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By P. L. Crouse

"SynopsisFluorine – in the form of hydrofluoric acid, anhydrous hydrogen fluoride, elemental gaseous fluorine, fluoropolymers, volatile inorganic fluorides, and more – has played, and still plays, a major role in the nuclear industry. In order to enrich uranium, the metal has to be in the gaseous state. While more exotic methods are known, the standard and most cost-competitive way of achieving this is by means of uranium hexafluoride (UF6). This compound sublimates at low temperatures, and the vapour is enriched using centrifugal processes. The industrial preparation of uranium hexafluoride requires both elemental fluorine gas and anhydrous hydrogen fluoride (HF). HF is prepared by the reaction of sulphuric acid with fluorspar (CaF2). Fluorine gas in turn is prepared by the electrolysis of HF. Yellowcake is first converted to uranium tetrafluoride (UF4), using HF, after which the compound is treated with fluorine to yield UF6. After enrichment, the UF6 is reduced to UO2 for use in fuel elements in pellet form.South Africa has the largest reserves of fluorspar internationally, and is the third largest producer after Mexico and China. Fluorine technology has many associated difficulties, because of the reactivity of fluorine and the toxicity of HF. The main barriers to entry into the fluorochemical industry are thus the abilities to produce both HF and F2. Both these substances are produced locally, at the industrial scale, at Pelchem SOC Ltd. Should South Africa contemplate developing its own nuclear fuel cycle as part of the awaited new-build nuclear project, it will be imperative to leverage the existing skills with respect to fluorine technology, resident at both Pelchem and Necsa, for this purpose. This paper summarizes the fluorochemical skills developed locally over the past several decades, and suggests strategies for maintaining the technology base and developing it for the next generation of scientists and engineers.IntroductionFluorine chemistry has always had a very close relationship with the nuclear industry. Although the first mention of fluorspar was recorded in the sixteenth century, and the fundamentals had been well-developed by the Second World War, it was only during the Manhattan Project (Banks et al., 1994), when almost unlimited funds were made available for the large-scale industrialization of fluorine and related compounds, that the technology took off. Expertise in both the chemistry and the engineering aspects of fluorine is essential for the design and running of several of the unit processes in the nuclear fuel cycle."

Jan 1, 2015

By T. K. Roy

INFACON XI has no doubt earned the distinction as the first such Congress in India. This prestigious occasion could become a reality of a long cherished dream of the Indian Ferroalloy Producers, consumers and ex-porters. The International Committee of Ferro Alloys (ICFA), South Africa, the august body for organising INFACON, every three years, could be convinced by the Indian Ferro Alloy Producers? Association (IFAPA) to award INFACON (XI) to India. This Congresss, organized by IFAPA, has opened a window for the Ferroalloy Community of India, the up-coming Asian Tiger, to register their strength and weakness to the world forum with the principal objectives of evolving long and short-term optimum road-maps for development. It is to be reckoned that India is poised to be a steel giant by 2020 when it is envisaged that the steel production may reach a level of 120 million tons of which significant proportion has to be in the categories of alloy and special steels, requiring standard and high grade ferroalloys. Keeping the above objective in view, the theme of this Congress has been rightfully designed as ?Innovations in Ferro Alloy Industry.? This Congress has also earned a distinction of more than eighty papers, finally selected for inclusion in the Proceedings. More than 100 internationally and nationally reputed experts in the field of ferroalloys (technology and manufacturing practices as well as world scenario) have been approached for critical review of abstracts and selection for the proceedings. It needs to be mentioned without the cooperation received from ICFA the high standard of INFACON could not have been assured. The papers are suitably grouped under seventeen heads, starting from world situation to production and operation followed by present and future technologies and finally to modelling and simulation. It is a Herculean task to the Technical Committee to fit these papers in proper sequence. The Commit-tee members kept no stone unturned to ensure the cogency with the subject matters and at the same timekeeping the flexibility of interests of the participant, especially in the context of three parallel sessions. The Proceedings containing only refereed papers of high quality, will serve the entire gamut of ferroalloy industry and will also highlight the present status of concerned countries. The areas of attention to make the industries globally competitive and at the same time laying emphasis on the prevailing practices, will help the industry leaders to formulate an appropriate global approach. Following the break-through step, instilled by INFACON XI, the Proceedings will be available both in bound and in searchable electronic CD-ROM format. I, as the Chairman of the Technical Committee would like to express thanks and high appreciation to all the Committee members for their whole hearted efforts in all respects without which it would not have been possible to complete these proceedings in the scheduled time. Technical Committee desires to place on record their gratitude to Organising Committee for their synergic cooperation all through in successfully executing multifarious tasks, associated with such a grand international technical Congress.

Jan 1, 2007

By Daniel W. Kappes, Pierre F. X. Mousset-Jones

"In this paper a discussion is presented of a program designed to produce a 40-day production forecast for an underground stoping system.The program is intended to be a tool for the operations department in an underground mine, and is designed to utilize data readily available from production reports. Brevity of data input, ability to revise slope conditions easily and the accuracy of starting stope status are stressed. Applicability of the program to a wide variety of sloping methods makes the program potentially useful in a large number of mines.The general functions of the program subroutines, and input and output lists are discussed. An example is also given of a stope in operation for a three-day period, which shows how the program can handle production irregularities as they arise."

Jan 1, 2014

By S. A. Hosseini, O. Asghari

"Recoverable mineral resources assessment has become a standard geostatistical application in the mining industry, with various geostatistical techniques currently available. This investigation aimed to improve the prediction at the Sungun deposit and to obtain mineral resource models capable of handling (i) the change of support from drill-hole composites to selective mining units (SMUs), (ii) the multivariate nature of the ore control selection criteria that involves both copper and molybdenum grades; and (iii) the local uncertainty on the true (unknown) grades. The solution presented in this paper is to use direct block-support sequential cosimulation in order to construct a set of alternative outcomes of the copper and molybdenum grades on block support over the deposit, with no need for storing point-support values, hence with a considerable gain in memory management and CPU time. The grade realizations so obtained are then processed to calculate the uncertainty in the mineral resources that can be recovered above given cut-off grades, both globally and on a blockby- block basis. IntroductionGeostatistical methods are widely used by mining companies to determine a resource model of the tonnage and head grade of a potential orebody, which is one of the first and most critical inputs underpinning any mining project. The prediction of the grade, tonnage, and recoverable metal for a particular mining plan and the corresponding financial forecast constitute the main technical risks in mineral resource evaluation. The conventional approach to this problem is to predict the mineral grade for constant volumes relevant to the mining plan and to base the recoverable mineral resource calculations on those predictions. Alternatively, one can directly predict the local variability in the mining block grades based on a spatial distribution model (David 1988; Rossi and Deutsch 2014). Multiple realizations can also be constructed by conditional simulation, providing a more complete representation of block grade uncertainty, as well as the uncertainty over multiple blocks. Simulation methods allow quantification of the uncertainty of the mineral resource prediction risks in downstream studies such as mine design, mine planning, or operational optimization studies; the risk assessment is achieved after applying transfer functions to the conditional simulation models (Dimitrakopoulos 2012; Rossi and Deutsch 2014)."

Jan 1, 2017

1. Book review . Australasian coal mining practice, edited by C.H. Martin. Reviewer: R.B. MacGilIivray This book is an extremely comprehensive coverage of coal-mining practice in Australasia, the countries covered being Australia, New Zealand,and Papua New Guinea. 2. From The Institute of Metals The folowing are available from The Institute of Metals, 1 Carlton House Terace, London SWl Y 5DB. Physical and elastic characterisation, edited by M. McLean. 1989. 228 pp. £25.00. High nitrogen steels, edited by J. Foct and A. Hendry. 1989. 461 pp. £49.50. Proceedings of the First International Calcium Treatment Symposium. 1988. 116 pp. £15. New cored-wire injection techniques, particularly as Design for recyc/ability, by Michael E. Henstock. 1988. 150 pp. £15. Solidification processing. 1988. 549 pp. £45. Marine engineering with copper-nickel. 1988. 103 pp. £18. Characterisation of High Temperature Materials. 3. New journal FMJ International Publications Lid have announced a new quarterly publication, Aluminium Today. 4. Other new publications Algorithms in real algebraic geometry, edited by Denis S. Arnon and Bruno Buchberger. London, Academic Press, 1988. 274 pp. £15.95. Proceedings, Foundry and Heat Treatment 88. R150 per set of 5 volumes, or R40 per volume.

Jan 1, 1989

By I. M. Wolf, S. A. Usmar, L. A. Cornish

The limiting criterion in the use of stainless steel for certain forming operations such as coining is its hardness, which determines parameters such as required striking pressure, wear on dies, and integrity of pattern detail. Attention is given here to the development of ultra-soft ferritic stainless steels for coinage. In the first instance, the influence of carbon content on the striking properties of a series of commercial and experimental 17%Cr alloys was evaluated. It was found that a lower carbon content permitted the striking of relatively highly profiled and intricate patterns, provided that the hardness did not exceed 125 HV. Hardnesses as low as 115 HV were achieved in the fully annealed condition, but these alloys required high striking pressures. In a further study, three grades of experimental 14%Cr ferritic stainless steels were produced with a view to optimizing the ductility. When the residual impurities were minimized, hardness values of about 100 HV and lower were achieved. Micro-alloying additions allowed the heat-treatment response and grain size to be controlled. Excellent tensile properties, with elongations of up to 42 per cent, were achieved in the fuly annealed condition, and highly profiled patterns were produced in coining trials.

Jan 1, 1993

By P. J. van Staden, T. W. Walker

The Minfurn is a novel carbon-regeneration furnace developed at Mintek. It combines the advantages of direct resistive heating in a vertical-tube furnace with those of continuous operation, in a furnace whose capital, operating, and maintenance costs compare favourably with those of conventional rotary kilns. After successful tests under experimental conditions on carbons containing different contaminants, a 3 kg/h unit was installed on the carbon-in-pulp (CIP) plant at the Klipwal Gold Mine near Piet Retief, where it has been operating at, on average, 123 per cent of its design capacity. Since the installation of the Minfurn, monthly average losses of dissolved gold of less than 0,02 p.p.m. have been maintained for several successive months for the first time since January 1989. It is also possible that the monthly average residue values have been reduced. Further improvements to the carbon circuit are possible, and the possibility of making further savings by a reduction in the carbon-throughput rate still needs to be investigated. The mathematical modeling of the furnace has progressed to the stage where the future scale-up and design of the Minfurn can be carried out by simulation of the performance of different designs, and choosing the design that yields the desired performance.

Jan 1, 1993

By Q. G. Reynolds

The problem of direct-current plasma arc behaviour, interaction, and dynamics is considered in the context of metallurgical DC arc furnace applications. Particular attention is paid to the transient flow behaviour of arc systems. A mathematical formulation of the physics used to describe the arc system is presented, and includes the spatial and temporal evolution of fluid flow, heat transfer, and electromagnetism. Based on this formulation, a numerical model is developed using a finite difference approach on a regular cartesian grid in both two and three dimensions, with a special focus on robust stability, high resolution modelling, and high performance. A collection of results produced using the numerical model to study pilot plant-scale furnaces is then presented. These address a range of process and design variables and their effect on the numerical model?s results. Where possible, the qualitative behaviour of the model is compared to available experimental data. A number of novel effects and phenomena are seen in the dynamic behaviour of the DC plasma arc model for both single and multiple arc systems, which may lead to improved understanding, control, and manipulation of such systems where they occur in industrial applications. Keywords Pyrometallurgy, direct-current furnace, plasma arc, modelling.

Jan 1, 2010

The depletion of favourably located and higher-grade mineral deposits, combined with more favourable metal prices and higher capital costs, has stimulated research into heap leaching of lower grade ores and wastes. This has resulted in renewed interest in heap leaching of uranium ores, and in the development of processes for the bacterial heap leaching of low-grade chalcopyrite ores and the acid heap leaching of nickel laterites. A complete programme of heap leach testwork typically involves a sequence of bottle roll tests and column tests, followed by piloting on test heaps. The initial testwork is aimed at determining the amenability of the ore to heap leaching, which depends on the characteristic of the ore with respect to porosity and permeability to leach liquor, acid consumption, metal recovery and percolation. Subsequent phases of the testwork focus on the development of the process design criteria for the treatment of the ore. Basic techno-economic models have also been developed as a tool for the initial estimation of heap leach viability. Mintek has also developed in-heap monitoring probes, coupled to an operator guidance system, in order to assist the operator in achieving optimal conditions for bacterial growth and heat preservation during pilot-plant operation.

Jan 1, 2009

It is widely accepted that the type of grinding media has an impact on the grinding chemistry and subsequent flotation behaviour of the sulphide minerals being separated. There are countless laboratory investigations demonstrating that inert grinding media produces more oxidizing pulp potentials, reduced levels of grinding media corrosion products, and superior concentrate grades and valuable metal recoveries. However, taking these results to industrial scale has proved difficult. This paper provides details of the protocol developed and used during a high-chrome grinding media plant trial. It describes the test regime employed to measure changes in pulp chemistry as well as concentrate grades and recoveries to produce a statistically meaningful result. The work also highlighted the need for close cooperation between the metallurgists on site and the researchers conducting the trial. To demonstrate the protocol, data gathered during a plant trail in a PGM concentrate will be presented describing the changes in pulp chemistry and metallurgical response observed.

Jan 1, 2012

By A. G. Royle

The reasons for constructing a model of an orebody for which both the parent population and the sampling distribution are known are discussed and details of the model are given. A brief summary of Matheron's theory of regionalized variables is included, with particular reference to his kriging estimators and their variances. Using the model, a comparison is then made between these kriging estimators and other commonly-used estimators. These are compared to find the one with the minimum variance, and an analysis is included to investigate whether any of the estimators is biased. Also included is a comparison between theoretical and experimental variances for some of the estimators.

Jan 1, 2014

By G. E. Blight

Several aspects of the behaviour and properties of backfills consisting of cemented cyclone underflow tailings are illustrated by means of examples, and guidelines are given on the optimization of the performance of cemented fills. The stretch characteristics of the geofabric used to contain freshly placed backfill are described, as well as the relationship between these characteristics and the forces acting on retaining barricades. The properties required to achieve a self-supporting, stable free face in cemented backfill are explored, and a graphic relationship between stable height and shear strength is presented and compared with that for uncemented (classified) tailings. After a description of the characteristics of Witwatersrand quartzite gold-tailings backfill and commonly used cements, the process of drainage and air entry into backfill is outlined. Following this, the early-age gain in strength and the shear-strength characteristics, as well as the compressibility characteristics of cemented backfill, are described. Two phenomena that are potentially damaging to cemented backfill are seismic effects (or blasting acceleration) and the closure that takes place during the curing of cement. Investigations show that neither of these phenomena is actually significantly deleterious to gold-tailings backfill: liquefaction does not Occur as a result of seismicity, and hydration of cemented fill is not significantly impeded by closure.

Jan 1, 1996

By V. N. Medvedev, A. M. Bryukhanov

Stationary mine air control equipment enables monitoring of CH4 concentration only in sensor locations. CMC-4 individual indicator built into a caplight has been developed in Ukraine, extending CH4 monitoring to manned job sites. Major technical characteristics of the indicator are demonstrated. It features two operation thresholds: 1st threshold 1.0 to 2.0% vol. 2nd threshold 1.5 to 2.5% vol. Basic absolute accuracy ± 0.2% Caplight battery is a common power supply for the lamp and CH4 indicator, providing at least 10 hours of the system non-stop operation. Average pre-failure life is at least 10,000 hrs. It features: an explosion proof design and intrinsically safe test circuit; a small-sized sensor as an integral part of the caplight; a hybrid microcircuit to facilitate functioning of methane monitoring unit. The CMC-4 indicator weight is the weight of the caplight itself and equals 2.4 kg. A two-threshold design makes possible to distinguish between methane sources: slow accumulation due to diffusion or sudden rushes due to a gas-dynamic event. CMC-4 indicators in addition to stationary equipment minimize the risk of CH4 explosion underground determined as a product of accident intensity by calculated time interval.

Jan 1, 2003

Metso Minerals Cisa have developed VisiofrothTM - a system which calculates parameters of the froth surface using vision from remote cameras mounted about individual flotation cells. The parameters calculated from this system can be utilised within process control strategies to achieve stabilisation or optimisation of the flotation process. As part of a JKMRC AMIRA P9 field campaign, froth vision was collected from various cells operated at different air rates and froth depths within Rio Tinto's Northparkes copper roughing and scavenging circuit. At the same time, samples were collected to determine the cell metallurgical performance at each operating condition. These froth images have been processed using the VisiofrothTM system with froth velocity, bubble size, froth collapse rate and various froth colour parameters calculated. These parameters have been compared to the measured concentrate flow and concentrate grade produced at each condition. This analysis shows that the concentrate tonnage flow is strongly correlated with froth velocity whereas the concentrate grade is best correlated using froth velocity in combination with a bubble stability parameter which affects the bubble size distribution on the top surface of the froth. This paper summarises the results from this analysis as well as an overview of the VisiofrothTM system and the parameters that are measured by the software.

Jan 1, 2007

By L. R. Nelson

The efficiency and cost-effectiveness of the aluminothermic reduction process in the production of ferro-alloys and 'pure' metals depends strongly on appropriate balancing of the process energy required. Insufficient energy results in a poor metal yield, while over-supply can result in excessive fuming and possibly even ejection of the reactor contents in a potentially dangerous 'thermite bomb' reaction. This situation becomes even more critical when the suitability of limited quantities of oxide from new sources must be evaluated, dictating smaller-scale testwork. The resulting higher relative heat losses from the system complicates control of the energy balance, and usually requires the addition of thermal boosters or reactant preheating in order to sustain an autothermic process. This often detracts from the quality of the metal product, and adds to the hazards of batch aluminothermic- reduction testing. The development of a small-scale method (producing less than 2,5 kg of metal) for the plasma-assisted aluminothermic reduction of chromium oxide that overcomes such difficulties is described. The technique involves the use of a sealed 50 kVA plasma-arc furnace to provide controlled electrical ignition and supplementary energy to the reactants contained in a water-cooled copper crucible. The application of the method to the evaluation of the aluminothermic production of pure chromium metal from a unique chromic oxide source is reported.

Jan 1, 1996

Orange Free State Branch Minutes of a General Meeting held at the Welkom Mine Canteen on Wednesday, 21st November, 1973, at 4-.00 p.m. Present Mr E. T. Wilson (Chairman) in the Chair, 15 Fellows and Members, 12 Associates, Graduates, and Students, and 11 Visitors (Total 38). Book review Symposium on Environmental Engineering in Coal Mining The 20 papers presented at the symposium cover some 14 subjects related to environmental engineering in coal mines, such as dust, heat, gas emissions, ventilation, noise, and lighting. Competition for students Each year the Institute offers a prize (or prizes should the entries warrant it) of up to Rl00 for the best paper or dissertation on a topic appropriate to the interests of the Institute. A.8. & T.8. Trust The A.S. & T.S. Trust has been formed with the specific object of establishing a worthwhile source of funds which can be used to further the progress of science and technology in South Africa. Nim reports Report No. 1573 A pilot-plant investigation of a flotation model. Report No. 1597 The role of sulphur in the flotation of sulphide minerals. Report No. 1599 The analysis of silicate rocks and metallurgical slags by X -ray-fluorescence spectrometry. Report No. 1607 The analysis of ion-exchange resins by X-ray- fluorescence spectrometry. Report No. 1617 An electronic differential precision thermometer.

Jan 6, 1974

By T. R. Twiddle

The sequential flotation of copper, lead, and zinc in that order is practised at the Broken Hill Concentrator of the Black Mountain Mineral Development Company (Pty) Limited. The minerals of economic importance are chalcopyrite, galena, and sphalerite, with associated silver. The targets for recovery and grade in the lead and zinc circuits were reached quite readily after start-up, but the copper circuit failed to meet the performance requirements with respect to both recovery' and grade. The original circuit for copper is described, together with the subsequent investigations and modifications that were required to produce acceptable metallurgical results. Circuits for semi-bulk and bulk flotation were tried, and the effect of the oxidation state of the pulp was investigated extensively and found to be all important. Tests were conducted on the depression of lead in the cleaning circuit by the use of sodium dichromate, and on heating with the addition of sulphurous acid. The latter technique was ultimately the more successful. The proportion of fresh to recycle water entering the circuit was shown to be important. The original reagent regime was altered and augmented. A more recent problem has been the contamination of the ore with cemented backfill. The changes that this new condition necessitated are described. Success has been measured by a continuous improvement in the economics of the copper recovery.

Jan 1, 1984

By D. D. Hawat

The locations of potential reserves of chromite ores throughout the world are discussed. Reference is made to the marked changes in international trade in chromite ores during the past ten to fifteen years, and to the change in locality of the production of ferochromium aloys, which is curently largely carried out in the country of origin of the ores. The influence of these changes has been very profound in South Africa, which has the largest smelting capacity and the largest production of ferochromium aloys in the world. A proportion of South African ore is stil exported to meet the demands for the production of chromium chemicals and refractories, including a large tonnage of foundry sands. Ferochromium smelters in South Africa have a capacity of virtualy 1 Mt of aloy per annum. Nearly al this development has taken place since the introduction of the argon-oxygen decarburization (A.O.D.) process for the smelting of stainless steels. Formerly, expensive Iow-carbon ferochromium aloys were required as raw materials, but the AO.D. process, which is being used world wide, permits the use of high-carbon ferrochromium, the main product of the smelters in this country. The production in South Africa of chromium-containing corrosion- and heat-resistant steels is stil on a relatively smal scale, but serious atention is being paid to the exploitation of low-carbon weldable feritic chromium steel.

Jan 1, 1986

1. Reviews A concise world atlas of geology and mineral deposits, by D. R. Derry. London, Mining Journal Books, 1980. (Reviewer: B. C. Alberts) The geology of the Western Cordillera of northern Peru, by various authors. London, Institute of Geological Sciences, Overseas Memoir 5. (Reviewer: C. E. Feather) 2. New books Influence of diffusion coatings on the strenth of steel, by G. V. Karpenko, V. I. Pokhmurovskii, V. B. Dasilov, and V. S. Zamikhovskii, second revised and updated edition by A. Aladjem. Aedermannsdorf (Switzerland), Trans Tech Publications, 1979. 200 pp. Sw. Fr. 68.00. Mechanical and corrosion properties, by G. S. Ansell, P. Haasen, J. Weertman, D. J. Fisher, U. Gramberg, and F. W6hlbier (editors). Heat-resistant and refractory steels, by K. L. Lanskaya. Aedermannsdorf (Switzerland), Trans Tech Publications, 1979. 266 pp. Sw. Fr. 86.00. Hardening of metals, by P. Feltham (editor). Aedermannsdorf (Switzerland), Trans Tech Publications, 1980. 316 pp. Sw. Fr. 78.00. Precious metals The 6th International Precious Metals Conference will be held in Newport Beach, California, from 7th to 11th June, 1982. Strata mechanics A symposium on Strata Mechanics is to be held in Newcastle-upon-Tyne from 5th to 7th April, 1982. Over the past thirty years, mining of coal and stratified mineral deposits has become increasingly capital-intensive, and the level of investment demanded by modern methods has led to demands for improved assessment of their likely performance.

Jan 1, 1981

By A. J. Van Rensburg, N. B. Strydom, C. H. Van Graan

The design, construction, and use of a practical ice-jacket for miners by N. B. STRYDOM, Ph.D. (Illinois) (Fellow), D. MITCHELL, Ph.D. (Rand) (Member), A. J. VAN RENSBURG, M.Sc (Poteh) (Visitor), and C. H. VAN GRAAN, M.Sc (Pretoria) (Visitor) Microclimate suits have been shown to be very effective in decreasing physiological strain in hot, wet environments, thus enabling men to work without risk in areas that would normally carry a high risk of heat stroke. In this paper, some design considerations in the development of the frozen jacket are described. Water complied with most of the desirable properties required of a coolant material for use In a microclimate suit. The Human Sciences Laboratory has developed a jacket in which ice is used as the coolant and which is designed according to the most acceptable anthropometrical characteristics. The jacket consists of an inner poncho-type waistcoat containing 28 water compartments. Over this is worn an insulating jacket, which minimizes warming of the coolant by the environment. Suitable refrigeration units have been developed to freeze the jackets underground. Laboratory tests have shown that these jackets are effective for about 2,5 hours, Irrespective of the wet-bulb environment, when men are working at a moderate rate. Jackets should, however, be used only in environments in which the wet-bulb temperature is in the range of 32,S0 to 35,S °C.

Jan 9, 1974