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By I. Liebman

The Bureau of Mines conducted research to develop triggered barrier systems for protection against gas explosions that can occur in underground coal mines during the use of continuous miners. Several extinguishing agents were tested in barriers at a simulated mine face. Water, powered by pressurized nitrogen, was found to be efficient in stopping fully developed gas explosions, but it had little effect against the explosion during its incipient stage. Hybrid combinations of currently known extinguishants, however, were successful against incipient explosions. Three hybrids that were developed and tested consisted of Halon 1301, combined with either an aqueous foam solution, water, or a dry chemical powder. The three hybrids were found to be more efficient than any constituent alone. Results of the tests point to a synergism between the hybrid components, and indicate that the Halon aids in dispersing its constituent and also converts the aqueous foam solution into a stable fine foam and the water into fine drops.

Jan 1, 1978

By N. H. Coates

A small, special-purpose centrifugal compressor was developed to circulate 60 pounds per hour of helium at 1,000° F and 250 psig because standard, commercial units were not available. Performance characteristics of this compressor were determined at helium flows of 2,000 to 18,000 std cu ft per hour, pressures of 100 to 250 psig, and temperatures of 100° to 1,000° F. This range is 2 to 90 actual cu ft per minute. Several graphs show the adiabatic head developed by the compressor over this wide flow range at various combinations of temperature and pressure. A compressor performance map relates pressure ratio to mass flow, temperature, pressure, and speed. This map can be used to accurately predict compressor performance factors within the range of operating conditions covered by the experiments.

Jan 1, 1963

By James Noll

Total carbon (TC) is sometimes used to measure or characterize diesel particulate matter (DPM) in occupational settings such as underground mines. DPM samples are collected on quartz fiber filters. When using quartz fiber ?lters, adsorption of gas phase organic carbon (OC) has been reported, causing a positive bias in the particulate TC results (adsorption artifact). Most of the data on the sampling artifacts and corrections apply to environmental air sampling, where samples are collected at a much higher filter face velocity and the OC concentrations are generally much lower relative to occupational sampling. In this study, we investigated the effects of adsorption artifact on samples from occupational settings. Samples were collected with and without denuders to determine the amount of gas phase OC collected and the accuracy of certain corrections. In underground stone mines, the adsorption artifact was found to positively bias the particulate TC by greater than 20% for filter loadings below 25 µg/cm2 TC (8-h time weighted average) 262 µg/m3). The tandem ?lter correction reduced the effect of the artifact, as high as 60% of the TC value, to less than 11% for laboratory data. It also significantly reduced the effect of the artifact obtained for field samples.

Jan 1, 2008

By F. L. Wideman

Materials handled at metal and non-metal mines in the United States increased 10 percent compared with those of 1965 as a result of expansions in output at existing mines and development of others to meet increasing demands for mineral products. The tonnage of commercial materials mined or quarried increased as did the quantity of waste handled. Crude material from which metal or nonmetal products were derived comprised 71 percent (75 percent in 1964) of the total materials handled. Great strides were made in mining technology and there were indications that, in the future, earth moving by the mining industry will involve materials-handling systems of increasing size and complexity. Materials Handled.-Output of ore and waste at metal and nonmetal mines and quarries in the United States in 1966 totaled 3,518 million tons (3.213 million tons in 1965). The quantity of materials handled has increased at an average annual rate of 5 percent since 1962. Ore production increased 4 percent over that of 1965, also comparable to the average annual rate of increase in the last 5 years. Waste removal in 1966 increased 25 percent over that of the previous year.

Jan 1, 1967

By Larry A. Haas

A major problem encountered in dump leaching operations is the plugging of both the dump and the piping by precipitated iron compounds. Bureau of Mines research to obtain basic data on agitation leaching and dump leaching methods has shown that the addition of organic chelating reagents can significantly enhance the lixiviant permeability through the ore and the concentration of the metal values in the liquor. For example, the addition of 5 giL citric acid (CA) to a conventional sulfuric acid lixiviant almost doubled the fluid flow rate through 5-cm-diameter laboratory columns containing copper ore. After 185 h of per-colation leaching, the metal concentrations with (and without, in parentheses) CA were 1.7 (1.5) giL Cu, 200 (70) ppm Mn, 160 (40) ppm AI, and 6 (3) ppm Co. The enhancement of metal concentrations with chelating reagents such as CA was confirmed by determining the solubil-ity of several metal ions as functions of pH and chelating reagent con-centration. When ferric ions became insoluble at pH values above 3, the concentrations of other ions also decreased. The addition of che-lating reagents kept iron, as well as the other dissolved metals, in solution even at pH values as high as 5. Citric acid was a more effective chelating reagent than gluconic acid, oxalic acid, or sodium lignin sulfonate.

Jan 1, 1985

By T. E. Sterner

A laboratory investigation was conducted to determine the applicability of the thermal oil-recovery method as a means of increasing ultimate oil recovery in the Appalachian region. The primary objective was to establish self-sustained combustion in consolidated and unconsolidated sand test assemblies saturated with various amounts of Pennsylvania Grade crude oil and synthetic brine. Tests using blocks of sandstone were unsuccessful because of sealing problems and fracturing of the rock due to thermal stresses. A combustion wave of about 700° F was propagated through the sand-oil-water packs in the linear tube tests. The high air flux used resulted in high oil consumption and rapid movement of the combustion wave through the tubes. Analytical tests on the sand pack showed that sufficient fuel was deposited during the linear tube experiments for a self-sustained combustion wave.

Jan 1, 1967

By Gregory M. Molinda

The Bureau of Mines conducted an investigation into the occurrence of outbursts of salt known to be responsible for explosions, fatalities, and damage in domal salt mines. The purpose of the investigation was to develop a basis for predicting these outbursts based on geologic and associated physical properties of salt. The investigation was conducted at the Cote Blanche salt mine in southern Louisiana. Because outbursts are the primary mode of methane emission into the mine, more than 80 outbursts, ranging in size from 1 to 50 ft in diameter have been mapped. These outbursts generally are aligned and elongate parallel to the direction of salt layering. More than 200 salt samples, both random and selected, were tested for methane content. It was found that outburst zones are well correlated with high methane content. Detailed mapping also revealed that the zones are well defined, with salt crystal size abruptly increasing upon entry into the zone. The intensity of folding and kinking of the salt layering within the outburst zone also appears to increase. An interbedded sand layer occurring throughout the mine does not appear to be a significant source of methane. However, fine-grained salt may be related to outburst occurrence.

Jan 1, 1988

By Donald R. Irving

ALTHOUGH the quantity of material handled at metal and nonmetal mines in the United States in 1962 was 2.7 billion tons, the same as in 1961, a larger proportion was waste. At metal mines, crude ore production declined 1 million tons and waste output rose more than 18 million tons; at nonmetal mines crude ore production declined 6 million tons and waste output rose 36 million tons. Copper and iron ore producers increased their share of crude ore and material handled from about three-fourths to four-fifths of the national metals total, and sand and gravel and stone producers in-creased their share of the nonmetals total, also from three-fourths to four-fifths. Six States-Arizona, California, Florida, Michigan, Minnesota, and Utah-each handled more than 100 million tons of ore and waste, and together they accounted for 43 percent of the U.S. total. When the large-volume construction materials (sand and gravel and stone) were excluded from the totals, four States-Arizona, Florida, Minnesota, and Utah-supplied over half of the material handled.

Jan 1, 1963

By B. W. Gandrud

The upper part of the Alabama deposits of crystalline graphite consists of an oxidized ore derived from, the underlying unoxidized ore through prolonged weathering. The degree of oxidation in different sections and at different depths within the bed is nut. uniform. The original ore is hard and blue-gray; the weathered product is soft and brown and is the only part that has been mined to any extent. Samples of both oxidized and unoxidized ores were obtained from two of the large graphite deposits of Clay County. Three additional samples of oxidized ore were obtained from different portions of a third property in the same region. In this report, ores 1 to 5 are of oxidized material and ores 6 and 7 of unoxidized.

Jan 1, 1934

Researchers with the National Institute for Occupational Safety and Health (NIOSH) have developed a training module to educate both new, inexperienced miners as well as veterans on important issues related to self-rescue and escape procedures. These include: (1) physical and environmental conditions that can be encountered in a mine after a major explosion, (2) knowledge of emergency meeting locations and escape routes, (3) the importance of using self-rescuers, even in seemingly clear air, to keep the lungs isolated from contaminants, and (4) why miners should not go off to look for others who are missing. In addition, the module may stimulate miners to think about and discuss mine explosions and the devastating effects of such an event.

May 1, 2009

By E. Morrice

High-purity neodymium, praseodymium, and didymium (a cerium-free mixture of light rare-earth elements) were prepared by electrolysis of the oxides in a medium consisting of the respective rare-earth fluorides and lithium fluoride. The metals were electrodeposited in the liquid state and collected as nodules on a skull of frozen electrolyte. Cells were operated from 1,000° to 1,100° C. The requisite temperature was maintained by passing alternating and direct currents through the bath. Graphite was used for the anodes and tungsten for the cathode. The metal products contained <0.02 percent each carbon and oxygen and <0.025 percent tungsten as major impurities. Analysis of typical didymium metal nodules showed an approximately twofold enrichment in neodymium and praseodymium over their respective concentrations in the cell feed. The lanthanum content of the metal was about one-half its content in the oxide.

Jan 1, 1967

By Adam K. Smith

Over-exposure to noise remains a widespread, serious health hazard in the U.S. mining industry despite 25 years of regulation. Most other categories of illnesses and injuries associated with mining have improved, with the exception of hearing loss. In order to reduce cases of Noise Induced Hearing Loss (NIHL) in the mining industry, retrofit acoustic treatments and controls are being developed to subdue noise at the source. The Mine Safety and Health Administration (MSHA) coal noise sample data collected from 2000 to 2005 has determined that continuous mining machines rank first among all mining equipment whose operators exceed 100% noise dosage. The continuous mining machine conveyor, used to move coal from the cutting face to the rear of the machine, has been identified as a dominant noise source. A dual sprocket conveyor chain was tested as a potential solution. Sound power level measurements conducted at the Pittsburgh Research Laboratory (PRL) accredited reverberation chamber showed a 3 dB reduction in the A-weighted sound power level when the dual sprocket chain was implemented. Underground results show an 8-hour Time Weighted Average (TWA8 hrs) reduction a 3 dB for continuous mining machine operators. Utilizing this newly developed noise control, along with previously proven controls, provides continuous mining machine operators an opportunity to be within the MSHA-Permissible Exposure Limit (MSHA-PEL).

Jan 1, 2009

By Jack C. White

The purpose of this Bureau of Mines research was to determine the technical feasibility of direct sulfuric acid digestion of Florida land-pebble phosphate matrix. Preliminary tests in a continuous digestion circuit showed that 92 to 96 percent of the P2O5 contained in the matrix was extracted, while the P.05 concentration in the product acid ranged from 21 to 30 percent. The waste filter cake contained about 1 percent P205 and up to 18 percent water. These sandy compact filter cakes, comprised mostly of quartz and gypsum, appeared to be suitable for backfilling and reclamation of mined lands.

Jan 1, 1975

By CDC CDC

In 2004, a total of 251 metal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Metal mines were the smallest mining commodity sector, comprising 1.7% of all mining operations. • Gold mines

Sep 1, 2007

By R. W. Stahl

Gas accumulation and dust suspension are the major safety hazards in coal stockpiling and reclaiming operations. This report presents a schedule of safety precautions and plant design features devised by the Bureau of Mines to reduce danger from these and other sources.

Jan 1, 1965

By William R. Vogel

The Bureau of Mines Information and Analysis organization collects worldwide data on virtually every commercially important nonfuel mineral commodity. These data form the base for tracking and assessing the health of the minerals sector of the U.S. economy. This data collection activity was instituted by the 47th Congress in an appropriations act of August 7, 1882 (22 Stat. 3291, to place the collection of mineral statistics on an annual basis. The most recent authority for the Bureau of Mines Information and Analysis activity is the National Materials and Minerals Policy, Research and Development Act of 1980 (Public Law 96-479, 96th Congress), which strengthens protection for proprietary data provided to the U.S. Department of the Interior by persons or firms engaged in any phase of mineral or mineral- material production or consumption.

Jan 1, 1989

By R. L. King

This report describes a method for designing and constructing ground beds that has been developed under the sponsorship of the Bureau of Mines. The procedures for designing and constructing a driven-rod ground bed with a resistance of 5 ohms or less are given. Some of the theory of soil resistivity and fall-of-potential resistance measurements is included. Results of a bed constructed at the Bureau of Mines mine car roadway are presented.

Jan 1, 1978

By R. L. Hopkins

Some typical thiacyclopentanes and thiacyclohexanes were synthesized to provide reference compounds needed for the identification of sulfur compounds in crude oils. Two general methods of synthesis were employed: (1) cleavage of 2-alkyltetrahydropyrans with hydrogen bromide followed by the reaction of the resulting dibromoalkanes with sodium sulfide and (2) the catlyzed reaction of cyclic ethers or 1)4-or 1)5-alkanediols with hydrogen sulfide. Both methods produced mixtures of 2-alkylthiacyclopentanes and 2-alkylthiacyclohexanes with 2-alkyltetrahydropyran as the starting material. The structures of the reaction products were established by analysis for sulfur; desulfurization; gas-liquid chromatography (GLC); mass, infrared, and nuclear magnetic resonance (NMR) spectra; and an alternate synthesis. The synthesis of the cyclic sulfides contributed substantially to the identification of 10 members of this class of sulfur compounds in crude oil.

Jan 1, 1967

By J. W. Town

The Bureau of Mines determined the physical properties of southeastern Idaho phosphate fines as related to mineral composition, particle size and liberation, beneficiation, and potential use in structural clay products. The phosphate mineral in the fines was identified by unit-cell dimensions to be essentially the same as the phosphate mineral fluorapatite identified in the coarser sizes. The mean particle frequency as determined by electron-microscopy and pipet-analyses was between 0.5 and 0.2 micron. Liberation of the phosphate could not be definitely determined because of the weathered condition of the minerals and their extreme fineness. No beneficiation scheme was developed that would concentrate the phosphate into a marketable fertilizer product; therefore, forming and firing tests were made to demonstrate that the fines can be used to manufacture structural clay products.

Jan 1, 1968

By J. D. Hadden

The Bureau of Mines conducted drilling studies in the Pocahontas No. 3, the Pittsburgh, and a western coalbed to establish the gas migration characteristics for each. Gas pressures in the Pittsburgh coalbed were about 260 lb/in2 and in excess of 550 lb/in2 in the Pocahontas No. 3. Caving in drill holes prevented pressure measurements in the western coalbed. The Pittsburgh coalbed contained intersecting "clay veins" which formed gas pressure cells. Although these geological features hamper mining, they can be used to control the flow of methane into a mine working. Methane control techniques are proposed for the Pittsburgh and Pocahontas No. 3 coalbeds.

Jan 1, 1969