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By Chris D. Winkler

Vanadium-based sulphuric acid catalyst has been utilized to oxidize SO2 to SO3 since the early 1900?s. This versatile product displaced the expensive and easily-poisoned platinum-based catalyst in nearly all applications by the 1930?s. MECS has been manufacturing the vanadium-based catalyst since 1925 and today is the leading supplier in the world of sulphuric acid catalysts in a variety of forms. Currently, MECS has world-wide customer/technical support for the catalyst as well as a dedicated catalyst manufacturing plant in Martinez, California. MECS also has a strong technical and research and development program dedicated to creating new and improved products and services. This paper will describe some of the technical details of vanadium-based sulphuric acid catalysts as well as offering a unique look into how caesium-promoted MECS catalysts can be used in single and double absorption acid plants, and off-gas plants running on irregular gas feeds, to reduce emissions and pre-heater run times. An update on MECS technical services extended for use in characterizing converter performance is also presented.

Jan 1, 2009

By Chris D. Winkler

Vanadium-based sulphuric acid catalyst has been utilized to oxidize SO2 to SO3 since the early 1900?s. This versatile product displaced the expensive and easily-poisoned platinum-based catalyst in nearly all applications by the 1930?s. MECS has been manufacturing the vanadium-based catalyst since 1925 and today is the leading supplier in the world of sulphuric acid catalysts in a variety of forms. Currently, MECS has world-wide customer/technical support for the catalyst as well as a dedicated catalyst manufacturing plant in Martinez, California. MECS also has a strong technical and research and development program dedicated to creating new and improved products and services. This paper will describe some of the technical details of vanadium-based sulphuric acid catalysts as well as offering a unique look into how caesium-promoted MECS catalysts can be used in single and double absorption acid plants, and off-gas plants running on irregular gas feeds, to reduce emissions and pre-heater run times. An update on MECS technical services extended for use in characterizing converter performance is also presented.

Jan 1, 2009

By A. M. Hefny, F. P. Siew, P. G. Ranjith

Fracture initiation and propagation, being one of the most intensive subjects in rock mechanics; contribute significantly to the deformation of jointed rock masses. An experimental study on fractured granitic rock was carried out to determine the peak strength of specimen under triaxial loading conditions. The commonly observed failure mode for rock specimens in this study was found to be the shearing of the plane of weakness. The minimum peak strength of fractured rock is observed when the joint orientation is approximately 70° to the horizontal axis. Based on experimental test data, an empirical expression was developed to accommodate the effect of joint orientation and joint trace length in estimating the peak strength of fractured rocks. The predicted values of peak strength using the proposed equation well agree with the experimental results carried out on singly fractured specimens under triaxial loading conditions. The threshold stress values of crack initiation and propagation depend on joint geometrical parameters, their degree of interconnectivity, as well as surrounding stresses on the fracture plane.

Jan 1, 2003

The processes by which particles and bubbles interact capture many of the central concepts of colloid science and hydrodynamics. This area of research embraces hydrodynamics, interfacial(including capillary) forces, particle and bubble behaviour and solution chemistry. In this review, we discuss collision, attachment and stability efficiencies. We deal with the identification of a flotation ?domain?, the deformation of a bubble surface upon interaction with a solid surface, the kinetics of three phase contact line expansion and the determination of attachment efficiencies through to the direct measurement of bubble-particle interaction forces. We have recently carried out a test of collision theory where the latter embraces both inertial and centrifugal forces. The real challenge is now to quantitatively describe the behaviour of real systems and to incorporate a reliable description of the behaviour of particles in flotation froths. The approach described is very robust when applied to flotation, both from qualitative and quantitative points of view, providing an intellectual foundation for understanding this complex process in separation science and technology.

Jan 1, 1999

By M. F. Wells

The method used to salvage South Deep?s Main Shaft after it was flooded by an inrush of water at about 450 m below collar on 1 May1996 is described. The individual techniques employed in the salvage were all proven technology, but the combination in which they were applied is considered to be novel. The operation involved the following activities in order of occurrence. ?the dewatering of the shaft with submersible pumps ?the placement of a French drain on the shaft bottom muck pile ?the positioning of large diameter heavy walled draft tubes, and smaller tightening up, grout intrusion and reverse flow pipes ?the casting and curing of a structural concrete plug; the capping of the draft tubes; the intrusion of several thousand tons of cement grout into the aquifer by pressure induced reverse flow ?the sealing of the aquifer ?extensive probe drilling and sealing of the zone around the inrush point with cement and other specialized grouts ?the mining out of the plug and the re-establishment of normal sinking routines.

Jan 1, 1999

By W. V. Mutler

Present day capital costs are analyzed for a 2,000 metric tonne per day (MTPD) pyrite burning plant and compared with a sulphur burning plant of the same capacity. Power, raw material and steam production rates are then compared for the two facility types. A sensitivity analysis is conducted to highlight the impact changing sulphur, pyrite, capital and operating costs have on the relative economics of these feeds. Technological improvement effects on capital cost and energy recovery are also discussed. Besides the steam produced from the burning of pure sulphur or pyrite, plants using an advanced form of heat recovery can produce up to 10 bar steam using heat from acid formation. The quantity depends on the overall water balance which is influenced by such factors as gas strength and product acid concentration. Modern materials and innovative process design also improve the ability to increase the high pressure steam from the roaster boiler in pyrite plants above the traditional 1.25 kg of superheated steam per kg of acid produced.

Jan 1, 2009

By W. V. Mutler

Present day capital costs are analyzed for a 2,000 metric tonne per day (MTPD) pyrite burning plant and compared with a sulphur burning plant of the same capacity. Power, raw material and steam production rates are then compared for the two facility types. A sensitivity analysis is conducted to highlight the impact changing sulphur, pyrite, capital and operating costs have on the relative economics of these feeds. Technological improvement effects on capital cost and energy recovery are also discussed. Besides the steam produced from the burning of pure sulphur or pyrite, plants using an advanced form of heat recovery can produce up to 10 bar steam using heat from acid formation. The quantity depends on the overall water balance which is influenced by such factors as gas strength and product acid concentration. Modern materials and innovative process design also improve the ability to increase the high pressure steam from the roaster boiler in pyrite plants above the traditional 1.25 kg of superheated steam per kg of acid produced.

Jan 1, 2009

By Martin Banda, Gift C. Chisakuta, Moses Chabinga

KCM made a major modification to the Nchanga Tailings Leach Plant (TLP) changing the circuit from feeding post leach thickeners in parallel with leach discharge for solid ?liquid separation to a Counter Current Decantation (CCD) configuration utilising most of the existing equipment. The new circuit is aimed at improving copper recovery from approximately 70% to 79% through enhanced wash efficiency. The re-introduction of CCD circuit at elevated throughput of 46 000-tpd design was made possible due to the EIMCO E-Duc technology design which is an auto-dilution system that enhances solids settling rate. Commissioning (manual operation) which accommodated on-going operational requirements was phased and completed in January 2004. The circuit stabilised in subsequent months and in March alone an all time record copper recovery of 81.8% was achieved which contributed an extra 779 tonnes copper above the plant?s projected production plans. 100% of the project cost was paid back by end of April 2004 This paper discusses the work involved and the challenges faced during the re-commission

Jan 1, 2005

This Spotlight gives a brief summary of the proposed 1991 tax amendments of relevance to mines and mining houses. It should be read together with the author's article South African mining tax in the 1990's', which appeared in the August 1990 issue of this Journal. A number of tax amendments of relevance to the mining industry were proposed by the Minister of Finance in his March 1991 budget speech. In addition, certain other measures that may be implemented were set out in the budget review document released at the same time. A word of caution is necessary: these measures will become law only if and when they are enacted in the appropriate legislation. When this legislation is tabled in June, it may not contain all of the measures discussed below, some of the measures may appear in modified form, and other measures not discussed at the time of the budget may well appear. Unless otherwise stated, the 1991 tax amendments will affect companies with years of assessment ending in the twelve-month period to 31st March, 1992.

Jan 1, 1991

Book reviews Fiftieth Annual Report (1971) of the Safety in Mines Research Establishment, published by H. M. Stationery Office, London on behalf of the Department of Trade and Industry. Advances in extractive metallurgy and refining. This excellent volume, published by the Institution of Mining and Metallurgy, contains all the thirty papers presented at the International Symposium held in London in October, 1971. Electric Melting Practice by A. G. E. Robiette, Charles Griffin and Co. 412 pp. In recent years the application of electric furnaces to melting processes has expanded to such an extent that it has become a topic in its own right, quite distinct from the related subject of electric smelting which is still limited, for the most part, to those areas where inexpensive electrical power is available. Optimum use of manpower by A. J. van Zyl. The sixties represented one of the longest periods of sustained economic growth South Africa has experienced. At the same time it caused a certain amount of inflation and an acute manpower shortage.

By A. N. Brown

This title of is not that originally chosen for the Colloquium, which was 'A high gold price'. Such a title would have been unfortunate because it would have related the Colloquium only to the high gold price of the past two years, which reached the dizzy peak of 850 dollars per ounce in January 1980. The chosen title is, of course, the right one because it places the whole problem in the right perspective. It relates to a situation that has occurred many times before. Over the course of the past century, the gold price has periodically been inhibited from rising, so that it has undergone a succession of stepwise increments. With each increase, the relationship of the working cost to the gold price alters, and gives rise to a jump in ore reserves. Award for CMI fuelling technique Consolidated Metallurgical Industries Limited - the Lydenburg-based ferrochromium producer in the J.C.I. group - was one of the five recipients of the 1981 National Productivity Institute annual award.

Jan 1, 1981

By H. M. Friede

Notes on the composition of pre- European copper and copper-alloy artefacts from the Transvaal by H. M. Friede. Ph.D. (Visitor) Seven copper artefacts (five ingots and two ornaments) found at prehistoric sites in the Transvaal were submitted to analysis. All the artefacts showed a high copper content and a relatively Iow level of impurities. A little-known ingot type from the Limpopo Valley ('nail' ingot) is described, and its analysis is given. The analysis of two copper ornaments that come from sites dated to the 5th Century AD. and the 11th Century AD. showed the constancy of the composition of copper articles over long periods. The well-known 'Blaauwberg Ingot' was re-analysed, and the results showed that this ingot cannot be regarded as a true bronze. Analytical values for the composition of three brass artefacts from Bambandyanalo (Mapungubwe), Northern Transvaal, are given. Some aspects of pre-European bronze manufacture and brass smelting, and of early metal trade from the East Coast into the interior of South Africa, are discussed.

Jan 2, 1975

By A. J. S. Benade, N. B. Strydom, W. H. Van Der Walt

The influence of two weeks of microclimate cooling on the state of heat acclimatization by N. B. STRYDOM, M.Sc., Ph.D. (Illinois) (Fellow), A. J. S. BENADE, M.Sc. (Potch.) (Visitor), and W. H. VAN DER WALT, B.Sc. (Potch.) (Visitor) Five volunteer Black subjects were acclimatized according to the climatic-room acclimatization procedure, and their states of heat acclimatization were determined by the usual heat-stress test. The subjects thereafter wore pre-frozen jackets in a somewhat higher environmental temperature (33,9/35,6 °C). stepping at the same rate as before for four hours a day for fourteen days. The heat-stress test was repeated and followed by a similar test at the higher environmental temperature. It was found that fourteen days of microclimate cooling in a very hot environment had no adverse effect on the degree of heat acclimatization. The sweat rates during microclimate cooling remained high, even though no sweating is possible beneath the pre-frozen ice-jacket. which indicates that there is an increase in sweat rate from the areas of exposed skin.

Jan 7, 1975

By M. W. Hildyard, J. A. L. Napier

The improved design of support systems and stoping strategies when changes in depth, stratigraphy, or mine layouts are considered must rely on the designer's fundamental understanding of the deformation mechanisms adjacent to underground openings so that he can extrapolate and predict expected mining conditions. This paper presents a numerical approach to the modeling of the growth and interaction of mining-induced fractures near the edges of deep tabular excavations in brittle rock. Fractures are represented by displacement-discontinuity elements that are allowed to propagate according to prescribed growth rules. This procedure is justified by the reproduction of several features observed in laboratory simulations of fracturing around openings in blocks of rock subjected to uniaxial and biaxial compression. An attempt is then made to explain some of the attributes of the fracture zone surrounding tabular stopes. Particular questions of interest are the sequence in which fractures form and are mobilized in front of the mining face, the effect of parting planes parallel to the plane of the excavation, and the distribution of stress parallel to the hangingwall and footwall.

Jan 1, 1992

By P. J. D. Lloyd, Jill Urban, M. R. Urban

The adsorption of gold from cyanide solutions onto constituents of the reef, and its role in reducing the efficiency of the gold-recovery process by M. R. URBAN. M.Sc. (Chem. Eng.) Rand (Visitor). JILL URBAN. B.Sc. (Chem. Eng.) Rand (Visitor) and P. J. D. LLOYD. Ph.D. (Cape Town) (Fellow) Evidence for the adsorption or re-precipitation of gold from cyanide solutions onto gangue minerals of the Witwatersrand reefs has been gathered over a number of years by various investigators. The evidence from tests using radioactive tracers is conclusive and indicates thlt adsorption contributes about 0,1 g/t to the total gold loss from conventional reduction works. The loss is a function of the alkalinity and cyanide concentration of the solution, and it appears to be affected by the extent of time between milling and cyanidation. The heavy minerals appear to be the strongest adsorbers, and the clay minerals somewhat less strong adsorbers. A sensitive qualitative test based on thin-layer chromatography permits the extent of adsorption and desorption to be readily determined.

By M. H. Moys, K. S. Liddell

The dynamics of the ball load within a wet-grinding mil are examined, using measurements of torque and load position, The test equipment provided an accurate torque measurement, and the toe and shoulder positions of the load were measured by the use of a conductivity probe mounted in the mill shell. Both the variables tested-mil filing and rotational speed-influence the position of the load, and hence the torque, and have interactive effects on both the torque and the load position, An increase in mil speed and filing causes the torque to increase to a maximum value, after which further increases in speed or filing cause the torque to decrease. The position of the load toe is influenced only by the filing up to speeds of approximately 80 per cent of critical, whereas the speed and filing both cause the load shoulder to rise as their magnitudes are increased, The power drawn by the mill is predicted by the use of published equations, and these values are compared with the measured power draw.

Jan 1, 1988

By M. C. Mulligan

Counter current decantation (CCD) thickener circuits are used to recover soluble metal as pregnant liquor solution from ore leach residue. The basis of CCD operation is to concentrate suspended solids thereby minimizing liquor content in underflow slurry that flow in one direction. Then the underflow slurry liquor is diluted with wash liquor that flows in the opposite direction and the suspended solids are concentrated again and again. The amount of liquor in the thickener underflow contributes to determining the number of CCD stages required to recover the desired amount of soluble metal. Furthermore, similar results could be achieved at a lower wash quantity, reducing the size of downstream equipment. High density thickeners (HDT) are designed to use gravity and compression, and minimize the amount of liquor in the underflow thus minimizing the number of CCD stages. This paper reviews the process used to select HDTs rather than high rate thickeners (HRT) for the Ruashi II copper-cobalt hydrometallurgical process in the Democratic Republic of Congo (DRC), using laboratory HDT simulations, to CCD simulations and thickener design details.

Jan 1, 2009

By Ralph H. Nafziger

This paper reviews the major deposits of lower-grade chromite in the world, and a wide variety of methods used for the recovery of chromium from them. Gangue materials in more coarsely sized ores can be separated by gravity means, whereas flotation techniques are required for finer-grained materials. However, unless there is considerable Iron In the ores, physical means cannot increase the Cr/Fe ratios. Chemical techniques such as hydrometallurgical methods, chlorination, roasting and leaching, and smelting are required for this purpose. A greater understanding of the physical properties of chromites and the chemical reactions that take place in the recovery operations is required before. the recoveries from lower-grade chromites can be maximized. More efficient recovery operations can be realized If It can be shown definitively that the reduction of chromites occurs via either a gas-solld or solid-solid mechanism, for example. The effects of specific impurities on the chromite reduction reactions need to be better understood, as do reagent and pH control in the flotation of chromite.

Jan 1, 1982

By N. Saldía, C. Riveros, R. Hills, S. Barrera

The transport of tailings composites provided by different sources is a field of study where a limited amount of research has been conducted. Nevertheless, such systems are important sources of operational difficulties, especially in the case of high clay content tailings. The case presented in the present paper consists of a free surface flow pipeline transporting a composite of two different tailings with high clay content. It has presented operational difficulties such as partial blockages and upstream box and air intake overtopping events. In the present paper, the causes of these difficulties are identified. These include lack of complete mixing of the different tailings, multi-layered flow with low velocity and high yield values with high frictional losses. The pipeline characteristics and performance are analysed in three stages: design, initial operation and enhanced operation, the latter accomplished by means of increasing turbulence in the box located upstream from the pipeline. The last section of the pipeline and another distribution pipeline system located downstream from the pipeline have performed well. The cause of different behaviour of both systems is also assessed.

Jan 1, 2007

The block caving mining method is used to mine large orebodies in weak rock types. The layout for block caving requires that a considerable amount of development is carried out on the extraction drives and drawpoints at the bottom of the caving block. The development further weakens the rock mass, and stability problems arise in the extraction drives and extraction pillars. This paper describes the application of three-dimensional boundary element models in analysing alternative extraction level layouts for a block caving mine. The objectives were to establish whether the use of lateral pillars between drawpoints was warranted, and whether the lateral pillars should be offset or not. The stability of the rock mass within the pillars as well as the stability of the extraction drives were taken into account. The results showed that after undercutting, the horizontal and vertical stresses in the extraction level would be reduced. The lateral pillars would significantly improve the stability of the extraction pillars and extraction drives. There would be a minor improvement in stability if the lateral pillars were offset.

Jan 1, 1987