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By K. C. Dean

Discarded automobiles represent the greatest single resource of reusable metals, plastics, and rubber in the United States. This report presents results of Bureau of Mines research, conducted from 1965 to 1983, on separating and recovering useful materials from the scrapped hulks, using old and new metallurgical techniques combined with standard scrapyard methods. The Bureau determined the materials composition of three composite cars designated as circa 1960, mid-1970's, and early 1980's, and used these cars to study smokeless incineration and hand-sorting techniques. In studies on treating rejects from automobile shredders, the Bureau designed a process that included air classification, water elutriation, magnetic separation, handpicking, and heavy-medium separation, and also investigated cryogenics and liquation. Complete recovery of cop-per and other metals was economically made by hand and tool dismantling, leaching, or selective melting of starters and generators. Techniques are also discussed for plastic recovery and waste tire treatment.

Jan 1, 1985

By C. H. Fisher

Coal carbonization, the basis of a major industry, consists in heating coal in the absence of air at various temperatures (ranging from 500° to 1,000° C.) that are selected according to the kind of products desired. During this treatment, the complex organic substances that comprise the major part of the coal are converted into several useful products that are quite different from the original material. The principal products of coal carbonization or distillation are coke and gas. These products, as well as others of which lower yields are obtained (light oil, tar, and ammonia), occupy an important place in present-day commerce and civilization. This paper is concerned with the composition of the tar and light oil, which, as complex mixtures of organic compounds, are the source of many important dyes, inter-mediates, medicinals, resins, etc. The volatile products obtained when bituminous coals are destructively distilled or carbonized are tar, aqueous liquor, and gas. These products vary in composition and properties, depending on the nature of the coal and the temperature and conditions of carbonization. The tar is a dark, rather thick and viscous liquid at ordinary temperatures, becoming semisolid when cooled to the freezing point of water. The aqueous liquor (chiefly water) contains several inorganic substances and certain organic compounds, which, because of their solubility characteristics, have been extracted from the tar. The carbonization gases consist chiefly of carbon dioxide, carbon monoxide, hydrogen, hydrogen sulphide, ammonia, methane, ethane, ethylene, and several hydrocarbons of higher molecular weight. The hydrocarbons of higher molecular weight (benzene, toluene, xylene, etc.) may be re-moved as liquids from the gas by suitable means. This liquid and the first fractions obtained on distilling the tar are known as light oil.

Jan 1, 1938

By Slavoljub Makslmovic

One important element of the U.S. Bureau of Mines computer-assisted mining research program is the development of a reliable coal interface detection (CID) system. Several candidate CID concepts currently being investigated by the Bureau include use of natural gamma radiation (NGR), vibration, passive infrared, video, and radar. To help establish which CID sensor technologies need to be developed for a given seam, the Bureau has collected geological and mining practices data from over 460 underground and surface mines in the United States. Also, over 500 coal and rock samples have been obtained for laboratory analyses of ash content, sulfur content, heating value, and NGR. The Bureau's findings indicate that the immediate roof strata in 81% of the underground mines and 93% of the surface mines are made up of shale, draw slate, or claystone. The immediate floor strata in 88% of both the underground and surface mines consist of fireclay, shale, draw slate, or claystone. The results of the NGR testing indicate that the NGR method appears to be a potentially useful CID tool, provided that the immediate roof and floor are both composed of a high percentage of shale-type material.

Jan 1, 1993

By B. H. Clemmons, B. G. Saunders, R. H. Stacy

"INTRODUCTION This investigation was undertaken to determine the response of Birmingham (Alabama) red-iron ore to heavy-medium concentration. Specifically, the work involved a study of the efficiency of the process in separating coarse gangue diluents from the ore and an endeavor to evaluate the potential economic results. The investigative work was not intended, nor is it to be construed, to be adequately exhaustive in scope to enable immediate plant construction. Rather, the primary objective was to determine the grade of ore that could be produced by heavy-medium treatment and the resulting indicative or tentative benefits to be derived from such treatment. The latter, in turn, would determine the merits of the more exhaustive study that would be required for an ultimate decision on the heavy-medium treatment of the ores.The problem of avoiding excessive contamination of red-iron ores by shale and/or ferruginous sandstone has been before the operators of the iron mining industry of the Birmingham, Alabama, district for many years. Within the last two decades, increased mechanization of mining methods has increased this contamination to a considerable degree. In fact, general utilization of scraper loading and other mechanical methods of mining, in conjunction with small increases in the natural insoluble content of the ores, in some cases has actually resulted in the production of ""acid"" or excessively insoluble ore, where ""basic"" or excessively lime ores were produced formerly.The contaminating materials are derived largely from roof spells and natural parting seams in the ore, a condition that to some extent has been aggravated by the irregularity of the ore beds. The latter have been subjected to both primary and secondary folding in many places. Considerable faulting has taken place, also. In many localities these conditions render virtually impossible complete avoidance of ore contamination from the over and underlying sandstones and shales. However, in a few localities, where the ore beds are less disturbed and shale partings are absent, mining can and is being accomplished with relatively little dilution."

May 1, 1948

This final report summarizes the effort on a very aggressively scheduled and demanding development program undertaken by Westinghouse for the U.S. Bureau of Mines under Contract No. H0101262. The objective of this program was to produce hardware and test it to determine the efficacy of certain concepts of Coal Mine Rescue and Survival as established by the request for proposal and the study performed for the U.S. Bureau of Mines by the National Academy of Engineering (NAE). (These are stated in paragraph 1. 1 for reference.) In carrying out this program, Westinghouse provided specific hardware designs in consonance with the objectives of the concepts outlined in the NAE study final report. Though this contract did not require producing final design hardware ready for introduction to the coal mining community, components of the CMR&SS - as delivered - have some value in disaster situations and are to be kept on standby alert. Additional design and production development is required and should be undertaken on most of the subsystems and components before they can be used in the competitive coal mining community.

Jan 1, 1971

This report is the 22d in a series summarizing Bureau of Mines research and technologic work on coal and related investigations.2 3/ A summary of work published during 1957 and of work in progress is presented. Details regarding the subjects treated in the publications may be found by referring to articles cited in the footnotes. The objective of the coal work of the Bureau of Mines is to obtain information that will lead to improved production and utilization of coal, thus conserving a most important national asset.4 5/ Though studies of mining methods and exploration of various coalfields ma; contribute directly to improved production, no less so does the work in health and safety. The many problems relating to chemical and physical properties of coal reflect the need for an understanding of these properties for the most effective use of coal in its various fields of application and for the development of new methods of processing coal. Studies of existing and proposed processes of combustion, carbonization, gasification and hydrogenation of coal are necessary for increased efficiency in its use. Engineering service provided by the Bureau is of direct value in the conservation program in preventing waste. Stations where the main coal activities of the Bureau are carried out are shown in the following list:

Jan 1, 1959

By Stanton L. Tainter

As a part of a wartime program to aid in the development of known ore bodies and in the discovery of hitherto unknown deposits of strategic minerals, the Bureau of Mines investigated the feasibility of diamond-drilling the Christmas copper deposit, in Gila County, Ariz., to increase the reserves of milling ore. Upon recommendation of the examining engineer, drilling was begun in September 1942, from the bottom (770) level of the mine. One month later, in cooperation with the Bureau, the Federal Geological Survey started geologic mapping of the mine workings. Since extensive and costly development would be required, the War Production Board concluded that ore below the bottom level could not be mined at that time because of the wartime shortages of equipment and man-power. In January 1943, drilling was moved to the 300 and 400 levels to locate reserves readily accessible for continued production of fluxing ore. This drilling, which was under the supervision of L. G. Marshall, was completed in January 1944.

Jan 1, 1948

By William W. Adams

Accidents to men employed in the quarrying and related industries of the United States were more numerous, absolutely and relatively, in 1937 than in 1936. Fortunately, the entire increase was in the category of nonfatal injuries, as accidents causing death declined in number and in proportion to the number of man-hours worked. Employment increased. More men were employed, more man-days and man-hours were worked, and the average employee had more hours of work than in 1936. Reports covering all commercial operations showed that 84,094 men were employed an increase of 5.1 percent over 1936. The number of man-hours of work performed by the industry was, 158 millions, an increase of 7.6 percent. Seventy-seven men were killed by accidents, a, reduction of 14 from the year before, and 6,348 men were injured and disabled for more than the remainder of the day on which the accident occurred, 11 percent more than in 1936. The fatality rate of 0.49 per million man-hours of exposure in 1937 compared favorably with the rate of 0.62 for the previous year, whereas the non-fatal-injury rate of 40.10 was 3.2 percent higher than the rate of 38.87 for 1936.

Jan 1, 1940

By William C. Cooley

A literature search and survey were prepared on the technology of surface hydraulic mining, with particular reference to its possible use in the United States forstripping overburden from surface coal mines. Extensive use was made of Russian references which were translated into English. The advantages and disadvantages of hydraulic mining and hydrotransport are identified as well as criteria for selecting potential applications. At present, the major U.S. application is in the phosphate industry of Florida and North Carolina. Potential locations for hydraulic stripping of overburden from coal seams are identified in the states of Alaska, Illinois, Montana, Washington and Wyoming. Other potential applications include the hydraulic mining of peat in Minnesota, and the stripping of overburden from lignite in Texas, Montana, North Dakota and South Dakota. Further research is recommended, particularly on the subject of dewatering of fine clay slimes to avoid water pollution and to permit rapid reclamation of mined areas.

Jan 1, 1976

This volume constitutes the Survival Subsystem portion of the final report for the Coal Mine Rescue and Survival System (CMR&SS) program, which was conducted by the Westinghouse Electric Corporation under contract to the United States Bureau of Mines (Contract Number H0101262 dated June 17, 1970). The program was directed by the Special Systems Department of the Westinghouse Baltimore, Maryland, facility. The basic objectives of the CMR&SS program were to develop and test hardware to determine the efficacy of a variety of coal mine rescue and survival concepts and techniques. These concepts were drawn from two major sources: the Request for Proposal from the Bureau of Mines1 and the final report on the Mine Rescue and Survival Study conducted by the National Academy of Engineering2 (NAE).

Jan 1, 1971

By Ralph H. Whaite

In undermined urban areas, new solutions to subsidence problems are being sought. The Bureau of Mines is investigating a hydraulic backfilling technique whereby fill material is pumped as a slurry through a closed system and widely distributed in inaccessible mine workings from a single borehole. A full-scale demonstration was completed in 1973 in Scranton, Pa., which is underlain by abandoned anthracite mines in several coalbeds superposed one above another. A 30-acre residential area was stabilized by injecting about 450,000 cubic yards of crushed mine refuse into two coalbeds through five injection boreholes. Nearly 200,000 cubic yards was injected through one borehole from which the material moved into the mine workings on all sides; the injected material reached a maximum lateral distance of 640 feet and filled mine openings from floor to roof. In the gravity-feed method formerly used to backfill inaccessible mine workings, quantities of fill injected per borehole averaged about 300 cubic yards. The gravity-feed method required many closely spaced injection holes and provided incomplete filling. The new method, designed for inundated mines, proved successful also in mine workings about mine-water pool level. Distribution of slurry through a buried pipeline minimized disturbance to the community.

Jan 1, 1975

By C. M. Harrer

This paper describes the location and general features of iron occurrences in Colorado. Most of the deposits were examined; many are in forested and mountainous areas at altitudes of 5,000 to 13,700 feet. Iron is known to occur in 30 counties of western Colorado. Transporting the ore to market is a handicapping economic factor involving long truck and railroad hauls; the nearest purchaser of smelting ores is the Colorado Fuel and Iron Corp., at Pueblo, Colo. When the ore can be sold locally for special purposes and at higher prices than can be obtained at iron smelters, small-scale operations can supply that market.

Jan 1, 1959

By J. J. de Barbadillo

This report describes a process for recovering chromium and other metals from superalloy scrap. Part I contains the results of laboratory scale experiments which were conducted to test a complex flowsheet utilizing a wide range of extractive metallurgical operations. The novel basis for the process is the formation of a sulfide matte in which chromium is concentrated in a discrete chromium sulfide phase. Mineral processing and hydrometallugical procedures are used to separate chromium sulfide from the other matte constituents. The products of the process are a chromium-nickel alloy suitable for reuse in the superalloy industry, electrolytic nickel, electrolytic cobalt, and an iron-molybdenum residue. Recovery of the principal elements contained in the scrap are chromium(Cr)-93 percent, nickel(Ni)-99 percent, cobalt(Co)-96 percent, molybdenum(Mo)-92 percent. Part II encompasses a preliminary engineering design of a pilot plant capable of treating 100 pounds(lb) of superalloy scrap per hour. Also included is an economic analysis of the operation of the pilot plant.

Jan 1, 1980

By Grant R. Brown

The report provides guidance for determining those environmental impacts associated with the surface mining of steeply pitching coal seams. In addition to the environmental impacts, four additional issues are addressed, namely (1) Time and motion studies of those coal mining systems employed in mining seams which pitch in excess of 250, (2) Assessment of those mining techniques, (3) Development of rationale for the mining methods employed, (4) Identification of the reclamation practices and determine whether these practices were in compliance with appropriate Federal and State regulations. Five surface mines located in three geologically distinct basins of the United States were analyzed during the period of August through November 1979. The three basins include the Hanna Basin of Wyoming, the North Park Basin of Colorado and the Southern Anthracite Field of Pennsylvania.

Jan 1, 1980

By P. G. Guest

MANY of the gases and vapors used in anesthesia form explosive mixtures with oxygen or air. Sources of ignition for these mixtures always have existed in operating and anesthetizing areas. When ether was first introduced, candles,5 gaslights, and coal stoves caused fires and mild explosions of the vapor-air mixtures. Today the chief causes of ignition are electrical. Fires and explosions are still much too frequent; and, because many of the mixtures are rich in oxygen, the explosions sometimes are very violent. Obvious sources of ignition, such as electric-power sparks and arcs in open motors, switches, and receptacles, as well as exposed incandescent wires and hot plates, usually are recognized by hospital personnel and corrected. A source of ignition that is not so obvious to many is static electricity. Until quite recently the presence of this hazard in a large majority of anesthetizing areas was not even suspected. However, numerous explosions-many of them fatal to patients-have been attributed, with good reason, to sparks from static electricity.

Jan 1, 1953

Airy kind of a power system is a complicated network of various electrical components, such as cables, transformers, electric machines, circuit breakers, etc. For a system to work continuously and efficiently, each of the components has to be in perfect operating condition. The failure of any of these components can cause serious interruption of the supply and may in several cases involve a lot of precious time and labor in removing and replacing the damaged equipment it may also give rise to dangerous overvoltages on the system, thereby causing a safety hazard. Any piece of electrical equipment can have two likely modes of failure. The first would be the degradation of solid insulation material due to overheating, mechanical damage or a combination of the two, In this mode of failure it is possible that If the insulation damage is not an instantaneous phenomenon (a cable damaged by severe mechanical, Stress) that a detectable leakage current will do lop prior to the faint. The fault would probably he a result of heating and deterioration of the insulation by the leakage current.

Jan 1, 1975

By Morton Corn

The U. S. Federal Coal Mine Health and Safety Act of 1969 placed limits on the permissible concentration of airborne respirable coal mine dust. Evidence exists which suggests that the effects on health of respirable coal mine dust may depend on both host factors and dust properties other than concentration. Dust particle size, shape, density, specific surface area and chemical composition are among the dust parameters of interest in an epidemiological investigation of coal workers' pneumoconiosis and coal miner exposure to mine dust. The purpose of this investigation was to develop and demonstrate the feasibility of techniques to determine selected properties of respirable coal mine dust. An approved underground horizontal elutriator which samples air at 36 cfm was designed, fabricated and utilized in this study to collect respirable coal mine dust in three mines representing the Pittsburgh, Lower Freeport and Lower Kittanning coal seams. Analytical procedures for measurement of respirable dust sample particle size, density, random projected area, total surface area and chemical composition are presented. Results of analyses of three samples collected in each mine are presented. Up to five full work shifts of sampling were required to accumulate approximately five grams of respirable coal mine dust in each sample. Statistical tests were applied to determine the significance of differences between properties of dust samples collected in the same mine and between arithmetic mean values of dust properties representing three samples collected in each mine. A comparison was also made between

Jan 1, 1972

By M. M. Gilkey

This report on water requirements for the New Mexico mineral industry includes data on industrial operations closely related to mineral production. It contains general information concerning public water supplies at five principal cities and a short discussion of water needs for agriculture. Background data are presented regarding the geography, hydrography, and water laws of New Mexico, as well as precipitation and evaporation characteristics of the State. Most of the information on source, quantity, distribution, cost, and treatment of water was obtained in interviews with company representatives. Water systems at 46 operations are illustrated by schematic waterflow diagrams. The study revealed that the New Mexico mineral industry in 1962 used about 16 billion gallons of new water and reused 152 billion gallons, a total usage of 168 billion gallons. Consumption amounted to 7.6 billion gallons. Of the 16 billion gallons of new water, 11.9 billion gallons was "self- supplied" from ground water sources, and 2.6 billion gallons was self supplied from surface sources. Approximately 1.5 billion gallons was purchased. Some of the water from company-owned wells is piped as far as 30 miles. Reported costs of the self-supplied new water range from 1 to 20 cents per 1,000 gallons and average 8 cents per 1,000 gallons for power and maintenance. Inadequacy of the supply of new water at many operations necessitates large-scale recirculation. Reported costs for recirculating water (power and maintenance) average 1.8 cents per 1,000 gallons. For the entire New Mexico mineral industry in 1962, the value of product was $42 per 1,000 gallons of new water intake and $88 per 1,000 gallons consumed. Analyses of 40 water samples, listed in the appendix, show the wide range in water quality at plants throughout the State. Projection of the 1962 water requirements of the mineral industry indicate that the total demand for new water will increase from the 16 billion gallons used in 1962 to 24 billion gallons in 1980, a 50 percent increase; and to 36 billion gallons in 2000, which is 125 percent more than the 1962 intake of new water.

Jan 1, 1965

By D. Harrington

The primary objective of this paper is to discuss the hazards and furnish a list of recommendations for the safe operation of quarries and related works. They have been compiled from Bureau of Mines publications covering the safety experience of engineers before and during the year in the mineral industry,5 from a publication of the National Safety Council, Inc.,6 from explosives recommendations made by various explosives manufacturers,7 and from suggestions obtained from quarries visited. The second objective is to describe and illustrate safety devices, practices, and quarrying methods. The quarrying and related industries of the United States had a lower accident-frequency rate than either the metal- or coal-mining industry as reported for 1942.8 However, the quarry industry ranked eleventh in 15 major industries during 1942 in lost-time accident fre¬quency; metal mining ranked fourteenth and coal mining fifteenth.

Jan 1, 1950

By Robert T. MacMillan

A process has been developed in the laboratory and expanded to semi-pilot-plant scale for recovering titania, iron, and byproducts from two types of titaniferous iron ores. A reducing roast with coke and soda ash followed by grinding and magnetic separation produced powdered iron and slag from which titania and byproducts were recovered by H2SO4 decomposition. Based on the steps tested on a. semi-pilot-plant scale supplemented by the results of the laboratory investigations, enough data are available to make a balanced flow sheet. Combined data from the laboratory and semi-pilot plant indicated that 85 to 9O percent of the titania content of the ore was recoverable and that approximately 90 percent of the iron could be recovered as a metallic-iron powder. Tahawus magnetite from the Maclntyre mine at Tahawus, N. Y., was successfully treated as follows: (1) The ore was roasted at 1,050° to 1,080° C. with carbon and soda ash, thereby reducing the iron to metal sponge and retaining the titania in the slag. (2) The metallic iron was separated, after wet grinding, by magnetic or gravity means. (3) The slag fraction was air-roasted at 850° C. and leached with NaOH to recover Na3VO4. (4) The leached solids received a dilute-H2SO4 leach to remove interfering impurities, chiefly Na2O and SiO2. (5) Titania was dissolved from the leached solids of step (4) by a H2SO4-bake followed by a water leach. (6) Titania was precipitated by seeding and boiling the resulting solution. The spent liquor was used for the dilute-H2SO4 leach in step (4). The following scheme was found to be technically feasible for recovering other byproducts of the process. (1) The gelled filtrate from the dilute-acid leach step was washed and dehydrated to produce a commercially acceptable silica gel. (2) The wash liquor containing sulfates of Na2O, Al2O3, Fe2O3, and TiO2 was combined with the highly alkaline filtrate from the wet-grind and metallic iron-separation steps, precipitating iron and titanium hydroxides, which were separated for special treatment. (3) Anhydrous Na2SO4 and Al2O3?3H2O were recoverable from the alkaline filtrate from step (2) by evaporation and carbonation, respectively, and the barren liquor was recycled to the magnetic-separation step.

Jan 1, 1952