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The kinetics of cyanide loss were found to be first order under any given set of conditions, allowing rate constants to be easily determined. At room temperature and in the absence of activated carbon, some cyanide is lost by hydrolysis to hydrogen cyanide, but this does not occur to any significant extent at pH values higher than about 10. A higher rate of hydrolysis occurs when air agitation is used. When activated carbon is present, an additional carbon-catalysed oxidation reaction is responsible for a fairly high loss of cyanide. The evidence indicates a reaction mechanism that consumes oxygen and produces cyanate ion. Some of the cyanate thus produced decomposes to form a mixture of ammonia, carbonate, and urea, depending on the solution conditions. Additional cyanide is lost as a result of the adsorption of sodium cyanide by the activated carbon. At high temperatures, an additional hydrolysis reaction, which involves the formation of ammonium formate as an intermediate, occurs an/j is responsible for. a high loss of cyanide, leading ultimately to the formation of ammonia, hydrogen, and carbon dioxide. The presence of activated carbon has no effect on the rate of this reaction.

Jan 1, 1990

By N. C. Gay

The quantitative evaluation of the performance of fill materials placed in gold mine stopes is achieved by (i) measurement of the in-situ load- displacement, or stress-strain, characteristics of the materials; (ii) an objective comparison between the observed fill performance and that predicted from suitable computer modelling techniques; and (iii) objectively comparing conditions in backfilled and conventional stopes. Considerable problems have been experienced with the development of sufficiently robust instrumentation which can be installed within filled pad- docks and give reliable information over a long period of time. However, at most mines where backfill performance is being monitored, it has been possible to correlate stress measurements within the filled paddocks with strain measurements adjacent to the paddocks. The resultant stress-strain curves agree relatively well with those determined in the laboratory. Measurements in the hangingwall strata of filled and unfilled stopes indicate that the placement of fill does reduce the amount of inelastic convergence due to bed separation. Moreover, in some stopes, the rate of convergence with respect to face advance does reduce to that of the theoretical elastic convergence. Quantification of changes in the conditions at the stope face due to placement of fill has proved difficult. Observations indicate that, provided the fill is placed close to the face (- 5 m), and adequate temporary face support is used, conditions in filled panels are superior. In addition, in filled panels the damage caused by a rockburst in the stope and, particularly, in gullies is generally much less than would be expected in an unfilled stope. To quantify these improvements, parameters such as stope height, face advance and the frequency of falls of ground are being monitored.

Jan 1, 1988

By R. J. Davidson, N. Schoeman

SYNOPSIS The paper describes each of the stages in a carbon-in-pulp (CIP) or carbon-in-leach (CIL) plant, and details the steps that can be taken to achieve effective carbon management by referring to practices at the Daggafontein CIP plant. This approach was adopted because of the difficulty in summarizing current carbon management in the many varying operations in South Africa, Daggafontein being chosen as a high-tonnage dedicated well-run plant of recent design. Because of the major role played by the consumption of carbon in the operating costs of CIP and CIL plants, an attempt is made to develop a series of indexes based on quality parameters and price that can be used as a guide In the selection of carbon.

Jan 1, 1991

By H. A. Uys

The metallurgy of tin smelting In a submerged arc furnace By H. A. UYS, Ing. Metallurgy (Pretoria) (Visitor) The control of tin smelting demands a knowledge of slag characteristics and of the equilibrium reaction that governs the process. These factors are explained by reference to the tin-smelting operation at Iscor, Vanderbijlpark. In the primary cycle, it is important to obtain the highest possible FeO content in the slag. In the secondary cycle, a primary slag high in FeO gives a hardhead (iron-tin alloy) high in iron, which is essential if a high ratio of FeO to SnO is to be obtained in the secondary slag. This determines the economy of the smelting operation: the iron that is introduced into the system from the ore concentrate must go out in the secondary slag. Additions of lime are necessary in the secondary cycle but must be limited if the volume of slag is to be kept Iow.

Jan 1, 1977

By L. A. Vermeulen, D. D. Howat

New distribution functions are derived to describe the size distribution of grinding elements in ball mils. The formulations are based on the assumption that abrasive as well as impactive interactions occur during bal milling-an assumption that is supported by a large body of experimental evidence. It is shown that the functions can be used in the estimation of the magnitudes of abrasive and impactive components in the total rate of bal wear. The relative magnitudes of the wear components provide a basis for optimization of the chemical and metallurgical properties of the balls in a given milling situation. However, it is contended that these quantities are also useful indicators of the relative intensities of the abrasive and impactive interactions that are operative in the size reduction of mineral particles within ball mils. These quantities can be determined for any industrial ball mil, and their magnitudes provide practical guidelines for mil operation. The theory is used in an analysis of samples of ball charges from two industrial ball mils, and it is also applied to al the data on bal-size distributions found in the literature. The qualitative correlation between the calculated values of the wear components and the reported operating conditions is good for a variety of industrial ball mils, in conformity with the hypothesis that the relative magnitudes of the wear components are related to the milling conditions.

Jan 1, 1986

By L. W. Helle

This paper summarizes the investigations carried out into a defect involving the corners of billets rolled from continuously cast blooms, which broke open during the rolling process. As it was believed that the defect must be connected with the formation of subcutaneous blowholes in the bloom, the investigations were directed towards an understanding of the roles of the three gases involved in the process. In an extensive trial programme, samples were taken from the heat at all stages of processing, as well as from all the raw materials and alloys. The main sources of nitrogen were found to be re blows, pick-up from the alloys added to the ladle (especially graphite), and open-stream casting. The major source of hydrogen was moisture in the alloys, especially high-carbon ferromanganese and silicomanganese. Further, it was established that the moisture content of the alloys is closely related to the appearance of the defect in steels with a carbon content of less than 0,20 per cent; 72 per cent of all the defects were present in this type of steel. Most of the remaining defects were found in steels with a carbon content of more than 0,60 per cent, where the nitrogen content was substantially higher than in the lower-carbon steels. It is suggested that the defect arises from the combined effect of oxygen. nitrogen, and hydrogen. Its occurrence in low- and high-carbon steels is triggered by the formation of subcutaneous blowholes when the critical oxygen level for carbon monoxide blowholes is lowered by the presence of excessive amounts of hydrogen and nitrogen respectively.

Jan 1, 1984

By R. Singh, A. K. Dhawan, M. Dixit, H. Dev

ABSTRACT: The modulus of deformation of rock mass is an important engineering parameter required for the design of foundation of hydraulic structure and to study the interaction of rock mass and the structure at the foundation support. Different equipment and techniques are used to arrive at the design modulus value. Since any error in the estimation of modulus values results in multiplication of its effects in the analysis, it is necessary to know about the reliability of testing equipment and procedures. In the present study modulus values obtained by different in-situ equipment at different project sites have been compared. KURZFASSUNG: Der Verformungsmodul von der Felsenmasse ist technisch ein wichtiger Parameter, den man zur Konstuktion des Grunds fuer die Hydro – Tektonik, benoetigt um auch die gegenseitige Beeinflussung der Felsenmasse und der Tektonik am Traggrund zu betrachten. Verschiedene Geraete und Methoden werden angewandt, um den Ausfuehrungsmodul -Wert zu erreichen. Es ist erforderlich, die Zuverlaessigkeit der Pruefeinrichtung sowie des Verfahrens zu kennen, da irgend ein Fehler in der Abschaetzung von Modulwerten in der Analyse zu einer Vervielfachung ihrer Einwirkung fuehrt. In der vorligenden Arbeit werden die Modulwerte gewonnen aus unterschiedlichen Einrichtungen an Ort und Stelle and verschiedenen Projekt -Stellen mit einander verglichen. SOMMAIRE: Le module de deformation d’une roche est un parametre important pour la conception et realisation des ouvrages hydrauliques ainsi que pour etudier l’interaction de la roche et de la structure d’appuis de base. De divers equipments et techniques sont employes pour determiner la valeur de ce module de conception. Puisque l’effet d’une erreur d’evaluation du module devient multiplie dans l’analyse, il est necessaire de savoir la fiabilite des equipments et des methods qu’on ulilise. Dans cette etude, on a compare les valeurs des modules obtenues en employant les equipments in-situ aux sites differents de projets.

Jan 1, 2003

By N. A. Barcza

An investigation was conducted into the reactions between the slag system MnO-CaO-MgO-SiO2(AI2O3) and the alloy system Mn-Fe-Si-(C). Synthetic slags representative of plant melts and a plant alloy were reacted in alumina crucibles at temperatures of 1400°C, 1450°C, 1550°C, and 1600°C. In similar experiments, slags were used that comprised a South African manganese ore with various amounts of lime and several synthetic alloys with various silicon contents and manganese-to-iron ratios. These experiments were conducted in a vertical molybdenum-wound resistance furnace with full temperature control. Slag-to-alloy ratios were also varied during the tests. The rate of reduction of Mn.O3 and the MnO from the slag by the silicon in the alloy was extremely rapid, most of the reaction being completed within five minutes. The strongly exothermic nature of the reaction resulted in considerable generation of heat at the slag-alloy interface, causing convectional stirring of the contents of the crucible and promoting the rate of reaction. Equilibrium was usually attained after fifteen minutes. The major limitation governing the recovery of manganese is the need for the silicon content of the alloy to meet a maximum specification of 2 per cent. Higher concentrations of silicon in the final alloy of between 8 and 12 per cent favour good recoveries of manganese from the slag, but, since such an alloy is not salable, lower recoveries must apparently be tolerated. In alloys of 2 per cent silicon, low activities of the silicon are responsible for poor recoveries of manganese. The activity of MnO in the slag can be increased by moderate additions of CaO and small amounts of MgO, i.e., by an increase in the basicity of the slag.

Jan 1, 1979

By M. Timucin

High-temperature phase relations in the Pb-PbS system were established by the quenching of samples equilibrated in evacuated and sealed silica capsules. The liquid-miscibility gap seen in some previously published phase diagrams was not observed. The thermodynamic activities of PbS in liquid solutions of this system were derived at 1473 K from the isopiestic equilibration of samples belonging to this solution series with Cu2S-PbS melts of known PbS activities. The behaviour of Pb-PbS melts was found to be compatible with a subregular solution model. This model also made it possible to obtain an analytical liquidus for PbS that was in excelent agreement with the experimental determination.

Jan 1, 1988

By E. Uslu

The kinetics of the reduction of chromite from the LG-6 layer of the Bushveld Complex in Fe-Cr-C alloys were studied in the temperature range 15OO°C to 1680°C under an inert argon atmosphere. The rotating cylinder technique was used, and the rotational speed of the chromite cylinder ranged from 0 to 1000 r/min. The melt consisted of 30 to 80 per cent chromium and 2 to 8 per cent carbon. The initial chromium-te-iron ratios of the melts varied between 0,42 and 4,95. The reduction of chromite spinel was analysed in terms of the decarburization of the metal. It was found that decarburization increased with an increase in the temperature, the carbon content of the bath, and the rotational speed of the cylinder up to 400 r/min, after which it remained almost constant. Decarburization also increased with an increase in the chromium content up to about 50 per cent chromium but, at higher chromium contents, it decreased. In the early stage of the reduction, up to about 30 minutes of reaction time, the liquid-state mass transfer of oxygen was found to be the most likely rate-determining step. The apparent activation energy was calculated to be 84,864 kJ per mole of oxygen. In the later stage, diffusion of iron and/or chromium in the solid state is the most likely rate-determining step. The apparent activation energy for the diffusion was calculated to be 471,18 kJ/mol.

Jan 1, 1991

By J. P. G. Pretorius

The size effect in tests of the compressive strength of coal specimens differs from predictions based on the Weakest Link theory. Predictions of the size effect in tensile tests on lengths of cotton yarn and glass fibre, the behaviour of which is analogous to the weak link process, also differ from observations. This discrepancy is shown to be caused by the correlation between the strengths of the unit lengths in a composite specimen. The Weakest Link theory is reformulated as the Weakness Correlation theory to account for such correlation. It is shown that weakness correlation is found in rock and it is concluded that at least part of the discrepancy between the predicted and observed size effect in rock strength tests could be attributed to this correlation.

By J. N. Van der Merwe

It is shown that the safety factor as calculated traditionally by use of the tributary-area theory is not valid for high-extraction methods of coal mining. An alternative approach is suggested in which the pillar loads are calculated more realistically for the period during which pillar extraction is in progress. This safety factor, which is known as the Extraction Safety Factor (ESF), can be used in determining the effects of strong layers in the overburden on pillar sizes.

Jan 1, 1990

By C. Liu, F. Ye

"To extend the variety of lump ores that are used in the COREX shaft furnace and to optimize iron ore blending, the original evaluation method for iron ores that was proposed by Voestalpine AG has been improved. Physicochemical and metallurgical properties of iron ores, including Sishen lump ore and CVRD pellets, which are currently used in the COREX process, and three other lump ores, were assessed and compared. Ore matching principles were proposed and five optimized iron ore blending schemes designed and verified by laboratory experiments to prove the effectiveness of the improved evaluation method. The replacement of Sishen lump ore by the alternative L2 and L3 lump ores without varying the proportion of CVRD pellets could improve the degree of reduction and rate of metallization, and decrease the bonding index. Based on the results of laboratory test work and industrial- trials, an ore blending scheme of 60% CVRD, 20% L2, and 20% L3 is recommended for use in the COREX process. IntroductionIn recent years, problems such as environmental pollution and a shortage of coke and coal resources for blast-furnace ironmaking have become increasingly apparent. Based on sustainable developments in the iron- and steelmaking industries, the environmentally friendly COREX smelting-reduction process with low energy consumption was developed and introduced (Zhou and Du, 2013; Song, Lv, and Yin, 2015; Xu et al., 2016; Kurunov, 2010). The evaluation system for lump ore that was proposed by Voestalpine AG recommends that only Sishen lump ore from South Africa be used in the COREX process, because of the stringent physicochemical and metallurgical property requirements. This situation significantly hampers improvements to the technical and economic aspects of the COREX ironmaking process, especially in China (Eberle, Siuka, and Bohm, 2006). No theoretical or technical basis has been provided for the evaluation system, and the assessment approach for iron ores also presents problems that need to be discussed and resolved.The COREX process consists of two reactors: the prereduction shaft furnace and the melting gasifier as shown in Figure 1 (Wu et al., 2017). Pellets and lump ores which are charged to the prereduction shaft should have a good reducibility and metallization with a low degradation index (Li et al., 2016; Wu et al., 2011; Kumar et al., 2009; Kang, Gupta, and Sahajwalla, 2007). The properties and microstructure of the iron ore pellets which are required to achieve a high productivity and a lower fuel rate in the COREX process have been investigated (Umadevi et al., 2011). Some efforts have also been made to investigate the behaviour of lump ores in the COREX shaft furnace, including the disintegration characteristics and the reduction degradation (Umadevi et al., 2011; Zhou et al., 2015; Xu et al., 2013; Li, Feng, and Zou, 2013; Hou et al., 2014). However, few studies have focused on the optimization of ore blending for partial or total substitution of the expensive Sishen lump ore by other, cheaper lump ores to reduce the production cost. The technology for the utilization of blended lump ores in the COREX process is still in its early development stages (Zhou et al., 2017; You et al., 2017)."

May 1, 2019

By P. Linzer, L. M. Linzer

The gravity method is often applied in mining-related scenarios such as geological and mineral exploration, detecting subsurface cavities and voids (“receptacles”) that may become sinkholes, siting of surface structures, fault-mapping, and more. It is also widely applied in geotechnical engineering to map subsurface karst profiles and to detect subsurface cavities, such as can occur in open pit mines. While it is widely acknowledged that, compared with other available geophysical methods, this method is the most applicable to the karst profiling problem, survey geometries applied in the field are often far from optimal. The gravity surveying specifications prescribed in SANS 1936 omit some key requirements for optimal survey outcomes, and this paper is intended to fill those gaps. The authors have seen scopes of work that require only a few measurements over the footprint of a proposed structure, indicating a lack of understanding of the nature of the gravitational field. A single gravity measurement is subject to the camouflaging effects of several influences, many of which can be larger than the anomaly caused by the subsurface density variation itself. Papers in the body of literature show an awareness of the need to map the regional field so that it can be subtracted to unmask the residual gravity anomaly, but rarely do they examine how instrument sensitivity governs the size of detectable anomalies or discuss how a detailed terrain correction can be instrumental for isolating faint targets. This paper aims to explain how to apply the gravity method correctly to mining and geotechnical problems, specifically in the detection of subsurface cavities. It discusses various factors to assist with optimising the acquisition of gravity data and its processing so as to maximise the practical value of gravity surveys.

Sep 1, 2025

By M. Akyüzlü

The equilibrium between carbon-saturated Fe-Cr-Si-C alloys and SiO2-CaO-MgO-A2O3-CrO2-FeOy slags was studied under atmospheres of argon and carbon monoxide at temperatures of 1500 and 1600°C. The equilibrium distribution of chromium, silicon, and iron between the slag and the metal phases was determined for different compositions of both phases under different atmospheres and temperatures. It is shown that silicon transfer from the slag to the metal increases with increasing temperature, decreasing carbon monoxide partial pressure, decreasing carbon content of the metal, increasing chromium-to-iron ratio of the metal, increasing silica content of the slag, and decreasing lime-to-alumina ratio of the slag. Some activity calculations were made for the experiments conducted at 1600OC in a carbon monoxide atmosphere. It is also shown that a decrease in the iron content and an increase in the slag basicity decrease the chromium content of the slag. A major proportion of the chromium present in the slag was found to be in the divalent state under the highly reducing conditions prevailing in the experiments. The chromous capacities of these slags were calculated and were found to decrease with increasing basicity.

Jan 1, 1992

By P. S. Piper

In the 1960s it was suggested that the volume of stope convergence, and hence the rockburst hazard, could be reduced by the emplacement of backfill. Recent advances have facilitated the placement of large quantities of backfill underground, and a reassessment of its potential benefits as part of a regional support strategy is now timely. In this paper the principal criteria of effectiveness of backfill are taken to be its impact on face energy release rate (ERR) and average pillar stress (APS) levels, and maximization of acceptable ore extraction ratios. The possible effects of backfill on excess shear stresses (thought to modulate large seismic events) are also briefly reviewed. Analytic solutions describing backfill properties and their impact on ERR and APS in certain idealized geometries are also presented, and compared with the results of an extensive suite of computer simulations, in which parameter sensitivities are explored. Results indicate that a regional support strategy is required at depths exceeding 2 km in order to maintain acceptable levels of ERR, and backfill ribs can on their own fulfil this role at depths less than 3,3 km. At greater depths use of stabilizing pillars becomes imperative, but here too supplementary backfill ribs can reduce ERR and APS levels and permit significant increases in ore extraction ratios.

Jan 1, 1988

By M. F. Handley

This paper covers in situ stresses in the Earth?s crust prior to any man-made disturbances, such as mining. It introduces the Southern African Stress Database, which contains primitive stress measurements obtained from locations spread all over southern Africa. The measured stress data shows large variability without any visible trends, except a relationship with increasing depth. The stress database is reviewed briefly, establishing means to measure the variability or dispersion in the measurements, and showing that the dispersion is not as much a result of experimental error as it is a feature of primitive stress. The paper demonstrates from the beginning that the state of stress in rock is highly variable, but that there are well-defined maximum and minimum limits to all the stress components in rock. Formal error analysis is introduced to check the consistency of the database and to separate out a database of consistent stress measurements for use in a primitive stress model. The aim is to provide a picture of primitive crustal stress based on objective stress measurements together with interpretations of how the primitive stress can be affected by the five main influences; namely, depth, rock mass properties, tectonism, isostacy, and erosion. Four elementary models for primitive stress are introduced and compared with the measured data. It is quite clear that none of the elementary models is sufficient to describe the data. In the absence of a better model, this paper suggests a generic model based on the Hoek-Brown failure criterion and the consistent stress database, since it incorporates the variability in the stress tensor that is likely to be encountered underground all over southern Africa. Rock engineers should take every opportunity to obtain local primitive stress data at every mining operation and civil engineering project, and to adjust the proposed model accordingly Keywords primitive stress, Southern African Stress Database, error analysis, generic primitive stress model.

Jun 1, 2013

By R. M. Stroh, D. F. H. Grave

In this paper ventilation planning methods are discussed, with particular reference to the application of computer techniques to the solving of the many problems associated with the forecasting of ventilation and refrigeration requirements in mines of high production rates going to depths and rock temperatures higher than previously experienced. The use of the Starfield-Dickson programmes for calculating heat flow into airways and advancing stopes is demonstrated in the case of ventilation planning on a large mine extending to a brief depth of over 3 km below the surface. The possible effects of new mining methods on ventilation requirements in the future is briefly discussed.

By Z. Song

Real-time monitoring makes it possible to detect any disturbance occurring in production, while decision instruments can efficiently assist decision-makers to optimize production, reduce iterative workload, obtain better solutions, and preview possible results. Technologies for the above already exist and have been proven in the process industry, i.e. refining and smelting. Optimization is also essential for profitable and stable mining production. Real-time monitoring has already taken hold in mining operations, especially in surface mining, while optimization techniques have also been widely used in underground mining, particularly for planning and scheduling. This review is limited to the hard-rock mining production of metallic ores such as gold and copper. It reviews optimization techniques developed for mine planning and scheduling, and communication technologies suitable for underground applications. It also presents control features for individual operation units, and discusses the technical viability of a mining production real-time optimization (MPRTO) system for underground mines, with possible benefits and challenges. Operational disturbances always occur in mine production. An MPRTO system can be useful to maintain operational effectiveness and efficiency by allowing quick changes to short-term plans. This paper briefly describes the MPRTO system, including the input, output, and basic algorithms. The technical prerequisites for the system specified here are already available. Further studies that are required to improve the system are discussed. Keywords real-time optimization, underground mining, production, operation.

Dec 1, 2013

By deur R. R. Mears

The expected curtailment of activities within the gold-mining industry by the closure of the more marginal mines, and the shortening of the life of the industry as a whole as a result of rising costs and/or an uncertain gold price, are factors that are bound to harm the South African economy in a number of ways. The industry has no option but to regard the gold price, which is determined on the world market, as a given quantity. The remaining ore reserves al tend to be of a lower grade and/or to be found at greater depth. Therefore tighter control of working costs would seem to be almost the only option open to the industry. Working costs can be divided into two broad categories: costs emanating from the environmental characteristics of the orebody, and costs emanating from the general inflationary environment in which the industry has to purchase its inputs. Working costs stemming from the physical environment also fall into two categories: those relating to the grade of the orebody, and those resulting from working at increasing depth and temperature, together with the need to pump increasing quantities of water. The industry is both capital- and labour-intensive in absolute terms, since it requires large inputs of labour as well as of capital. It is limited in its scope to adjust its production function by becoming more labour- or more capital intensive, and is dependent on a large labour force, which cannot easily be replaced by capital inputs. On the other hand, large amounts of capital are required for investment in shafts, development, machinery, and equipment. Since the early seventies, the working costs of the South African gold-mining industry have increased at an annual rate that was significantly higher than the general rate of inflation. This rapid rise in working costs has caused some mines to find themselves in a difficult profit position. At times, the gold-mining industry has even been compelled to restructure its cost/revenue relationship rather fundamentally by revising the grade of ore worked sharply upwards or downwards, as the case may be. The rise in the gold price since 1972 has made it possible for the industry to introduce significant changes in its Black wage policy. The main aim was to increase the permanency of the Black labour force and to encourage local Black workers to join the industry. At the same time, significant increases were also experienced in the cost of machinery and stores, as well as of capital, mainly as a result of inflation. In the study on which this paper is based, the author attempted to measure the influence of environmental factors on working costs, using the physical consumption of electricity as a criterion for measurement. He found that the usefulness of this criterion in relation to factors such as depth, temperature, and water quantities pumped was invariably more than neutralized by the effects of greater productivity and economies of scale. The effects of these environmental factors on the working costs of the industry could therefore not be determined to any degree of accuracy. It seems that good progress is being made with the development of capital-intensive forms of technology aimed at coping with rapidly rising working costs and other effects of increasing depth. Techniques are also being developed to improve rock-cutting procedures and to eliminate the use of explosives in order to introduce a continuous mining process. On the whole, the gold-mining industry seems to be more sensitive to general inflationary pressures than to the cost effects that are associated with depth, temperature, and water quantities pumped. Greater control is possible over physical environmental factors such as the grade of ore mined, temperature, rate and nature of development of a mine, and adaptation of the daily working cycle to a continuous mining process. Wolfe and others hold the view that the industry will lose control over labour costs as a result of the 'sharp increase in wages and the growth of Black trade unions. However, the use of more capital-intensive technology will allow the industry to reduce its labour force, and a smaller, better-trained, and more permanent labour force will enable the industry to cope with the increasingly difficult physical environment and higher wages.

Jan 1, 1987