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By R. J. Hundermark, L. R. Nelson

The critical importance of tap-hole design and management to furnace performance and longevity is explored through examining some of the specific matte, metal and slag tapping requirements of non-ferrous copper blister and matte converting and smelting, ferroalloys smelting and ironmaking systems. Process conditions and productivity requirements and their influence on tapping are reviewed for these different pyrometallurgical systems. Some critical aspects of the evolution of tap-hole design to meet the diverging process and tapping duties are examined. Differences and similarities in tapping practices and tap-hole management are reviewed. Finally core aspects of tap-hole equipment and maintenance are identified that are considered important to securing improved tap-hole performance and life, so pivotal to superior furnace smelting performance.

Jan 1, 2014

By R. J. Hundermark, L. R. Nelson

"The critical importance of tap-hole design and management for furnace performance and longevity is explored through examining some of the specific matte, metal, and slag tapping requirements of non-ferrous copper blister and matte converting and smelting, ferroalloy smelting, and ironmaking systems. Process conditions and productivity requirements and their influence on tapping are reviewed for these different pyrometallurgical systems. Some critical aspects of the evolution of tap-hole design to meet the diverging process and tapping duties are examined. Differences and similarities in tapping practices and tap-hole management are reviewed. Finally, core aspects of tap-hole equipment and maintenance are identified – aspects that are considered important for securing improved tap-hole performance and life, so pivotal to superior furnace smelting performance. IntroductionThe sheer diversity of tapping configurations used on industrial pyrometallurgical operations is at first bewildering. They range from historical tilting furnaces without tapholes to modern eccentric bottom tapping (EBT) tilting and/or bottom slide-gate electric arc furnaces; to classical single tap-hole multiphase tapping (e.g. metal/matte and slag); to dedicated phase tap-holes (e.g. dedicated metal/matte-only and slag-only); to dedicated phase multiple tap-hole configurations (up to eight metal/matte-only tap-holes and six slag-only tap-holes); to more esoteric metal/matte-only siphons and slag overflow skimming, e.g. Mitsubishi Continuous Process (Matsutani, n.d.). This can be further complicated by periodic batch tapping; consecutive tapping on a given taphole; alternating tap-hole tapping practice; near-continuous slag-only tapping, with discrete batch matte/metal tapping on higher productivity, but low metal/matte fall (<20% by mass feed) Co and Ni ferroalloy and platinum group metal (PGM) matte furnaces; near-continuous tapping through batch tapping of individual tap-holes that are opened consecutively (Tanzil et al., 2001; Post et al., 2003); to fully continuous tapping on coupled multi-furnace cascades (Matsutani, n.d.)."

Jan 1, 2016

By C. O. Aksoy, G. G. U. Aksoy, A. Fisne, I. Alagoz, E. Kaya

Coal produced in underground mines is transported to the surface by means of conveyor belts throughout long roadways. The combustion of belts puts a large number of employees at great risk. Underground collieries differ from other underground mines -due to the combustible nature of the product. The most prevalent cause of belt fires in underground coal mine is spontaneous combustion due to oxidation of the coal, which also enables the conveyor belt to burn over time. In 2014, a belt fire in an underground coal mine in Manisa-Soma, Turkey caused 301 fatalities. A study has been conducted on this accident for approximately 3 years, consisting of combustion tests in a purpose-built research gallery, comparison of the test results with mine records of the accident, and CFD modelling of the mine environment. The intensity of the fire was sufficient to redirect the air flow underground, causin large amounts of toxic gases to fill almost the entire mine in approximately 15 minutes. It is recommended that CFD analysis be used in planning emergency action strategies in underground mines.

Dec 13, 2023

By N. Duda, P. Śliwiński, P. Stefaniak, B. Jachnik

Ventilation and air-conditioning are some of the most energy-consuming processes in deep underground mining. Additionally, the energy consumption of these processes systematically increases along with the expansion of the mine. Therefore, proper energy efficiency assessment and consumption forecasts of these systems are particularly important in modern mines for ongoing tracking and planning of the likely costs. In the article, a short-term prediction model for surface air–conditioning stations is described. This model takes into account dependencies that were identified, based on the data from the supervisory control and data acquisition (SCADA) systems. These dependencies between the response value and the external conditions are then incorporated into the model. This way, for example, the ambient temperature or the total number of specific days of the week (with sometimes significantly lower or higher than the weekly average energy consumption levels) are included. Taking into account these dependencies, and e.g. forecasted average monthly temperatures allow us to include the seasonality of energy consumption in the presented model. In the article, a sample energy efficiency analysis of the A/C system based on an example of the KGHM Polish Copper Polkowice-Sieroszowice mine is performed. The results of the solution proposed in the article are then evaluated, and compared to the currently functioning, more basic forecasting methods. However, given the general nature of the dependencies used in the model, similar solutions could be used in other case studies.

Sep 1, 2021

By S. T. Johansen, B. T. Løvfall, T. Rodriguez Duran

In this paper we develop a physics-based model for lining erosion in steel ladles. The model predicts the temperature evolution in the liquid slag, steel, refractory bricks, and outer steel shell of the ladle. The flow of slag and steel is due to forced convection induced by inert gas injection, vacuum treatment (extreme bubble expansion), natural convection, and waves caused by the gas stirring. The lining erosion takes place by dissolution of refractory elements into the steel or slag. The mass and heat transfer coefficients inside the ladle during gas stirring are modelled based on wall functions which take the distribution of wall shear velocities as a critical input. The wall shear velocities are obtained from computational fluid dynamics (CFD) simulations for a sample of scenarios, spanning out the operational space, and a model is developed using curve fitting. The model is capable of reproducing both thermal and erosion evolution well. Deviations between model predictions and industrial data are discussed. The model is fast and has been tested successfully in a ‘semi-online’ application. The model source code is available to the public at [https://github.com/SINTEF/refractorywear].

Apr 16, 2024

By C. Ndou, T. Mothupi, H. Mandende

The technological advances in efficient, rapid, and non-destructive hyperspectral core logging systems for systematic mineral mapping have led to the discovery and exploitation of new mineral deposits Hyperspectral imaging in the long-wave infrared range has been recently used successfully to identify various phosphatebearing minerals (monazite, xenotime, and britholite), with limited work on apatite associated with mafic-ultramafic layered intrusions. In this study we investigate the effectiveness of a hyperspectral imaging (HSI) system with long-wave infrared (LWIR) bandwidthsto identify apatite in the Upper Zone of the Bushveld Complex. The accuracy of the HSI results was validated by mineralogical and geochemical data. The two apatite-enriched zones detected by HSI suggesting widespread development of apatite throughout the uppermost 600 m of the Upper Zone. The lower apatite-enriched zone is approximately 40 m thick, while the upper apatite-enriched zone is about 23 m thick, consistent with previous thickness determinations by traditional logging and analytical methods. Spectral mixing observed in the response of apatite is ascribed either to the common association of apatite and olivine in these rocks, or to differences between the spatial resolution of the hyperspectral image and the size of apatite grains. The VNIR-SWIR wavelength region did not show prominent spectral features of apatite. Nonetheless, HSI in the LWIR range is effective in mapping apatite and should therefore be considered as an exploration tool. This research advances our knowledge of the reflectance spectroscopy of REE-bearing minerals, which makes it easier to detect, identify, and quantify REE-bearing silicate minerals by HSI.

Feb 6, 2023

By S. Fazluddin, K. C. Sole, M. R. Serwale, T. Coetsee

The CSIR-Ti process employs lithiothermic reduction of titanium tetrachloride feedstock to produce titanium sponge. The product is therefore contaminated by a range of lithium and chloride species. In this study we examine the effects of particle size, temperature, and HCl concentration as input leaching variables on the removal of chlorides from the crude titanium sponge. A review of the aqueous chloride chemistry of Li and Ti provided initial conditions for leaching of impurity species from the sponge. Experimental results confirm that the effectiveness of leaching and removal of dissolved impurities from the sponge are dependent on leaching kinetics, which are influenced by temperature, particle size, and morphology. Of the variables tested, reaction temperature had the strongest influence on the oxygen content of the leached product. The HCl lixiviant concentration had a negligible effect under the conditions tested. Leaching of crude titanium sponge (−10 mm size fraction after crushing) at 14°C in either 1 M or 0.032 M HCl yielded a titanium sponge product that met the ASTM standard specification for commercially pure Grade 1 titanium, i.e., oxygen content < 0.18 mass% and chloride content < 0.15 mass%.

Dec 13, 2022

By B. D. H. Knights

In November 2009 Mintek installed the FloatStar? advanced flotation stabilization system on Vale&apos;s Cauê iron ore beneficiation plant in Brazil. In September 2010 the system was upgraded to include flotation optimization. The circuit consisted of two parallel cleaner circuits producing final concentrate. The tailings from the cleaner section passed through a scavenger circuit. Large, well-instrumented feed sumps played an important role in circuit stability, presenting a good opportunity for advanced control. Previously the plant was controlled using distributed control system (DCS) level control only. The flotation circuit processes roughly 30kt/day. The FloatStar system provided advanced control of the flotation circuit as well as of the sumps feeding the circuit. The system underwent a lengthy trial to assess the benefit that it provided. Two data sets were analysed, showing performance under advanced stabilization and optimization respectively. Several validation and consistency criteria were employed to ensure the quality of the analysis. Iron recovery and iron tailings grade were used to measure system performance. The analysis showed that the system increased recovery by up to 2.7%. In addition, the system decreased the iron tailings grade by between 1.2% (from 23.5% to 22.3%) and 4.3% (from 31.3% to 27.0%) during different test campaigns. The analysis also showed that the entire FloatStar stabilization system was active for 72.7% of the time from first activation to the end of the first data set (approximately 200 days). From the analysis it was concluded that under similar conditions for &apos;ON&apos; and &apos;OFF&apos; tests, the system provides a clear benefit. It was also found that over the longer term, the system continues to provide a benefit. This finding suggests that the results were not simply due to a short-term advantage. The size of the data set, as well as the magnitude of the recovery improvements, lends considerable confidence to these results. Therefore, it can be concluded that the FloatStar control system provides substantial benefit to operations at this site.

Jan 1, 2012

By G. Akdogan, T. P. Kekana, Q. G. Reynolds

The DC arc plasma gasifier concept is currently under development at Mintek for testing the feasibility of producing syngas from waste coal fines and dry steam. The technology is intended for the valorisation of low-grade discard coals into market-quality syngas, which may then be used for largescale electrical power generation to address current grid supply challenges in South Africa. Other potential applications include feedstock for petro-chemical plants, fuel for transportation vehicles, domestic and industrial heating, and others. The proposed concept of a DC arc plasma gasifier was developed based on a plasma torch, metallurgical-based and entrained flow coal gasifiers. The principles of design and operation of the proposed gasifier are based on the concept of the Westinghouse Plasma Corporation (WPC) gasifier where the torches are substituted by graphite electrodes from which electric arc plasmas are generated. The DC section of the gasifier will be designed considering Mintek’s experience in the sealing of the furnace as carried out in the Mintek Thermal Magnesium Process. As part of the building blocks of a full conceptual design, the feasibility of the DC arc plasma gasifier was investigated through testing and modelling of its critical elements as proof of concept. The main activities of this work included pilot scale evaluation of the arc behaviour in the presence of dry steam, modelling of the temperature distribution within the reactor and explosibility studies on three different coal dust samples. Keywords: DC arc plasma gasifier, explosibility index, lower explosion limit, minimum ignition energy

Jan 1, 2020

By S. Botes, H. van der Merwe

While the refractory lining contains the process on a steady-state basis, the tap-hole must provide a channel for transport of molten materials at discreet intervals, with thermal cycling as routine. The tap-hole introduces a discontinuity in any lining, and this fact can lead to failure in the region around the tap-hole before general lining failure occurs. Hence there is a need for a rapid and reliable tap-hole repair technique that can be readily implemented in conjunction with all types of linings. The UCAR®V Repair supplied by GrafTech is a durable solution capable of repairing all types of lining designs and has been extensively utilized in the ferroalloy industry. More than 20 UCAR®V Repairs have been successfully performed in South Africa alone. This paper describes the system in general and reviews recent repairs and their unique challenges.

Jan 1, 2014

By R. T. Jones

"SynopsisScientific progress relies on the publication of ideas and experimental results that can be replicated, tested, and improved over time. The first printed book on metallurgy to have been published in Europe is considered to be De la Pirotechnia, written in Italian by Vannoccio Biringuccio, and published in Venice in 1540. Together with De Re Metallica, written by Georgius Agricola and published in Latin in 1556, this can be considered to mark the start of scientific and technical literature in this field. Scientific publishing of journal papers has been in existence for 350 years, since the world&apos;s oldest and longest-running scientific journal, the Philosophical Transactions of the Royal Society, was first published in London in 1665.The nature of scientific societies has changed significantly since the early days when regular meetings were held to discuss science and conduct experiments, and the reading of scientific papers took place, and publication of papers was undertaken to record the proceedings of meetings, often including rather robust debate. In today’s world, there is a plethora of publications, and it is close to impossible for anyone to keep up with the vast flow of information. International conferences with hundreds of presentations have taken the place of the local meetings that used to discuss a single paper or experiment. In this frenetic environment, it is essential that researchers are able to trust the material they read.The system of peer review is used to maintain standards and to improve the quality of papers. This vital system is, however, significantly flawed. There is little incentive for reviewers to invest sufficient time in picking up all errors in publications, and any ineptitude on their part is usually protected by anonymity. It has reached the point where some reviewers have mistakenly permitted the publication of hoax papers deliberately presented with a complicated scientific facade. In light of such astounding inadequacies, perhaps a more open review process would be an improvement. Electronic publishing allows errata to be linked to the original papers.There is an increasing trend towards open access for papers in scientific journals and conference proceedings, which helps to reach as wide an audience as possible. This also supports the statement in the Universal Declaration of Human Rights, which says ‘everyone has the right freely to … share in scientific advancement and its benefits’."

Jan 1, 2015

By H. Cevizci

"Numerical simulation of the plaster stemming method (PSM) was performed and compared with the conventional drill cuttings stemming method (DCSM). Many earlier in situ tests have proved that PSM can use the blast energy more efficiently than DCSM. Despite PSM generating more blast vibrations, it has advantages over DCSM such as better fragmentation and lower cost per unit volume of rock blasted. In this study, numerical simulation with Autodyn software using a 2D tool was employed to prove the efficiency of plaster stemming by comparing parameters such as pressure, Y-velocity, Y-force, internal energy, acceleration-Y, and compression. For example, the maximum pressure attained at the top of explosive column was 7 395 MPa for DCSM whereas it was as high as 11 945 MPa for PSM. Most of the computed parameters were significantly higher in PSM than those obtained for DCSM. This paper is the first study elucidating the efficiency of PSM by numerical simulation. It is concluded that PSM can save substantial amounts of money and effort. IntroductionThe stemming of blast-hole collars in surface mines with an inert material redirects blasting energy to the rock more efficiently, thus the blast-induced energy is utilized more effectively in breaking rock. With proper stemming, the gases should not escape due to loose stemming material. More efficient stemming with better confinement therefore increases the blast fragmentation. In addition, the distance of scatter is increased, giving rise to a looser rock pile that can be more easily loaded and transported. In order to improve the performance of a blast, stemming is used to help maintain the gas pressure over time (Konya and Konya, 2018). Proper stemming has been shown to increase the explosive efficiency by over 41% (Snelling and Hall, 1912).The most common stemming material in open pits and quarries is drill cuttings because of their ready availability at blast sites and the drill cuttings stemming method (DCSM) is a low-cost method. However, it has a major disadvantage in that dry drill cuttings eject very easily from blast-holes during an explosion, thus a great percentage of the blast energy is wasted and lost to the atmosphere. Cevizci (2012, 2014, 2013, 2017) studied blasting parameters in open pits and obtained better results with the plaster stemming method (PSM) in many limestone, basalt, and clay quarries. Moulding plaster is preferred for stemming because of the fast hardening time of 25–30 minutes."

May 1, 2019

By E. Lutz, M. Momayez, K. W. Brown Requist

As real-time air quality monitoring becomes more prevalent in US underground mines, it is important to provide the highest data reliability with the fewest possible sensors. Real-time sensors remain costly, and these costs are not exclusively financial; the time required to install, calibrate, and maintain real-time sensors poses a large barrier to widespread implementation. Current atmospheric monitoring systems typically rely on displaying point-specific values. This requires operators to infer real-time airborne contamination distributions. Monitoring and control software utilizing mine ventilation network (MVN) solvers has been implemented in limited cases because of their ability to simulate ventilation systems quickly, but these solvers use a one-dimensional representation of the mine, limiting spatial resolution of estimated distributions. Computational fluid dynamics (CFD) has likewise been considered as a means to improve spatial resolution, but processing times prevent its use as a basis for monitoring and control. For the real-time monitoring of airborne contamination distributions, we propose a spatial interpolation method that can estimate the distribution of airborne contaminants in near-real time. This method provides a middle ground between fast processing times and increased spatial resolution. With the use of a pathfinding algorithm and optimization through absolute percentage error minimization, this method outperforms spatial interpolation with a Euclidean distance. By providing contamination distribution information to operators, this method and its derivatives stand to outperform current atmospheric monitoring systems.

Apr 16, 2024

By D. O’Connor, A. Pytlik, D. J. Corbett

The resistance of yielding rockbolts to multiple impact loads was tested by means of a drop hammer. The methodology was based on the ASTM D7401-08 standard as well as the requirements specified for rockbolts by Luossavaara-Kiirunavaara Aktiebolag (LKAB – a Swedish mining company) and the Safety In Mines Research Advisory Committee of South Africa (project number GAP 423). During the tests, the loading force and bolt elongation were measured with a sampling frequency of fs = 19.2 kHz. In order to analyse the phenomena involved, the tests were recorded using two independent high-speed video cameras (600 and 1000 frames per second) and one thermal camera (128 frames per second). The tests demonstrated that all the samples transferred double the gravitational potential energy of Ep = 50.85 kJ from the impact load of mass m = 2825 kg and impact velocity of v = 6.0 m/s without failure. Damage to the bolt-resin contact in the upper anchoring zone of the bolt in the steel tube occurred after subsequent impacts. As a result, the macro-deformed bolt exhibits additional yield, and its operation following the shearing of the resin bond is similar to that of a ‘cone bolt’. Only one test resulted in damage to the threaded bolt rod-nut coupling, during the fourth impact; however, no damage to the bolt-resin contact zone was observed.

Nov 6, 2023

By J. A. Theron

"This paper provides guidelines on performing mass and energy balance modelling involving coal and coal derivatives. Usually, the inputs to a pyrometallurgical process would be specified in terms of elements and compounds. Reliable thermochemical data is more widely available for species involving uniquely defined, relatively smaller molecules. However, in the case of coal, the molecules are extremely large and not uniquely defined. Consequently, modelling processes involving coal and its derivatives have several potential pitfalls. These are outlined in the present paper. The main findings are as follows:•,Coal proximate analysis should not be regarded as absolute; it could vary with several parameters, including heating rate •,For modelling, the use of ultimate analyses should be considered a preferable option to proximate analyses, where, ‘fixed carbon’ and ‘volatiles’ are not defined in terms of chemical composition •,Significant errors could be made if the larger molecules are neglected during calculation of the calorific value (CV) of coal gas (the gas liberated when coal is heated in the absence of oxygen) •,For elemental analyses, the oxygen content (which is calculated by balance) should be checked to ensure it is within the expected range •,For representation of sulphur in coal, double-counting due to SO3 in the ash analysis should be avoided •,Potentially, oxygen in coal could be represented as O2, H2O, CO, or CO2; however, use of some of these species without considering the experimentally determined gross CV results in significant errors in the energy balance. If coal enthalpy is calculated from elemental analyses without correction, representation of coal oxygen as H2O(l) gives reasonable accuracy (up to 6.9% error for a set of South African coals). Coal volatiles could be represented by a complex mixture of compounds, even using different oxygen-containing species than the abovementioned four, provided the enthalpy is corrected •,It is recommended that an ‘enthalpy correction value’ is incorporated in energy balances involving combustion, devolatilization, or conversion of coal and coal derivatives, e.g. coke, char, or tar. That would imply that proximate analysis, elemental analysis, as well as the gross CV would be required for all solid or liquid coal-derived substances being modelled. No other correction due to the form of carbon being different than graphite should be used, as that would imply doublecounting some effects."

Jan 1, 2014

"Coal seam gas problems can adversely affect the safety and productivity of underground coal mines, leading to fatalities and financial losses. Conventional gas management technologies using ventilation and gas drainage are unable to deal with the high and irregular gas emissions associated with high-production longwall mining. New technologies need to be developed to supplement the traditional gas management techniques to minimize the hazard of coal seam gas. Thin spray-on liners (TSLs) have gained some success for rock surface support since their introduction to the mining industry. Due to their relatively low permeability and appropriate mechanical properties, TSLs also show potential to be used as a gas management tool in underground coal mines.In this paper we review the current gas management challenges and discuss the potential use of TSLs as a gas management tool in underground coal mines. This may involve reducing gas migration into the excavations/roadways, enhancing in-seam gas drainage, and preventing spontaneous combustion. Some potential areas for future research work are identified. IntroductionWhen a coal seam is influenced by mining activities, gas stored inside is liberated into the underground ventilation system. Gas emissions have created serious difficulties for the coal mining industry around the world. Therefore, coal mines have to develop effective strategies to control the gas concentration below the threshold value to meet statutory requirements. Ventilation has been the first solution in gas management for underground coal mining. When the emitted gas cannot be effectively diluted by ventilated air, gas drainage using pre- and/or post-drainage has to be introduced. However, even with ventilation and gas drainage, irregular gas emissions usually increase the gas concentration in roadways and slow down the development rate, thus causing significant economic loss to the coal mining industry (Thakur, 2006). Therefore, new technologies need to be developed to address this issue and mitigate the explosion risk."

Jan 1, 2016

By L. Roux

The initial evaluation of a coal deposit often raises uncertainty with regard to the accuracy of the reported Resources and Reserves. Reconciliation of results from mining and beneficiation with the original raw field data highlights deficiencies in original estimations. Credible Resource and Reserve estimation forms the basis on which an entire mining enterprise is motivated, initiated, funded, and established as a commercially viable proposition. This is required for sustainable extraction purposes and to support vital downstream industries such as power generation. Accurate determination of the density of the matrix of the material being evaluated is the key to credible values being obtained for Resources and Reserves. Losses between 15% and 20% of the Resource/Reserve can be realized if incorrect densities are applied to the tonnage derivation. Coal plies and particles have different relative densities, determined by the maceral composition, rank, and mineral and moisture content. These factors in turn contribute to the moisture, volatile matter, ash and carbon contents of a coal, which affect the overall density of the raw coal. More specifically, the relationship of ash to density and the effective matrix porosity were found to be critical in solving the greater majority of the problems in predictive calculations. A major deficiency identified is the inability to determine effective porosity, allowing absorption of adventitious moisture and altering the mass of the core sample. Although the volume of the raw material is altered through crushing, the change in mass after controlled air-drying, used with the original geometrical volume of the raw material, provides a credible air-dry density and allows the determination of the volumetric change related to effective porosity. This parameter can be validated through the evaluation of proximate ash using the ash-adjusted algorithm and a correction for the inherent moisture applied to also give a credible relative density value for an air-dried sample. A combination of theoretical, empirical, and reconciliatory evaluations of the available data, taken from the exploration phase through the mining process to final production, has shown that an integrated approach using the ash-adjusted density (AAD) methodology, in conjunction with other evaluative techniques, provides credible results with a considerably higher degree of accuracy than is currently possible.

May 1, 2021

By C. V. O?Keefe

Volumetric flow and mass flow are two of the critical process parameters needed to understand and control flotation processes, with others being levels, densities, and metal analyses. Both volumetric flow and density measurements can be adversely influenced by entrained air, which will result in artificially high flow readings and artificially low mass flow calculations. Array-based instrumentation has been used successfully to accurately measure both volumetric flow of aerated slurry and the quantity of air entrained within the slurry. The latter measurement has been used to correct density measurements, thus providing an accurate mass flow calculation. A case study involving the use of this technology to measure both flow rates and air entrainment levels at Eland Platinum processing facility (concentrator) will be covered in detail. In addition, with certain traditional flow meters such as electromagnetic meters, erroneous volumetric flow rates can be recorded in the presence of paramagnetic or ferromagnetic material. The use of this array technology to avoid spikes in measurements due to steel fragments passing through the pipe will also be discussed.

Jan 1, 2012

By T. S. Kagogo

The factors affecting haul truck tyre performance and the effectiveness of the management system at Rossing Uranium Mine were investigated with the aim of increasing tyre performance in terms of running hours until failure. The main objectives were to identify the types of tyre failure, their causes and cost implications, and evaluate the effectiveness of the management system. A site severity survey, weight study, and TKPH studies were conducted to determine the pit conditions, and an analysis of failed tyres carried out. The results showed that tyre performance at the mine has declined from 2009 to date, and the increase in lost value amounted to R5.7 million in 2012 alone. The main cause of tyre failure is loose rocks in the pit. The present management system in the load and haul department is not effective enough due to operational constraints it is facing.

Jan 1, 2014

By P. O. Osifo, K. Premlall, X. Goso, R. H. Matjie, M. R. Mulaudzi, J. R. Bunt, K. Mphahlele

This study investigates the transformation of pyrolytic spent tyre-derived char and crumb rubber into high-performance activated carbon chars for industrial wastewater remediation. Utilising an in-house macro-thermogravimetric analysis system under an argon atmosphere, spent tyre-derived activated carbon char were synthesised via physical temperature activation and aqua regia demineralisation. Comprehensive characterisation using x-ray diffraction, Raman spectroscopy, and scanning electron microscopy, revealed a predominantly amorphous structure with nanoscale crystallites (~1 nm) and active surface functional groups. Proximate analysis confirmed that both crumb rubber and leached tyre crumb rubber with aqua regia derivatives achieved favourable compositions (ash ≈ 9.6%; fixed carbon ≈ 84%), comparable to commercial activated carbon (AC). At an optimal activation temperature of 850°C, the char of tyre crumb leached with aqua regia variant exhibited a significant surface area of 300 m²/g. Crucially, the tyre crumb char produced at 850°C variant developed a pore volume of 0.8 cm³/g—effectively doubling that of commercial activated carbon (0.4 cm³/g)—facilitating the sequestration of large organic molecules. In application tests using high-strength starch wastewater, char of tyre crumb leached with aqua regia and tyre crumb char, both produced at 850°C, achieved total organic carbon removal efficiencies of 60% and 50%, respectively, bridging the performance gap between waste-derived and commercial adsorbents. These findings validate waste tyres as a viable, low-cost precursor for industrial-grade adsorbents, offering a sustainable circular economy route for tyre valorisation and reduced industrial disposal costs. Future research will focus on kinetic modelling and the recovery of zinc from spent tyre-derived activated carbon char residues.

Mar 30, 2026