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By M. J. Ferrante

Relative enthalpies of cuprous iodide (CuI) were measured at the Bureau of Mines to provide thermodynamic data for the advancement of min-eral technology. Enthalpy measurements between 298.15 and 1,396.3 K were made with a copper-block drop calorimeter. The temperatures of transition were measured by differential scanning calorimetry (DSC). Reversible transitions were determined at 643 K with a standard enthalpy of transition [(6Htr)] = 0.74 kca1/mol, at 679 K with a [6Htr = 0.65 kca1/mo1, and at 868 K] with a standard enthalpy of fusion [(6H~) = 1.895 kca1/mol.] Tabulated values are listed at selected temperature increments from 298.15 to 1,600 K for the standard relative enthalpy (HO -H298), heat capacity (CpO), entropy (SO), and Gibbs energy function [-(Go -H298)!T]. The enthalpy data are also given in the form of equations and combined with thermodynamic data from other investigations to derive values of standard entha1pies of formation [(~HfO)], Gibbs energies of formation [(6GfO)], and logarithms of the equilibrium constants of formation (log Kf).

Jan 1, 1987

Use water-jet-assisted cut-ting technology to reduce the exposure of mi ne workers' to respirable dust. Approach Install water-jet-assist on mining machines and evaluate its impact on respirable dust. How It Works Water-jet-assisted cutting involves a mechanical cutting bit working in combination with a moderate pressure (generally up to 10,000 psi) water jet directed just in front of, or through, the bit tip. One of its advantages is reduced dust generation because the jet wets the face of the material being cut more efficiently than a conventional low-pressure water spray, thus capturing much of the dust before it ever becomes airborne. It also removes loose cuttings ahead of the bit before they are pulverized by the bit into respirable dust. Total water consumption is about the same as for conventional low pressure dust control water spray systems. However, there is some increase in power consumption because of the energy needed to provide the high pressure water.

Jan 1, 1987

By Wilton Johnson

Native asphalt was produced by four companies in two States, Texas and Utah. Bituminous limestone, used primarily as a paving material for street and road repair, was produced by one firm. R. L. White Co., Dabney Quarry, Uvalde County, TX. Gilsonite, a solidified hydrocarbon found only in Utah and Colorado, was mined by three firms: American Gilsonite Co., a division of Chevron Resources Co. (a subsidiary of Standard Oil Co. of California); Ziegler Chemical and Mineral Corp.; and Hydrocarbon Mining Co. (a subsidiary of Oberon Oil Inc., a Utah corporation), from properties in Uintah County, UT. Gilsonite is used for a variety of purposes including automobile bodysealer, light-weight aggregate for cement used in oil well drilling, asphaltic building board, protective coverings, anticorrosive paints, and roofing compounds. Gilsonite production in 1985 declined 57% owing primarily to reduced oil well drilling activity. The value per ton was essentially unchanged.

Jan 1, 1987

By Richard D. Miller

The helium resources base of the United States was estimated by the Bureau of Mines to be 1,070 Bcf as of January 1, 1985. These resources are divided into four categories in decreasing degree of assurance of their existence: (1) helium in storage and in proved natural gas reserves, 280 Bcf, (2) helium in probable natural gas resources, estimated at 243 Bcf, (3) helium in possible natural gas resources, estimated to be 287 Bcf, and (4) helium in speculative natural gas resources, which makes up the remaining 260 Bcf. These helium resources are further divided into depleting, non-depleting, and stored classifications. The depleting resources are those associated with natural gasfields that are, or will be, produced for the natural gas they contain. Almost all of the helium in potential (probable, possible, and speculative) natural gas resources is included in this classification. These depleting resources are estimated to contain 900 Bcf of the total helium resource base. Helium resources contained in nondepleting natural gas resources, those in shut-in, abandoned, or otherwise nonproducing natural gasfields, are estimated to total 133 Bcf. There is 37 Bcf of helium in storage in the Federal Government-owned Cliffside Gas Field near Amarillo, TX.

Jan 1, 1987

By A. Visnapuu

Excessive noise and high vibration are inherently associated with equipment used in the mining, extraction, and processing of mineral resources. High vibration degrades structural components, often leading to catastrophic failure and loss of productivity, and excessive noise can result in permanent hearing loss. In order to foster efficient utilization of the Nation's mineral resources and minimize occupational hazards associated with mineral processing, the Bureau of Mines investigated the relationship between the microstructures of carbon and alloy steels and cast irons and their damping capacities (ability to absorb vibration). Researchers measured damping capacity and other properties and investigated the effects of carburizing, spheroidizing, and annealing. The investigators found that in carbon and alloy steels, rounded colonies of fine-grained pearlite in a ferrite matrix correlate well with low damping capacity. Steel microstructures that exhibit sharp-faceted pearlite in ferrite matrix and partially or fully spheroidized cementite in ferrite show considerably higher damping. In cast irons, the lowest damping capacity is associated with nodular graphite microstructure, and the specific damping capacity (SDC) increases as the graphite micro-structure progresses from nodular to compacted to flake. Predominant ferrite in cast irons is also associated with good damping. SDC data are presented for selected carbon and alloy steels and cast irons.

Jan 1, 1987

By Joan Weinberg

The real gross national product (GNP) expanded by 2.3% during the second quarter, down from the anomalous 4.4% growth rate in the previous 3 months. If the expansion continues through October, it will have lasted 5 yr and become the second longest in 40 yr.2 As in the first quarter, improvement in U.S. exports played a role in the continuing--albeit slow--growth. More than 2 yr of declines in the dollar relative to currencies of other industrial countries have contributed to a slight reduction in the trade deficit in real (volume) terms, as real net exports of goods and services rose $1.9 billion (table 1). Exports grew a strong 12.1% while imports, which had fallen the previous two quarters, rose 7.4%. Manufactured goods and petroleum products accounted for most of the second quarter import increase. The American Petroleum Institute estimates that the volume of crude oil and refined products imports in the first half of 1987 surpassed those in the same period last year by 7.5%, reflecting falling domestic production and higher than expected demand. Expenditure on durable goods--those that last at least 3 yr-by both consumers and producers also contributed to the second quarter expansion. Personal consumption of durable goods rose 9.0%, after having fallen the two previous quarters. Motor vehicle purchases accounted for most of the second quarter increase and the first quarter decrease. Sales of automobiles surged in the last quarter of 1986, as consumers rushed to capture the sales tax deduction that was eliminated on January 1. Sales fell in the first quarter of 1987, but have now moved closer to the trend line exhibited in the first three quarters of 1986. Automobiles accounted for half the 0.8% July gain in retail sales, and two-thirds of the 1.4% June gain. Producers durable equipment purchases also rose this quarter, accounting for the increase in nonresidential fixed investment.

Jan 1, 1987

By Ronald T. Mayerle

In 1986, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied a 20,500-acre part of the 104,085-acre Rincon Wilderness Study Area (OR-002-082) in order to evaluate its identified mineral resources. The wilderness study area is located in Harney County, OR, about 12 miles west from Fields. No mineral resources were identified within the study area. A literature search found no records of mining or minerals exploration, nor did a ground search find any evidence of mining-related activity. Of seven alluvial samples taken from the major drainages of the study area, all were barren except one. This sample, taken from a dry streambed along the southern boundary, contained $0.07 gold per cubic yard; however, this small amount of gold is of no economic significance, and the source is probably outside the study area. The Pueblo-Steens mining district extends to within 4 miles east of the study area. No evidence of geological environments similar to those that were responsible for the formation of resources or occurrences of metals and nonmetals within the district is known within the study area.

Jan 1, 1987

By Catharine T. Fogg

The Bureau of Mines investigated the availability of flake and high-crystalline natural graphite from 4 domestic and 25 foreign mines and deposits in 11 market economy countries (MEC's). Demonstrated resources were estimated to be 95 million metric tons (Mmt) containing 5.61 Mmt of recoverable flake and high-crystalline graphite products. Fifty-five percent (3.17 Mmt) of the total recovered product is estimated to comprise plus 100-mesh (150-µm) flake pro-ducts and "lump" and "chip" high-crystalline products, designated as "graphite A" in this study; 45 pct (2.44 Mmt) of the total is minus 100-mesh (150-µm) flake products and "dust" high-crystalline products, designated as "graphite B." Total production costs, including all costs needed over the life of each operation, were determined at a 0-and 15-pct discounted-cash-flow rate of return (DCFROR) for both graphite A and graphite B products. For a 15-pct DCFROR, 1.74 Mmt (54.9 pct) of the graphite A products is available at $600/mt or less and 2.13 Mmt (67.2 pct) is available for $800/mt or less. For the same DCFROR, 1.08 Mmt (44.3 pct) of the graphite B is available at $200/mt or less, and 1.71 Mmt (70 pct) is available at $325/mt or less. No domestic resources were determined to be economic at present prices. A sensitivity analysis of the relative economics of the Alabama graphite deposits under various operational parameters is presented in an appendix. All evaluations are in January 1984 dollars.

Jan 1, 1987

Provide the mining industry with a simple, accurate and readily available means of measuring the gas flow from pipe outlets such as gob holes Approach The Bureau of Mines conducted laboratory studies to establish correction or method factors for anemometers when used to measure gas flow from pipe outlets. Using the Anemometer Anemometers are used by the mining industry to make air velocity measurements in mine entries. Although the instrument has no appreciable influence on the airstream in mine entries, especially since the cross-sectional area of an entry is much larger than the cross-section of the anemometer, correction or method factors are used to correct the center line anemometer velocity to average velocity. This adjustment is made because the air velocity in a mine entry is highest in the center and lower at the sides. Anemometers can be used to measure gas flow from small diameter pipe outlets; however, since the instrument diameter is much larger than one-sixth of the pipe diameter, it will influence the air-stream from these small outlets. Resulting velocity measurements are erroneously high by as much as 30 percent. Method factors must be applied to such anemometer measurements taken at pipe outlets. Through a research investigation the Bureau of Mines established a set of method factors for center-line anemometer readings taken at the discharge end of 4-to 8-inch diameter pipes. These method factors were combined with method factors which were developed by the National Coal Board of Great Britain for 12-to 30-inch diameter pipes. The anemometer was mounted on the end of a short rod and held against the pipe for support except on the 4-inch pipe where the instrument was started and stopped remotely to prevent hand interference with the air-stream during measurements. Method factors were determined by comparing the anemometer measurements at the pipe outlet to the true average airflow which was simultaneously determined upstream by venturi measurements. Consequently, a method factor is nothing more than the ratio of the true velocity to an anemometer measurement.

Jan 1, 1987

By B. J. Moore

This publication contains analyses arid related source data for 274 natural gas samples from 20 States. Of the total samples, 269 were collected during calendar year 1985; the reminder were collected earlier, but releases granting permission to publish were not received before 1986, All samples were obtained and analyzed as part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1987

By W. L. Staker

The Bureau of Mines investigated methods for selectively eluting mercury, silver, and gold from strong-base anion-exchange resins, including Rohm and Haas resins lRA-430 and 900 and Dow Chemical resins 2lK, SMA-I, and SBR. Resins were typically loaded to 145 oz/st of each metal. Loaded resins were eluted with H2S04, NaCl-H Cl, NaOCl, and NaCl04 solutions. The resins tested had similar elution characteristics for mercury and precious metals. The best selective elution scheme was achieved by eluting in a column with 2N H2S04 to recover 99 to 100 pct Hg, with 200 giL NaCl in IN HCI to rec;ver 99 to 100 pct Ag, and with 2M NaCl04 to recover 79 to 89 pct Au.

Jan 1, 1987

By Stephen A. Swan

This Bureau of Mines report discusses research to analyze and evaluate extended bumper systems in order to determine the degree of protection provided to equipment operators in the event of rear-end collisions be-tween off-road rear-dump haulage trucks. The basic characteristics of rear-end collisions were determined, and a detailed analysis of the col-lision dynamics was performed to identify the magnitude and direction of impact loads, the amount of energy that must be absorbed during impact, and the major factors that affect the outcome of a collision. Separate bumper designs were developed to facilitate attachment to four 170-st-capacity haulage truck frame types.

Jan 1, 1987

By Terry R. Neumann

A mineral survey of the 23,760-acre Abert Rim Wilderness Study Area (OR-1-101) was conducted by the U.S. Bureau of Mines in 1986 at the request of the Bureau of land Management in order to evaluate its identified mineral resources. The study area is located in south-central Oregon, 26 mi north-northeast of Lakeview, OR. Federal and Lake County mining records indicate no mining claims, geothermal leases, or oil and gas leases within the study area as of January 1, 1987. No economic concentrations of minerals were found in the study area. The Wilderness Study Area is dominated by Abert Rim, a north-trending Basin and Range fault scarp that parallels the study area's western boundary. Exposed on the scarp is an approximately 2,000-ft-thick volcanic sequence consisting of Oligocene-Miocene basalts, tuffs, and tuffaceous sedimentary rocks.

Jan 1, 1987

By Alan R. Buehler

In 1986, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied part of the 256,430-acre Alvord Desert and part of the 22,240-acre East Alvord Wilderness Study Area (OR-002-074 and OR-002-073A, respectively), in order to evaluate their identified mineral resources. The study areas are located in Harney and Malheur Counties, OR, about 25 mi northeast of the small village of Fields. There are no mines, prospects, or identified mineral resources inside the study areas. Basalt flows within the study areas contain chalcedony-lined vugs and banded agate which may be of interest to rock hounds. An ignimbrite flow contains perlitic material, but crystalline contaminants make it unsuitable for commercial uses. Lacustrine (lake) sediments contain diatomite and clays, and evaporite crusts contain boron too low grade to profitably mine. Small quantities of common opal and petrified wood occur which might be of possible interest to rock hounds. Some of the petrified wood is black, free of fractures, and polishes well; it may be suitable as backing material for soft, thin, and brittle gemstones, such as precious opal. The lacustrine sediments also contain black, fetid layers which have above background, but economically insignificant concentrations of zinc, cobalt, nickel, barium, iron, manganese, aluminum, and potassium. Large quantities of fine-grained dune sands within the study areas are too far from markets for economic consideration. Ephemeral streams in the study areas contain small amounts of placer gold of no economic interest. The western portions of both study areas are reported to have moderate favorability for occurrences of natural gas, and both study areas are reported to have high favorability for the occurrence of geothermal resources. As of December 1986, oil and gas leases covered 3,100 acres in the study areas.

Jan 1, 1987

By David K. Ingram

The Bureau of Mines conducted underground mapping and rock strength tests to describe and analyze mine roof conditions surrounding ancient stream channel deposits (paleochannels) in the Pittsburgh Coalbed in southwestern Pennsylvania. Paleochannels in the study mine consist of sandstone and/or siltstone and affect the Pittsburgh Coalbed through erosion and/or differential compaction. Differentially compacted sediments within and adjacent to channel deposits caused slip planes, faults, clay-dike faults, clastic dikes (clay veins), coalbed rolls, and slumped structures. Paleochannels can be predicted by recognizing these features and associated sediments, which allows for modification of long-and short-term mine planning and development. Mine entries located beneath the paleochannel deposits exhibit less stable roof conditions than entries with normal (nonchannel) roof. Paleochannel deposits comprise only one-fourth of the mapped study area; however, they contain one-half of the hazardous roof. This study deter-mined that rock strength evaluations, including rock quality designation (RQD), unconfined uniaxial compressive strength testing, and point-load testing, must be accompanied by underground observations. Suggested remedial support techniques include angled and/or longer tensioned bolts, steel mats or crossbars, steel sets or cribbing, and roof trusses.

Jan 1, 1987

Control the release of ground-water into active underground coal workings by short-term pumping from dewatering wells sited on fractures. Approach The sudden release of fracture-stored groundwater into underground coal workings often occurs when mine workings are developed beneath fracture valleys, Pumping from fracture trace-sited dewatering wells, prior to development of the underlying workings, can be an efficient means of intercepting fracture-stored groundwater before it is released into the mine. Dewatering operations are discontinued once the underlying mine workings have been fully developed, and the maximum possible reduction in fracture storage has been achieved through pumping. How It Works An aerial photographic technique known as fracture trace analysis is used to site dewatering wells on rock fractures in a valley bottom. Downhole caliper and temperature logs are used to assess the fracture flow potential of each dewatering well drilled.

Jan 1, 1987

By A. Adams

The Bureau of Mines determined the composition of the vapors liberated during thermal decomposition of aluminium nitrate nonahydrate. Small samples were heated from room temperature to 5500 C with initial heating rates from 500 to 2000 C/min. Gases were rapidly swept away from the heated chamber with Ar and subjected to immediate analysis in order to minimize reaction between the components. In addition to H20, four N-containing compounds were identified: HN03, N02, NO, and N20. Nz could not be determined in the presence of the nitrogen oxides, and at-tempted separation from the oxides led to the formation of more nitrogen. Relative amounts of each component were found to vary over a period of time; however, total amounts measured with different heating rates were reasonably constant and were typically as follows: 84.2 pct HN03, 7.1 pct N02, 4.3 pct NO, and 4.2 pct N20. HN03 and NO were determined from chemical reactions with a permanganate solution, N20 was measured with a mass spectrometer, and NO2 was measured with a spectro-photometer. Details of the methods used are described. Since NO2 and NO can readily be converted to HN03, about 96 pct of the N from the decomposition can be recovered as HN03

Jan 1, 1987

By Steven R. Munts

In 1985, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied 39,420 acres of the 60,960-acre Skedaddle Wilderness Study Area in order to evaluate its identified mineral resources. There are no known mines or mining operations in the study area. None of the prospects or claims in or within a 1 mile peripheral zone around the study area have recorded production. At least 276 recorded lode, 6 unrecorded lode, and 29 placer claims have been located in and within about 1 mile of the study area. Approximately 191 of the claims are in the study area. Four of these were current in 1985; all four are wholly or partly inside the study area. None of the study area was being explored by private industry in 1985. Metallic and nonmetallic commodities present in the study area consist of gold, mercury, perlite, basalt, pozzolan, stone, and sand and gravel. Perlite is represented by a single deposit which contains 184,000 tons of subeconomic resources in and adjacent to the study area. No other sites contained identified resources. There are no other identified nonmetallic resources in the study area. Occurrences in and near the study area contain small amounts of gold and mercury in vein-type deposits and show characteristics similar to bulk-tonnage, low-grade gold deposits. No base-metal resources were identified. The gold and mercury mineralization and perlite deposit are spatially related to a volcanic center located in the Skedaddle Mountains. Prospects in the Skedaddle Mountains may contain both precious metals and perlite resources, but additional work is required to adequately delineate these areas.

Jan 1, 1987

By G. T. Fisher

The material requirements of carbide cutting tools for machining steel and cast iron are dependent on WC bonded with Co, with additions of TaCand TiC. The Bureau of Mines is conducting research to devise substi-tute materials, based on Ni-alloy-bonded TiC, for C-5-grade cutting tool applications. This substitution would result in less dependence on foreign sources for Co, Ta, and W, and use of lower cost materials. In this preliminary study, the Bureau investigated the effects of composition and processing variables on the transverse rupture strength and hardness of Ni-alloy-bonded TiC to identify compositions that exhibit promising mechanical properties. Further systematic modification of these compositions by soild-solution strengthening additions would subsequently be evaluated to obtain cutting tool materials with requisite properties and performance for C-5 applications. Compositions for evaluation were prepared by a powder metallurgy method of cold-pressing and liquid-phase sintering. Complementary analysis of compositions included chemical analysis, X-ray diffraction, energy-dispersive X-ray spectro-scopy, and density measurements. Based on results of this investigation, promising compositions were determined to be 59.37TiC-25Ni-5Mo-lO.63Mo2C, 59.68TiC-25Ni-3.33Mo-1.77Mo2C-6.67W-3.55WC, and 59.35TiC-25Ni-l.67Mo-3.54Mo2C-3.33W-7.1WC.

Jan 1, 1987

By Michael S. Miller

In 1985 and 1986, at the request of the U.S. Forest Service, the U.S. Bureau of Mines studied the 17,000-acre Pyramid Peak planning area in order to evaluate its identified mineral resources. The planning area is located in Riverside County, CA, 15 miles south of Palm Springs. The planning area contains marginally economic resources of marble and mica, subeconomic resources of garnet and occurrences of gold and tungsten. The area is underlain by marble, quartzite, schist, migmatite, intrusive rock, and a wide zone of intensely sheared rock. Quaternary stream, landslide, talus, and colluvial material overlie the older rocks. Ten claims for marble in or overlapping the southwest and southeast parts of the planning area are current (1986). Many other current claims are outside the planning area, adjacent to or within 2 miles of the southwest and southeast corners. Hundreds of millions of tons of inferred, marginally economic marble in and near the planning area may be mined for cement or lime after other developed resources near markets are depleted or if large-scale construction or other markets develop nearby.

Jan 1, 1987