Search Documents

By Wm. W. Adell

"These hydrocarbons belonging to the same chemical series as methane, having the general formula CnH2n have many chemical properties in common with methane and their addition to a lean gas charges the properties and burning characteristics of the gas in the same general direction although to a different extent. The hydrocarbons of this series do not readily enter into chemical reaction with other substances and therefore are incapable of combining with oxygen or polymerizing in the disturbing system and thus cannot cause gum and room troubles commonly met with in the distribution of manufactured gas.As the number of carbon atoms in the molecule increases, i.e. in proceeding from methane throughout the series, the oxygen requirements for the complete combustion of unit volume of the gases also increases; in other words, the calorific values of these hydrocarbons (as gases) increases from methane. Similarly the specific gravity increases from methane in the same order. In Table 1 are shown some of the physical constants and properties of a few of these hydrocarbons which hive bearing on their use for enriching gas."

Nov 1, 1927

By W. D. Monaghan, G. L. Mowrey, C. W. Ganoe

In addition to developing various types of coal-interface detection system, the US Bureau of Miner is actively in involved in developing a coal rib-thickness monitoring system for highwall mining applications. One particular system that shows promise in a ground-pentetrating radar system to detect the coal-air boundaries of coal rifts. Based on preliminary laboratory and field tests results indicate that this method can be applied successfully in highwall mines to maintain constant rib thickness. The coal seam should be relatively clean in the vicinity of the antenna (e.g., have minimal partings or dirt bands) for best results.

Avoid errors in determining the amount of trace elements in overburden when core drilling samples, particularly as required by PL 95-87, the Surface Mining Control and Reclamation Act of 1977. Reason Metal additives present in certain drill stem joint lubricants appear to contaminate overburden samples. If these lubricants are used in assembling the drill string, they can interfere with the analytical methods used to establish concentration of trace metals. Errors In trace element determination appear to be as much as 30 times true concentration, and may falsely Indicate that the amount of trace element in the overburden exceeds the

Jan 1, 1981

By Robert H. Lambeth

The Madison RARE II study area has four prospects with identified resources. These are listed in table 1 and are described in the following text. A high potential for Sillimanite exists at the Placer Creek occurrence (fig. 1, no. 7) and potential for phosphate rack in all areas underlain by the Phosphoria Formation. Some prospects exhibit minor potential for copper, lead, zinc, silver, and gold in the southern portion and very minor potential in the northern portion. Deposits in the northern end also have low potential for rare earth, asbestiform anthophyllite, or kyanite group minerals (including sillimanite).

Jan 1, 1982

By E. P. Carman

This report is the 19th in a series summarizing Bureau of Mines research and technologic work on coal and related investigations. The first 17 reports covered fiscal years; however, the 18th report3/ covered the 18 months from July 1, 1952, to December 31, 1953, to permit the publication of this and subsequent reports on a calendar-year basis. Most of the material in this report relates to publications by Bureau authors issued during the reporting period. Some work is referred to on which the results have not yet been published or may not be published for security or other reasons. In a few instances publications are mentioned that were issued before the reporting period but were not included in previous reports. Further details on the published work described herein may be found in the publications cited in the footnotes. Research and technologic work on coal by the Bureau is directed toward developing and encouraging increased conservation of coal resources through safer and more efficient mining, preparation, and utilization. Significant advances were made during the year in these fields, particularly in coal-mine safety and in preparation and utilization of the various ranks of coals.

Jan 1, 1956

By Joseph Cervik, Maurice Deul, Albert Sainato

This Bureau of Mines report deals with water infusion of coalbeds, which can control methane emission at face areas during developmental mining and which may sometimes suppress dust. Studies show that water infused into the coalbed flows through the fracture system and displaces the methane in the fractures and prevents migration from the solid coal. Displaced gas migrates away from the face area that has been water infused and enters the return ventilation airways. A gradual decrease in methane emission is observed from the start of infusion until the infused zone is mined through. Depending on the permeability of the coalbed, infusion pressures ranged from 300 to 2,200 lb/in2. Face emissions in the Upper Kittanning coalbed were reduced by 89 pct; reductions of 38 to 79 pct were measured in the Pittsburgh coalbed depending on the relationship between the face cleat direction and mining direction. Respirable dust levels were reduced by about 75 pct on a longwall section in the Pocahontas No. 3 coalbed and by about 50 pct on a development section in the Upper Kittanning coalbed, but no statistically reliable reduction was found in the respirable dust levels in the Pittsburgh coalbed.

Jan 1, 1977

By Charles Vaught, Kathleen Kowalski

Emergency personnel, like all workers, carry out their duties within an environment composed of a set of discrete elements. First, there is the emergency itself. Whether a forest fire in France, a tornado in the American Midwest, or a mining disaster in Russia, the emergency imposes certain exigencies upon the responders. Second, a social structure exists with specific social units, rules, and forms of association. An emergency response, therefore, takes place within a context of prescribed behaviors, expectations, and value judgments that are sometimes in conflict with each other. Third, there is a technology that must be understood in order to accomplish group goals. If the technology itself is implicated in the emergency, the entire emergency environment may be impacted. Clearly, a breakdown in any of these elements could result in worker injury and might heighten responder stress. This paper discusses how emergency workers not only get injured but may come to experience bum-out, post-traumatic stress syndrome, or impaired work and family relationships, even though their normal work setting (the emergency) is expected to be 'abnormal'. The authors suggest areas in each of the three environmental elements that, deserve further inquiry.

By Sabri Ergun

The method of constant compositions involves the determination of the time required for the attainment of a given conversion at various temperatures. Heretofore, it has been used in evaluating the energy of activation only. A development of the method, made in the present study, makes possible the evaluation of the functional dependence upon composition and the frequency factor in addition to the energy of activation. INTRODUCTION Kinetics of reactions are best analyzed in the light of the mechanism, energy requirements, and forces involved in the reaction. Such physico-chemical information is not often available in solid state phase transformations. The reaction rates are followed by changes in a physical property during the course of the reaction, and repeating the experiment at different temperatures permits the determination of activation energy only. The possibility of a complete kinetic analysis by such a purely "phenomenological" approach has been questioned.4/ In this report a method is developed making possible the evaluation of the functional dependence upon composition and frequency factor in addition to the energy of activation. The application of the method to a study of solid state order-disorder changes is demonstrated.

Jan 1, 1960

By Knox Van Dyke, Vincent Castranova, Lixin Wu, Mark J. Reasor, James M. Antonini

"One of the proposed mechanisms involved in the pathogenesis of silicosis is that inhaled silica dust activates a ""respiratory burst"" in pulmonary phagocytes, such as macrophages and neutrophils. This increase in oxidative metabolism results in enhanced generation of reactive oxygen species which if produced in excess, would overwhelm natural defense mechanisms and cause damage to the lung parenchyma. This damage would then result in scarring, fibrosis, and decreased gas exchange.Weiss and LoBuglio' have listed several oxygen species produced by phagocytes which may be involved in cellular injury. These oxidants include superoxide anion, hydrogen, peroxide, hydroxyl radical, and hypochlorous acid. Superoxide anion (0;) is generated from molecular oxygen by the plasma membrane bound enzyme NADPH oxidase according to the following reaction:Once generated, superoxide anion can form hydrogen peroxide:In the presence of myeloperoxidase and halide, hydrogen peroxide can form hypochlorous acid:Superoxide and hydrogen peroxide can also form highly reactive hydroxyl radicals. Hydroxyl radicals can be generated slowly by the Haber-Weiss reaction:In addition. hydroxyl radical production can be catalyzed via the Fenton reaction:Hydroxyl radicals can also be generated from the reaction of superoxide and hypochlorous acid as follows:Recent investigations suggest that, in addition to the reactive oxygen species discussed above, nitric oxide may be a potential mediator of silica-induced toxicity.2-4 Nitric oxide (NO') can be generated by the cytosolic enzyme nitric oxide synthase according to the following reaction:NO synthase exists in two forms. i.e.. a constitutive. Ca2+-calmodulin-dependent form and an inducible. Ca2+-calmodulin-independent form. In pulmonary phagocytes. the activity of the constitutive form of NO synthase is low. However. NO synthase can be induced in macrophages and neutrophils by a variety of stimulants such as lipopolysaccharide. interferon y. chemotactic peptide, platelet activating factor, or leukotriene B4.3.5Once generated. nitric oxide can combine with superoxide anion to form peroxynitrite as follows:Peroxynitrite is a potent oxidizing agent. In addition, peroxynitrite can form peroxynitrous acid. which in turn can produce hydroxyl radical and nitrogen dioxide (all of which exhibit strong oxidizing potential) by the following reactions:Oxygen metabolites have been shown to cause lung damage in vivo.6 Such damage includes edema. leakiness of the alveolar endothelial/epithelial barriers, and airway constriction.7 Superoxide and hydrogen peroxide have been associated with membrane damage and cell lysis.8 These oxidants have also been associated with alteration of cytoskeletal structures at cell-cell junctions and elevation of transepithelial conductance in cultured monolayers.9 Macrophages or neutrophils can be stimulated by bacteria or phorbol myristate acetate to produce sufficient oxidant levels to lyse lymphoma cells.10 This cell killing is inhibited by catalase but is unaffected by superoxide dismutase. hydroxyl radical scavengers. or azide. i.e., an inhibitor of peroxidase. This implicates hydrogen peroxide as the active oxidant. Similarly. Weiss et al.11 have reported that hydrogen peroxide is critical in the death of cultured endothelial cells due to neutrophil activation. In addition. hydroxyl radicals generated by monocytes have been associated with cell injury.12 Lastly. peroxynitrite has been shown to oxidize sulfhydryl groups and to inactivate proteinase inhibitor making the lung more susceptible to damage caused by phagocytotic enzymes.' Therefore. a strong case can be made that activated pulmonary macrophages and neutrophils are capable of causing oxidant injury. This chapter presents in vitro and in vivo data indicating that silica is associated with the production of reactive oxygen species from these pulmonary phagocytes."

Jan 1, 1998

By M. J. Ankeny, J. J. Forbes

Several sets of questions and answers on the fundamentals of first aid to the injured, based on the Manual of First-Aid Instruction of the United States Bureau of Mines, are now in use in various parts of the United States. Persons experienced in first-aid instruction believe that a standardized set of questions and answers will assist materially in preparing men for examin- ations conducted by the Bureau for first-aid certificates. Inquiries as to whether a set of standardized questions and answers is available have been made frequently by those training men for the Bureau of Mines examination for certificates. It is believed that the following list of 171 questions and answers com- piled directly from the manual will be useful to company officials and em- ployees who are engaged in cooperative first-aid training to qualify for Bureau of Mines certificates. The list may also be used by field men of the Bureau in training instructors preparatory to a cooperative training campaign and in examining classes or individuals for first-aid certificates. The page references in parentheses refer to pages in the Manual of First-Aid Instruction.

Oct 1, 1935

By Madan M. Singh

Hydraulic mining has been practiced in the United States since 1852 and many mineral commodities, such as gilsonite, phosphates, lead-zinc, silver ores and St. Peter Sandstone can be mined in this manner. In 1958, the U. S. Bureau of Mines initiated research into the mining of coal using these techniques.1-4 These early investigations were conducted in the 5000 psi pressure range. The large nozzle diameters used in this pressure range produced extremely high flow rates which created visibility problems at the coal face, and required removal of large amounts of water from the mining area. Besides, the production rates were not much better than with mechanical methods. This indicated that with higher pressures the water quantities might be reduced using the same or higher horsepowers but enhanced breakage. For this reason intensive investigation in material removal using fine water jets at extremely high pressures (50,000 psi to 100,000 psi) has been undertaken. This was not the entire reason for this contract from the Bureau of Mines, however. The contract objective is outlined later. IIT Research Institute has done pioneering work in high pressure jet development in the United States.5-8 Similar schemes have been investigated abroad. 9-13 Hydraulic mining of coal at relatively low pressures is successfully being done in the Soviet Union, Japan, Canada, and most recently, in Germany.

Jan 1, 1973

By John C. Machisak

The Nation's mining and quarrying industries have again met the annual challenge to their ingenuity--that of reducing disabling work injuries among their employees. The effectiveness of management in facing this problem and in meeting this responsibility from the results of the 1961 National Safety Competition. Three hundred ninety-three or 45.3 percent of the mines and quarries participating in the competition established a new record number of participants operating throughout the competition year without a disabling work injury. Another record established in the 1961 contest was the number of participants (868) enrolled in the competition. This annual safety competition was begun in 1925 and is conducted by the Bureau of Mines, U.S. Department of the Interior. It provides for six bronze Sentinels of safety trophies which are awarded each year to the winning participant in each group. Since its inception, the competition has exerted a strong influence in the field of safety promotion. The statistical record of its accomplishments over the years gives strong support to the theory that well-organized and well-administered safety programs are effective tools to be used to reduce the number of disabling work injuries. It stimulates and holds the interest of employees and management in accident prevention. Because of this, mines and quarries participating in the contest have a more favorable safety record than those operations not enrolled.

Jan 1, 1963

By John C. Machisak

The Nation's mining and quarrying industries have again met the annual challenge to their ingenuity--that of reducing disabling work injuries among their employees. The effectiveness of management in facing this problem and in meeting this responsibility is evident from the results of the 1961 National Safety Competition. Three hundred ninety-three or 45.3 percent of the mines and quarries participating in the competition established a new record number of participants operating throughout the competition year without a disabling work injury. Another record established in the 1961 contest was the number of participants (868) enrolled in the competition. This annual safety competition was begun in 1925 and is conducted by the Bureau of Mines, U.S. Department of the Interior. It provides for six bronze Sentinels of safety trophies which are awarded each year to the winning participant in each group. Since its inception, the competition has exerted a strong influence in the field of safety promotion. The statistical record of its accomplishments over the years gives strong support to the theory that well-organized and well- administered safety programs are effective tools to be used to reduce the number of disabling work injuries. It stimulates and holds the interest of employees and management in accident prevention. Because of this, mines and quarries participating in the contest have a more favorable safety record than those operations not enrolled.

Jan 1, 1963

By Eugene Frey

The Romur is one of several properties in the Copper Mountain mining district, Fremont County, Wyo., that contain scheelite deposits. The district lies on the southern slope of the Bridger Mountains, 18 miles northeast of Shoshoni and 15 miles from the rail point at Bonneville on the Chicago, Burlington & Quincy Railroad (figs. 1 and 2). The tungsten deposits occur in a zone of pre-Cambrian schists and gneisses that have been cut by numerous basic dikes and granite pegmatite dikes. Scheelite occurs in lenses and pods that lie parallel to the foliation and bedding in the metamorphic rocks. The more important deposits are found in a lime-silicate rock consisting primarily of zoisite but with small quantities of quartz and carbonate. Scheelite was found in December 1941, and the area was mapped by the U. S. Geological Survey early in 1942. In November 1942 the Bureau of Mines commenced work on the Stardust-Comet group for the purpose of developing reserves for war requirements. The initial work consisted of driving an alit in the ore zone a distance of 109 feet. This zone was sampled during the progress of the work, and subsequently surface and underground exposures on adjoining properties also were sampled (figs: 5, 6, 7, and 8). One hundred twenty-four samples were obtained. Sample and assay data are shown in tables 2, 3, and 4.

Jan 1, 1950

By Scott Turner

We have gathered here in Pittsburgh, at the Nineteenth Annual Safety Congress, in order to advance the cause of safety. Although my personal inter- est in this movement alone would have been sufficient to insure my presence here, specific duties have brought me to this congress in an official capacity. My responsibilities as the head of the United States Bureau of Mines, which makes the promotion of safety in the mining and allied industries one of its major activities, necessitate my attendance. My obligations as president of the Joseph A. Holmes Safety Association, an organization closely allied to the bureau and which has for one of its objects the public recognition and reward of outstanding achievements in safety, require that I be present at this time. This morning, my job is to present the Holmes safety certificate to the Lehigh Portland Cement Co. First I will remind you of the nature of this safety association, named in honor of the first director of the Bureau of Mines. After Mr. Holmes' death, in 1915, a number of influential organizations banded together to commemorate the name of this leader in the conservation of human life. In order that you may appreciate the significance of an award by the Joseph A. Holmes Safety Association, I shall read you the list of 24 national organizations which comprise its membership:

Nov 1, 1930

By W. E. Wallace, P. Bolsaltis, M. J. Keane, B. L. Rauaboni

Thermal treatment of respirable size silica dust samples results in marked changes in their hemolytic activity. These changes can be correlated with changes in the characteristics of the particle surface as measured by infrared spectra, zeta potentials, and specific surface area. Silica samples from various sources (Min-U-Sil, fumed silica, and a NIOSH standard sample) were heated or calcined at temperatures ranging from 100-1095C. The hemolytic activity of the crystalline materials decreased after thermal treatment. The behavior of the fumed material was found to be more complex. Material of very large surface area (small particle size) exhibits an initial increase in hemolytic activity upon calcination. This result confirms other experimental observations pointing to a particle size of maximum toxicity. Tre changes in hemolytic activity can be related to infrared spectra and zeta potentials of the materials. The absorption band in the 3200-4000 cm-1 frequency region of the fumed material disappears upon heat treatment while a sharp, characteristic band at 3750 cm-1 increases in intensity. Zeta potential measurements conducted in the pH range of 2.0-10.5 exhibit a unique change in zeta potential v.s. pH profile with heat treatment. These findings indicate that the removal of active surface silanol groups by calcination results in reduced cytotoxicity, as measured by a hemolysis test.

Jan 1, 1988

By Travis Q. Lyday

Gold continued to dominate mineral production in the group of volcanic islands and atolls of Melanesia in the southern Pacific Ocean, which comprise the British Commonwealth nation of Fiji. The Fijian mineral sector, however, remained of minor importance in terms of export earnings, Government revenues, and employment to the economy of the country, which was primarily agrarian with sugar as its mainstay. The Vatukoula gold-silver mine on the north side of the main island of Viti Levu remained the largest and most important mining operation, as well as Fiji's only operating metalliferous mine. In October, Western Mining Corp. (Fiji) Ltd. (WMCF), a wholly owned subsidiary of Australian-registered Western Mining Corp. Holdings Ltd., increased its interest in the Vatukoula joint venture from 10% to 20% by exercising its option with Emperor Gold Mining Co. Ltd., also of Australia. The assumption of mine management operations at Vatukoula in 1983, with its attendant influx of additional capital and technological expertise, enabled WMCF to increase both efficiency and output at the mine during 1984. Higher output was obtained owing to an increase in underground ore production, which was partly offset by a reduction in opencut tonnage, as well as to modifications in the recovery circuit. Rate of recovery increased from about 15% to over 82% of the gold contained in the ore and from about 40% to 45% of the contained silver.

Jan 1, 1986

Provide a means of evaluating the in place structural properties of coal seams and coal measure rocks in advance of mining. Approach Develop a sonic logging probe for use in dry wells, a condition common to shallow wells and semi-arid coal regions. How It Works The Bureaus' sonic probe differs from conventional sonic probes because it does not require fluid in the well to couple sonic vibrations to the drill hole wall. A self-contained hydraulic system forces pistons containing the measurement transducers against the wall and clamps them in position until the sonic waveform information has been recorded. The pistons are then retracted and the probe is raised or lowered in the well as required. In the clamped position, the piezoceramic transmitter emits a sonic pulse which travels along the drill hole wall and is detected at the receivers in the form of compressional (P) and shear (S) wave motion. The receivers are designed to be sensitive to either the (P) wave or (S) wave motion as determined by the operator so that discrimination between the two wave types is improved by comparison of the respective output channels, and the travel time between transmitter and detectors can be accurately determined. Use of two receiver stations eliminates errors in timing of pulse travel because of electronic delays inherent in the probe.

Jan 1, 1981

This chapter summarizes data on crude mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are tables that show the principal mineral commodities exported from and imported into the United States, and that compare world and U.S. mineral production. Except for the mineral fuel commodities, the detailed data from which these tables were derived are contained in the individual commodity chapters of volume I and in the State chapters of volume II of this edition of the Minerals Yearbook. In October 1977, responsibility for the collection of data on mineral fuels-coal, petroleum, natural gas, and natural gas liquids-was transferred to the newly created Department of Energy. Although chapters covering these commodities will no longer appear in Volume I of the Minerals Yearbook, quantity and value data have been included in most of these summary tables to maintain statistical consistency in State and national value of overall crude mineral output. This shift in responsibility has also resulted in changes to the composition of the "Nonmetals? and "Mineral Fuels" groups in table 1 and table 2. The commodities-asphalt and related bitumens (natural), carbon dioxide (natural), helium, and peat-have been removed from the ?Mineral Fuels" group, and are now included under the "Nonmetals" group. There has been no change in the components of the "Metals" group.

Jan 1, 1981

By R. Havens

During investigations of the occurrence of manganese in the western United States in the early 1940?s, examining engineers of the Bureau of Mines collected samples from seven claims and mines in southern Arizona. For convenience in reporting the results, the work on the properties is grouped in three districts. As the ores were too low grade to be acceptable to producers of ferromanganese, beneficiation studies were made to determine the amenability of the ores to concentration. The San Fernando group is about 10.5 miles south of Patagonia in the Harshaw mining district. G. T. Humphries and D. Alonso held an option on the property, which was owned by H. Bender. Two samples were taken; 1 was a picked sample and the other a representative sample of ore as exposed in the mine.

Jan 1, 1954