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In extracting base metals from orebodies, sulphide as well as oxide, the main environmental concern is sulphur, whether in the form of sulphurous gases or sulphate in liquid form. Generally sulphur is in over supply in developed countries mainly because of strict legislation to capture it. In developing countries, on the other hand there is usually a shortage of sulphur because of less strict environ-mental legislation. Africa falls in this second category and the African continent imports substantial amounts of sulphur, despite the fact that large quantities of sulphur are emitted by smelters, thermal power stations, coalmines, fertilizer manufacturers and others. Other than making acid from gaseous emissions, existing methods to capture sulphur from gaseous and liquid effluents are uneconomical and it ends up in the environment either as ammonium sulphate (from gaseous effluents) or as gypsum (from liquid effluents). The CSIR?s Environmentek and Key Structure Holdings have developed a process whereby gaseous sulphur emissions and sulphates in liquid effluents can be economically captured and converted into elemental sulphur and metal carbonates. The elemental sulphur is of high purity as it is precipitated from a gas stream and is readily marketable. The metal carbonates (barium or calcium) can be recycled back to the process or marketed. The only harmful by-product of the process is carbon dioxide. Should natural gas or methane be available, the carbon dioxide could be reduced by about one third. Should solar, wind or hydro energy be available to generate hydrogen, the carbon dioxide emissions would be zero. Employing this technology could make Africa independent of sulphur imports and furthermore reduce the impact of acid rain and seepage of sulphate from gypsum and other waste dumps into the environment.

Jan 1, 2005

By M. M. Makhofane

Anhydrous zirconium tetrafluoride can be used as a precursor for the manufacturing of nuclear-grade zirconium metal. This can be done by fluorinating plasma-dissociated zircon with ammonium bifluoride in a batch reactor. This paper describes the batch process. It was proved that anhydrous zirconium tetrafluoride can be manufactured by this route as confirmed by X-ray diffraction. The process shows potential for scaling up to the kilogram scale and possibly the tonnage scale.

Jan 1, 2012

By R. Van Rijswick

Crankshaft driven piston and piston diaphragm pumps inherently generate a varying flow each crankshaft revolution. Depending on the system connected, this flow variation results in a pressure pulsation. This pressure pulsation may, depending on the structural design, result in structural vibrations. In order to limit the level of pressure pulsations, volume absorbing devices, mostly gas filled vessels, are used. The standard selection of these so-called dampeners is based on the flow variation of the pump but does not incorporate the interaction with the connected system. The paper discusses the application of a pulsation analysis tool developed by WEIR Minerals Netherlands, manufacturer of GEHO positive displacement slurry pumps. The paper first discusses the basics of pressure pulsation analysis, such as flow variation generated by crankshaft driven pumps, and hydraulic effects such as capacitance, inductance and resistance and their influence on the hydraulic response of a system. Furthermore, the relation between pressure pulsations and structural vibrations, known as fluid structure interaction, will be discussed. Additionally, the capabilities of the pump pulsation analysis tool are presented, illustrated by examples of simulation results and experimental verification.

Jan 1, 2007

By R. L. Pienaar

Paper written on project work carried out in partial fulfilment of B Eng (Min. Eng.) degree A study was conducted to investigated and compare the feasibility of two single level extraction layouts for an intact part of theorebody of the De Beers diamond mine, Koffiefontein. Two layouts were chosen and the tonnage profile, development schedule and production ring blast layouts were calculated by applying the information acquired through a literature study. Current principles used on the mine were also applied. The first layout chosen is described as a simple straightforward layout with 6 production tunnels spaced 15 m apart, and is referred to as Layout A. The second layout, named Layout B, is described as a complex chevron layout with 9 production tunnels spaced 15 m apart. This layout has a rim tunnel situated in the kimberlite ground, which is called a chevron and this made the layout more complex than Layout A. By comparing the financial results of the two layouts, it was found that Layout B is a more feasible option than Layout A. Sensitivity analyses show that both layouts are extremely sensitive to the revenue of the projects. Therefore it is recommended that Layout B can prove to be a source of additional tonnage to add to the total tonnage profile of the mine and to extend the life of mine by 20 months, only if certain financial/economic factors improve. There is, however, still some areas of the project that need to be investigated.

Jan 1, 2006

By B. Ulrich

The basis of this paper is a compilation of work in the design and construction of copper heap leach facilities, and interviews with various heap leach operations personnel in Chile and Peru. The purpose is not to highlight specific mines and their performance, but rather to discuss geotechnical/civil features of copper heap leach facilities that function well, as well as features that do not. During the 1990s several copper heap leach facilities were brought on-line in South America. Many of these facilities have now been operational for a number of years during which time the operators have been able to monitor the performance of their heaps. This paper serves as a compilation of operators? experiences, and provides a discussion of the lessons learnt over the past decade. Several key geotechnical issues are examined, focusing upon the integrity of the ore, drainage material and pipe network, along with the success of inter-lift liners. This conference provides a timely update of the original paper (Burkhalter et al, 2002).

Jan 1, 2003

By J. P. Harrison, J. A. Hudson.

ABSTRACT: When considering the rock stress component of rock mechanics design, the basic procedure is to consider the pre-existing stress-state in the rock mass and then estimate the disturbance to this stress state as a result of engineering excavation. Failure criteria are applied to the final stress state to establish whether failure will occur. However, during the evolution of the stress state, the failure locus may be reached before the anticipated failure state and, in this case, failure will occur unexpectedly. This indicates that the complete stress path (defined as the variations in magnitudes and orientations of the stress tensor components resulting from engineering-induced or natural changes) must be considered. We list a set of stress path principles with their corollaries and then introduce a new and powerful method for simultaneously illustrating changes in the six independent components of the stress tensor. This method plots the magnitudes of the principal stresses above their orientational paths on the hemispherical projection, to provide a three-dimensional stress path locus for each of the three principal stress components. In connection with this presentational device, we illustrate a number of concepts associated with the stress path in rock engineering. For example, we show how the minor principal stress approaches zero at an unsupported excavation face, the interchange of the trajectories of two principal stresses when their magnitudes become equal, and the influence of the bounds on the principal stresses given by strength criteria. RESUME: Si on s’interesse à la composante “contrainte” lors d’un dimensionnement en mécanique des roches, la méthode de base consiste à considérer l’état de contrainte pré-existant dans le massif rocheux, puis d’estimer la perturbation à cet état générée par l’excavation projetée. Des critères de rupture sont appliqués à l’état de contrainte final pour établir si une rupture va se produire. Cependant, lors de l’évolution de l’état de contrainte, la surface critique peut être atteinte ce qui provoquera une rupture anticipée et, dans ce cas, cette dernière sera inattendue. Cela indique que le chemin de contrainte complet (défini par les variations de l’intensité et de l’orientation des composantes du tenseur des contraintes liées à des causes anthropiques ou naturelles) doit être pris en compte. Nous présentons un ensemble de règles pour les chemins de contraintes ainsi que leurs corollaires et, ensuite, nous introduisons une méthode, nouvelle et puissante, pour présenter simultannement les changements des six composantes du tenseur des contraintes. Cette méthode consiste à tracer l’intensité des contraintes principales sur le chemin d’orientation des contraintes à l’aide d’une projection hémisphérique afin d’obtenir le lieu, en trois dimensions, de chaque contrainte principale. En relation avec cet outil de représentation, nous illustrons certains concepts associés au chemin de contrainte en ingénierie au rocher. Par exemple, nous montrons comment la contrainte mineure tend vers zero à la surface d’une excavation sans soutenement, le changement de direction des deux contraintes principales quand leur intensité deviennent égales, et l’influence des conditions aux limites sur les contraintes fournies par un critère de rupture. ZUSAMMENFASSUNG: Bei ingenieurmassigen Taetigkeiten in Felsgesteinen ist es noetig die ungestoerten Gesteins Stress Componenten, die vor einem anthropogen Eingriff im Gestein vorhanden waren, zu kennen und erst dann Vorhersagen ueber Stoerung des Stress Zustandes, der durch einen ingenieurmaessigen Eingriff hervorgerufen wird, herzuleiten. Kriterien fuer das Versagen werden im letzten Stadium, des Stress Zustandes angewendet, um zu erfahren ob ein Versagen wohl eintreten wird. Es ist jedoch zu beachten, dass waehrend des Stress Aufbaus ein oertliches Versagen eintreten kann, welches vor dem eigentlichen, erwarteten Versagens Zustand auftritt. Diese Moeglichkeit weist darauf hin, dass der gesammte “Stress Path” (definiert durch die Variationen der Stress Tensor Komponenten in Richtung und Groesse, hervorgerufen durch ingenieurmaessig hervorgerufene oder natuerlich Vorgaenge) betrachtet werden muss. Wir fuehren eine Liste der “Stress Path” Prinzipien auf und stellen dann eine neue und wirksame Methode zur gleichzeitigen Darstellung der sechs unabhaegigen Komponenten des Stress Tensors vor. Diese Methode stellt die Groesse der “Principal Stresses” in Abhaengigkeit von ihrem rauemlichen Weg auf einer hemispherischen Projektion dar und erlaubt hiermit eine drei dimensionale Darstellung fuer jeden Ort des “Stress Path’s” in die drei Haupt Stress Komponenten. Im Zusammenhang mit der hier gegebenen Darstellungsart, verdeutlichen wir eine Reihe von Konzepten in der Felsmechanik. Wir zeigen zum Beispiel, wie der “Minor Principal Stress” Null zustrebt an einer Wand von einer nicht abgestuetzten Ausschachtung, den Austausch von Trajektorien zweier “Principal Stresses” wenn ihre Groessen sich gleichen, und den Einfluss der Groesse von “Principal Stresses” bei gegebenen Kriterien des Festgkeits Versagens.

Jan 1, 2003

[Consider a square block W in an ore body S2, to be valued from one centre sample w, and one corner sample w2 (Fig. 9.1). The sample set is ws = Iw,;w21. We can estimate the block average µw by the average of the sample values x, and x2: µw = 'z (x, + xz). (9.1) The error made is measured by the estimation variance: o' (ws to W) = 2 - (ws; W) - - (ws;ws) - - (W; W). (9.2) However, we know that the centre sample w, gives more information about the block value than the corner sample w2. In the example studied in § 8.4, where w, and w2 were considered to be points, we found that of (w, to W) was nearly one third smaller than o2E (w2 to W), therefore when estimating W one should give more weight to w, than to w2. In general, when evaluating a block W from a set of n samples ws, where WS = l w;w2; ... wn1, a better estimator of µw can be obtained if we give different weights to the sample values, depending on the size and the positions of the samples. Some desirable properties of such an estimator µw are: ? It should be a linear function of the sample values xi: n µw = bi xi (9.3) =t where bi = weight given to sample x . ? It should be unbiased, i.e. its expected value should be equal to the true block value: E [µw - µw] = 0. (9.4) ? The mean squared error of estimation of µw should be a minimum E [(µw - µw)2] = a minimum. (9.5) The estimator which satisfies these properties is a minimum variance, linear and unbiased estimator, and is known as the kriging estimator. The corresponding error of estimation is the kriging error. This estimator is also known as the BLUE (for Best Linear Unbiased Estimator) estimator. This was named by Matheron in acknowledgement of the early work of Krige's in the optimization of the evaluation of the South African gold mines. The following notations will be used: µK kriging estimator. o2k = o2K (w,, to W) kriging error.]

Jan 1, 1978

By Nicolle Krusberski

Potential errors in XRF analysis are discussed and investigated with specific reference to the analysis of ilmenite samples. A selection of ilmenite samples was chosen and prepared using two XRF preparation techniques: pressed powder pellet and unroasted fusion bead. The merits of the two methods have been discussed in this paper for ilmenite analysis by XRF. Recommendations have been made regarding the use of pressed powder pellets especially with regard to the mineralogical effects that were evidenced during this investigation. The fusion bead technique was found to be far more accurate and able to meet short turnaround requirements provided the calibration methodology used is specific to the grade of samples analyzed.

Jan 1, 2014

By M. Tangstad, D. Lu, G. Tranell, S. Gaal, J. Safarian

The kinetics of MnO reduction from high carbon ferromanganese slag was investigated using a sessile drop technique at 1600 ºC. The effects of reductant type, ambient atmosphere and slag composition on the MnO reduction were illuminated. Two different types of industrial reductants (ground to a particle size of 44 to 106micron and pressed to pellets) were used as substrates for small slag droplets of varying composition, which were reacted in a CO or Ar atmosphere with the reaction studied in-situ. The cross sections of the reacted slag-carbon samples were subsequently studied by EPMA to find the extent of MnO reduction as a function of reaction time. It was found that the rate of MnO reduction is affected by both the type of reductant, the ambient atmosphere and the presence of metallic components in the slag. Higher reduction rates were obtained for charcoal than for coke as reductant while a CO atmosphere unexpectedly yielded faster MnO reduction than an Ar atmosphere. It was also found that metal prills in the initial slag will increase the rate ofMnO reduction.

Jan 1, 2007

By Z. Zhang, R. G. Reddy

Experimental and thermodynamic modelling studies on the structure of alkali borate melts and properties are discussed. A thermodynamic structure model for alkali borate melts is developed to describe the distribution of structural groups in the alkali borate melts as a function of composition. A qualitative interpretation for the boron anomaly in viscosity has been proposed, which regards the boron anomaly as a manifestation of the various antithetical effects caused by the introduction of alkali oxide into boric oxide. It has been found that the viscosity of alkali borate melts increases or decreases according to the changes in rigidity and spatial connectivity of the glass network structure, which is the function of temperature and composition. These concepts with some key examples are discussed in relation to their usefulness and practicality in industrial slags. Keywords: alkali borate melts; structural model; activities; structural groups; viscosity;

Jan 1, 2004

By D. G. Krige

Recent publications have demonstrated the important role that can be played by a priori information of the grade levels, variability, and spatial patterns in adjacent or nearby areas in improving the quality of grade estimates for virgin or sparsely drilled areas. A research project was therefore conducted involving the collection and analysis of extensive sampling and borehole data from 7 reefs on some 30 Witwatersrand mines. This paper shows that the 'equivalent' log variance for the two-parameter lognormal model provides a good basis for the study and comparison of the levels and behaviour of relative variances. The trends of these against the corresponding log areas were found to form distinctive patterns, which are useful for these purposes. The patterns for the Basal, Vaal, Carbon Leader, and Main Reef Series form a reasonably close group, whereas those for the V.C.R.(particularly where the facies are mixed), B Reef, and Kimberley-Elsburg Reefs (particularly for narrow channel widths) do not always conform. The patterns shown by underground chip samples are also compared with those obtained from borehole cores. It is shown how this information can be used to improve the borehole valuation of new mines and of virgin areas in existing mines.

Jan 1, 1993

By Pekka Taskinen

Advanced optimizing control of the fluidised bed zinc roaster has been in use for an extended period at Boliden Kokkola and the implications are seen as extended bed stability, increased throughput and far better on-line availability. The roaster furnace control system developed is based on a dynamic and predictive furnace model, with parameters determined experimentally at the site. The controller maximises the concentrate feed and keeps the furnace operational parameters inside limits given by raw material mix and equipment constraints. The products of a zinc roaster, calcine, sulphur dioxide and the side products, such as mercury, meet gradually more stringent requirements, in particular as to their assays and total recoveries in the process chain. The end users of sulphuric acid in northern Europe, among others in the pulp and paper industry, require mercury levels much less than the conventional 0.2-0.4 ppm Hg. Therefore, secondary de-mercurising circuits have been used over the last five years for further cleaning the SO2 stream allowing production acid grades with less than 0.08 ppm Hg.

Jan 1, 2008

By M. B. Shongwe

Pt-based alloys are being developed for high-temperature applications with the aim of replacing some of the currently used Ni-based superalloys (NBSAs) in the highest temperature applications. The Pt-based alloys have a similar structure to the NBSAs, and since Pt is more chemically inert than nickel and has a higher melting point, they can potentially be used at higher temperatures, up to 1300°C, and in more aggressive environments. Several experimental Pt-based alloys were studied at Mintek, and an optimum composition was found to be Pt84:Ahi:Ru2:Cr3 (at.%). On the basis of hardness and microstructure, a later study identified a new optimum: Ptr8:A111:Ru5:Cr6 (at.%). There are at least two Pt3A1 allotropes, and the high-temperature cubic structure has better properties than the lower temperature tetragonal form, and so needs to be stabilized. This work describes the latest results obtained in transmission electron microscopy (TEM) studies of the quaternary Pt-based superalloys. These results are both interesting and important, because the samples have a higher precipitate density compared to those from earlier work. The precipitate morphology is mainly cubic, with minor areas having irregular-shaped precipitates. The high volume fraction of the precipitates is a major breakthrough, since the objective of this work is to improve the alloys. A prior disadvantage was that the proportion of the precipitates was too low in samples before this work, especially compared with the work from Germany on Pt-Al-Cr-Ni¬-based alloys as well as the NBSAs. TEM -Pt3A1 diffraction patterns were studied, and for each diffraction pattern, many possible lattice point combinations were tried, with the angle between the lattice spots as well as interplanar spacings being calculated for each phase (cubic or tetragonal) to match the measured results. An overall analysis of the diffraction results indicates that the cubic phase fitted the experimental lattice points with much lower errors compared to the tetragonal phase. Thus, with the close match achieved with the cubic structure, the structure of -Pt3A1 precipitates is likely to be cubic. X-ray diffraction has been carried out on selected samples, and the results confirmed the presence of cubic -Pt3A1 and (Pt). Different X¬ray diffractometers were used to further verify the results, and the results were also compared with those from TEM.

Jan 1, 2012

By Zdenek Kunicky

Kovohute Pribram is a plant recycling lead wastes, lead acid batteries in particular. Relevant new recycling technologies are being gradually developed. Outdated technology of smelting lead plates has been replaced by a new technology based on processing of entire batteries in a blast furnace according to the process developed by know-how of German Varta company. The classical Harris refining has been substituted by the oxygen refining. New technologies aimed at utilization of related wastes arising from refining lead bullion in Kovohute Pribram are being developed in house. At present, a new technology of utilization of spent battery acid for extracting zinc from various wastes has been developed. Zinc oxide dross from alkaline refining of lead bullion, during which residual zinc from the preceding vacuum de-zincing is removed as well as waste zinc galvanic sludges (a product of neutralizing precipitation of metals from industrial wastewaters with lime) were treated. In this study, the new developed technology yielding basic zinc carbonate - a valuable raw material for zinc electrowinning, is described together with the first experience of applying the developed method to processing zinc wastes on a pilot scale. Most of the equipment used in the past to regenerate alkali solutions originating from Harris refinery was utilized in the practical realization of this new technology.

Jan 1, 2008

By A. P. N. Sutherland

Pipelines for transporting high concentration slurries are often designed using methods applicable to homogeneous non-Newtonian laminar flow. Many industrial slurries though comprise coarse particles in a non-Newtonian carrier fluid, and existing experimental evidence from tests with such slurries demonstrates that they are not homogeneous. Under laminar shear conditions the coarse particles settle, even in statically stable carrier fluids. To understand this better, the Institute of Materials Science and Technology (IMST) at Cape Peninsula University of Technology (CPUT) is conducting ongoing research into the flow of these high concentration non-Newtonian settling slurries. Since pressure gradient and flow rate measurements alone are insufficient to adequately model the flows, an electrical resistance tomography (ERT) instrument developed by the University of Cape Town (UCT)was incorporated into the pipe test loop to determine pipe cross-section concentration and velocity profiles. The software developed to do this is modular and allows different image reconstruction and cross-correlation algorithms to be implemented and tested without significantly changing the rest of the application. At a total frame capture rate of 566 frames/sec a 2.67 GHz Intel Celeron processor with 500 MB of RAM is fast enough to calculate and display velocity profiles in ?real-time? at an update rate of one profile every two seconds. Examples of experimental concentration and velocity profiles obtained using the system are shown and some proposed improvements/extensions to the system are listed.

Jan 1, 2008

By K. Ford, R. Urquhart, D. Hobbs

CIS countries are home to some of the world's largest producers of chrome, manganese and silicon ferro alloys and leading suppliers to world export markets. The region's ferro alloys production is rising faster than demand from its domestic steel industry - unit alloy consumption in domestic steelmaking is in fact falling as process efficiencies improve - and there is significant spare capacity available to increase production. CIS producers enjoy certain strategic advantages in the production of ferro alloys - for example, captive ore sup-plies, low power and labour costs - but must also meet certain challenges - such as lower labour productivity and greater distance to market than some of their competitors. CIS producers are ambitious but new investment is needed to upgrade some aging plants and overhaul outdated process technologies if they are to be more competitive with the world's leading producers and address the environmental issues that are now moving up the agenda. This paper describes the structure of the region's ferro alloys industry and discusses its advantages and disadvantages by alloy and by country. It considers how the ongoing process of restructuring and new investment in the industry might move forwards, based on its strengths and weaknesses, technical and environmental factors and the strategies of the main players. It asks how the industry might maximise its substantial potential - in particular, for the production of chrome and manganese ferro alloys - and examines the implications this holds for all global ferro alloys players.

Jan 1, 2007

By L. Andrews

Nickel is recovered as a by-product of the platinum-producing process operated by Anglo Platinum. The metal is mined mainly as sulphide minerals contained in platinum ores. These pass through the concentrating, smelting and converting process route and nickel is finally recovered by electrowinning. Smelting of the concentrated ore in the electric furnace produces a melt with a high slag to matte ratio. The resulting furnace slag is granulated and later milled and floated to recover matte. A project was initiated to investigate the distribution of nickel in the slag in order to improve recovery. Slag samples were examined using a combination of chemical and mineralogical techniques. The granulated slag was found to consist mainly of a silicate glass phase, which reflects the composition of the molten slag in the furnace. Nickel occurs as free matte granules, as matte phases locked inside the glass, and in the glass phase itself. Whereas nickel in the matte is as sulphide, most of the nickel in the glass phase appears to be oxide- bound(i.e. in solid solution). Milled slag as flotation feed showed recovery-limiting features such as free matte with oxidized surfaces and unliberated matte inclusions in the slag. The biggest nickel losses, assuming no tapping problems, are in the glass phase solid solution. Only around 40% of nickel would be recovered from the slag, even under ideal conditions. Spoon and pot slag samples were also examined to see if casting and crushing would improve recovery. Although larger and therefore more easily recovered matte phases formed, nickel partitioned into crystalline silicate phases, limiting the maximum theoretical nickel recovery to 70%.

Jan 1, 2004

By M. B. Fonseca

Risk quantification in grade-tonnage curves is critical for capital investment in mining projects and can be obtained through geostatistical simulations of orebodies. A practical difficulty may arise in multi-element deposits, as the joint modelling of the related attributes using the traditional co-simulation approaches is computationally intensive and may be impractical for use in the industrial environment. This paper presents the construction of risk-integrating grade-tonnage curves for a complex copper deposit in northern Brazil, by jointly simulating its key geochemical attributes of interest: Cu, Fe and K. The joint conditional simulation of these elements is based on Minimum/Maximum Autocorrelation Factors (MAF). MAF is an approach, based on principal components, that spatially decorrelates the variables involved to non-correlated factors. MAF’sspatial decorrelation at any lag distance is the main and critical difference of this approach from the principal component approach attempted in the past. In the MAF approach, the independent factors are individually simulated and back-transformed to the conditional simulations of the correlated deposit attributes that reproduce the cross-correlations of the original variables. Keywords: Joint simulation; mini/max autocorrelation factors; grade-tonnage curves.

Jan 1, 2003

By S. J. C. L. Peeters

Geographical information systems (GISs) provide sophisticated functionalities t1tat can be used by the personnel in many aspects of the mining industry to visualize, analyse, and manipulate spatial and tabular data. This paper presents an experimental case study for Hartebeestfontein Gold Mine. It shows how data from different computer systems can be brought together into a GIS by use of the Arc/Info and ArcView programs.

Jan 1, 1996

By J. Keyser

The realization of an Integrated Technical Resource Asset Management System (ITRAMS) has so far evaded all software developers in the mining industry. The major factors that have prevented the development of such a system are limitations on software, hardware and network systems. Several factors have come together at Venetia Mine, which has made the undertaking of such a project both possible and desirable. This has led to the formation of a strategic partnership between Venetia Mine and Gemcom Software International Inc. This partnership is dedicated to develop and provide an Integrated Technical Resource Asset Management System based on Microsoft Back Office architecture, Gemcom for Windows™ and the MinRas system. This paper will elaborate on the phased approach of the integration of systems into the core repository, mechanisms of integration, the functionality of the system, final results, techno-economic benefits and general project management issues.

Sep 1, 2001