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By M. Saghaeian, R. Hejazi, V. Sheikhzadeha, A. H. Baladastian, A. Dehghani Ahmadabadi

This paper describes research done to remove apatite (phosphorus) from hematite ultrafine (70% finer than 25 micron) concentrate, recovered by electromagnetic separators at the FST Tailing Recovery Plant located in Chadormalu Iron Ore Complex through reverse froth flotation. As a result, iron and phosphorus content in magnetic concentrate (flotation feed) were 53.52% and 0.58%, respectively. Therefore, to increase the Fe content and decrease the P content of the sample, reverse flotation tests were applied. Chemical reagents used in this research consisted of sodium silicate as a depressant, sodium hydroxide and sodium carbonate as pH regulators, Alke & Dirol as fatty acid collectors and MIBC as frother. Process parameters including dosages of collectors, depressant and frother, preparation times of depressant and collectors, steps and time of frothing and pH range were selected. After doing flotation tests, in optimum condition, dosages of collectors were 1200 g/t, depressant 1200 g/t, pH in the range of 9.5 to 10, preparation time of collectors in the first step was eight minutes and at the other steps, four minutes; the number of frothing steps 4 and frothing time in each stage was three minutes. In this case, it was observed that the amount of phosphorus in the final concentrate was reduced to 0.05%, the Fe content increased from 53.52% to 61.66% and the Fe recovery achieved was 82.21%. Keywords: Iron ore, hematite ultrafine concentrate, iron and phosphorus content

Jan 1, 2020

By F. S. Hoseinian, B. Rezai, E. Kowsari, M. Safari

In order to remove heavy metal ions from a large volume of wastewater with a low ion concentration, ion flotation appears to be promisingly effective. In the ion flotation process, because of the high ion removal percentage, the amount of water recovery percentage is a very important factor which determines the process efficiency. However, ion flotation suffers from relatively high collector concentration to achieve the high removal percentage to the desired limit, which subsequently increases the water recovery. In this study, functionalised graphene oxide (FGO) was synthesised, using a chemical method in the ion flotation process, applied as a collector for increasing process efficiency by reducing the collector consumption and water recovery. The high ion removal was achieved with both collectors of sodium dodecyl sulfate (SDS) and FGO, while the water recovery with a collector of SDS was 3.4% higher than that with a collector of FGO. The results indicated that the FGO could be effectively used for high ion removal and low water recovery in the ion flotation process. Keywords: Ion flotation, synthesised collector, ion removal, wastewater, water recovery

Jan 1, 2020

By W. F. Lorch

Growing use of deionised water in surface coating techniques by w. F. LORCH Production engineers in the metal plating, paint, plastics-coating and printed circuit industries are increasingly aware of the cost of sub-standard or blemished items which have been poorly processed. An area where quality control can quickly produce higher efficiencies is in the choice of suitably purified water for making up solutions, for rinse baths and 'drag-out' baths, for cleansing lines and electrophoresis tasks, for maintaining electrolyte density and hence consistency, and for facilitating the recovery of valuable minerals. The author of this article examines the general problems of using nonpurified water, and shows how purified water has become accepted by the principal surface coating industries to improve processes and effect economies.

By P. A. Olubambi

The leaching of zinc and copper from Nigerian bulk sulphide ore with sulphuric acid in the presence of hydrogen peroxide was studied. The aim of the study was to investigate the effectiveness of hydrogen peroxide as an oxidant for the sulphuric acid leaching of zinc and copper from a complex sulphide ore. Distribution of elementals within the various particle sizes was initially determined by ICP-OES and XRF to provide a basis for explaining the dissolution process. The effects of concentration of hydrogen peroxide, particle size, stirring speed, and leaching time at a constant temperature of 298K were studied. There were variations in elemental and mineralogical composition within the different sizes. The concentrations of zinc and copper reduced as particle size decreased while silica, sulphur, iron and lead contents increased. Dissolution results showed that the leaching rate of copper was lower than that of zinc. The highest recoveries of zinc and copper were obtained at a leaching time of 180 minutes, stirring speed of 160 rpm, particle size of 75 µm and a concentration of 1M H2SO4/1MH2O2. It was observed that the leaching rate of zinc and copper increased with increasing hydrogen peroxide concentration. Increased stirring speed had a negative leaching effect as it promotes hydrogen peroxide decomposition. Keywords: Nigerian sulphide ore, zinc, copper, hydrometallurgy, sulphuric acid, hydrogen peroxide.

Jan 1, 2006

By H. Askari-Nasab, S. Upadhyay, A. Moradi-Afrapoli

Material handling in surface mines accounts for around 50% of the operational cost. Optimum truck dispatching plays a critical role in the reduction of this operational cost in truck and shovel surface mines. Researchers in this field have presented several mathematical models to solve the truck dispatching problem optimally. However, a critical survey of the literature has shown that three significant drawbacks exist in the available truck dispatching models. The published models underestimate the importance of the interaction between truck fleet, shovel fleet, and the processing plants. They also disregard goals set by strategic-level plans. Moreover, none of the available models account for the uncertainty associated with the input parameters. In this paper we present a new truck dispatching model that covers all of these drawbacks, using a fuzzy linear programming method. The performance of the developed model was evaluated through implementatin in an active surface mining operation. The results show a significant improvement in production and fleet utilization.

Sep 1, 2021

By O. Acaroglu

Selection of the most suitable roadheaders (boom type tunnelling machines) for the galleries/tunnels to be excavated in certain rock and under known project conditions is important for avoiding problems during application. This research utilized a multiple attribute decision-making method and studied how this will be applied for the selection of boom-type excavation machines. The Cayirhan Coal Basin was used for selecting roadheaders using the analytical hierarchy process, which is one of the multiple attribute decision-making methods. To conclude, this study reveals that decision-making methods can be used in the process of selecting roadheaders for the excavation of galleries. Keywords: roadheaders, multiple attribute decision-making, analytical hierarchy process.

Jan 1, 2006

By W. P. C. Duyvesteyn, J. R. Cutland, J. R. L. Russell

In 1970 it was decided to build a large new plant at the Chingola Division of N.C.C.M., Ltd., to treat concentrator tailings and leach residues with a low copper content by a leach-solvent extraction-electrowinning process. In order to assist in the establishment of the design parameters for the new plant, and to study the interaction of this plant with the existing leach-electrowinning plant, mathematical models, formulated as linear programs, have been developed and used extensively. The paper outlines the metallurgy of the plants and describes briefly the way in which the models have been formulated and used. The formulation involved the use of separable programming to form the products of some variables.

Jan 1, 2014

By J. Y. Foley, K. Eden, A. E. Grosz, C. J. Giles, J. E. Grosz

"Portions of the Icy Cape placer Au district have been described and exploited since the early 1900s. Industrial studies of Au-bearing garnetrich intervals established a 3.5 million troy ounce resource in the western half of the district. This estimate is not compliant with CIM and SME definition standards for Mineral Resources and Mineral Reserves. We note high variability in the textures of sediments and their heavy mineral (HM) content and composition in the district, probably as a function of the depositional environment. Sediments are medium- to fine-grained sands with a valuable HM assemblage that averages 26.0% in a range of 1.1– 72.6%. Valuable heavy minerals (VHMs) garnet, magnetite, ilmenite, rutile, and zircon, but excluding Au, average 7.9% in a range of 1.0–37.6% of the HM assemblage. Trace quantities of uraninite, thorite, monazite, xenotime, and others are noted. Garnets have an average Y content of 726 ppm with a range of 0–2150 ppm. Energy-dispersive X-ray fluorescence confirms compositions commensurate with Ca, Al, and Mg silicates. We provide empirical analytical data and note high variability in the textures, HM content, and compositions as a probable function of depositional environment. Icy Cape District land and resources are owned by the Alaska Mental Health Trust Authority and managed by the Trust Land Office (TLO). IntroductionThe Icy Cape Heavy Minerals (HM) District in Alaska subtends more than 200 km2 fronting the Pacific Ocean and backing to the foot of the Robinson Mountains at about 1700 m above sea level. We classify the district into geomorphic provinces; the eastern region as deltaic (Figure 1) and the western region as coastal plain (Figure 2), based on geomorphologic expressions. The coastal plain is entirely built up of unconsolidated outwash sediments and ancient beach sand deposits."

Jan 1, 2017

By J. P. Hoffman

In 1988 the Japan Iron and Steel Federation started a research-and-development programme known as DIOS (direct iron-ore smelting). Eight Japanese integrated steel producers and the Coal Mining Research Centre, subsidized by the Ministry of International Trade and Industry, are involved in the project. The aim of the programme is to have a 500 v/d pilot plant for the production of iron via an oxygen-coal in-bath smelting converter in operation by mid 1993. The three main components of the DIOS process are as follows: ?a fluidized bed for the pre-reduction of iron-ore fumes ?in-bath smelting reduction in a converter ?off-gas reforming by the addition of coal fines. The main drive is to provide a smelting process that is more energy-effective, using coal instead of coke and/or electricity. The advantages claimed include inter alia ?direct use of fine iron ore ?direct use of non-coking coals-low coal consumption ?low capital expenditure-replaces costly coke ovens, agglomeration plants, and the blast furnace ?economical production on mini-plant scale ?less of an impact on the environment. This concept of 'direct steel has been carried over to the production of stainless steel direct from the ores, again bypassing such energy-intensive units as the submerged-arc furnace for the production of ferrochromium. A number of Japanese companies have indicated a certain amount of success. Several interacting elements are recognized that could have a productivity-limiting aspect. The possibility of the direct production of stainless steel from chromite is discussed briefly with reference to the Highveld of the eastern Transvaal as a possible site for such a plant

Jan 1, 1992

By D. Rankin, H. J. Stucke, W. K. B. Loftus

SYNOPSIS Planning for the Finsch opencast mine is described with particular reference to the proposed stages of mining, the method used to determine the limits of surface waste rock stripping and the derivation of the waste rock mining rate. Actual mining practice is described and the possibility of installing a skipway into the open mine at a later date is discussed. In addition, the waste dumping policy is referred to: this includes the cutting of slots through the hill on the west side of the pipe to increase tramming speeds. The crushing, washing and recovery sections of the treatment plant are described together with the various changes being made to the circuit. The most important of these are the installation of X-ray sorters for the final recovery of + 7 mesh diamonds, and the vibrating grease belt for the recovery of - 7 mesh diamonds. INTRODUCTION The Finsch Mine, a subsidiary of De Beers Consolidated Mines, Limited, is situated approximately 90 miles west of Kimberley, and some two miles from the village of Lime Acres, in the Northern Cape. Lime Acres is a company village shared with the Northern Lime Company which operates a limestone quarry and works near the township. The mine is near the southern end of a well mineralized belt producing limestone, asbestos, diamonds, manganese and iron ore, and the whole area has developed rapidly in the last 20 years. Power for mining operations is drawn from the Electricity Supply Commission. The mine is conveniently close to the main Kimberley-Postmasburg railway line. Water is drawn from the Vaal River through a 57 mile State-owned pipeline at present temporarily operated by mine staff. DISCOVERY AND PROSPECTING OPERATIONS The diamondiferous orebody is situated on the farm Brits, which is State-owned ground that has been leased to the Company for the period of mining operations. There are indications of interest in the area by prospectors (Richter, de Bruin and others) over a period of some 30 years and the discovery would possibly have been made years earlier but for a law preventing prospecting for precious stones on State-owned land. Although the pipe formed a clear depression on the hill where it was situated, it was overlain by some 5 to 40 ft of banded ironstone rubble which was washed into the depression from the hillside above the pipe and obscured the deposit. In 1958, Mr Allister Thornton Fincham applied for, and was granted, the right to prospect for base minerals on the farm Brits. Asbestos is known to occur in the area and, initially, was Mr Fincham's primary interest. However, during the prospecting operations, garnets were discovered and it was realised that diamonds might be present. In 1960, when the Precious Stones Amendment Act was passed, a company

By M. Shamsi, M. Nehring

One of the most challenging aspects in semi-mobile in-pit crushing and conveying (SMIPCC) system design is determining the optimum depth at which to change from a purely truck-based haulage system to a conveyor-based haulage system. We used scenario analysis to determine the optimum transition depth between a truck and shovel (TS) system and a SMIPCC system. Traditional pit-limit algorithms were used to generate the final pit limit on a copper deposit, which was then divided into four pushbacks. The final operating pushbacks (phases) were designed for both TS and SMIPCC. The end depths for each phase are viewed as candidate transition points to switch from the TS to SMIPCC haulage system. Economic calculations were applied for five different scenarios, including adopting SMIPCC from the outset (pure SMIPCC), after the first, second, and third phases, and finally not using the SMIPCC system (pure TS) at all. The analysis indicates that the second scenario, at a depth of 335 m, results in the lowest cumulative discounted cost (CDC). In this case, the CDC is 17.6% lower than that for the pure TS scenario and 10.7% lower than for the pure SMIPCC system scenario.

Sep 1, 2021

By Xiaoxu Sun, Jianchao Yao, Qiheng Zhu, Dubo Wang, Jiancheng He, Shijie Lu

Tower mill is considered to have a better regrinding and fine grinding effect compared with ball mill, and its application is much broader. The spiral agitator of the tower mill is driven by the motor. Media inside the mill is under the combined actions of the spiral mechanism, the cylinder, and media nearby, and these parameters are key factors affecting the grinding effect. However, it is not possible to obtain detailed information of kinematic law of media based only on traditional laboratory experiments, let alone the relationship between parameters of kinematic law of media and grinding effect. Experimentation is the only way to develop industrial equipment. However, this is time-consuming and costly, which hampers the further research of the tower mill’s grinding mechanism. The paper selects two structural parameters (gap between the edge of the spiral agitator and the cylinder wall, ratio between the diameter of cylinder and that of the spiral shaft.) and three operating parameters (diameter of media, filling ratio, the speed at the edge of the spiral agitator) as variables to do an orthogonal designed experiment of five factors, four levels, and thereby obtaining change law of grinding indicators of different parameters. Experimental equipment may be simplified to enable an applicable simulation strategy. Simulation based on a discrete element method is conducted to obtain the change law of the speed of media, collision frequency, normal force, and radial force. The relational curve between parameters of kinematic law of media and energy consumption of grinding is clarified, and key factors affecting grinding efficiency are determined. Those factors will be used for optimising the design and operating process. The research result of this paper obtained from laboratory experiments and computer simulation provides data support and theoretical bases, and has directive meaning and applicable value for tower mill’s optimisation and large-sized design. Keywords: Tower mill, discrete element method, kinematic law of media, energy consumption of grinding

Jan 1, 2020

By M. Rahmanpour

"Mine planning is a multidisciplinary procedure that aims to guarantee the profitability of a mining operation in changing and uncertain conditions. Mine plans are normally classified as long-term, intermediate-term, and short-term plans, and many factors affect the preciseness of these plans and cause deviations in reaching the objectives. Commodity price is the heart of mine planning, but it has a changing and uncertain nature. Therefore, the determination of mine plans in the presence of uncertain mineral price is a challenge. A robust mine plan reduces the risk of early mine closure. A procedure is presented to determine the value at risk (VaR) in any possible mine planning alternative. VaR is considered together with downside risk and upside potential in order to select the most profitable and least risky plan. The model is tested on a small iron ore deposit. IntroductionMining projects are normally evaluated with the objective of maximizing economic value, as measured by the net present value (NPV). The aim of mine planning is to develop a yearly extraction plan that guides the mining operation to the highest NPV (Dagdelen, 2007; Yarmuch and Ortiz, 2011). This plan considers the technical constraints such as blending requirements, block sequencing, and pit slope (Caccetta and Hill 2003). Thus, the mine plan affects the economics and the payback period of mining operations.Mine planning is a procedure based on which the profitability of the mining operation is guaranteed in changing and uncertain conditions (McCarter, 1992). However, conventional mine planning ignores the volatility and uncertainty of future commodity prices and does not allow for managerial flexibility. It is common practice to assume a deterministic and constant commodity price through the mine life. The problem with this approach is that the commodity price is the heart of the mine planning procedure and governs the profitability and feasibility of the operation; thus ignoring price volatility will result in a sub-optimal mine plan."

Jan 1, 2016

By D. G. Krige

For the purpose of determining confidence limits for ore grade estimates, an extensive simulated database was used, which included 1728 ore blocks with ?actual? grades and the corresponding estimates based on ordinary and simple kriging. The practical results show that conditional unbiasedness is essential and that acceptable confidence limits can then be set using Normal theory for the simulated error distribution based on the logarithms of the ratios of ?actuals?/estimates with a variance related to the kriging variance. The mean of the data used to prepare the variogram and the estimated block grade are to be used properly in this approach. A practical analysis was also done of the actual point and block data from a very large mined out Carbon Leader area. The distributions of the actual grades for two levels of block sizes with different levels of variability were fitted using three models, ie. two three and compound lognormal. The trends of tonnages, grades and relative profits for a range of pay limits, as well as the usual tonnage-grade curves, show a practical insensitivity for the choice between the three lognormal models considered.

Jan 1, 2004

By Turgay Gurun

"Digital simulation can be used as an analytical tool to optimize the design of crushing plants without need for large-scale experimental programs.General mathematical description of a crushing operation permits the simulation of a crushing plant flowsheet under various operating conditions. The process model encompasses multistage open- and closed-circuit crushing of hard and soft rock. Crushing balances are analyzed in the light of crusher and screen performance and a comparison of different closed-circuit arrangements is made in terms of process and layout criteria.The simulation model allows comparison of process alternatives to be made in terms of equipment selection and capital and operating cost estimation. It thus provides the pertinent practical information to maximize plant efficiency, and to minimize expenditures in such items as equipment, structures, power consumption, and so on."

Jan 1, 2014

By R. Weber

Methane explosions in underground coal mines are a major concern across the mining industry. After the Pike River disaster, Arnot Coal became even more aware of the explosion risk. To determine whether Arnot has adequate precautions against a methane explosion, such as the one that led to the Pike River disaster, a literature survey covering the causes of the incident and what preventative measures should have been in place was conducted. Many different methane explosion prevention methods were evaluated, as well as codes of practice. Based on the findings, Arnot?s measures to prevent conditions favourable for a methane explosion were evaluated.

Jan 1, 2014

By C. R. Speers, M. I. Forsyth

The paper describes how stress analyses were used to show the defect of a tunnel's shape on the overstressing potential of its periphery. The best profile was found to be that of a horizontal ellipse, for which there was little significant scaling, permitting temporary support to be incorporated into a permanent tunnel support system. This investigation was followed by the modeling of several support systems for tunnels with a horizontal-ellipse profile, which showed that such a profile can reduce the installed support required for a tunnel of different cross section by an average of 57 per cent.

Jan 1, 1994

O.F.S. Branch Minutes of the Committee Meeting held in the Committee Room at the St. Helena Club at 4.45 p.m. on Wednesday, 3rd September, 1975. Book reviews JONES, M. J. (ed.). Minerals and the environment. London, Institution of Mining and Metallurgy, 1975. Mining Companies of the world.. 1974/75. London, Mining Journal Books Ltd (15 Wilson Street), 1975. £12. 303 pp. NIM reports Report no. 483 Summary of the mineralogical investigation of pegmatites. (11th April, 1969; re-issued October 1975). Report no. 1697 A petrographic and mineralogical investigation of silica samples from the farm Elandskraal 470JQ, Rustenburg district. (24th Jan., 1975; reissued October 1975). Report no. 1761 The determination, by atomicabsorption spectrophotometry, of minor elements in anode sludges and residues. Report no. 1762 The determination, by instrumental neutron-activation analysis, of some elements in the NI M ROC standard reference materials. Report no. 1770 The spectrophotometric determination of vanadium in chromiumbearing materials. Foundry conference An international foundry confcrence, spomored and organized by South African Institute of Foundrymen, will be held in Johannesburg from 23rd to 27th February, 1976. The themes for each day are follows: Coordination chemistry A symposium on coordination chemistry in extractive metallurgy is to be held in Kelvin House, Johannesburg, on 18th and 19th March, 1976. Practical jet cutting The third international symposium on jet-cutting technology to be organized by BHRA Fluid Engineering will be held in Chicago from 11th to 13th May, 1976, in conjunction with the lIT Rese:uch Institute of Chicago. Hydraulic transport The fourth international conference on the hydraulic transport of solids in pipes (Hydrotransport 4) is being organized by BHRA Fluid Engineering.

Jan 12, 1975

By A. V. Z. Brink

Rock engineering risk is defined in this paper as a function of the potential ground motion; the vulnerability of the workplace; exposure of people; and a general term – quality of information. The paper describes the development of prototype software that is a combination between an expert system approach for determining overall risk assessment, a risk control recommendation and a basic GIS (Graphic Information System) approach for graphically overlying input parameters and the output risk. The expert system uses a Bayesian probabilistic approach to combine various workplace-related information, a quantified seismological environment and the exposure of underground staff to provide an overall RE risk rating. The risk assessment is dynamic in that it is recalculated each time that any of the input parameters change, for example each time a seismic event is recorded in the area of interest. The code was tested on a data set from Savuka Gold. As risk assessment is not an absolute prediction of a specific outcome, it is therefore not possible to relate to individual case studies and the reliability of this method would only be determined after an extensive period of use with appropiate back-analysis. Le risque dans le génie minier est défini dans cette étude comme une fonction du mouvement potentiel de terrain ; la vulnérabilité du lieu de travail ; l’exposition des personnes ; et un terme général – la qualité de l’information. L’étude présente décrit le développement d’un logiciel prototype qui est une combinaison entre une démarche de système expert pour déterminer une évaluation générale du risque, une recommandation pour le contrôle du risque, et une démarche de SIG (Système d’Information Géographique) pour superposer graphiquement les paramètres d’entrée et le risque de sortie. Le système expert utilise une méthode de probabilité bayésienne pour combiner des informations variées sur le lieu de travail, des données quantifiées sur l’environnement sismique, et l’exposition du personnel travaillant sous terre, pour finalement produire un classement général de risque minier (RE). L’évaluation du risque est dynamique en ce sens qu’elle est recalculée à chaque fois qu’un des paramètres d’entrée change, par exemple à chaque fois qu’un évènement sismique est enregistré dans la région. Le code fut testé sur un ensemble de données obtenues de Savuka Gold. Comme l’évaluation du risque ne constitue pas une prédiction absolue d’un résultat spécifique, elle est par conséquent difficile à rattacher à des cas individuels et la validité de cette méthode ne pourrait être déterminée qu’après une longue période d’utilisation avec analyse rétrospective appropriée. Das Gesteinstechnikrisiko wird in dieser Arbeit als Funktion einer möglichen Bodenbewegung definiert; die Anfaälligkeit des Arbeitsplatzes; das Ausgesetztsein der Belegschaft; und ein genreller Begriff - Qualität der Informationen. Das Papier beschreibt die Entwicklung einer Prototyp-Software, die eine Kombination zwischen einem Expertensystemzugang für die Bestimmung der gesamten Risikobeurteilung ist, eine Empfehlung zur Risikokontrolle und eines fundamentalen GIS (graphisches Informationssystem) Zuganges für graphisch darüberliegende Eingangsparameter und das Outputrisiko. Das Expertensystem verwendet eine bayesische Wahrscheinlichkeitsannäherung, um verschiedene mit dem Arbeitsplatz in Verbindung stehende Informationen, ein quantitativ bestimmtes seismologisches Umfeld und das Ausgesetztsein des Untertag-Personals zu kombinieren, um eine gesamte RE-Risikobewertung zur Verfügung zu stellen. Die Risikobeurteilung ist insoferne dynamisch,daß sie stets nachkalkuliert wird wenn sich irgendeiner der Eingangsparameter ändert, z.B. jedesmal wenn ein seismischer Fall im Interessensbereich aufgezeichnet wird. Der Code wurde auf einem Datenbestand von Savuka Gold geprüft. Da die Risikobeurteilung nicht eine absolute Vorhersage eines spezifischen Resultates ist, es ist folglich nicht möglich, sich auf einzelne Fallstudien zu beziehen und die Zuverlässigkeit dieser Methode könnte nur nach einer umfangreichen Benutzungsdauer mit geeigneter Postanalyse bestimmt werden.

Jan 1, 2003

By R. Minango

Solvent extraction of Cu from acidic leach, using an oxime extractant, e.g. LIX 984 or Acorga is a well-known and establishedprocess. As the process advances, Cu is extracted to the solvent and is replaced by H+in the aqueous phase. At high acidity the distribution coefficient of Cu between the solvent and the aqueous phase decreases, and eventually a relatively high concentration of Cu remains in the raffinate, regardless of the number of equilibrium stages. In many processes this phenomenon is immaterial, as the raffinate returns to the leaching and no copper is lost. But when the copper raffinate is used for processing of additional metals, minimal concentration of Cu in the raffinate is essential for an effective process. The recommended process includes three steps: SX-1?standard extraction of Cu with oxime. The resulting raffinate contains about 6?8 g/lCu and 50 g/lH2SO4. SX-N?Extraction of most of the acid into an amine-based solvent, and stripping it with a base, e.g. aqueous ammonia, caustic, Na2CO3etc. The extraction removes no metals, but decreases the concentration of acid from 50 to10 g/l. SX-2?Extraction of the neutralized solution once more with oxime, to remove the residual copper. Such a process enables one to get down to 100?150 ppm Cu in the final raffinate. This process was developed and tested in the R&D facility at Chambishi Metals plc, by a joint team of Chambishi & Bateman, using Cognis LIX 984N and real solutions from the plant. In the laboratory the equilibrium isotherms for SX-1, SX-2 and the neutralization were developed. Computer simulation of the results showed that the optimal configuration is two stages for both extraction and stripping for SX-1. For SX2, 2?3 stages of extraction and two stages of stripping are needed. The stripping stages may be common to both SX-1 and SX-2. The neutralization of SX1 raffinate was tested both by conventional precipitation with lime and by extraction with alamine-based solvent extraction and stripping with a solution of 10% NaOH. For the SX-N only one stage was needed for both the extraction and stripping. The bench scale pilot plant was run for both SX-1 and SX-2. The results were very similar to the simulated ones, and the configuration of 2E2S for SX-1 and 3E2S for SX 2 delivered the required raffinate with less than 150 ppm Cu.

Jan 1, 2005