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By Edward F. Divers

Tills U.S. Bureau of Mines report briefly evaluates the advantages and disadvantages of basic dust control techniques presently used by U.S. coal preparation and mineral processing plants. These include ventilation, baghouse-type collectors, wet scrubbers, electrostatic precipitators, source control, sprays, good housekeeping, and personal protection devices. Two specific problems in these types of operations are also considered: dust collector system duct clogging, and control room dust control. Information provided in this report results from dust control research projects conducted by the Bureau at various coal preparation and mineral processing plants over the past decade to reduce workers' dust exposure. These studies indicate that plant ventilation systems normally provide the most cost effective method for dust control. Baghouses and scrubbers were also effective in specific applications, and examples of each are given. In extreme dust conditions, personal protection devices, such as respirators or the dust helmet, can also be highly cost effective.

Jan 1, 1990

By E. L. Litchfield

This report of work by the Federal Bureau of Mines has two primary objectives: A survey of the present status and usefulness of the minimum ignition-energy concept, and the presentation of recent data that are believed to bear on the safety problem associated with the ignition of combustible gases by electric discharges. The minimum ignition-energy concept has widespread applicability, especially to safety. The primary obstacle in making theoretical calculations of the requisite ignition energy is the lack of data on chemical kinetics and flame hydrodynamics. The new data on electrical ignition are representative of the great increase in knowledge that can be achieved by proper utilization of geometrical and electrical characteristics associated with the ignition source. CONCEPT OF MINIMUM IGNITION ENERGY The basic concept of a minimum ignition energy (the minimum amount of energy required to cause ignition) follows quite naturally from general physical principles and from the stability (lack of chemical reaction) of the gaseous mixture under the initial conditions. It also follows that if, as a first condition, lossless, instantaneous, and spatially localized energy can be injected and, as a second condition, the relaxation time for conversion of this type of energy to the type required for the reaction is short compared to some characteristic time scale of the ignition phenomenon, the energy requirements will be essentially independent of the type of energy source. Even if condition one cannot be fulfilled, it is sometimes possible to estimate the energy content of the gas required for ignition, and under these circumstances, condition one is fulfilled in effect. There are several instances where results can be interpreted for circumstances that effectively satisfy conditions one and two; these will be discussed later.

Jan 1, 1960

By K. C. Dean

A flotation method was developed by the Bureau of Mines for concentrating pollucite, a cesium-aluminum-silicate mineral that may contain from 20 to 40 percent cesium oxide. Separation of the pollucite from three typical ores was achieved by froth flotation of the associated micas, feldspars, and other gangue minerals, using sulfuric and hydrofluoric acids and a cationic-type collector. A low-tenor, 8 percent cesium ore from Maine was upgraded to 20 percent cesium with recovery of 87 percent of the cesium. Relatively high- grade ores from Canada and Southern Rhodesia were beneficiated at lower ratios of concentration to 28 and 29 percent cesium content respectively with recovery of over 92 percent of the cesium. In addition to concentrating the cesium content of ores, the method also effectively separates cesium from sodium, potassium, and lithium, and in certain ores from rubidium. This is accomplished by selective froth flotation of the alkali metal-bearing gangue minerals such as lepidolite, other micas, and feldspars. Since the alkali metals, especially potassium and rubidium, are difficult to separate chemically or thermally from cesium to prepare high- purity cesium products, separation by physical mans is important.

Jan 1, 1962

By M. E. Tyrrell, C. W. Houck

Mixtures of zirconium diboride and refractory metals of group VI were resistance sintered to high - density compacts using modified electric welding equipment . To evaluate the use of chromium , molybdenum , or tungsten as binders for zirconium diboride the sintered compacts were examined in polished sections and tested for crushing strength , hardness , microhardness , oxidation rate , and resistance to mechanical shock . Chromium yielded the highest compressive strength , the greatest resistance to mechanical shock and oxidation , and a satisfactory Rockwell hardness . Molybdenum did not yield a satisfactory cermet . Tungsten yielded compacts having high microhardness but very low mechanical strength .

Jan 1, 1964

By William D. Monaghan

The U.S. Bureau of Mines evaluated a teleoperated continuous mining machine for deep mining in thin-seam applications as low as 1 m. Teleoperation increases the safety of mining machine operators because it removes the operator from the face, an area of immediate hazards to safer outby locations. By using teleoperation, the miner can avoid many including unexpected roof falls that can maim or kill miners instantly, methane and coal dust explosions that can be ignited with just a small spark or flame, adverse health effects from miners breathing coal and silica dust, adverse long-term inner ear damage from loud noise pollution, and other hazards related to heavy mining equipment moving about in confined underground roadways. This report presents the surface evaluation results of a teleoperated control system.

Jan 1, 1994

By R. N. Roby

In the course of the Bureau of Mines investigations for suitable sources of high-aluminum clay for the production of alumina, the Whiteware clay deposit was examined in August 1942 by G.N. Bennett, mining engineer, Bureau of Mines, Montana District Office. This report presents the factual data obtained by the investigation, which also includes data on trenching and drilling, and the results of some refractory tests and chemical analyses of representative samples of the clay later taken from some of the best trench exposures and from adit dumps.

Jan 1, 1949

By A. C. Richardson

During the past two and a half years the U. S. Bureau of Mines and the University of Alabama, with the cooperation of the different coal operators, have been making an extensive study of coal preparation in the State of Alabama. Considerable time has been devoted to the study of the washing characteristics of the Mary Lee bed and the various methods used in preparing from it a low-ash coal suitable for the manufacture of metallurgical coke. One of the phases of this problem is the utilization of middlings products from the washing plants. This paper gives the results of treating jig middlings on a coal-washing table at the Bureau of Mines laboratory at Tuscaloosa, Ala. The sample used was secured from the Sayreton washery Of the Republic Steel Corporation, Sayreton, Ala.

Jan 1, 1931

By Larman J. Heath

Preliminary results of an explosive fracturing-solvent injection heavy oil recovery experiment conducted by the Bureau of Mines at a shallow oil reservoir near Bartlett, Kans., are given. Three wells 35 to 50 feet apart were drilled to a depth of 360 feet, and an open hole interval from 300 to 350 feet in the Bartlesville Sandstone Formation was explosively fractured with 3,000 pounds of pelletized TNT in each well. Laboratory tests were made on cores obtained from these wells to confirm the suitability of using an aromatic-type solvent. Injection of a 74-percent aromatic solvent was begun into one well and continued intermittently for approximately 2 months. Crude oil production amounted to 29.6 bbl, or 11.7 percent of the total oil con¬tained within the three-well interwell zone.

Jan 1, 1972

By N. S. Dalal, X. Shi

While it is known that vanadate and related compounds of pentavalent vanadium ( V (V)) exert potent toxic effects on a wide variety of biological systems, the underlying biochemical mechanism is still not fully understood ( 1- 3). One of the pathways is thought to involve the oxidation of NAD ( P) H. Thus, considerable effort has been devoted to finding the mechanism of NAD ( P) H oxidation by Vcvi (1-15). Erdmann et al. (5) first noted that vanadate stimulated the oxidation of NADH by plasma membranes and attributed this effect to a membrane containing NAD(P)H-dependent V(V) reductase. Later studies by Liochev and Fridovich indicated that endogenous superoxide ( 02 ) plays a central role in this reaction ( 4, 12, 13) . They proposed that NAD ( P) H dehydrogenases or oxidases produce 02, which causes VCV ) to stimulate NAD ( P) H oxidation via the following free radical chain mechanism ( 4, 12, 13) :

Mar 1, 1992

By C. N. Adams

The purpose of this investigation was to evaluate the physical and mechanical properties of high-purity titanium made by two processes. Sodium-reduced metal with 58 Brinell hardness number (B.h.n.) and electrorefined metal with 60 B.h.n. and 70 B.h.n. were used. Titanium of these hardness levels did not work-harden excessively, and beyond 40 percent cold work the hardening effect was not great. Rapid softening occurred when the metal was annealed at temperature between 300° and 600° C. Full annealing, as determined by property and microstructure studies, was accomplished after 30 minutes at 700° C. A recrystallization diagram is presented which is based on determinations of annealed grain size as a function of rolling reduction and annealing time. For reductions of less than 20 percent, exaggerated grain growth occurred during annealing; for reductions greater than 20 percent, the variation in grain size for each annealing temperature was minor.

Jan 1, 1961

By Phillip R. Moyle

A cobalt/manganese occurrence in Clark County, Nevada was the subject of a site-specific mineral investigation by the U.S. Bureau of Mines in 1988-90. The study site is in the northern part of the Million Hills (wilderness) study area which is administered by the Bureau of Land Management. Field work during a period of one week consisted of geological mapping and sampling of workings and outcrops, and geochemical and geophysical surveys conducted on four transects totalling 7,600 ft. Although the concentrations of cobalt (0.1 to 0.5 percent) detected in samples from the fissure zones are within the range of grades associated with world-class economic deposits, the volume of material enriched in cobalt at the study site is insufficient to warrant consideration as a potential resource. Concentrations of manganese, nickel, copper, lead, zinc, barium, and thallium, although anomalous, are too low for economic consideration. At the study site, workings consist of three trenches and nine pits. The exploration history is unknown, and no production is reported.

Jan 1, 1990

By Halagowder Devaraj, Mostafa Sheykhnazari, Veer P. Bhavanandan

"A sensitive colorimetric assay for detecting mucins and glycoproteins rich in 0-glycosidically linked saccharides is reported. The method combines the susceptibility of N-acetylgalactosamine terminating 0-glyco idically linked saccharides to P-elimination with the Morgan-Elson reaction for N-acetylhexosamines with free reducing ends. All mucin and mucin-type glycoproteins but none of the serum-type glycoproteins tested resulted in characteristic color production. All mucins tested gave linear responses in the range 5 to 200 ""g and the assay was also adapted to the microscale involving the use of 96-well microtiter plates. The microassay in which the volumes of samples and reagents are scaled down 2.5-fold was particularly useful in monitoring of mucins, in the presence of other glycoconjugates, in large numbers of samples obtained during fractionation procedures. Cesium chloride, cesium bromide, potassium thiocyanate, and various detergents do not interfere with the colorimetric determination. Guanidine hydrochloride, cesium triftuoroacetate, and B-mercap- . toethanol decreased color by 30 to 45%; however, the interference was not serious to prevent the use of the method for detection of mucins in their presence. The use of the method for the specific detection of mucin during fractionation by gel filtration and density gradient centrifugation of cystic fibrosis sputum samples is demonstrated. Mucins are an important class of biomacromolecules whose structure-function relationship is poorly understood (1,2). The investigations of mucins are hampered by difficulties in purifying these very large size molecules which appear to avidly bind other components of the mucus (3,4). One of the problems during purification is the specific detection of mucins. For example, during the various purification steps, the fractions containing mucins are typically detected by assaying for neutral sugars (hexoses) (5,6), for sialic acids (7), or for periodate oxidizable saccharide units (8). However, these methods are not entirely satisfactory because neutral sugars, sialic acids, and periodate-oxidizable saccharides are also components of other glycoconjugates. In addition, the neutral sugar and sialic acid measurements are also subject to interference from high levels of proteins and nucleic acids."

Jan 1, 1990

By C. A. Komar

Laboratory-scale hydraulic fracture tests were conducted by the Bureau of Mines on directionally oriented sandstone material, along with measurements of directional rock properties such as tensile strength, permeability, ultrasonic velocity, and dynamic elastic constants. In these tests, fracture orientation was determined as a function of various combinations of stress, rock saturation, rate of borehole pressurization, and direction of minimum tensile strength relative to minimum horizontal compressive stress. The objective of the experiment was to investigate whether horizontal stresses always controlled the orientation of induced vertical hydraulic fractures, or if under conditions of small differences in stress and/or slow borehole pressurization rates, the induced fracture direction was influenced by directional properties of the rock matrix. This study shows that the expected influence of horizontal earth stress on the orientation of an induced hydraulic fracture becomes negligible when¬ever the magnitude of the difference between the compressive stresses is 200 psi or less. When this occurs, fracture orientation is controlled by the directional properties of the rock--primarily permeability and tensile strength.

Jan 1, 1973

By David N. Montgomery

The characteristics of a closed cavity acoustic coupler were measured. Various configurations were investigated to determine their feasibility for use in a portable audio dosimeter calibrator.

Jan 1, 1976

By D. Harry Chambers

The Bureau of Mines, through a memorandum of agreement with the Department of Defense, conducted research to recover silver from aircraft scrap. Silver was recovered by an electrolytic method from stainless steel honeycomb sections separated from the aircraft. These sections had been constructed by sandwiching a stainless steel honeycomb core between stainless steel sheets and then brazing the assembly with a silver alloy. Over 300 pounds of silver was used in the B-58 bomber, concentrated in certain honeycomb sections of the aircraft. Following shredding of the aircraft parts, an average of 95 percent (ranging 67 to 100 percent) of the silver was recovered in a single electro-refining step. After the electrorefined product was magnetically cleaned, purity of the recovered silver was greater than 99.3 percent.

Jan 1, 1980

By John E. Kelley

A method for measuring the spark-shower radiance of metals when abraded on a grinding wheel was developed by the Bureau of Mines for evaluating the sparking tendency of metals. The radiance was measured in units of emissive power per solid angle per area of the detector. Over 100 metals were tested and rated relative to commercially pure iron. The metals tested included elemental metals, iron binary and ternary alloys, iron-carbon ternary alloys, commercial steels, nonferrous alloys, and a few hard-metal compounds. Some alloys were synthesized; others were obtained commercially. Alloys that possessed good strength properties were emphasized for selection. The results indicate that the spark-shower radiance of plain carbon steels and carbon alloy steels was greater than that of pure iron. Certain elements, particularly vanadium and chromium, reduced the sparking tendency of iron. Stainless steels and particularly nickel alloys displayed low spark-shower radiance. Some metallic elements had much lower radiance than iron; others, much greater. Plain carbon steels, heat treated to a variety of hardnesses, gave radiance values that generally increased with increasing hardness. The effect on sparking tendency of an increase in hardness of an alloy steel was studied. The sparking tendency increased with an increase in hardness to a maximum, then decreased with a further increase in hardness.

Jan 1, 1974

By F. E. Joyce

This paper describes the development of a process for producing manganese and iron pellet concentrates from low-grade manganiferous iron ores of the Cuyuna range by a two-stage sulfatization-reduction roast. First, the manganese minerals (7.5 percent manganese) were converted to water-soluble manganese sulfate by roasting in sulfur oxide gases at 700° C, then, the hematitic iron minerals (31 percent iron) in the hot sulfatized are were reduced to magnetite with simulated reformed natural gas in the temperature range of 350° to 425° C. Batch tests were made in a 3-inch-ID by 6-inch-long, gas-heated, stainless steel retort, and continuous countercurrent experiments were performed in a 2-inch-ID by 10-foot-long, electrically heated shaft furnace. Manganese sulfate was removed from the roasted product by leaching with water, and over 90 percent of the manganese was recovered in an oxide product (65 percent manganese) obtained by precipitation, drying, and thelmal decomposition of the sulfate. An iron oxide concentrate (60 percent iron) with an iron recovery of 75 percent was obtained from the water-insoluble residue by magnetic separation.

Jan 1, 1973

By Fred Leighton

The Bureau of Mines has developed rock noise source location techniques that may be used to obtain precise and practical source locations from micro-seismic field data. These techniques enable one to monitor all or any part of a rock structure and map progressive stress buildup or rock movement. Thus, the microseismic method of determining instability in rock structures is becoming an invaluable engineering tool for the mining or civil engineer engaged in rock excavation and construction.

Jan 1, 1970

By Stephen C. Tadolini, Thomas M. Barczak, Paul McKelvey

A new generation of hydraulic mine support prestressing devices has been developed. These thin-walled steel shells are machine-welded and can be inflated with water or any liquid to provide prestressing for a wide variety of roof support products ranging from Can supports to props and cable bolts. With an expansion capability of several inches, depending on the geometry and size of the unit, they can also establish roof contact eliminating the need for wooden wedges or crib blocks that are commonly employed with several standing roof support products. Capable of withstanding pressures from 1,000 to 6,000 psi, these cells are able to transfer roof loading into the support structure without rupturing. A recent development has been the addition of an inexpensive yield valve that provides control of the maximum pressure and load development on the support. This paper examines the performance capabilities of these inflatable prestressing units and the impact they have on the performance of various support systems, including an evaluation of the overall stiffness of the support system and the load control during yielding of the prestressing unit. Recommendations are made regarding the design requirements of the prestressing unit to optimize the support performance. A summary of mine applications using this technology is provided with general comments regarding their impact on ground control.

By R. O. Dannenberg

The Bureau of Mines conducted laboratory batch and small-scale continuous tests to remove traces of dissolved molybdenum from water simulating waste discharged from a molybdenum concentrator, Molybdenum concentrations, initially ranging from 2 to 10 ppm, were decreased to 0.5 ppm or less by coprecipitation of the molybdenum with freshly precipitated ferric hydroxide" The precipitate was separated as a froth by dissolved-air flotation for subsequent disposal. Although the treated water met current environmental standards for contained molybdenum, contained particulate iron might have to be removed by filtration for the water to be acceptable. Estimated costs for treating concentrator effluent water were 55 cents, 57 cents, and 64 cents per 1,000 gal at initial molybdenum concentrations of 2, 4, and 10 ppm, respectively.

Jan 1, 1982