaceous. The Colorado No. 3 deposit occurs in the Cutler formation, which consists of many small lenses of conglomerate, sandstone, and shale. Mineralization is closely associated with faulting. On the Pyramid group the enrichment occurs in a zone of fracturing and jointing end also spreads into the adjoining sandstone. The ore deposition on the Copper Rivet claim is associated with a fault zone and is confined to en area above the contact of the Dolores-Wingate formations. Mineral deposits on the Sinbad claims occur at intersections of faults with blue-gray Pennsylvania limestone. Copper enrichment occurs along faults and as replacement of the surrounding limestone. Metallurgical tests indicate that ores from the Colorado No. 3 and Pyramid claims can be treated successfully by leaching with sulfuric acid. This method cannot be applied to ores from the Copper Rivet or Sinbad deposits because of high calcite content. Flotation tests at Boulder City, Nev., showed a recovery of less than 60 percent with a 14.24 percent copper concentrate.

Jan 1, 1952

By Ralph Husack

The Bureau of Mines investigated the effect of gamma radiation on reactions between Pennsylvania anthracite and fluorine and chlorine. In the tests with fluorine about 90 percent of the coal reacted at 350° C to form volatile products whether or not irradiation was employed. Up to 0.8 ml of liquid products per gram of anthracite was collected. Among the 25 com-pounds indicated by gas chromatography, fluoroform and l,l-difluoroethylene were tentatively identified from their relative retention times and perfluoro-cyclopentane from its infrared spectrum. In addition, a clear, hard, wax, probably a fluorocarbon, was formed at 45° C in both the presence and absence of radiation. With chlorine there was no significant difference due to radiation, and preliminary tests indicated that the chlorine reacted more with the organic matter of anthracite at 200° C than with inorganic matter. At 400° C the results were inconclusive because of excessive corrosion in the reaction vessel.

Jan 1, 1966

By A. Tewarson

Combustibility data are presented for 14 samples representing commonly used mine materials (treated and untreated wood, conveyor belt and brattice cloth). The combustibility data were obtained in the Factory Mutual Small-Scale Combustibility Apparatus (sample area -0.008 m ). The hazards associated with the mine materials were evaluated in terms of: 1) ignition/ surface flame spread using an ignition parameter (IP). A reasonable correlation was found between IP values and U.S. Bureau of Mines ratings for conveyor belts and brattice cloth and large-scale fire test data for treated and untreated timber sets; 2) generation of combustible vapors, using a vapor generation parameter (VP); 3) heat release using a heat generation parameter (HP). A reasonable correlation was found between HP values and the large-scale fire test data for treated and untreated timber sets; 4) generation of "smoke," toxic and corrosive products using a chemical compound generation parameter (CP); and 5) light obscuration by "smoke" using the light obscuration parameter (LP). All the wood treatments, except Fireguard, were found to be effective in reducing the fire hazard. The effectiveness of the treatment appears to be due to enhancement of carbon formation in the solid phase and enhancement of water formation in the vapor phase. Concepts are presented for establishing 1) the relationship between various parameters (IP, VP, HP, CP, and LP) and basic properties of materials, and 2) the usefulness of the parameters as criteria for the combustibility and fire hazard evaluations of the mine materials.

Jan 1, 1982

By C. Daniel Kealy

Dissolved and suspended solids are present in the free water of tailings ponds. This Bureau of Mines study was designed to identify the influences of the slime zone in preventing these solids from reaching the environment outside the tailings pond. The finite-element method was used to determine the rate of discharge of subsurface water from the Van Stone tailings pond in northern Washington. The slime zone was sampled and tested for the first time, and results were interpreted and incorporated into the mathematical model. Computer results were verified by installing and monitoring piezometers in the field and by a simulated (16- by 1/2- by 3 foot) laboratory model. Output from the numerical model defined critical seepage zones and revealed that proper pond design and maintenance can reduce pond seepage losses to a minimum. Minimization of seepage requires maintaining the pond water level over the slime zone. Sufficient physical, chemical, and limnological data were collected and analyzed to conclude that the only realistic reflection of synergistic effects is obtained by study of the indigenous biota in combination with quantitative chemical and physical data. Proper planning and management of the milling and waste disposal operations are the key to minimal pollution.

Jan 1, 1974

By E. P. Youngman

From a scientific point of view , the zircon is by far the most remarkable of the gem stones , and a satisfactory solution of the problems offered by its characters and constitution has not yet been made . 3 Three distinct forms have been recognized , differing in specific gravity , hardness , optical properties , behavior when heated , and color.4 ( See section of this paper entitled "Description and Properties . " ) Zircon as a gem stone has not been as well known as its properties warrant . It is one of the most brilliant of the precious stones (having a high refractive index) . The colorless zircon rivals the diamond in brilliance and fire play to such an extent that a judgment based entirely upon optical inspection might be erroneous . In the opinion of gem authorities , the colored stones likewise have much merit . The blue zircon ( " Starlite" ) was so named by Kunz because of its resemblance to a " star twinkling in the night . " Another gem authority describes the leaf- green stone as one possessing a restful beauty , the red stone as having a certain ( though somber) grandeur , and the golden-yellow stone as being unsurpassed in magnificence . The slowness with which the zircon , a stone frequently mentioned in ancient literature , has come into use in modern jewelery may be owing to the fact that authorities differ as to whether the colorless and the blue zircons are found as such in nature or are treated stones . Any treated stone , although the material of which it is composed may be essentially genuine , has been considered a deception . However , according to Kunz , " Starlite is now sold over the entire world ; never has anything been so well introduced. "7 Dr. Foshag, mineral curator of the United States National Museum, states that the first allotment of zircons to enter the United States was obtained in 1921 from Siam ( through France ) for scientific or museum purposes and that four or five years later the stones were adopted by the jewelers of this country . Retail jewelers are displaying the colorless type and the blue stones , especially , in finger rings , necklaces , and like ornaments . Fine crystals have been used somewhat extensively in jewelling watches and as supports for the edges of fine balances . At one time zircons were though to be appropriate in mourning jewelery .

Jul 1, 1931

By E. O. Binyon

"INTRODUCTION The Gibellini manganese—zinc-nickel deposits, are in southeastern Eureka County, Nev, T. 15 N., R. 53 E. M.D.B.M. 27.5 miles south of Eureka, the county seat.The partly explored deposits, locally known as the Black Iron or Gibellini property, were examined in May 1944 by an engineer 3/ of the Bureau of Mines, who recommended that the deposits be explored further by means of core drilling. The proposed program called for drilling six diamond—drill holes, or eight if necessary, and for trenching at two places — 200 feet northeast and 280 feet west of the shaft on the main deposit.In 1946 the project was set up, and In July, of that year diamond drilling as started. Six holes were drilled for a total length of 1,198.5 feet. No trenching or other exploratory work as done. Work on the project was stooped. October 30, 1946.OWNERSHIPAccording to county records, the property comprises a group of 13 unpatented lode claims, and ownership is divided among Louis P. Gibellini,Louis P. Gibellini and wife (both of Eureka, Nev.), and the International Smelting & Refining Co., of Salt Lake City, Utah. Five claims of the group - the Black Iron No. 1, Black Hill No. 2, Manganese No. 3, Flat No. 1, and Flat No. 2 - are owned by Gibellini. Three claims - the Black Hill No. 1, Black Iron No. 3, and Manganese No. 4 are owned jointly by Mr. and Mrs. Gibellini, and the International Smelting & Refining Co. owns the remaining five - the Black Iron No. 4 and No. 5, and Black Hill Nos. 4, 7, and. 9."

Jan 1, 1948

By R. W. Van Dolah, N. E. Hanna, F. C. Gibson

Measures that were taken to eliminate noise resulting from explosives work at the Bureau of Mines facility at Bruceton , Pa . , are described . A method for monitoring sound transmission characteristics of the atmosphere and control of the explosives testing is presented as a noise control measure that offered partial relief during the period in which the modifications were made . Design details of the replacement gallery , used for permissibility testing of explosives , and the modifications of four types of bombproofs are given . Operation of the closed facilities are completely satisfactory , and the noise problem has been entirely eliminated .

Jan 1, 1964

By Steven J. Page

The Bureau of Mines used fiber-laden air to test two identical fibrous aerosol monitors (FAM) in order to establish the FAM-optical count correlation. The FAM is a unique instrument developed by GCA Corp. (GCA) to measure real-time fibrous aerosol concentrations. It will also respond to particulates that have sufficient shape irregularities to possess fiber characteristics such as the 3:1 length: diameter (L:D) aspect ratio. Results of the Bureau's laboratory tests showed that the FAM response is linearly correlated to concentration data obtained using the optical membrane filter count technique approved by the National Institute for Occupational Safety and Health (NIOSH), U.S. Department of Health, Education, and Welfare. A plot of the FAM-optical count correlation showed that FAM concentration readings are generally well within ±25 pct of the optical membrane filter count. Initial tests to estimate the best ratio control setting of the FAM for 5-µm fiber-length discrimination were performed using one instrument only (the ratio control setting determines the minimum threshold fiber length that will be detected by the FAM). The estimated setting was then used to correlate both FAM units. The result was a 65 pct difference in correlation between the two units. It appears that the major factor responsible for this difference was the internal adjustment of the photomultiplier detector sensitivity for each of the two FAM units.

Jan 1, 1980

By Sam S. Taylor

Subsurface disposal of oil-field brines was practiced in Oklahoma on a limited scale as early as 1925. The technique of subsurface injection has been improved immensely and has been applied with varying success in many oil-producing areas in Oklahoma, and elsewhere. This method of disposal, however, is only one of several methods available to operators of oil-producing properties, but, in contrast with usual methods of handling brines on the surface it eliminates the damaging effect of mineralized water on fresh-water supplies, vegetation, and aquatic and other animal life. Other methods of brine disposal approved by regulatory agencies in some States include (1) impounding in impervious ponds and solar evaporation, (2) controlled diversion into surface waters, and (3) recovery of the mineral salts of the brine. In most, States where oil is produced regulatory bodies authorize the use of one or more of these methods of brine disposal. In Oklahoma, for example, the Oklahoma Planning and Resources Board of the Conservation Commission has been authorized to adopt whatever methods or means may be necessary to prevent contamination by mineralization of all potable waters within the State.

Jan 1, 1942

By W. H. Tavenner

The Bureau of Mines gathered test data on the use of a continuous borer in mining an anthracite bed, which was 30 feet thick on a pitch of 15° to 45°. Gangways were driven with the continuous borer, ventilation openings between gangways were driven with a large-diameter auger, and the blocks of coal between completed gangways were mined by the long-hole method, Conveyors were used to transport the mined coal. The continuous borer operated on a coal floor that was frequently soft because of heaving. The continuous borer could not bore openings on a grade exceeding 27 percent (15° pitch). Because 150 was also the lower limit of the pitch, of the bed, the continuous borer was used only to drive gangways. The continuous borer virtually filled the workplace, leaving insufficient space to place heavy-duty timber and cushioning material between the timber and coal back to allow for normal expansion of the uncut coal. The light? weight yieldable steel arch against the coal back gave inadequate support to control convergence, which in a disturbed area sometimes occurred with explosive violence. This exposed the machine operator to a hazardous condition, since a satisfactory solution could not be found, the company discontinued the use of the continuous borer.

Jan 1, 1966

By James H. Russell

Alkalized alumina (an active form of sodium aluminate) has been considered as a sorbent for the removal of sulfur dioxide from industrial flue gases. Four rate equations, each based on a different mechanism, were compared with the results of thin-bed sorption tests. It was found that each equation agreed with the experimental results, within experimental variance, over most of the range of sorption studied. First-order rate equations were generally satisfactory in explaining both sorption and regeneration. It is concluded that the equations developed are adequate for the design of commercial fluidized beds for the sorption of SO2 from industrial flue gases and regeneration of the alkalized alumina.

Jan 1, 1970

By Robert L. Lagace

[Suuple Iheorctrccil models are I'M lllolalcd to cltaraclerl/c medium frequency (MF) radio vase pi opaiation in undcrgiounli room arid pillar coal mines fur the purpose of predleiln the most lavolable operating fIegtucncics,md nr,ixunum communic;IIIoil ranges for pottahIe rldu)s with I top antennas. I or conductul IrCC areas, at hree layer propaeaIion IltodcI wit II a Iiallsmissloil IIIIi- lhlllllIIal'u11 lot the plupa!edti ii unlstallt Iris been dcvcloped ;md verified experimentally. 1 lie mode u1 propaCaUetl lakes Ills form of i parallel plane (0,t)) TIM lransnussu)nhne 1% PC of mode with the electric held vertical and the magnetic held hoti/cntal t itliin a planar coal scam in which the tunnels Can he ignored and which 1s hounded above and below hp richer conductivity rock. 1lie model lilt the data best river the 200 io 1000 kH/ frequency hand and exhibits a rc;;lon of optlnrul1l Pelffelntance, with respect Io maxnluiulg radio Communication range, between 300 and 100 klf/. Maximum cunununlcatrorl ranges are sliongls dependent oil the sigiial alleilliatroil sale, ant) Illelclulc on the electrical conductivltles of the coal seam and surrounding ruck. These ranges v;ny tutu about ,,5 Io 100 nleleis Ill a high Iuss scam such as the Ilelllit No. fl to about .100 to 400 meters in a low loss seam such as the Pittsburgh foil portable intrinsically safe radios. The ieslllls die haled on the comparison oftheorc' and experiment for eleven n n. ill sesen coal seams. V OT ate is dice: a conductor such as a power Cable, is present a model has been developed for the coupling of loop antennas to a low loss Coaxial TEM ti;u?smisslon line mode in which the cable acts as the inner conducl,lr and the rock above and below acts as the outer conductor. The electuc and md' nctic Itelds for till` (node are apprlixitllatcly transverse to the cahlC and fall oil expontially with distance in the transverse plane. The principle of reciprocity is used to simplify the analysis. More expelitnental data arc needed to help resolve discrepancies between the theory and the limited data available to date.]

Jan 1, 1980

By W. E. Tournay

In accordance with a cooperative agreement between the Bureau of Mines, United States Department of the Interior, and the Linde Air Products Co., an investigation was made at the Bureau Explosives Testing Station, Bruceton, Pa., to develop suitable test methods for evaluating the performance and sensitivity characteristics of liquid-oxygen explosives. This report presents the results of the investigation. The unique nature of liquid-oxygen explosives necessitated both modification of standard techniques and development of entirely new test methods. The latter requirement was due to the fact that differences exist in the kind of information that must be developed for studying relative safety and performance properties of these explosives compared to that of fixed explosives.

Jan 1, 1949

By J. A. Markovits

Coal has been hydrogenated in Germany on a lather extensive scale for the past 20 years, but the process is new to the United States. Although pressures up to 15,000 pounds per square inch have been employed on commercial scale in the synthesis of anhydrous ammonia, and there is evidence that valves, tubing, and equipment have been developed recently up to 30,000 p.s.i. working pressure at moderately elevated temperatures for limited industrial production of plastics, such pressure ranges are unusual in American industry, and equipment designed for them is not commonly available. In the Coal Hydrogenation Demonstration Plant at Louisiana, Mo., 10,000 p.s.i. operating pressures are combined with temperatures up to 1,000° F., and the materials to be processed under these conditions range from gases to mixtures of viscous liquids containing high percentages of abrasive solid particles. These service conditions presented unusual engineering problems requiring thorough investigation, Limited financial resources arid rigid time schedules inherent in the synthetic liquid fuels act often forced decisions before the best answer to a problem could be developed. Sometimes the ideal technical solution proved to be beyond the financial limitations of the demonstration-plant program.

Jan 1, 1949

By Jeffrey Y. Foley

Chromite deposits along the Border Ranges Fault in southern Alaska were investigated by the Bureau of Mines. This report, part 1 of a two- part series, describes the deposits. Part 2 describes the mineralogy and the results of metallurgical tests. Fieldwork began in 1981 and continued through 1983. Ninety-four subeconomic podifom chromite deposits in eight mafic-ultramafic complexes were investigated. Previously unreported chromite deposits at Red Mountain on Kenai Peninsula, on Kodiak Island, and near Tonsina are described. Deposits range in size from less than a thousand tons to over 1.25 million tons of contained chromic oxide (Cr203). Grades range from about 5 to 10 pct chromite. Excluding all deposits more than 10 miles from tidewater or existing roads and all deposits containing only chemical- or refractory-grade chromite, about 2,200,000 tons of Cr203 are contained in 41 hard-rock deposits. A placer deposit contains an additional 556,000 tons. These 42 deposits constitute a subeconomic indicated and inferred reserve sufficient to meet the Nation's chromite demands for about 4 yr, or the metallurgical industry's demands for over 5 yr, at 1981 consumption rates.

Jan 1, 1985

By Michael J. Pazuchanics

This report documents the current status of the U.S. Bureau of Mines ongoing investigation of the use of adaptive signal discrimination (ASD) systems to distinguish between cutting coal and cutting rock. Cutting-tool forces and vibrations were measured in the laboratory using both conical bits and roller cutters in a linear-cutting apparatus for several material samples and two cutting directions. A number of ASD systems consisting of one or more signal classifiers were trained and tested to study how data window size, type of signal feature, and combining (polling) of classifier results influence system performance. The results show that ASD system recognition rates can be improved by increasing data window size, removing air-cutting portions from the signal data, overlapping data windows, and combining (fusing) information at various levels of ASD system operation.

Jan 1, 2010

By H. -F. Krausse

Roof failures in underground coal mines are related to the lithology and geologic structure of the roof. There are two distinct suites of roof rock above the Herrin (No. 6) Coal in Illinois, and each has distinctive patterns of structure and roof failure. In black shale-limestone roof areas, roof instability is correlated with thinning of limestone beds and presence of faults and clay dikes. In gray shale roof regions, the prime roof hazards are posed by rolls, shear bodies, and presence of coal or carbonaceous partings in the roof. Most structural features examined are believed to have formed during early stages of sediment diagenesis and compaction. Structural trends and lithologic patterns are strongly interdependent for this reason. In many cases geologic patterns are so complex and locally variable that prediction of roof stability far in advance of mining is difficult. The need for greater flexibility in roof control planning is apparent.

Jan 1, 1979

By A. F. Colombo

Infrared spectroscopy employing attenuated total reflectance (ATR) techniques on thin films of dried gelatinized starch solution was used during Bureau of Mines research to determine the structural and impurity differences in starch products and to correlate these characteristics with the flotation response of a nonmagnetic taconite. All of the starch products evaluated gave spectrograms which were characteristic of the anhydroglucose monomer and its polymerization product. Distinct infrared absorption peaks caused by the protein molecule were observed and were used to classify the starches. Correlation of laboratory flotation of calcium-activated gangue from a Mesabi Range nonmagnetic taconite and infrared spectra produced from gelatinized starches showed that protein impurities and linear chain structure limited the effectiveness of starches as iron mineral depressants. Starch products having spectrograms similar to pure amylopectin were generally good depressants for iron oxides, were effective at about one-half the addition that was required for starches that gave infrared responses similar to pure amylose, and yielded acceptable iron concentrates containing 61.5 percent iron and 6.5 percent silica.

Jan 1, 1969