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By William Seymour, L. D. Schmidt, J. W. Myers, W. T. Reid

"This investigation was conducted by the Bureau of Mines as part of a program of the Solid Fuels Administration to encourage the utilization of anthracite fines, the objective being to determine the practicability of using anthracite fines in the manufacture of packagedThe experimental loss of packaged fuel covered by this report were made at a commercial plant using the Glenn Smith process and ordinarily making packaged fuel from Pocahontas screenings. These lots included several made from straight antimacite mines and others made from various blends of anthracite fines with four different bituminous coals. In all cases an asphalt binder was used. Determinations of the physical properties and the cobustion characteristics o the various samples of packaged fuel were made by the. Bureau of Mines at the Central Experiment Station.The physical tests indicated that a packaged fuel of sufficient strength for ordinary handling can be made from straight anthracite coal or from a wide variety of blends of anthracite fixes with bitunimous coal, using asphaltic binder. However the combustion tests indicated that packaged fuel made from anthracite alone tended to crumble excessively during burning and that as much as 30 to 50 percent of a caking coal may be required In the mixture to produce a block having satisfactory combustion characteristics.The authors wish to acknowledge the. splendid cooperation of Messrs. H. W. Kelly, J. L. Mooney and C. H. Stoss of Columbus, Ohio, who were chiefly responsible for obtaining the materials and making all the arrangements necessary for the production of the packaged fuel for testing.Thanks are due to the officials of Carnegie Institute of Technology for the use of their Olsen. Testing Machine and to H. M. Cooper and W. A. Selvig of the Bureau of Mines for analyses and tests."

May 1, 1946

Empirical methods involve the scientific interpretation of real-world experience. Many problems in ground control lend themselves to an empirical approach because the mines provide us with plenty of experience with full-scale rock structures. During the past 10 years, powerful design techniques have emerged from statistical analyses of large databases of real-world pillar successes and failures. These include the Analysis of Retreat Mining Pillar Stability (ARMPS), the Analysis of Longwall Pillar Stability (ALPS), the Mark-Bieniawski rectangular pillar strength formula, and guidelines for preventing massive pillar collapses. In the process, our practical understanding of pillar behavior has been greatly enriched.

Jan 5, 1999

By L. B. Pankratz

Heat contents were measured for Na2CaSi04 and Na2Ca2S02 between 298° and 1,300° K, for Na2Ca2Si309 between 298° and 1,500° K, and for Na4CaSi3O9 between 298° and 1,350° K. Copper-block drop calorimetry was employed. Reversible, first-order transitions were found for Na2CaSi04 and Na2Ca2Si309. The transition for Na2CaSi04 is at 830° K with a heat absorption of 160 cal/mole; that for Na2CagSi309 occurs at 750° K with a heat absorption of 1,550 cal/mole. Results for the other two silicates showed no irregularities. A table of heat content and entropy increments above 298.15° K and heat con-tent equations are included for use in thermodynamic calculations.

Jan 1, 1968

By W. L. Schmidt

The effect of a water-repellent film in sandstone cores on the effective permeability-saturation relationship was investigated as part of a cooperative research program between the Bureau of Mines and the American Gas Association. The repellent film was formed by the reaction of methyltrichlorosilane3 with the connate water in the core. Other researchers have reported on the use of silicone chemicals to alter the flow characteristics of porous media (1-3, 5-7, 9, 10).4 The previous studies, however, dealt almost entirely with oil-water or oil-gas systems and not with water-gas systems. The primary purpose of this study was to determine the feasibility of using silane to retard the influx of water into natural-gas storage wells and to determine the necessary requirements for achieving this result. The success or failure of silane treatment as a remedial measure depends on its effect on gas-production rate and attendant water production.

Jan 1, 1961

By David B. Doan

This regional report covers 1993 mining and related activity in approximately 40 countries and territories of Canada, Latin America, and the Caribbean Basin. These countries of the Western Hemisphere, as with the United States, are endowed with a great variety of minerals, including metals, industrial minerals, and energy minerals. For most of these countries, such mineral production helps form foundations for their economies and earns export credits including hard currencies. Table 1 depicts an overall view of Latin America and Canada's production of its major mineral commodities in 1993; subsequent tables show the role of Latin America and Canada in world mineral production, trade, and import dependency on minerals from Latin America and Canada by the United States. Overall, the picture emerges of a rich mineral diversity throughout the hemisphere, attracting increasing interest and investment, and complementing the mineral resources of the United States.

Jan 1, 1995

By J. B. Zink, M. J. Peterson

A semiquantitative spectrochemical method was developed and applied to the analysis of ash of U.S. coals . A low- temperature ashing procedure was used to minimize the loss of volatile elements . The analytical procedure provides for the estimation of 68 elements including major , minor , and trace constituents . Standards for the trace elements were prepared in a synthetic base mixture that approximates the average composition of U.S. coal ashes . Excitation was achieved with a d- c arc , spectra were recorded photographically , and interpretation was made by visual comparison of spectra of unknowns with spectra of graded standards series . Thirty- six trace elements were found in the analysis of 900 samples . Details of the procedure are presented , including sample and standards preparation , excitation and exposure conditions , spectral lines used , and approximate limits of detectability .

Jan 1, 1964

By W. D. Ludemann, E. A. Loria, E. A. Rowe

The isothermal recrystallization of electrorefined vanadium has been studied as a function of annealing time , temperature , and prior deformation . Specimens were cold- rolled from 30- to 75 - percent reduction in thickness , then annealed from 700 ° to 1,200 ° C at time periods ranging from 1 minute to 96 hours . The course of recrystallization was followed by means of hardness , metallographic , and X- ray techniques , and a recrystallization diagram was constructed . Interpretation of the data indicated that there was around 50- percent softening due to recovery ( first stage of softening) before recrystallization began . The defining of recrystallization limits with respect to the amount of deformation was precisely established for electrorefined vanadium . More than 30- percent reduction was necessary for recrystallization to occur at 850 ° C. With 60- percent reduction , it was initiated at 750 ° C and completed at 950° C. The activation energy for recrystallization , as derived from the data , was 95,300 cal per mole for 60 - percent reduction and annealing at 750 ° to 900 ° C. Recrystallization by the mechanism of nucleation and growth was the principal process during the second stage of softening . minor part of the second stage of softening took place as strain- induced boundary migration , which was observed in specimens reduced 30 percent , bent in L- shape , and annealed at 950 ° C. Grain size decreased significantly only with the largest reductions and annealing between 750 ° and 950 ° C. Grain growth was expressed by the empirical relation D = KKtt"" ,, the exponent being the same at 60- percent reduction and annealing from 750 ° to 900 ° C. Accordingly , the activation energy for grain growth was 75,000 cal per mole .

Jan 1, 1964

By H. E. Powell

The mineral dressing research here reported is part of a continuing program by the Bureau of Mines to develop new or improved concentration processes for oxidized or partly oxidized lead and zinc ores. A sample of low-grade sulfide-oxide, lead-zinc ore from Jasper County, Mo., containing galena, cerussite, pyromorphite, hemimorphite, smithsonite, and sphalerite was concentrated by froth flotation and tabling to a grade of 66 percent lead. Because of the presence of a high content of slime-size values, the overall recovery of lead was limited to 64 percent at this grade. Tests to recover the zinc by froth flotation and by gravity concentration did not give satisfactory results. INTRODUCTION Since its establishment, the Rolla Metallurgy Research Center has con-ducted studies of base metals as a part of its overall program (1, 2, 3, 4, 5,6,7).3/ This research has been, and is, directed to beneficiating complex and submarginal ores, to retreating rejects from commercial installations, and to developing fundamental data.

Jan 1, 1960

By Thomas M. Barczak

This Bureau of Mines report describes research on developing technology to utilize shields as roof load monitors. Three-dimensional equations of static quilibrium are presented for a generic two-legged long-wall shield. The equations are presented in the most general form, assuming a force and moment vector at each reaction by rigid-body analysis of the shield mechanics. The resulting system of equations was found to be indeterminate to a very high degree. A three-dimensional solution to measurement of the resultant reaction on the canopy by the strata activity and shield response required the elimination of several forces or moments that were thought to be nonparticipating or to not significantly affect overall shield mechanics. Required measurements for solution of the equilibrium equations were leg, canopy capsule, and lemniscate link forces. Two-dimensional analysis, which considered forces acting only in the roof-to-floor and face-to-waste plane, was also provided by reduction of the three-dimensional equations~

Jan 1, 1987

By R. L. Grant

During the last decade or more , experimental research on commercial detonators used for initiating the detonation of dynamite and other high explosives has led to important improvements . Developments , especially in the United States , have been directed toward improvement in the construction of detonators to make them safer to manufacture and use . More suitable and safer initiating charges also have been found . Although for many years mercury fulminate was unrivaled as the initiating charge for dynamite , during the last decade it has been replaced to a large extent by less sensitive , more efficient, and cheaper combinations of ignition , priming , and base charges . Commercial detonators were once of relatively simple construction and almost universally identical . Today they are technically complex, with special nodifications for particular uses ; they have developed along different lines n various countries and even among the several manufacturers within any one country .

Apr 1, 1943

By Forest J. Sur

"This report describes an exploratory project conducted by the Bureau of Mines on a fluorite deposit near Vado, N. Mex. Results of trenching are given. Together with analyses made upon samples of the ore. The Federal Geological Survey3/ completed a preliminary geologic study and mapped the deposit during the summer of 1944. A Bureau engineer examined the deposit in August 1944. As a result of these investigations, it was concluded that the deposit contained substantial inferred ore reserves. Exploratory work was recommended to obtain information that might possibly lead to production from the property. Assistance was given the Bureau by the Geological Survey.A gasoline-powered air compressor, other equipment, and supplies were delivered to the property from January 20 to 25, 1943. Trenching began under the direction of a Bureau of Mines engineer on January 25, 1947, and ended on March 15, 1945. The results of trenching and sampling form he basis of this report.In its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. IT is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, R.G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervisions of Dr. R. S. Dean, assistant director."

Sep 1, 1946

By E. E. Harton

Bureau of Mines Information Circular 7516, Bibliography of Investment and Operating Costs for Chemical and Petroleum Plants, was published in October 1949 to aid in estimating investment and operating costs of processes for manufacturing synthetic liquid fuels. Development of such processes by the Bureau of Mines was authorized by Public Law 290, 78th Congress. This bibliography included references to and abstracts of publications appearing from. 1930 to September 1948 on all processes in general use in the petroleum refining and chemical industries. Bureau of Mines Information Circular 7705, Supplemental Bibliography on Investment and Operating Costs for Chemical and Petroleum Plants, was prepared to cover the area from September 1948 through June 1952.

Jan 1, 1956

By Alex C. Smith

This report describes laboratory studies conducted by the Bureau of Mines to evaluate the effectiveness of 10 additives to inhibit the self-heating of coal. Aqueous additive solutions were applied to a bituminous coal with a high spontaneous combustion potential, and the minimum self-heating temperatures (SHT's) of the dried coal-additive mixtures were determined in the Bureau's adiabatic heating oven. The relative effectiveness of the additives was determined by the observed changes in the minimum SHT's of the mixtures, or by the time required for the sample temperature to reach 150" C, compared with the untreated coal and a coal-water blank. Sodium nitrate, sodium chloride, and calcium carbonate were found to be the most effective inhibitors, followed by ammonium dihydrogen phosphate, calcium chloride, ammonium chloride, sodium acetate, and potassium chloride. Two additives, sodium formate and sodium phosphate, promoted the self-heating process. Differential scanning calorimetry experiments on the coal-additive mixtures showed that reactions occurred between the coal and some of the additives, but these reactions did not influence the self-heating process.

Jan 1, 1988

The Technology Transfer Seminar on Mine Communications held on March 21-22, 1973, at the Pittsburgh Mining and Safety Research Center, Bruceton, Pa., presented information about recently developed equipment, instruments, and techniques for use in mine communications systems. All of the basic ideas presented in the fine seminar are operational in the Bureau of Mines Safety Research Mine in Bruceton.

Jan 1, 1974

The Bureau of Mines equipped a longwall shearer with a water-jet-assisted cutting system and measured dust levels during the cutting of a simulated coal block. The block was cut dry, at a conventional water spray pressure of 190 psi, and with water-jet-assisted cutting pressures ranging from 1,000 to 6,000 psi. At water pressures of 3,000 psi and higher, dust concentrations were reduced by as much as 85 pct via water-jet-assisted cutting in comparison with conventional water sprays. This reduction was achieved without any increase in the water flow rate.

Jan 1, 1986

By W. Beckering

IN CHARACTERIZING tars obtained by the low-temperature carbonization or North Dakota lignite, infrared spectra have been an invaluable aid in both qualitative and quantitative examination. Quite early it became evident in the tar-research program of the Bureau of Mines, U.S. Department of the Interior, that the small number of published spectra available for hydroxy aromatics would be inadequate for comparative purposes when dealing with the wide range of compounds present in coal tar; therefore, compiling a catalog of spectra was initiated as a continuing part of the tar program. As these spectra should be valuable to other investigators in this and related fields, they are being presented in this report. This group or spectra (figs. 1-98) represent 97 compounds, largely phenolic materials. The major problem of this project has been the availability of materials for examination. Samples have been obtained from commercial and private laboratories or synthesized at the Bureau of Mines Lignite Experiment Station, Grand Forks, N. Dak.

Jan 1, 1959

By John J. Sammarco

The U.S. Bureau of Labor Statistics reports that the mining industry has the highest average annual fatality rate (31.9 per 100,000 workers) among all major American industry. To address this, a major research program to reduce hazard exposure of miners with computer-assisted mining equipment was initiated by the U.S. Bureau of Mines.1 One application involves the manual process of extracting and hauling coal where operators, in the tight confines of a mine, can be struck or caught by mobile machinery. The approach to remedy this problem uses a guidance system on the haulage equipment so that it follows the machine that extracts coal. This, in essence, involves sensor-based docking of the machines. Sensors that can survive the hostile mine environment of dust, methane gas, and water, play the key role. Computer analysis of the mining machine's movements and empirical machine characterizations were conducted to establish operating requirements and spatial limitations to ensure proper loading of coal into the haulage equipment. These data served in the selection of a sensing system. Various technologies such as scanning laser systems and ultrasonic sensors have frequently been used in other applications but were found unacceptable. However, a near infrared (IR) sensor employing active targets met the requirements. The sensor has a nominal 75° conical field-of-view and a range from 0.1 to 18.0 m. For the single target mode, nominal range accuracy was 4.3% at a distance of 3.56 m. Correction algorithms were generated reducing the error to 0.6%. Airborne dust testing showed less than 0.8% accuracy (worst case) degradation at levels exceeding (by a factor of 7.5) concentrations permitted by Federal law. The sensor can track multiple active targets providing five degrees-of-freedom (DOF) measurements. Using four targets, the nominal range accuracy was 0.4% without correction algorithms. A guidance system for the haulage system to follow the mining machine does not exist commer¬cially. Such a system can reduce fatalities and injuries by current haulage mining equipment, and is a viable alternative to current haulage control.

By K. O. Bennington

The thermodynamic properites of petalite (Li2A12Si8O20) were determined by the Bureau of Mines. The enthalpy of formation was determined by hydro-fluoric acid solution calorimetry. The values from the elements and from the oxides are ?Hf°298.15 = 2,335.8 ± 3.0 kcal/mole and ?H°295 (from oxides) = -50.60 ± 1.20 kcal/mole. Low-temperature heat capacities were determined by adiabatic calorimetry from 10.69 to 302.11 K. The derived standard entropy is S°298.15 = 111.0 ± 1 cal/deg-mole. Enthalpy increments above 298 K were measured by copper block calorimetry from 298 K to 1,193.6 K. The various experimental data were combined with other data from the literature to calculate the Gibbs energies of formation and equilibrium constants of formation over the temperature range of the measurements. Tables of enthalpies of formation and Gibbs energies of formation are given as a function of temperature from the elements and constituent oxides. The Gibbs energy of formation is ?G°f298.15 = 2,203.8 kcal/mole.

Jan 1, 1980

By G. F. Friel, J. C. Edwards

A series of seven underground-coal-mine fire experiments was conducted in the Safety Re-search Coal Mine at the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory. Coal and styrene-butadiene-rubber conveyor belting were burned upwind of two sensor stations, 18 m and 148 m from the fire source. Exhaust from a diesel locomotive flowed over the fire sources in six of the tests. Metal-oxide-semiconductor (MOS), CO, and optical-path-smoke sensors were positioned at both stations and found to be an optimum set of sensors for the fire discriminations. A representative set of 7,679 samples of CO data and data from the smoke and diesel-exhaust MOS sensors were used as inputs to train a neural network (NN). By testing 42,538 data samples from the seven experiments, all fires were detected by the NN within 9.67 min from the onset of significant changes in the MOS voltages without any false alarms.

By Robert W. Freedman

In the Bureau of Mines study, a filter with a 20-by 20-inch-square cross section was inserted into the exhaust ducting of a 4-stroke-cycle, 90-hp diesel engine, and the efficiency of removal of total particulate was measured gravimetrically as a function of time. Removal efficiencies were close to 90 pct during the main portion of several extended runs employing several combinations of filter beds. Variations in engine load had little effect on collection efficiency. Particle size as measured by a Bureau-developed online instrument centered on 0.07 m based on number count. Removal efficiency increased rather sharply for both larger and smaller particles.

Jan 1, 1979