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By Y. Wang, S. Sridhar, B. Coletti, G. N. Shannon, S. Vantilt

The final removal of inclusions in the ladle, tundish, and mold in a continuous casting process involves the kinetic steps of liquid film drainage, interface rupture, and absorption of the inclusion into the overlaying molten slag. During this process, oxide inclusions can undergo chemical reactions with the slag. This paper presents recent results on imaging the slag/steel interface and elucidates the evolution of Al2O3and Al2O3-CaO inclusions during their separation from the steel and on their incorporation into the slag. Experimental results, obtained through a Confocal Scanning Laser Microscope, are compared with thermodynamic predictions.

Jan 1, 2004

By F. R. Camisani-Calzolari

Surface defects on continuously cast slabs require treatment by grinding. This extra phase in the process causes lower throughput of final product and extra energy costs. The elimination of slab treatment after casting implies that slabs can be direct rolled or hot charged, resulting in higher throughput and lower energy costs. To increase the number of slabs that can be direct rolled or hot charged, defects have to be predicted before a slab has completed the casting process. Transversal and longitudinal cracking, casting powder entrapment and other inclusions, bleeders, deep and uneven oscillation marks, stop marks and depressions are the defects thatare considered for prediction. A structure with two models is proposed. The first model describes the effect of mould level, water inlet temperature and casting speed (MV?manipulated variables) on 38 thermocouple temperatures (IV?intermediate variable). Casting speed is a manipulated variable while mould level and water inlet temperature are treated as measured disturbances. This model is known as the MV to IV model, and is used to control the occurrence of defects. The second model describes the effect of the thermocouple temperatures on the defects at different positions and locations on the slabs (OV?output variables). This model is known as the IV to OV model and is the predictor of defects. The models are determined using time-series methods in the form of auto regression with exogenous input using data of approximately 500 slabs cast over a period of 6 months. The models are validated using plant data from 44 slabs gathered three years later, with good results. As an example, published results give a sensitivity and specificity of 61.5 per cent and 75 per cent respectively for longitudinal cracks on validation data, while the presented method gives 63.6 per cent and 93.5 percent, respectively. The IV to OV model is used in an inversion to determine the optimal thermocouple temperatures for each slab width. Keywords: Continuous casting, model, defect, prediction, direct rolling, hot charging, goodness-of-fit, correlation, time-series, soft sensor, ARX.

Jan 1, 2003

By Q. Zhang, X. C. Wang, S. Mao

Phosphate ore is an important strategic mineral resource in which apatite is the main valuable mineral. Flotation is the most commonly used method to separate apatite from middle-low grade phosphate rock. Selective flotation separation is based on the difference of physical and chemical properties of minerals occurring at the three interfaces of mineral/bubble/water. Surface and interface chemistry of mineral have been playing an important role in interpreting and governing its flotation phenomenon. In-situ, visualized and high-precision analytical techniques, such as Time-of-Flight Secondary Ion Mass Spectrometry, Atomic Force Microscopy and Molecular Simulation, have been applied to explore and uncover microscopic nature of apatite flotation. Consequently, a great progress at molecular or atomic level on surface and interface chemistry of apatite flotation has achieved in the past decades. In this paper, the research progress of surface and interface chemistry of apatite flotation such as surface wettability, surface-charging characteristics, surface dissolution behavior, adsorption mechanisms of fatty acid collector and depressor on apatite surface were systematically reviewed. This review will be helpful for the development of more selective reagents and efficient technologies for apatite flotation. Keywords: Apatite, Flotation, Surface and interface chemistry, Surface analysis technology

Jan 1, 2020

South Africa remains the largest global producer of gold, accounting for 11.3 per cent of total world mine production, which amounted to 2520.2 t in 2005. The benefits and disadvantages associated with hedging practices in general, and among South African gold producers is examined. The wide variety and unique nature of risks faced by the mining industries provide a strong case for hedging. Only the principles of hedging, such as selling ounces of gold in the ground at a pre-agreed price for delivery at a future date as a cost-effective mechanism for price risk management, is discussed. Progressive and cumulative increases in the volume of forward sales in the major producing countries are considered by many to be the cause of the declining gold price over the past decade. In spite of negative publicity, forward selling continued as an industry-wide practice until recently (2002) when the global hedge book contracted by 352 t; contraction amounted to 158.6 t in first quarter of 2006. The objectives and benefits of hedging include continuity and stability of cash flows, stability in price achieved, reduction of frictional costs, and creating an effective management tool. The importance of a defined hedging strategy in reducing uncertainty about the hedging objectives is essential to a successful hedging policy. Historical patterns in hedging revenues at an industry level indicate five distinct periods during which the fortunes of hedgers have fluctuated. Finally, since 2001 the rising gold price and reduced price volatility through the consolidation in the global price means that the need to stabilize revenue flows is less urgent. This has meant that hedging is becoming progressively less important for the mining industry at large.

Jan 1, 2007

By Marthie Kotze, Jacolien Wyethe, Bert Van Hege, Richard Bell

Base metal refinery effluent streams may contain low metal concentrations that cannot be recovered by precipitation. Although the concentration is low, the total mass of unrecovered metal can have significant value because of the volumes of effluent generated. This metal may be recovered with high efficiency using selective ion exchange resins. Three process schemes are considered, viz., fixed bed column ion exchange, continuous countercurrent resin-in pulp, and continuous carousel resin-in-pulp. Each of these has different requirements in terms of equipment, resin inventory, capital and operating costs, and different limitations on feed conditions. Bateman and Mintek recently developed a model which allows an upfront economical evaluation of ion exchange options. The model evaluates the capital and operating costs for each process scheme for various base metals. This provides a general guideline for selecting the appropriate process arrangement for a given process stream.

Jan 1, 2005

By B. J. Buys

Rock bolt integrity is a critical issue for the mining industry because of its influence on the safety of mining operations. Guided ultrasonic wave testing of the defects associated with resin-anchored rock bolts was investigated. Axisymmetrical and three-dimensional finite element models were built, one of a partially encapsulated bolt and the other of a bolt with a simulated local corrosion crack. Experimental bolts were then installed in a testing block and typical responses were compared to finite element models of different defect scenarios. Encouraging results were obtained for the smaller axisymmetrical and three-dimensional finite element models, as well as during the experimental investigation. It is recommended that software with energy-absorbing elements should be utilized to consider higher frequencies and longer bolts. Once the integrity of models such as these has been established, the models could in principle be used to train neural networks for use in commercial equipment to determine the integrity of the installed bolt.

Jan 1, 2009

YEAR 1943-1944 Vol. 44 Page A major change-over in the ventilation of a deep level mine, by F. G. Hill and E. C. Ranson, 27; Discussion 56, 62, 67, 71, 72, 79, 123, 129 131 A note on the quarrying of surface limestone in the Sinai Desert, by V. L. Bosazza.. .. 59 Mining with diamond drills at the Nkana Mine of the Rhokana Corporation, Limited, Northern Rhodesia, by W. A. Odgers and A. G. Stirling, 95; Discussion 117, 121, 122 123 On silicates and dusts from the Witwatersrand gold mines (some preliminary notes), by J. J. Frankel, 169; Discussion .. 178 Presidential Address-Review of the rock pressure problem, by C. Biccard Jeppe, 3; Discussion 11,15 17 The chemistry, production and application of plastics, by P. N. Lategan, 138; Discussion 151 153 YEAR 1944-1945 Vol. 45 Page A microtechnique for the size-grading of mine dust, by S. R. Rabson, 34; Discussion 49, 50, 52 55 Activated carbon for regenerating used lubricating oil, by F. J. Tromp and J. J. Matthee 90 A contribution to the study of the production of zeolites, by C. C. le Grange and A. J. Petrick 235 A laboratory method for the determination of the suitability of South African coal and coal blends for the manufacture of metallurgical coke, by R. F. J. Teichmann .. .. 202 Copper containing cements for self-sanitising surfaces, by R. S. Young and H. L. Talbot 156 Notes on some sulphide minerals from the Far East Rand, by E. Mendelssohn, 84; Discussion, 88 89 Presidential Address-A review of underground support on the Witwatersrand with its Bearing on the Problem of ultradeep mining, by P. J. Louis Bok, 3; Discussion, 24, 25 27 Scientific management with particular application to a Witwatersrand gold mine, by J. S. Ford, 63; Discussion, 77, 80, 82 83 Some aspects of rock-drilling practice (the Witwatersrand gold field), by C. J. Irving, 163; Discussion, 185, 190 *197 Temperature measurements in a mine on the Witwatersrand with an electrical resistance thermometer, by O. Weiss, 127; Discussion, 136 137 The measurement of the geo-thermic gradient by means of the clinical thermometer, by R. A. H. Flugge-de Smidt, 105; Discussion, 136 137 The micro-chemical determination of free and combined silica in mine dust, by S. R. Rabson, 43; Discussion, 49, 50, 52 55 The oxidation of pyrites associated with South African coals, by R. F. J. Teichmann 141 YEAR 1945-1946 Vol. 46 Page Air cooling plant, No. 4 Shaft, City Deep, Limited. A review of layout and results achieved, by H. W. Unwin, A. Malcolm and R. E. Campbell Pitt, 66; Discussion, 100, 102, 103, 106, 110 115 A preliminary note on the Waterberg coal field as a possible source of coking coal, by P. E. Hall 124

This paper reviews the history of refractory materials, highlights the development of refractory technology over the years, draws attention to the technology behind these materials, and comments on future developments in this field. By walking the path with refractory materials, from their initial uses in BC times, to the composite materials that are used nowadays, and the nanotechnology developments that are currently taking place in this field, the reader will come to agree that refractory materials are indeed very ?cool?! Keywords: refractory materials; bricks; monolithic materials.

Jan 1, 2008

By H. Yilmaz

Tensile strength testing has been one of the most common physical property testing methods of thin spray-on liner (TSL) products worldwide. However, the variety of products tested has been insufficient for comparison purposes. Specimen preparation procedures and test parameters such as curing time and loading rate are not reported well. Comprehensive tensile strength testing on 20TSL products and one plain shotcrete brand was performed over 28days of curing period. Detailed information on the test procedures with particular attention on the important aspects during sample preparation and test execution are provided. As expected, the tensile strength increases with increasing curing period. The test results make the categorization and comparison of liner products possible.

Jan 1, 2010

By S. K. Gilman, P. S. Marcos

There are basic areas of importance within a concentrator or mineral separation plant, which require focus to ensure acceptable recoveries, throughputs remain at an acceptable level and product grades meet specification. Professional and para-professionals within the mineral sands industry are in demand due to the booming resource sector. Added to this, new mineral sands operations are being commissioned straining the industry further. These factors have increased staff turnover and introduced many new people to the industry. It is essential these new entrants are armed with basic plant troubleshooting skills relevant to the minerals sands industry to minimize production lost through poor recoveries. Mineral sands processing does not involve highly technical or sophisticated unit processes. However, success is often slow to arise due to a lack of detailed understanding, as well as managing multiple interrelated unit processes within a plant. Fundamental background physical conditions (such as equipment loading and water quality) must be met for unit processes to be efficient. Technical management of these process plants should always include observation of these background conditions for they often provide the answer to underperformance. Examples are presented with an indication of the possible effects on recovery and product grade.

Jan 1, 2007

By R. T. Jones

Slags have been produced as by-products from pyrometallurgical processes for thousands of years, and have generally been regarded as waste. Many of these slags are no longer seen as residues merely to be discarded, but as potential economic sources of metals, or as useful by-products in their own right. Slag cleaning can enhance the recovery of valuable metals in existing pyrometallurgical processes, or can produce economic value from recycling old slag dumps. For example, a process has been developed and implemented industrially for recovering cobalt from copper smelting slag in a DC arc furnace. The relatively non-leachable behaviour of glassy slags allows them to be used as a very safe means of disposal of metallurgical waste streams, including many that are classified as hazardous. The high temperatures, reducing conditions, and good mixing that can be achieved in a DC arc furnace enable the effective functioning of this environmentally beneficial means of disposal. Lead blast furnace slag can be rendered safe for disposal by treating it using the Enviroplas process, which strips most of the hazardous lead from the slag (and traps the rest in an insoluble glassy slag) and recovers economic quantities of zinc by absorbing (in a lead splash condenser)the zinc vapour that is fumed off in the furnace. Another example can be seen in the recovery of a chromium- and nickel-containing alloy from stainless steel plant dust, while producing a disposable residual slag. The examples presented here illustrate that it is possible to develop processes that are both economic and environmentally beneficial. Keywords: DC arc furnace, plasma, slag cleaning, cobalt recovery, zinc fuming, Enviroplas, jigging, re-melting fines, environmental, economic

Jan 1, 2004

While some of the practical details of ilmenite smelting are not well documented, there is a substantial body of literature on the principles of ilmenite smelting, and the behaviour of solidified titania slag. This information is summarized, focusing on the basic reactions, departure from equilibrium, the behaviour of impurities, and reactions of solidified slag. The emphasis is on the South African operations.

Jan 1, 2007

Mr Philipus Albertus von Wieligh, a former President of the Chamber of Mines and Executive Director of Johannesburg Consolidated Investment Company, died in Johannesburg on Thursday, 28th December, 1989. He is survived by his widow, a daughter, and two grandchildren. Mr Von Wieligh served the mining industry for 45 years. The P.A. von Wieligh Park in Hilshaven on the West Rand is named after him.

Jan 1, 1990

By Rodney Ishak, Merete Tangstad

In the HC FeMn production, better utilisation of coke and electric power is vital for reducing the production costs. The higher manganese oxides in the charge are reduced to MnO in the prereduction zone, where also the Boudouard reaction is active. These gas-solid reactions are to a large extent decisive for the total consumption of both coke and electrical power in ferromanganese production. In the present work formulas for calculating the Degree of prereduction have been developed for industrial practice. It shows that the typical Degree of prereduction is between 10-40%, but it may in good periods be as high as 60%. Statistical analysis has been done in order to find how various operational parameters influence the Degree of prereduction. A few parameters were observed to have an effect on the prereduction. Comilog ore definitely had a positiveinfluence on the prereduction, Comilog sinter and Mamatwan ore probably had a positive influence on the prereduction, all in relation to the average prereduction in the selected periods. Meanwhile, As man ore definitely, % H2O in raw materials and increasing Hd probably, had a negative influence on the prereduction. The findings for these raw materials were very much in coherence with the results of laboratory scale experiments performed, where the CO-reactivity of different ore materials was studied.

Jan 1, 2007

By R. J. Kendall

As we enter the new millennium, the South African mining industry has to ensure that it becomes more competitive if it is to survive in the ever more demanding global environment. Traditionally, mechanization in narrow stopes has been limited to the use of scraper winches, and numerous mechanization attempts have been restricted to pilot projects operated on an extremely limited scale (with varying degrees of success). The benefits of hydropower are well documented, and Northam Platinum has shown these benefits to be achievable on a mine-wide basis. However, the equipment originally developed for hydropower systems has followed the traditional labour-intensive approach commonly used in deep level narrow stoping operations. The problems experienced with the hydropower system are discussed and the rationale for developing alternate technologies is explored. The hydropower system has shown to be a versatile powering medium which can be harnessed for a diversity of uses. It (hydropower) enables the mining engineer to change traditional paradigms and to design an entirely new approach for optimizing the mining operation based on explosive techniques. The system developed for Northam consists of the following: ?Purpose-built stope drill rig operated off the hydropower system with special features to ensure accurate drilling patterns throughout the length of the blast hole ?Purpose-built high rate cleaning system for rapid transfer of fractured ore to the stope orepass ?Redesigned stope layout to facilitate in-stope water control and to recover fines from the run-off water ?Purpose-built drill rig for rapid establishment of reef raises and advanced strike gullies ?Purpose-built drill rig for flat end development. On both types of development end rig, emphasis is placed on ensuring accurate drilling patterns throughout the length of the hole to maximize linear advance per blast. The paper discusses the implementation of the Northam system on a large scale as well as current initiatives to further improve on the efficiencies of mining operations. It concludes by emphasizing that mechanized hydropowered stope technologies are in their infancy and thus offer unlimited scope in progressing beyond today?s paradigms to present as yet unthought of solutions for optimizing deep level ore extraction.

Jan 1, 2000

By I. A. Mwamba

Titanium aluminide of composition Ti-47.5 at.% Al was prepared by melting titanium and aluminium of commercial purity with additions of precious metals of 0, 0.2, 1, 1.5 and 2 at.% content. The microstructure, hardness and oxidation properties were assessed. It was found that at 47.5 at.% Al, the microstructure of plain TiAl alloys was duplex, consisting of duplex lamellar grains and ? grains. The lamellar grains consisted of alternating lamellae of ? (TiAl) and a2(Ti3Al), with overall aluminium content in the range of 43?47 at.%. The ? grains had a aluminium content above 50 at.%. The addition of precious metals to the TiAl alloy resulted in the formation of a new phase, with a high precious metal content, occurring mostly in the ?phase, without any major change to the microstructure. Increasing the amount of precious metals resulted in an increase of the new phase amount, at the expense of the ? phase. The hardness of the different alloys was around 300HV10. Overall, the research has shown that addition of precious metals to TiAl resulted in a slight increase in hardness and a significant improvement of the oxidation resistance. This shows that alloying TiAl with precious metals, at the addition levels investigated, does not alter the mechanical properties very much, but improves oxidation resistance.

Jan 1, 2012

The 106th Annual General Meeting of The South African Institute of Mining and Metallurgy was held in the J.C. Lemmer Auditorium, SA National Museum of Military History, 22 Erlswold Way, Saxonwold, Johannesburg on Wednesday, 13th August, 2003. Welcome The President extended a special welcome to the guests and representatives of our sister institutes and other associations, also to recipients of awards, senior members of industry, Honorary Life Fellows, Past-presidents, our Members and other guests, among them the following: Kevin Moxham, President, Association of Mine Resident Engineers Prof. Jay Barton, Vice President, The Geological Society of South Africa Dr Gus Muller, President, Institute of Certificated Mechanical and Electrical Engineers, South Africa Marius van Rooyen, President, Institute of Mine Surveyors of South Africa Benjamin Ngulube, Deputy Vice President, South African Institution of Electrical Engineers Dr Francois Malan, Chairman, South African Institute of Rock Engineering Dr Paul Jourdan, President, Mintek

Jan 1, 2003

By A. Dienenthal

"The casthouse floor has always been one of the most dangerous working places on a blast furnace or a ferro-alloy/nonferrous furnace. Apart from working in an atmosphere including toxic gases, fumes, and dust, the workers have to perform hard and heavy manual work close to runners and ladles filled with hot liquid metal and slag.Before the invention and installation of tapping equipment the tap-holes were opened and closed manually. Opening was done by means of steel bars and sledgehammers, whereas the tap-hole was closed by repeatedly ramming small amounts of clay or refractory material into the tap-hole, again with the help of long, heavy bars. In addition, on blast furnaces the blast had to be stopped, since it was impossible to close the tap-hole properly against the blast furnace pressure. This stoppage of the blast resulted in regular losses of production. Around 1900 a major change in technology occurred. Samuel W. Vaughen, superintendent of the blast furnace department of the Cambria Iron company at Johnstown, Pennsylvania (USA), invented the first clay gun in 1895 (Wiley, 1896) (Figure 1)."

Jan 1, 2014

By M. Abdellatif

The production of a 40% Al-Ti alloy was successfully proven at the lab scale, using pure TiO2, aluminium, and lime. These tests were conducted in an induction furnace maintained at 1600?16250C. The introduction of rutile into the feed recipe resulted in an alloy containing between 0.35 and 1.10% Zr, depending on rutile to TiO2 ratio. DC arc production of the alloy was largely accomplished at 40 and then 200kW scale. These tests evaluated various metallurgical and operational factors including target slag composition, Ti-content in the alloy, co-feeding versus sequential, furnace bath depth, and rutile as part of the Ti containing feedstock. Overall, an alloy containing 24?33% Ti was consistently produced with co-feeding of the reactants and with lower taphole tapping. When rutile was added, the zirconium analysis in the alloy remained below 0.2%. The main impurity elements were iron, silicon, carbon, nitrogen, and oxygen.

Jan 1, 2009

By H. Preßlinger, H. Hiebler, K. Klepp, W. Posch, M. Mayr

It was investigated in which form sulphur is bonded in ladle slags. For this purpose, the mineralogical phases of the ladle slags were qualitatively and quantitatively evaluated by means of a microprobe. This slag characterization allowed reconstructing the bonding of sulphur into the phases of the ladle slag. Moreover, the reaction process with regard to the ionic theory as well as the structural formula for the mechanism of sulphur bonding were discussed. The bonding of sulphur into calcium aluminate slags is determined by the sulphide ion content in the slag as well as by the ratio of (CaO)/(Al2O3). Calcium sulphide separates only if the slag contains a large number of sulphide ions. When Ca12Al14O33is separated, the sulphide ion is successively integrated into the lattice. The crystal lattice of Ca12Al14O33is characterized by an open, three-dimensional anionic network composed of aluminium-oxygen tetrahedrons linking the edges. In this network, large interstitial spaces are formed, which may be filled with calcium ions on the one hand and statistically with a free oxygen or sulphide ion on the other hand. Key Words: ladle slag, structure, phases, calcium sulphide, calcium aluminate, desulphurization

Jan 1, 2004