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By A. D. Pelton

The evolution of thermodynamic models of molten salts and slags, starting with Temkin in 1948, has culminated in today?s sublattice models. These modern models have permitted the development of large thermodynamic databases of model parameters, which can be used to calculate and predict accurately the properties of multicomponent solutions. The model parameters are mainly obtained by the critical evaluation and optimization of available thermodynamic and phase equilibrium data for binary and ternary subsystems. The models are then used to estimate the properties of multi component slags and salts from these assessed binary and ternary parameters. When used in conjunction with thermodynamic databases for solids and solid solutions (salts, oxides, sulphides, metals, etc.), other liquid solutions (such as liquid metals),and gases, these databases permit the calculation of complex multiphase equilibria in multicomponent systems, with applications in a wide variety of industries. These calculations can be performed with general commercial software for Gibbs energy minimization, which can also be incorporated into process simulation software packages. Keywords: slags, salts, solution models, thermodynamics, phase diagrams, oxide systems, molten salts

Jan 1, 2004

By P. Mokwena

Paper written on project work carried out in partial fulfilment of BSc (Hons) in Chemical Engineering Diamond synthesis has attracted a great deal of interest because of its exceptional properties and various applications. In this study, the chemical catalytic vapour deposition (CCVD) method was used to synthesize diamond films using acetylene as carbon source and hydrogen as carrier gas at a temperature of 1000°C, and their thermodynamic stability was studied. Photographic analysis revealed that these products are diamond films, Ramman spectroscopy confirmed that they are graphitic while confocal laser scanning microscopic image analyses proved that these diamonds films have structural defects due to iron impurity from the catalyst precursor. The quantity of diamonds films produced is also proportional to the acetylene to hydrogen ratio but these films are larger in size at lower acetylene to hydrogen ratio. Thermogravimetric analyses showed that transformation of these materials begins at 25°C but could not be used to determine if a temperature range below 25°C exists. The stability of these CCVD-synthesized diamonds also increases below 25°C when stored at different temperatures.

Jan 1, 2007

By P. Fredriksson, S. Seetharaman

In the ladle refining process, the ?FeO?-content of the ladle slag is of great importance in the chemistry as well as the energetics of the process. An optimization of the process requires an accurate knowledge of the thermodynamic activities of ?FeO? in the ladle slags. Due to the discrepancies in the existing data, renewed attempts are being made at the Royal Institute of Technology to generate reliable data for binary, ternary and multi component slags containing ?FeO? at steelmaking temperatures. In order to measure the activities of ?FeO? in the slags, a gas equilibration technique was employed in the present work. The slags, kept in Pt-crucibles, were equilibrated with a CO-CO2-Ar gas mixture and quenched after equilibration. The chemical composition of the slag was analyszed. From a knowledge of the thermodynamics of Fe-Pt system, the ?FeO? activities in the slag could be evaluated. The results of the present studies, together with other literature values, were optimized in the slag software, THERMOSLAG® developed in the Royal Institute of Technology, Sweden. The results of the optimization are presented. Model calculations were performed with the KTH slag software, THERMOSLAG®, by using plant data from OVAKO Steel, Hofors, Sweden. It was found that oxygen estimations in the metal from the ?FeO? analyses of slags, obtained by conventional sampling and analysis methods, where less reliable. Estimation of the oxygen levels utilizing the sulphur partition between the slag and the metal were carried out using the THERMOSLAG® software. Reasonable estimations of the oxygen contents in the metal confirmed that this could be a very useful tool for the plant operator. Keywords: ladle, thermodynamics, slags, ?FeO?, experimentation, modelling, sulphur partition

Jan 1, 2004

By J. Petersen, H. Naderi, M. H. Nikzad, M. Karimi

In this research, the thermodynamic study of sodium persulfate (Na2S2O8) solution in the presence and absence of H2SO4 and Fe3(SO4)3 was done. Eh-pH and equilibrium distribution diagrams were constructed using Outotec HSC Chemistry Software and the main stable ionic species were determined. Also, the mean activity coefficient and Pitzer model coefficients were evaluated. Effects of system composition, sodium persulfate concentration and temperature were investigated. According to the results, HS2O7 -, HS2O8 -, S5O3 2-, S4O3 2-, S3O3 2-, HS- and NaSO4 - are the main stable species in these three systems. Increasing of sodium persulfate concentration resulted in disappearing of SO4 2- and the appearance of NaSO4 -. The main effect of increasing the temperature from 25 to 75oC, is changing the stability regions of HS2O7 -, NaSO4 -, SO4 2- and S2-. From equilibrium studies, it was concluded that at 25 and 50oC, increasing the persulfate concentration results in a 55-60% decrease for HS2O7 - and an 20- 30% increase for HS2O8 -. At 75oC, HS2O8 - becomes the main species and its percentage decreases with increasing the persulfate concentration. Keywords: Thermodynamic, sodium persulfate, activity coefficient

Jan 1, 2020

By F. Bonnet, J. Lehmann, H. Gaye

A review of thermodynamic information and models of slags, including associated software when available, is presented. The pertinence and accuracy of these models is discussed by comparison of their predictions for various slag thermodynamic properties with the available experimental data. Practical industrial applications will be illustrated by a literature review of the dephosphorization process of ferromanganese alloys and by the description of Ti behavior during silico-manganese alloys production. This latter example will show how the thermodynamic models have been used to propose a flotation treatment at low temperature to enhance TiC removal.

Jan 1, 2004

By S. E. Olsen, K. Tang

Slag-metal and slag-metal-gas heterogeneous equilibria involving MnO-containing slags have been simulated using recently developed Mn-based alloy and IRSID oxide thermochemical databases. A large number of experimental equilibrium data have been used to verify the calculation results. The experimental slag-metal and slag-metal-gas equilibria in MnO-SiO2binary, MnO-SiO2-CaO and MnO-SiO2-Al2O3ternary, MnO-SiO2-CaO-Al2O3quaternary andMnO-SiO2-CaO-Al2O3-MgO higher-order system can be reproduced within experimental uncertainties. The influence of temperature, CO partial pressure and slag chemistry on the Mn-and Si-distribution equilibria have been quantitatively evaluated. This leads to a sound basis for optimizing the manganese ferroalloy production processes. Key words: MnO-containing slag, manganese ferroalloy, equilibrium simulation, thermochemical database

Jan 1, 2004

By M. J. Makhula, R. M. S. Falcon, S. O. Bada, L. M. Falcon

"SynopsisThe combustion and co-combustion behaviour of macadamia nut shell, high-ash coal, and anthracite, along with their blends was studied using thermogravimetry. The reactivities of all samples were analysed in air, oxygen, and CO2 atmospheres and at different heating rates from 10 to 40°C/min. Macadamia shell was found to have a lower ash content, 0.36%, than coal with 27.49% ash. The calorific values were similar, 19.64 MJ/kg and 19.44 MJ/kg respectively. The differential thermogravimetric results indicate that as the heating rates increase the ignition, peak, and burnout temperatures increase significantly, leading to high combustion rates. The interaction between the fuels was evaluated using the weighted average model, and the results indicated that there is more synergetic interaction between 20% macadamia plus 80% coal under oxygen than in air and CO2 atmospheres. The results of the investigation provide the combustion and co-combustion characteristics of various samples and their blends and indicate their combustion compatibilities. IntroductionThe global macadamia nut industry is developing at a very rapid rate. South Africa is currently the world’s third largest producer, with a production of about 35 000 t as of 2012 (Department of Agriculture, Forestry and Fisheries, 2013), compared to 840 t produced in 1996. The greatest numbers of the macadamia nut farms in South Africa can be found in Mpumalanga, Limpopo, and KwaZulu-Natal provinces, with Mpumalanga as the largest producing area. There are many factors influencing the increased demand for macadamia nuts, the most important factor perhaps being their nutritional value (California Dried Fruit and Nuts, 2011; MPC, 2014) and their suitability as a feedstock for manufacturing cosmetics, bakery products, nut paste, chocolates, sauces, and ice-cream. As a fuel, macadamia shell has a high heating value ‘as-fired’ of about 20.71 MJ/kg (Vhathvarothai et al., 2013), which could in turn be used in drying the nust, and the shell could also be milled and applied as a fertilizer."

Jan 1, 2015

By A. Sissing

Paper written on project work carried out in partial fulfilment of M.Sc. (Chemical Engineering) degree Thermophilic bioleaching, conducted at temperatures in excess of 65°C, provides considerable benefit over mesophilic bioleaching, particularly through extending the extent of leaching of base metal minerals such as chalcopyrite. Thermophilic bioleaching is facilitated through a group of micro-organisms known as the Archae, well adapted to extreme environment. In order to maximize the space time utilization of the stirred tank reactor in the thermophilic bioleaching process, it is desirable to maximize the loading of the finely divided mineral phase present while not adversely affecting the microbial performance. In this paper, the effect of the loading of the solid particulate phase on the bioleaching performance of Sulfolobus metallicus was studied in a stirred tank reactor. Emphasis was placed on the effect of the concentration of the finely divided solid phase (35 ? 75 µm). A model system comprised of 3% (w/v) pyrite in the presence of varying quantities of quartzite in the range 0 to 24% (w/v) was used to obtain the different solids concentrations. The bioleaching experiments revealed similar bioleaching performance in the presence of 3 to 18% (w/v) total solids. Above 18% (w/v) total solids (15% quartzite loading), bioleaching was impaired progressively with increasing solids concentration. At the highest solids loading studied of 27% (w/v), bioleaching was still observed. In terms of mass transfer, oxygen transfer potential was not significantly influenced in the bioleaching process over the range of solids investigated.

Jan 1, 2003

By M. Q. W. Jones

This paper presents a compilation of physical properties of rocks from the Bushveld Complex. The database consists of more than 900 measurements each of thermal conductivity and density. The data are well distributed from localities around the Complex and most rock types are well represented. Thermal conductivity and density are shown to vary widely in the ranges 1.8-4.2 W m-1K-1and 2600-4200 kg m-3respectively. Although only 190 heat capacity measurements are available, this parameter is quite uniform for most rock types present, 800-900 J kg-1K-1, except for chromitite, which has a lower average, 750 J kg-1K-1. Rocks encountered in deep platinum mines are particularly well characterized and this has important implications for prediction of mine refrigeration requirements. The heat flux into a semi-infinite region with properties typical of the Bushveld Complex as a function of time is substantially lower than an equivalent model for the Witwatersrand Basin.

Jan 1, 2015

By J. D. Austin, D. G. Kringe

Rates of return realized on investments in the gold mines of the newer goldfields outside the Witwatersrand were calculated and analysed over various time intervals and on various bases. It is shown that these rates of return are strongly correlated with changes in the gold price and cannot be equated with the returns that are expected when investments are made, and that the changes in gold price also affect the rates of return on the Johannesburg Stock Exchange as a whole. These correlations are used, together with a limited application of the Capital Asset Pricing Model, to suggest the expected levels of threshold returns in real terms for new mining projects, for projects on existing mines, and for share valuations.

Jan 1, 1980

By M. A. Belokrys, F. O. Milovich, D. D. Aksenova, V. A. Ignatkina, V. A. Bocharov, A. A. Kayumov

Copper remains one of the most sought-after metals in the industry. Tennantite (Cu12As4S13) and tetrahedrite (Cu12Sb4S13) that occur in pyrite copper, copper-zinc and polymetallic ores are an additional reserve for increasing technological parameters of flotation. Pyrite mass (85% and more) has similar flotation properties to other sulfide minerals, and imperfection of reagent regime is a common problem that occurs during quality copper concentrate processing. Due to tennantite's and chalcopyrite's differences in flotation properties with butyl xanthate at pH > 10, tennantite often reports to the flotation tails. Hight alkalinity of the medium increases the oxidation level of sulfide minerals, thus increasing the concentration of S2O3 2-, SO3 2- SO4 2-. At processing facilities in the Russian Federation, the concentration of thiosulfate ions in pulp is in the range of 0.5 to 1.5 g/l and higher, which leads to a decrease in flotation activity of the tennantite. The effect of butyl xanthate (as standard), thionocarbamate, dithiophosphate and M-TF (a mixture of dithiophosphate and thionocarbamate) on monomineral (tennantite and pyrite) flotation in the presence of sodium thiosulfate was studied. The variable parameters of the "thiosulfate-collector" flotation complex were thiosulfate concentration (100-900); pH (8-12,5). The scientific methods included contact angle for hydration assessment; TEM for surface studies; UV spectroscopy and iodometric titration for solubility control. Comprehensive studies have established a connection between the concentration of thiosulfate ions and tennantite flotation selectivity. Flotation activity of tennantite is higher at pH 8 with a thiosulfate concentration under 300 mg/l. Pyrite remains active with butyl xanthate under the same conditions. TEM images of the surface films of the collectors on pyrite were acquired at pH 8. The MTF provides the biggest difference in adsorption, wettability and flotation activity between tennantite and pyrite at pH 8 and thiosulfate concentration under 300 mg/l, in comparison with butyl xanthate. The results of the research will be applied to improve selective reagent regimes of tennantite minerals flotation. Keywords: Tennantite, pyrite, chalcopyrite, sphalerite, flotation, sulfhydryl collectors, thiosulfate, adsorption, mechanism, reagent regime

Jan 1, 2020

By S. A. C. Liedberg, M. H. Fricker

The conference was divided into a total of 12 different sessions. Apart from the keynote addresses, the papers covered many aspects of open-pit mining, from mine design and blasting techniques to mining operations and equipment, as well as water management and rehabilitation. A number of case studies were also presented. Most of the 68 papers originated from Australia; however, presentations were also made by representatives from Chile, Indonesia, Papua New Guinea, and South Africa. The keynote papers dealt with subjects such as the economics of open pits, project planning of a new large copper deposit, management principles, and rehabilitation strategies.

Jan 1, 1993

By J. Nell

Heavy mineral deposits often contain relatively high levels of radioactive elements (thorium and uranium in particular).It is difficult to obtain clean separation of ilmenite and monazite (the main impurity mineral containing radioactive elements), and physical intergrowths of the two minerals are, in fact, not uncommon. As a result, ilmenite concentrates obtained from such deposits often contain high levels of thorium and uranium. Because of the large negative free energies of formation of ThO2and U3O8boththorium and uranium report to the slag during smelting and if an ilmenite concentrate contaminated with monazite is used to make high titania slag, the concentrations of these elements in the slag end up about 40% higher than in the ilmenite feed. Previous work, patented by RGC Mineral Sands Limited, and subsequently confirmed by Mintek, showed that radioactivity may be reduced by roasting an ilmenite concentrate with borax at 1000°C to 1100°C and leaching it with hydrochloric acid1. It is evident that the cost of an ilmenite roast/leach process will be high and there may be economic benefits in removing the radioactive elements from the slag instead (the volume of slag to be treated is smaller than the volume of ilmenite feed). To remove radioactive elements from the slag it is necessary to know how these elements occur in the slag. Inother words, the distribution of uranium and thorium between the various oxide, silicate and metallic phases in high titania slag must be determined. Once the deportment of thorium and uranium between the various phases ha sbeen determined, an appropriate process for slag purification can be developed. Test samples High-titania slag was prepared in a pilot-scale DC furnace from ilmenite concentrates with different levels of uranium and thorium. Subsequently, ten slag samples representing a range of compositions were selected for bulk chemical analysis, scanning electron microscopy and micro-analysis. The samples were crushed to a maximum particle size of 1 mm and from each sample a 20-kg batch was riffled out for analysis. Bulk chemical composition Chemical compositions of the samples selected for test work are given in Table I. TiO2, Al2O3, SiO2, MgO, MnO, FeO and V2O5were analysed by ICP-OES, Na2O, CaO andCr2O3by atomic absorption spectroscopy and U and Th by XRF (the XRF detection limit for U and Th was around 4 ppm). The ?B? series has a higher silica content than the others as a result of small silica additions that were made during smelting. All samples have elevated alumina levels as a result of furnace refractory contamination during smelting. As expected, there is an inverse relationship between the concentrations of TiO2and FeO in the samples (Figure 1).The TiO2and FeO levels are similar to the levels found in industrial slags2. Extreme conditions of reduction under which reduction of more ?refractory? oxides (e.g., chromia, magnesia, silica, alumina and even urania and thoria) might take place were not explored in the study. Note that BB1and BBB1 contain more than 7% combined silica and alumina (SiO2as a flux addition during smelting, and Al2O3from refractory contamination) and they do not fall on the general trend defined by the other samples. The U and Th concentrations of sample E2 is noteworthy. In the preparation of slag E2, monazite concentrate was added to the ilmenite to increase the concentrations of radioactive elements in the slag. This was done primarily to facilitate the detection of Th and U during the phase chemical characterization of the slag. Radioactivity measurements Gamma ray emissions from the samples were measured [ ]

Jan 1, 2007

By H. Griesel

The overall supply of platinum is forecast to rise more than the demand, and market deficit will narrow somewhat, but is still substantial at about 480 000 ounces. Because of this deficit, the price of platinum is expected to remain high, not taking into account the impetus from funds and speculators. With this strong demand for platinum and the high price, platinum producers still need to initiate projects to not only sustain current production, but also expand output into the high demand. However, the rise in the platinum price does not entirely offset the drop in revenue due to the strong rand. Consequently, in the current economic environment, executives and managers are under extreme pressure to initiate only the highest yielding projects and implementing them successfully. During the initiation phase of a project, the cost of changing concepts is the least, and strategic project decisions are the most important. It is during this phase that the most value can be added to a project, therefore requiring inputs from highly skilled, creative and experienced people. This paper will discuss thought processes and paradigms during the initiation of projects that will assist project owners in the selection and initiation of successful and profitable projects. The project initiation process will also be discussed outlining selection models, risk analyses and funding considerations.

Jan 1, 2004

By F. T. Cawood

This article offers a personal and independent view on the threats to the sustainability of the South African minerals industry. It argues that if the six identified threats of insufficient spending on research and development, general standard of education, nationalization, inadequate infrastructure, Aids prevalence and labour inefficiency are not acted upon as a matter of urgency, the future of the mining industry, along with its important contribution to the economy, is at risk.

Jan 1, 2011

The finite element method of stress analysis is nowadays widely used in the fields of mining, mechanical and civil engineering. This paper presents a short description of the three-dimensional method, in which the elements used are arbitrary hexahedrons. Two examples of the application of the method are presented, namely, calculation of the elastic stress distributions in a coal pillar and in an opencast mine.

By X. Jia

The ability to perform three dimensional imaging at micron-scale resolution of real mineral floc sediments and structures using commercially available Micro X-ray Tomography (XMT) instrumentation can be used for the analysis of aggregates and granules, liberation and dewatering of sediments. This paper presents are view of recent work by the authors relevant to the mining and minerals industries. It covers three main topics: X-ray imaging of agglomerates and multi-component mineralic particles,, permeability of sediments, and dissolution of granules with potential application to heap leaching.

Jan 1, 2008

By J. -C. Tricket, W. A. Düweke, S. Kock

The high-resolution three-dimensional (3-D) seismic reflection data acquired for Impala Platinum between 1998 and 2002 in the western Bushveld Igneous Complex form an integral part of Impala?s mine planning and development programme. These data are of sufficiently high quality to provide unprecedented 3-D models of the geological structure of the Merensky Reef and UG2Chromitite Reef, from which the mine deduces the size, geometry and distribution of mineable blocks. Conversely, the seismic data details zones of un-mineable ground caused by structural disturbances in the form of potholes, fault zones and pegmatoid intrusions. Furthermore, variations in dip and strike are well imaged, allowing the mine planners to optimize the mine design and layout. Current interpretation work is focused on enhancing the accuracy of these geological model seven further through the analysis of ?seismic trace attributes.? Preliminary testing on the Impala Platinum 3-D seismic volume has shown that attribute analysis has the potential to illuminate a number of geological reef disturbances that are otherwise ?invisible? in the original seismic time volume. Potential areas of improvement include inter alia: ?Improved definition of major fault zones ?Improved definition of zones of reef depression (?slumping?) ?Identification of reef terracing and/or reverse dip.. Keywords: 3D reflection seismics; Impala Platinum Ltd; seismic attribute analysis; Seismic Micro Technology (SMT); rock solid attributes; dip-azimuth; instantaneous phase and similarity.

Jan 1, 2004

By J. -C. Trickett

The high-resolution three-dimensional (3-D) seismic reflection data acquired for Impala Platinum between 1998 and 2002 in the western Bushveld Igneous Complex form an integral part of Impala?s mine planning and development programme. These data are of sufficiently high quality to provide unprecedented 3-D models of the geological structure of the Merensky Reef and UG2 Chromitite Reef, from which the mine deduces the size, geometry and distribution of mineable blocks. Conversely, the seismic data details zones of un-mineable ground caused by structural disturbances in the form of potholes, fault zones and pegmatoid intrusions. Furthermore, variations in dip and strike are well imaged, allowing the mine planners to optimize the mine design and layout. Current interpretation work is focused on enhancing the accuracy of these geological models even further through the analysis of ?seismic trace attributes.? Preliminary testing on the Impala Platinum 3-D seismic volume has shown that attribute analysis has the potential to illuminate a number of geological reef disturbances that are otherwise ?invisible? in the original seismic time volume. Potential areas of improvement include inter alia: ?Improved definition of major fault zones ?Improved definition of zones of reef depression (?slumping?) ?Identification of reef terracing and/or reverse dip. Keywords: 3-D reflection seismics; Impala Platinum Ltd; seismic attribute analysis; seismic micro technology (SMT); rock solid attributes; dip-azimuth; instantaneous phase and similarity.

Jan 1, 2005

The block caving mining method is used to mine large orebodies in weak rock types. The layout for block caving requires that a considerable amount of development is carried out on the extraction drives and drawpoints at the bottom of the caving block. The development further weakens the rock mass, and stability problems arise in the extraction drives and extraction pillars. This paper describes the application of three-dimensional boundary element models in analysing alternative extraction level layouts for a block caving mine. The objectives were to establish whether the use of lateral pillars between drawpoints was warranted, and whether the lateral pillars should be offset or not. The stability of the rock mass within the pillars as well as the stability of the extraction drives were taken into account. The results showed that after undercutting, the horizontal and vertical stresses in the extraction level would be reduced. The lateral pillars would significantly improve the stability of the extraction pillars and extraction drives. There would be a minor improvement in stability if the lateral pillars were offset.

Jan 1, 1987