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By Theodore Kessler

The purpose of this Bureau of Mines investigation was to determine what new organic compounds or high concentrations of a particular organic species can be formed by exposure of coal derivatives to ultrasonic energy. Tetralin, l-methylnaphthalene, and pyridine were used as model compounds. Gaseous and solid reaction products resulting from the ultrasonic irradiation of these coal derivatives were determined using mass spectrometry. Products from the irradiation of tetralin were studied as a function of time, atmosphere, and sample size. The sonolysis (chemical reactions produced by ultrasonic energy) of tetralin and l-methylnaphthalene produced C2H2, HCN, CH4, H2, CO, and CO2, depending upon the experimental conditions. The ultrasonic irradiation of tetralin also produced diacetylene under certain experimental conditions. The cleavage of organic chemical bonds by ultrasonic cavitation in the absence of water was also observed in this study.

Jan 1, 1967

By D. E. Stone

Solid and liquid impurities must be removed almost completely from synthesis gas for the production of synthetic liquid fuels because of their effect on the synthesis catalyst and turbocompressors. The maximum permissible concentration of dust has been set at 0.05 grain per 100 cubic feet.5/ This is one part per million by weight, or about the same concentration as in average city air. The cost of synthesis gas is estimated to constitute 60 to 70 percent of the total cost of the synthetic liquid fuel. For this reason this station is developing processes using coal instead of the more valuable coke as raw material, which promises reduction in cost of the synthesis gas. This, however, increases the difficulty of attaining the above dust value. As failure of the dust-removing equipment to produce high-purity gas may ruin valuable equipment within a few minutes, it is imperative that a reliable and continuous method be obtained for determining such extremely low concentrations .of dust in the purified gas. A suitable device must also instantly sound an alarm and, if necessary, automatically actuate the proper valves to prevent damage. The Ess Instrument Co. designed and built an instrument which they believed might fulfill these specifications. It' continually compared, by means of photoelectric cells, the intensity of a light beam passing through the gas and a similar beam passing through clean air. For maximum sensitivity, the photocells were connected back to back, i.e., anode to cathode and cathode to anode. The difference in voltage produced by the two cells was amplified and operated an indicator.

Jan 1, 1951

"Minimizing Particle Contamination During Generation of Fresh Dust for Inhalation Studies J. Abraham, MS, Mechanical and Aerospace Engineering, West Virginia University, 1995Correlating Lung Crackle Using Holographic Interferometry Ali Afshari, MS, West Virginia University, 1989Effect of Bit Wear on Dust Generation Mudassar Ahmad, MS, West Virginia University, 1992 The Effect of Surfactants on Suppression of Non-Wettable Particles Ali Alaboyun, MS, Mineral Engineering, The Pennsylvania State University, 1989 Geochemical Characterization of Kerogens, Shales, and Coal Refuse Associated with Allegheny Formation of Cases of Northern West Virginia Dick Andre, MS, West Virginia University, 1987Size and Mass Characterization of Airborne Particulate Matter in Underground Coal Mines Using Diesel-Powered Equipment Indranil R. Bardhan, MEM Report, The Pennsylvania State University, 1992Size and Mass Characterization of Airborne Particulate Matter in Underground Coal Mines Using Diesel-Powered Equipment I. Bardhan, R. V. Ramani, and J.M. Mutmansky, Mining Engineering, The Pennsylvania State University, University Park, PA, Final Report to the U.S. Bureau of Mines, April, 1994Particle Concentrations in a Hazelton Inhalation Chamber Shahram Bavani, MS, West Virginia University, 1985Use and Potential of Lazer Holographic Interferometry and Subsidence Model- Study of an Underground Room and Pillar Mine Richard Begley, MS, West Virginia University, 1984Development of a Mechanistic Model for Prediction of Subsidence in a Longwall Mine Richard Begley, PhD, West Virginia University, 1990Redesign of Micro-Orifice Uniform Deposit Impactor Steve Behm, MS, University of Minnesota, 1991Evaluation of a Two-Phase Spray System for Dust Suppression B. Belle, MS, The Pennsylvania State University, 1996Evaluation of a Two-Phase Spray System for Dust Suppression B. Belle and R.-V. Ramani, The Pennsylvania State University, University Park, PA, Final Report, September 9, 1996A Fracture Mechanics Study of Crack Propagation Mechanism in Coal: The Mechanics of Fine Fragment Formation Z.T. Bieniawski and R. Karl Zipf, Jr., Mining Engineering Department, The Pennsylvania State University, University Park, PA. Final Report, October l, 1988A Mathematical Model for the Prediction of Ambient Dust Concentrations in Mine Atmospheres R. Bhaskar, MS, Mining Engineering and Operations Research, The Pennsylvania State University, 1984Spatial and Temporal Behavior of Dust in Mines-Theoretical and Experimental Studies –R. Bhaskar, PhD, Mining Engineering, The Pennsylvania State University, 1987"

Jan 1, 1998

By R. J. SHAW

Oil shale has been defined as, "a compact, laminated rock of sedimentary origin yielding over 35 percent of ash and containing organic matter that yields oil when distilled but not appreciably when extracted with the ordinary solvents for petroleum." The oil-yielding organic matter in oil shale, commonly called kerogen, decomposes upon application of heat to form bituminous materials that are soluble in organic solvents and may be extracted from the inorganic residue. However, separation usually is accomplished by continuing the heating and thereby cracking the primary bitumens to gas and oil, which distill, leaving a carbonaceous material on the mineral residue. It has been suggested that this conversion takes place only at relatively high temperatures - 750°F or higher. On the other hand, other workers have found that transformation may take place to some extent at temperatures as low as 400°F. In either a solvent extraction or a destructive distillation process for separating organic material from the inorganic portion of oil shale, the quantity of heat required to raise the temperature of the oil shale sufficiently to induce a satisfactory rate of conversion of kerogen to oil is important in determining the design of an economical process. Likewise, the quantity of heat recoverable from a spent shale is important in determining the overall heat balance of the process. Published data on the specific heat of American oil shales are meager. Gavin and Sharp present data for two samples of Colorado oil shale, one from near DeBeque and one from Parachute Creek, and for a sample of spent shale over a temperature range of 68°F to 1940°F. McKee and Lydor present data on the specific heat of two samples of oil shale from near DeBeque, Colorado. Additional thermal data on various grades of oil shale over a wider range of temperature are needed in order to apply sound engineering practices to the design of equipment for processing oil shale.

Nov 1, 1947

By J. B. Littlefield

The term "konimeter" is used generally to designate a type of dust-sampling instrument that collects the dust from a small volume of air by impingement on a glass plate prepared aced with an adhesive film. The konimeter was first developed by Sir R. N. Kotze about 20 years ago and was followed a few years later by the circular-type konimeter, by which a number of samples may be collected on a glass disk. The present discussion will be confined to the circular type, as it is used most. Various techniques have been developed for using the konimeter, and many materials, such as petrolatum, mineral oil, and glycerine jelly, have been used in preparing the adhesive film. In South Africa, Australia, and Canada, where the konimeter has been employed most widely, dust samples are treated by ignition and washing before being counted. In Canada the dust samples are collected on a disk of special heat-resistant glass prepared with a film of mineral oil; the disk is then heated to a dull cherry-red in a muffle-furnace to remove the film and organic matter, cooled, and washed with a few drops of 50-percent hydrochloric acid followed by distilled water and alcohol, and then heated again to remove residue left by evaporation of the alcohol. After this treatment, the dust samples are counted under a magnification of 150 diameters with dark field illumination.

Jan 1, 1938

By A. L. Engel

In the period of 1942-1945, medium-grade, oxidized, lead-silver ore was mined and shipped from the Diamond district near Eureka, Nev. An encouraging tonnage of low-grade ore was developed during these operations and partly blocked-out for future mining. If the low-grade ore could be treated profitably, further development of the district would result, and production of an important strategic metal might be increased. A representative sample of Diamond district ore was obtained through the Reno office of the Mining Division for the studies described in this report. The sample consisted of lumps and fines of a highly altered siliceous rock containing much earthy red hematite and some granular black hematite. Examination with the binocular microscope showed the lead carbonate mineral, cerussite, in seams and disseminated in the hematite. No zinc or silver minerals were identified, and no sulfide minerals were present. Analyses of the ore showed:

Jan 1, 1951

By R. W. Stahl

A survey of firefighting facilities and practices in coal mines conducted by the Bureau of Mines3/ showed such variations in equipment and apparent attitude toward fire protection that a comparison with other industry seemed advisable. Although other industry is confined generally to surface operations and the hazards probably are not as great, the same general methods of extinguishment are employed, so that the cost and protection at least should be comparable. An investigation of industry other than mines revealed a generally greater emphasis placed on fire-combating equipment, fire-brigade training, fire-fighting facility inspection, and fire-hazard elimination, as well as a greater average expenditure for fire protection.

Jan 1, 1959

By Alex U. Miller

Since its beginning, the occupation of coal mining has been considered hazardous. It is true that there are hazards inherent in mining, but it is believed that most of them, at least, can be guarded against. Moreover, many man-made hazards can be eliminated by officials and workers adopting safer practices. Notwithstanding the hazards in coal mining, the fatal accident rate in the United States has improved. During the, period from 1911, to 1941, inclusive, the fatal accident rate varied from 5.35 to 2.22 per million tons of coal. With many handicaps during the war period, 1942-45, such as the lack of experienced manpower. and the, employment of untrained men, the increased average age of workers, and the shortage of equipment and supplies, the industry s ill further reduced its accident rate, so that it ranged from 2.30 to 1.724/ deaths per millon tons of coal. During 1944, 684,000,000 tons of coal was produced with a rate of 1.91, and during 1945, 631,000,000 tons was produced with a rate of 1.724/ deaths per millon tons of coal. The accident rate for 1945 was the lowest for the industry since records have been compiled.

Jan 1, 1946

By B. I. Ferber

Sodium chloride aerosol was employed to determine respirator filter penetration in a manner suitable for use in Bureau of Mines approval and certification procedures. The aerosol was produced by an ultrasonic generator and treated to yield the proper conditions of relative humidity, particle size, and concentration. Respirator filters were exposed to the aerosol; filter penetration (down to 0.02 percent) was determined with a flame photometer. Results are comparable with those obtained in another laboratory using different equipment.

Jan 1, 1970

By R. Karl Zipf, Z. T. Bieniawski

"SummaryAs part of an effort.to understand the mechanics of fine fragment formation in coal, which is important in studies of respirable dust due to mining, fracture toughness measurements and the strain energy density (SEO) theory were applied to calculate the crush zone size under a cutting tool in coal. This · zone is the major source of fine fragments in the 1 to 10 µm size range. The model used in these calculations is a boundary element program containing a failure criterion based on the SEO theory. The boundary element program calculates linear elastic stresses at numerous points in the coal material ahead of a cutting bit. These stresses arc then input to a subroutine called critical ftaw length and orientation (CFLO) which uses the SED theory to determine the CFLO for a small crack at the boundary element stress computation point. The extent of crushing is based on earlier postulates about . the role of inherent flaws in a fragmentation process. To form 1 to 10 µm fragments requires firstly a local stress strong enough to activate flaws with a characteristic length less than 1 to 10 µm and secondly, a flaw density sufficient to provide an average spacing between flaws also on the order of 1 to 10 µm. The locus of active lO µm ftaws represents the maximum possible extent of fine fragmentation in the 10 µm or less size range assuming that a sufficient inherent flaw density exists. The approach offers a first order approximation to the extent of crushing under a tool tip. The size and shape of the crush zone volume is affected by the attack angle and geometry of the tool.IntroductionFine fragment generation in the 1 to 10 µm size range under the action of a generic coal cutting tool may be explained on the basis of fracture mechanics which suggests two major sources of fine fragments: first in a crush zone near the tool tip and second by shear fracturing. along major macrocrack surfaces (Zipf and Bieniawski, 1988a). In this paper, fracture toughness measurements and the strain energy density theory are used to calculate the crush zone size. This zone represents the major source of fine fragments in the 1 to 10 µm size range and understanding the mechanical factors controlling its size represents a first step toward using fracture mechanics to characterize the ·tendency of various coals to produce undesirable fine fragments."

Aug 31, 1989

By Charles A. R. Lambly

This paper, which describes the mining practices of the Pend Oreille Mines & Metals Co. at Metaline Falls, Wash., is one of a series being prepared by the Bureau of Mines on mining practices, methods, and costs in various mining districts of the United States. ACKNOWLEDGMENTS Acknowledgment is made to L. P. Larson, president, and Jens Jensen, secretary, of the Pend Oreille Mines & Metals Co. for permission to publish this paper. information was supplied by E. Berglund, mine superintendent; Earl Miller, chief engineer; Lynn Kinney, John Currie, and Wally Frick, engineers; Arthur Newman, chief clerk; and Jack Crampton, assayer.

Jan 1, 1941

The accompanying supply/demand flow diagrams and 10-year tables for mineral and fuel commodities present essential data required by government, industry, and others to formulate policies and programs that can help assure an adequate and continuing supply of mineral raw materials. The 10-year data base terminates with 1973 figures because adequate world information was not available beyond that date. Moreover, 1974 was an anomalous year with respect to prices, supply, and demand for many commodities. The selected mineral supply/demand tables and flow diagrams comprise but one "output" from the massive body of "information and data collected and com-piled by the Bureau of Mines on a continuing basis covering mineral production consumption, prices, shipments, imports, exports, and stocks, as well as industry activities in all States and abroad.

Jan 1, 1975

By L. W. Kelly

The primary purpose of this paper is to show the appreciable savings that were made by roof-bolting the main west entry of the Kings mine, which was to be the permanent, main haulage road, as compared to the cost of supporting the same roof with peg timbering as first planned. Additional items that might prove valuable to other mine operators are contained in this paper and detailed below. 1. A detailed cost of the system of roof support known locally as the peg-timbering method is given. It consists fundamentally of supporting steel cross bars on pegs inserted into holes drilled in the ribs close to the roof. 2. A method of supporting the roof in caved entries is shown, where such support must endure for an extended period in haulageways and air courses.

Jan 1, 1952

By Aner W. Erickson

"Magnetite iron deposits on Tolstoi Mountain were examined as part of the investigations by the Bureau of Mines of iron and copper ores on Prince of Wales Island. The Tolstoi Mountain project was a part of a program for investigating mineral deposits in Alaska, under the general supervision of R. S. Sanford, acting branch chief.A preliminary examination was made by S. P. Holt, mining engineer of the Bureau of Mines, in company with John Reed, L. A. Warner, and W. S. Twenhofel of the Federal Geological Survey, on July 14, l943. Three samples were taken, rough estimates were made, and it was proposed that the area be mapped, topographically and geologically,. Dip-needle work was added to the program, and it was decided that, should results warrant, the deposits would be diamond-drilled.From March 26 to May 28, 1944, the deposits were examined thoroughly by Bureau of Mines personnel under the direction of the author. Thirty-two acres were mapped with contour intervals of 10 feet, grids were established covering the principal outcrops, over 1,500 dip-needle readings were secured, and the magnetite bodies were outlined. Additional information was gathered by trench inch and channel-sampling, 600 linear feet of trench being dug and 32 channel samples being cut. Finally, the mapped area was checked for nonoutcropping deposits by taking dip-needle readings at 10-foot intervals along the traverse lines, creeks, trails, and all outstanding topographical features. This re-connaissance work gave sufficient coverage of the 32 acres to eliminate the possibility of further magnetite bodies of any consequence remaining undiscovered.Acknowledgment is made to Nile Johannsen, assayer, Territorial Department of Mines, Ketchfkan, Alaska, for determination of samples.The deposits are on Prince of Wales Island in Southeastern Alaska near Tolstoi Pay, a deep-water indentation at the northwest and of Kasdan Peninsula. The physical features are shown on figures 1 and 2 and the location of the deposition figure 3. Old workings were found on the west side of Tolstoi Mountain; between elevations of 650 and 1,150 feet, at distances of 3/4 to 1-1/4 miles from the east shore of Tolstoi Bay.Access to the area is over a brushed foot trail built by the Bureau of Mines. Topography would permit construction of either surface or aerial tramways at moderate cost but would make road building expensive. Deep-water navigation, permitting inexpensive water transportation, is possible the year around.Kasaan Peninsula is an area of moderate relief, being considerably less rugged than the mainland to the east. Most of the mountains and ridges are less than 2,500 feet in height and show evidence of having been covered by the ice cap of the Pleistocene age. Rock exposures below elevations of 2,000 feet are limited, as extensive overburden 2 to 20 feet deep covers the greater part of the peninsula."

Dec 1, 1948

By W. K. Overbey

Surface fracture trace density, changes in roof rock type, and topographic unloading due to drainage were mapped for the mining areas located in the Blacksville-Osage, W. Va., quadrangles to investigate their influence on mine roof falls. Using these factors, a technique was developed to predict probable roof fall areas ahead of projected mining operations. As a feasibility test of this proposed technique, areas were delineated where one, two, and all three of these factors were operating to formulate a "potential hazard map" for comparison with roof fall observations that were made. The limited evidence suggests that in combination these factors are reliable predictors of where roof falls are likely to occur. This technique promises to be a useful tool in planning mining operations.

Jan 1, 1973

On June 20, 1972, Ocean Energy was awarded Contract No. H0220055, entitled Portable Task Luminaire System Development. Initially, this was a 12 month program consisting of three phases: Phase I -- Design of the Luminaire System and Battery Chargers, Phase II -- Fabrication of Prototype Units, Phase III -- Fabrication of Production Prototype Units and Battery Chargers. In addition to developing the Portable Task Luminaire System, however, this contract was amended a number of times in the course of the program to include the development of a Low Coal Portable Task Luminaire, a Rib Mounted Luminaire System, and a Machine Mounted Luminaire System, all based upon the same high frequency fluorescent lighting and safety technologies involved in the Portable Task Luminaire. This report covers the activities of this program as amended, and includes the development and fabrication of all of the systems. This report constitutes the final fulfillment of the contract.

Jan 1, 1974

By T. A. Henrie, D. C. Fleck, D. G. Kesterke

Uranium metal was electrowon from uranium dioxide dissolved in fluoride melts . The UO₂ was fed directly to the cell in a continuous manner . Electrolysis was performed at 1 , 200 ° to 1,300 ° C in electrolytes composed of UF4 , LiF , and BaFa . A single regulus of metal was collected in a confined area of the crucible . Product purity of 99.8 percent was attained . Carbon was the major contaminant . Compartmented cells were studied as a means of confining the oxide feed to the vicinity of the anodes .

Jan 1, 1964

By Gilbert M. Farrior

The electrical resistivity the coefficient of electrical resistivity the Hall coefficient, and the absolute thermoelectric power were determined in this Bureau of Mines investigation for nine compositions of the TiB2-CrB2 sub-system. The numerical values of the electrical resistivity and the thermo-electric power were greater for the intermediate compositions than for the end members. The absolute values of the Hall coefficients and the coefficients of electrical resistivity were less for the intermediate compositions than for the end members. The electrical resistivities and Hall coefficients were about the order of magnitude of most metals--from 34 to 202 microhm-cm and from about 0 to -23.3 X 10-4 cuP/coulomb. The thermoelectric power was somewhat greater than that of most metals--up to 15.6 microvolts per 0 C.

Jan 1, 1965

By J. D. Davis

"Introduction.Sixty years ago, M. Berthelot found that ethylene could be selectively absorbed from gaseous mixtures by concentrated sulphuric acid, and that the compound formed by the chemical union of the gas and acid was readily decomposed by heating with water, yielding ethyl alcohol. Only within the last few years has there been any attempt to make use of this discovery technically.Bury*, working in England at the Skinningrove Iron Works and on a commercial scale, developed a technical method for converting, the ethylene of coke-oven as into alcohol. With a gas containing less than 3 per cent of ethylene, he obtained a yield of 1.6 gallons of alcohol per ton of coal carbonized.De Loisy** perfected a technical method for treatment of coke-oven as for alcohol. Evidently this work was carried out on a semi-commercial scale. His method is based on the use of catalytic agents for hastening the absorption of ethylene by sulphuric acid. He uses part of the spent acid for drying the gases and pact for the manufacture of ammonium sulphate. Excess acid is reconcentrated by waste heat. Others have worked on the problem, but so far there has been no large recovery of ethylene from coke-oven gases. The chief difficulty seems to lie in the low efficiency (about 50% of methods and tae relatively low concentrations of ethylene in the gases treated. Gas from Trent amalgam*** contains much larger percantages of ethylene than does coke-oven gas, as Will presently be shown, and if it should ever prove practIcal to treat industrial ;as for alcohol, this gas would offer attractive possibilities,* Bury, Ernest, Ethylene as Alcohol from Coke-Oven Gas: Gas Journal' Vol. 148, D. 30, 1919, pp. 718.** DC Loisy, M.E., Sur un procede' industrial de fabrication syntlotique de l'alcool et de l'ether a partir des gaz de distillation de la houil Comp Rend, vol. 170, Jan. 1920, p. 50-3.*** A paste consisting of approximately part oil such as that obtained as for cleaning coal. See Perrott. in cleaning coal, Chem 3 parts finely pulvarized coal and 1 final product in the Trent, process StJ, and Kinney, S.P. The use of oil Vol. 35 August 3, 1921, p, 183.. & Met."

Nov 1, 1922

By W. P. Yant

[This report describes results of a study bf the carbon monoxide and particulate matter in the air of the Holland Tunnel and metropolitan New York made by the Bureau of Mines (which had participated in the development]

Jan 1, 1941