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By A. A. Snodgaass

This paper reviews lead as a commodity, starting with a brief historical outline and dealing with the various uses of lead in some detail. It then goes on to discuss some statistics in relation to the production and reserves of lead, before sketching its mode of occurence. The topics are approached in regard both to the world and to South Africa, with the emphasis on the later. The mining and concentration of lead at Black Mountain Mine at Aggeneys in the north-western Cape Province are detailed, before a general account is given of the smelting, hydrometalurgical extraction, and refining of lead, together with the processes used in these activities. The paper concludes with a discussion of safety and health in regard to lead and a brief look at the commodity's future.

Jan 1, 1986

By L. K. Smith

The position of Australia as a continuing long-term supplier of mineral sands, and their upgraded products, has been reinforced with the discovery of the extensive mineral reserves in the Murray Basin, an area covering parts of South Australia, New South Wales and Victoria. A major impurity in the Murray Basin is chromium, mainly present in ilmenite concentrates as individual chrome spinel grains. Magnetizing roast treatments are being evaluated as a means of removing the chrome spinel impurity from the ilmenite and as a result of the roast and magnetic separation treatments, the chrome spinels can be expected to be concentrated in the non-magnetic reject fractions. It is from these fractions that attempts were made in this study to recover a chromium-rich product by magnetic fractionation and by application of flotation. The high gauss non-magnetic rejects from the roasting of a primary and a secondary ilmenite fraction were magnetically fractionated to obtain a product with 40.5 and 28.7 per cent Cr2O3,respectively. From the high gauss non-magnetic reject from the roasting of a primary ilmenite, flotation produced a chromium-rich product assaying 29.5 wt per cent Cr2O3at 69.0 per cent recovery. In another test a magnetic fraction assaying 32.9 wt per cent Cr2O3was floated to yield a chromium-rich product with 39.7 wt per cent Cr2O3at 96.4 per cent recovery. X-ray diffraction patterns of all the products indicated that the spinel concentrated was a ferroan magnesiochromite with rutile, ilmenite and hematite as impurities. Since all products were from a single pass, further processing can be expected to remove the impurity minerals and yield higher grade products. The material produced from the Murray Basin ilmenites in this study had similar compositions to commercial chromite ores, except for titania levels that were much higher. The high titania levels were due to residual rutile in the products, but it is expected that this can be removed with further processing. The mineral sand deposits in the Murray Basin are scattered over a wide area and the amount of chromite that may be produced from each of these deposits is unlikely to be sufficient to support an export market. Consequently, any chromite produced in the Murray Basin will most likely need to be processed locally to value added products for a niche market such as chemicals production. Keywords: Murray Basin, ilmenite, chrome spinel, roasting, magnetic separation, chromite ore

Jan 1, 2003

By J. L. Taylor, E. B. Viljoen, W. M. Craig, A. M. McIntosh

The Chemwes uranium plant treats old gold-plant residues from the Sttifontein and Buffelsfontein Gold Mines by acid leaching, belt filtration, countercurrent ion exchange (ClX), and Bufflex solvent extraction (SX). The uranium is recovered by precipitation as ammonium diuranate. Absorption and elution in the CIX section are achieved in four NIMCIX columns operating as two parallel streams. Each loading column is 4,85 m in diameter and contains 12 absorption stages. The elution columns are 3 m in diameter and contain 8 stages. The eluant used is 10 per cent sulphuric acid at ambient temperature. During the commissioning and initial operating periods reported here, the plant yielded an average barren solution of 1,6 p.p.m. of U3O8 from a feed with a mean U3O8 concentration of 132 p.p.m. The U3O8 concentrations in the barren solution were better than 2 p.p.m. some 85 per cent of the time, and better than I p.p.m.73 per cent of the time. Investigations are underway to institute an automatic control system that will result in the U3O8 values on the resin and in the barren solution being maintained at or near the target values in spite of changes in the concentration of uranium in the feed solution.

Jan 1, 1982

1. Mintek reports The folowing reports are available from Mintek, Private Bag X3015, Randburg, 2125 South Africa. They are available at R25 (plus R3,25 GST) per copy to South African addressees, and US$25 per copy (including airmail postage) to addressees elsewhere. Report M91D A mineralogical investigation of samples from the Renosterkop tin prospect near Upington, by M.J. Southwood. First issued Jul. 1983, reissued May 1989. 16 pp. Report M256D The upgrading of Mamatwan manganese ores heavy-medium separation, by P. W. Overbeek. First issued Apr. 1986, reissued May 1989. Report M299D A mineralogical investigation of samples from the Eenzaamheid cobalt-molybdenum deposit, by C.D. de Nooy. First issued Jan. 1987; reissued May 1989. Report M301D The evaluation of manganese metal powder by automatic image analysis, by E.J. Oosthuyzen. First issued Feb. 1987, reissued May 1989. 13 pp. Report M311D Mineralogical and beneficiation studies of ore from Lutzputz, by R.N. Guest and C.T. Logan. First issued Mar. 1987, reissued May 1989. 13 pp. Report M314D The beneficiation of a sample of magnesium ca/crete, by L. Jonker. First issued Apr. 1987, reissued May 1989. 13pp. Report M369 The determination, by flow-injection analysis, of thiocyanate, by E.A. Jones and M-J. Hennings. Jun. 1989. 7pp. Report M389 A spectrophotometric method for the determination of zinc by flow-injection analysis, by D.E. Barnes and RA. Jones. Jul. 1989. 15 pp.2. Recent publications Pumps-principles and practice. Available from K. Myles & Associates CC, P .0. Box 2212, Northclif 2115. :200pp. R99 including GST. Standard handbook of hazardous waste treatment and disposal, edited by H.M. Freeman. Bergano Book Co., P .0. Box 190, Fairfield, CT 06430, USA. 1120 pp. US$130.Quality control handbook, by J. Juran and F. Gryna Jr. Bergano Book Co. (address as above). 4th 00. 1536pp. US$125.Refractories in the manufacture and transport of pig iron. Verlag Schmid GMBH, P.O. Box 6609, 7800 Freiburg, West Germany. DM 100. The user-computer interface in process control, byW.E. Gilmore, D.I. Gertman, and H.S. Blackman. London, Harcourt Brace Jovanovich Ltd, 1989. " 312pp. $29.Aluminum alloys-contemporary research and applications, edited by A.K. Vasudevan and R.D. Doherty. London, Harcourt Brace Jovanovich Ltd, 1989. " 676 pp. " £90.3. TMS publications issued recently The folowing publications are available from The Minerals, Metals & Materials Society, 420 Commonwealth Drive, Warendale, PA 15086, USA (Telephone: (412) 776-9000, Telex: 9103809397, Fax: 4127763770). Advances in magnesium alloys and composites, by H. Paris and W.H. Hunt (eds.). 145 pp. $65. Arsenic metallurgy-fundamentals and applications, by R. Reddy (ed.). 515 pp. $104. Casting of near net shape products, by Y. Sahai (ed.). 7oopp. $155.Continuous casting of non-ferous metals and alloys, by H.D. Merchant, D.E. Tyler, and E.H. Chia (eds.). 360 pp. $90.Dislocations and interfaces in semiconductors, by K. Rajan, D. Ast, and J. Narayan (eds.). 210pp. $75.

Jan 1, 1989

By R. R. M. Cousens, W. S. Garrett

SYNOPSIS The paper gives a background to the water hazards of the so-called West Wits Line and refers to some geological aspects of the Wonderfontein Valley in which the West Driefontein mine property lies. It describes the precautions taken against flooding during shaft sinking, development and stoping; these include cover hole drilling with cementation, provision for water storage in worked-out areas, installation of water tight bulkhead doors and pumping capacity well in excess of the mine's normal requirements. The plan of campaign adopted after the inrush took place is explained and the reorganization and expansion of pumping arrangements are discussed. When it became clear that the only means of saving the mine was to construct plugs to isolate the inrush while still maintaining all emergency pumping measures, the work was put in hand with the utmost dispatch. In considering the design of the plugs a number of major factors had to be taken into account. The most vital was the need for speed which was complicated by difficulty of access to the plug sites because of the huge volumes of water flowing in the drives. How this and other factors affecting plug design and construction, leakage problems, sequence of operations and final closure of the valves, were overcome is detailed in the paper. INTRODUCTION The inrush of water into the West Driefontein mine, the biggest gold producer in the world, which began on 26th October, 1968 and continued unabated for 23 days before the flood was stemmed, was unprecedented in the history of mining. Also unprecedented were the tremendous efforts and organization which made it possible to bring the situation under control and so save the mine from being lost for a matter of years. BACKGROUND Before going into details of how the situation was brought under control it is appropriate to consider the background to the event. The water problem on the so-called West Wits Line has been recognized for many years. As far back as 1912 the Pullinger Shaft, situated in the centre of what is now the Venterspost mine property, had to be abandoned because there were no means then available of coping with the large quantity of water encountered. To appreciate what vast quantities of water were involved, it helps to refer to some geological aspects of the Wonderfontein valley in which the West Driefontein property lies. The narrow tabular Witwatersrand gold-bearing beds, which dip at about 25 degrees towards the south, are overlain by a surface layer of dolomite which reaches a maximum thickness of some 4,000 ft at West Driefontein. A number of vertical syenitic dykes intersect the valley more or less at right angles to its course (Fig. 1). These dykes are about 150 ft thick on average and are spaced at about eight-mile intervals in the West Driefontein area. They penetrate both the dolomite and the Witwatersrand beds and as they are impervious to water they divide the valley into a series of large underground water compartments.

Jan 5, 1969

By K. Esmeli, A. Ozkan

The enhancement of shear flocculation of a galena suspension by ultrasound in the presence of sodium isopropyl xanthate and potassium ethyl xanthate was investigated by studying the effects of surfactant concentration on flocculation efficiency, contact angle, and zeta potential. Strong flocculation was obtained under alkaline conditions (pH > 9) and a high ultrasound power level (150 W). Although the ultrasonic treatment increased the negativity of the zeta potential of the galena particles, this did not decrease the flocculation efficiency, thereby showing that the hydrophobic interactions between the particle were stronger than the electrical double-layer repulsion resulting from xanthate adsorption. The findings indicate that the ultrasonic treatment promoted the adsorption of surfactants onto the mineral surfaces.

Jul 5, 2023

By G. du T. Judeel

An investigation was carried out to determine whether a numerical model could be constructed that would produce results that realistically represent actual ground deformations in and around a vertical shaft. The ground deformation was brought about by the partial extraction of the shaft pillar. A special characteristic of the rock masses, affected by the shaft pillar extraction, was that the shaft was located in poor quality rock masses. After the extraction of a portion of the shaft pillar, excessive deformations occurred at the shaft/reef intersection. Therefore, a decision was taken to extract the entire shaft pillar protecting the shaft by a proposed waste-cut across the shaft. The effects of stress and displacement on the shaft were investigated by using inelastic numerical modelling in different stages. A calibrated numerical model was constructed producing modelled results comparable to the actual displacements along the shaft. Des recherches ont été poursuivies pour déterminer si on pouvait construire un modèle numérique qui donnerait des résultats représentant avec réalisme les déformations réelles du terrain à l’intérieur et autour d’un puits vertical. La déformation du terrain était entraînée par l’extraction partielle du massif de protection. Une caractéristique spéciale des masses rocheuses, affectées par l’extraction du massif de protection, était que le puits était situé dans des masses rocheuses de qualité inférieure. Après l’extraction d’une portion du massif de protection, des déformations excessives se sont produites à l’intersection du puits avec le filon. Par conséquent, la décision a été prise d’extraire le massif de protection en entier par une coupe de déblais à travers le puits. Les effets de contraintes et décalage furent étudiés en utilisant une modélisation numérique inélastique à des stages différents. Un modèle numérique calibré fut construit, donnant des résultats modelés comparables aux décalages réels le long du puits. Eine Untersuchung wurde durchgeführt um festzustellen, ob ein numerisches Modell konstruiert werden könnte, das Resultate produzieren würde, welche realistisch aktuelle Bodendeformationen in und um einen vertikale Schacht darstellen. Die Bodendeformation resultierte teilweise aus der Extraktion des Schachtpfeiler. Eine spezielle Eigenschaft der Gesteinsmassen, beeinflußt durch die Schachtpfeilerextraktion, war, daß der Schacht in Gesteinsmassen geringer Qualität situiert war. Nach der Extraktion eines Teils der Schachtpfeiler, traten übermäßige Deformationen am Schacht/Riff Kreuzungspunkt auf. Folglich wurde die Entscheidung getroffen, die gesamten Schachtpfosten zu extrahieren und den Schacht mittels eines geplanten Verlustschnittes quer zum Schacht zu schützen. Die Auswirkungen des Druckes und der Versetzung auf den Schacht wurden unter Anwendung unelastischer numerischer Modelle in unterschiedlichen Stadien untersucht. Ein kalibriertes numerisches Modell wurde konstruiert, welches berechenete Ergebnisse mit den tatsächlichen Versetzungen entlang des Schachtes vergleicht.

Jan 1, 2003

By S. Schmachtel

Several possible physico-chemical properties of composite electrodes for oxygen evolution are presented to describe experimental data for which a mathematical model had been developed. On this basis, local electrical and electrochemical properties of a composite electrode were investigated with conductive atomic force microscopy (CAFM) and scanning electrochemical microscopy (SECM). It could be shown by CAFM measurement that the boundary between matrix and catalyst particles seemed to have special advantageous electrical properties. The SECM measurements showed the presence of mass transport phenomena with increased surface concentrations, whilst the thickness of the Nernst diffusion layer was very small. An intermediate was detected and assigned to be hydrogen peroxide. From all species involved in the oxygen evolution reaction (H2O2, H+ and O2), it was concluded that local active spots exist on the electrode on which hydrogen peroxide reacts to oxygen and protons. A two?step two-material process was suggested to explain the whole oxygen evolution mechanism.

Jan 1, 2008

By J. Nell

Heavy mineral deposits often contain relatively high levels of radioactive elements (thorium and uranium in particular).It is difficult to obtain clean separation of ilmenite and monazite (the main impurity mineral containing radioactive elements), and physical intergrowths of the two minerals are, in fact, not uncommon. As a result, ilmenite concentrates obtained from such deposits often contain high levels of thorium and uranium. Because of the large negative free energies of formation of ThO2and U3O8boththorium and uranium report to the slag during smelting and if an ilmenite concentrate contaminated with monazite is used to make high titania slag, the concentrations of these elements in the slag end up about 40% higher than in the ilmenite feed. Previous work, patented by RGC Mineral Sands Limited, and subsequently confirmed by Mintek, showed that radioactivity may be reduced by roasting an ilmenite concentrate with borax at 1000°C to 1100°C and leaching it with hydrochloric acid1. It is evident that the cost of an ilmenite roast/leach process will be high and there may be economic benefits in removing the radioactive elements from the slag instead (the volume of slag to be treated is smaller than the volume of ilmenite feed). To remove radioactive elements from the slag it is necessary to know how these elements occur in the slag. Inother words, the distribution of uranium and thorium between the various oxide, silicate and metallic phases in high titania slag must be determined. Once the deportment of thorium and uranium between the various phases ha sbeen determined, an appropriate process for slag purification can be developed. Test samples High-titania slag was prepared in a pilot-scale DC furnace from ilmenite concentrates with different levels of uranium and thorium. Subsequently, ten slag samples representing a range of compositions were selected for bulk chemical analysis, scanning electron microscopy and micro-analysis. The samples were crushed to a maximum particle size of 1 mm and from each sample a 20-kg batch was riffled out for analysis. Bulk chemical composition Chemical compositions of the samples selected for test work are given in Table I. TiO2, Al2O3, SiO2, MgO, MnO, FeO and V2O5were analysed by ICP-OES, Na2O, CaO andCr2O3by atomic absorption spectroscopy and U and Th by XRF (the XRF detection limit for U and Th was around 4 ppm). The ?B? series has a higher silica content than the others as a result of small silica additions that were made during smelting. All samples have elevated alumina levels as a result of furnace refractory contamination during smelting. As expected, there is an inverse relationship between the concentrations of TiO2and FeO in the samples (Figure 1).The TiO2and FeO levels are similar to the levels found in industrial slags2. Extreme conditions of reduction under which reduction of more ?refractory? oxides (e.g., chromia, magnesia, silica, alumina and even urania and thoria) might take place were not explored in the study. Note that BB1and BBB1 contain more than 7% combined silica and alumina (SiO2as a flux addition during smelting, and Al2O3from refractory contamination) and they do not fall on the general trend defined by the other samples. The U and Th concentrations of sample E2 is noteworthy. In the preparation of slag E2, monazite concentrate was added to the ilmenite to increase the concentrations of radioactive elements in the slag. This was done primarily to facilitate the detection of Th and U during the phase chemical characterization of the slag. Radioactivity measurements Gamma ray emissions from the samples were measured [ ]

Jan 1, 2007

By M. Steyn

This article captures the intrinsic differences of thermal coal products, their utilization and their substitution characteristics. South Africa produces approximately 245 million tonnes of coal annually. Eskom consumes 46% (approximately 112 million tonnes), 26% (approximately 65 million tonnes) is exported, and SASOL Synthetic Fuels consumes 18% (approximately 44 million tonnes) and a further 9% (approximately 22 million tonnes) is consumed by domestic users in various different industries. Marketing theory contributes significantly to understanding the importance of technical product and quality appreciation and comprehension, encompassing elements of price, distribution, and promotion. Coal product specification is determined by the inherent geology of a resource and the number of complex actions to market the product to a specific consuming market. Sampling, analyses, beneficiation application, and an array of parameters contribute to matching thermal coal products to the value-in-use it provides to the different markets and its consuming industries. Coal producer shave come under increased scrutiny since South Africa has been experiencing electricity shortages since early 2008. General misunderstandings were declared on public forums and in the media by both legislators and the South African public since a perception developed that South African coal producers are exporting coal that could be utilized by Eskom.

Jan 1, 2010

By A. V. Wilke

The metallurgical balance is a tool usually applied in the mining industry. The final result is used for different objectives. All the existing software for the calculation of the metallurgical balance fits the numbers in such way that a logical correspondence between the input and output materials exist. Nevertheless, the accuracy of the metallurgical balance strongly depends on the quality of the input data. Division El Teniente of Codelco Chile has been optimizing the metallurgical balance system the last 14 years. As well, it has participated in the development of corporate norms to optimize the operations of sampling and weighting systems. As a consequence, the precision and the accuracy of the metallurgical balance have been improved in a significant way. Also the understanding of process variability was enhanced. The improvements have allowed Codelco to discover and minimize hidden losses and to better support top management decisions. The present paper describes the main aspect of the continuous improvement process.

Jan 1, 2009

By S. Lubbe

South Africa and Australia are the biggest suppliers of zircon sand to the international zirconium industry. However neither South Africa nor Australia is well known for zircon beneficiation. Geratech Zirconium Beneficiation Ltd (GZB) continued with additional research on sodium hydroxide (NaOH) cracking of zircon sand during 2002-2003. In 2003 GZB started extracting zirconium from zircon sand by means of NaOH cracking on a commercial scale. Experience has shown that temperature profile and atmospheric control inside the furnace is crucial for the beneficiation of zircon sand. Silica carryover to zirconium chemicals could result if a high temperature is used. Once the sodium silicate is extracted from the sodium zirconate and dissolved in hydrochloric acid, two distinct routes can be followed to precipitate various zirconium chemicals. The most common route is to precipitate zirconium oxychloride crystals (ZOC), with subsequent purification from all contaminants (crystal route). Less known is the process (liquid route) that involves the direct precipitation of zirconium basic sulphate (ZBS). This route will yield a less pure product, with contaminants such as silica and titanium. An important factor in this route is the prevention of silica gel formation, which could hamper final product filtration. For applications like paint drying (zirconium octoate) or antiperspirants (zirconium hydroxychloride) low levels of contaminants have no effect on the final product. The advantage of the liquid route is fewer production stages compared to the crystal route. The disadvantage of the liquid route is that the market for the products will be significantly smaller. The optimum solution could be a plant design that could cater for both routes. Another example of an application of zirconium chemicals is the use of ammonium zirconium carbonate (AZC) in the paper industry. Zirconium basic carbonate (ZBC) is dissolved in ammonium carbonate to produce AZC solution. AZC is used mainly in European countries in the paper industry. For example, carton boxes were initially produced with formaldehyde as the binder, however, it has now been replaced with AZC since formaldehyde is considered toxic. AZC reacts with the cellulose fibres in the paper to act as the binder. The resulting product is not toxic, and printing ink dries very quickly due to the porous paper structure. Other applications of zirconium chemicals involve the use of acid zirconium sulphate tetrahydrate (AZST), zirconium orthosulphate (ZOS), potassium zirconium carbonate (KZC), and zirconium hydrous oxide (ZHO). Fluoride-based zirconium chemicals like zirconium tetra-fluoride (ZrF4) and hexafluoro-zirconic acid (H2ZrF6) are used in the aluminium industry. Zirconium oxide (Zr02) can be produced from any of the abovementioned precipitated chemicals via a high-temperature decomposition process. The physical properties of such oxides can differ tremendously, depending on the final application. The fired density of sanitaryware is typically 5.8 g/cm3, compared to milling media at >6.1 g/cm3. The required fired density is achieved by controlling the precipitation and decomposition conditions for these two oxides. The same applies to stabilized and mixed oxides, for example where zirconium oxide acts as an oxygen carrier in fuel cells.

Jan 1, 2012

By D. A. Viljoen

While coal can be used as a chemical feedstock instead of oil for the production of the petrochemical based commodities that are so important to our modern way of life, the impact that coal is going to make on the world-energy scene is without doubt its more important role in the short- to medium-term. After inflation, energy is probably today's most talked-about and controversial economic issue. It is a plentiful supply of energy that has permitted each of us to live a life of convenience that is matched only by the most fortunate of the aristocracy in history.

Jan 1, 1979

By R. J. Fruehan

Slags have many useful functions in iron and steel making. In particular, slags are used to remove impurities such as sulphur, phosphorus and inclusions from the metal, and a large amount of research has been done in this area. Slags also insulate the metal thermally and form reactions with the atmosphere such as reoxidation and nitrogen pick-up. However, slags serve other more unique functions, several of which are reviewed in this paper. The role of slags in new iron smelting processes with regards to reduction of ore and gaseous desulphurization are discussed. In iron smelting processes, much of the reduction occurs by the reaction of carbon in the char and the metal suspended in the slag with iron oxide dissolved in slags. The slags also react with the gas resulting in sulphur removal from the process. The mechanisms of these reactions and pilot plant data for these processes are given in this paper. Slag formation within ferrous burden materials affects the cohesive zone and the performance of the blast furnace. Recent theoretical and experimental findings on this topic are presented. In the electric arc furnace, foamed slags are used to allow for higher power operation and productivity. Of particular interest, foaming in stainless steel production is more difficult than for normal steels. The foam index, or the ability of the slag to foam, for stainless steelmaking is similar to that for carbon steelmaking slags. The poor foaming is due to the lack of gas generation for the foam. Methods to increase foaming in stainless steelmaking are discussed.

Jan 1, 2004

By J. van der Walt, A. Whillier

Gravity-fed water systems in mines by A. WHILLlER, Pr. Eng., Se. D. (M.I.T.) (Fellow) and J. VAN DER WALT, Pr. Eng., B.A. Hons. (Bus. Admin.), Ph.D. (Eng.) (Visitor) South African mines often experience significant losses in production because of recurring shortages of water at work places as the result of underground dams running dry. Similar shortages have occurred during fire-fighting operations, and now, with the use of cold service water to aid in the cooling of mines, it is even more necessary that such shortages should be prevented. This paper draws attention to the primary cause of such water shortages, and an outline is given of some of the fundamental hydraulic principles that must be followed in the design of gravity-fed water-supply systems on mines.

Jan 4, 1977

By R. O. Heckroodt

After a brief review of the characteristics of clay minerals and their origin, a summary is given of the industrial uses of different types of clay materials. The mining and beneficiation of clays are discussed, with special reference to the upgrading of certain types of materials. The occurrence and resources of the more important varieties of clays are dealt with in some detail, viz residual kaolin derived from granite and sediments, brickmaking clays, refractory clays, bentonite, and palygorskite. The Republic of South Africa is well endowed with a wide spectrum of clay materials, with one important exception. Kaolin suitable for paper coating is not known to occur in the Republic, and efforts to beneficiate and treat local materials to achieve the desired properties have so far been unsuccessful.

Jan 1, 1991

By M. D. G. Salamon

If a transition from one equilibrium state to another occurs during the course of mining, energy transfer takes place in the rock mass, which is assumed to be an elastic continuum. The energy components are defined as follows: the work done by external and body forces, W; the increase in stored energy in the mass, Uc; the strain energy in the rock mined during the transition, Urn; the work done on mine support or backfill, Ws; and the released energy, Wr. The energy balance is defined as (W + Urn) - (Uc + Ws) = Wr> 0, where the first set of components in parentheses represents the sources of energy, while that of the second corresponds to the known modes of energy expenditure and the component on the right is the unaccounted-for energy surplus, which must be released and dissipated in some form. The inequality Wr ~ Urn> 0 applies. Expressions for the energy components are derived first for the general case and then for the 'slit' modal used to simulate tabular excavations. Through specific examples, the importance of the progressive nature of mining is emphasized. The size of the steps used to enlarge the excavations appears to play a significant role in the mode of energy transfer. This observation forms the basis of the second paper in this series of two papers.

Jan 1, 1984

By RT White

For a number of years the steel tube and pipe industry has worked on resolving problems of product quality. These have largely been resolved and new products have been developed to take advantage of new developments. To fully coordinate market acceptance guidance on use of galvanized piping was also required. This was largely achieved locally in 2004 with the publication by the SABS of ARP 060 - Guidance on the use and application of hot dip galvanized steel piping for the transportation of potable water in South Africa. Use of this document is not easy however and a need to have a simple computer model to assist the specifier was identified. Working with a major tube and pipe manufacturer this is now being developed and this paper will provide the background to the model?s development and its intended use. There is still a need for a partner Code of Practice on the performance of galvanized piping in buried conditions and the need for this will be highlighted together with current available information.

Jan 1, 2006

By W. J. Kotzé

Die derde colloquium van die Spesialiste-afdeling van die SAIMM is op 19 November 1980by die Universiteit van Pretoria gehou en is deur sowat 40 mense bygewoon. Dr J. P. Hugo tree as Voorsitter op en heet al die aanwesiges welkom, en stel elke spreker om die beurt aan die vergadering voor.

Jan 1, 1981

By Franz E. Pawlek

Synopsis This is a summary of investigations in the field of pressure leaching carried out at the Institute for Extractive Metallurgy of the Technical University of Berlin-West during the last seven years. The efficient dispersion of gas in a liquid and its dissolutions as well as the events at the phase boundary when leaching ZnS are reported. At the end two examples are given for the use of pressure leaching in the processing of smelter by-products. INTRODUCTION About 20 years ago, experiments were independently started in Canada and in Berlin on the subject of dissolving sulfidic ores without preliminary treatment by means of leaching under increased oxygen pressure. In Canada ammoniacal solutions were mainly employed, and F. A. Forward and his co-workers were successful in applying this process on a large industrial scale1, 2. This process is used in Fort Saskatchewan to produce about 15,000 tons of Ni per year. In Berlin, investigations were started on leaching with acid solutions3, 4. This process had also been used on a large industrial scale in the D.S.A., but the choice of unfavourable working conditions led to great difficulties, and to giving up this process for industrial use. Later on in Berlin work was carried out especially on the kinetics of pressure leaching 5, 6, 7, 8, 9 and its applications to the processing of smelter by-products, in particular of mattes and speisses10, 11, 12, 13, 14. The dissolution of ores and by-products can be subdivided into four steps: 1. the efficient dispersion of the gas, so that its dissolution occurs over as great a surface area as possible, since only the dissolved oxygen reacts with the solid, 2. the suspension of the solid, so that the entire surface can take part in the reaction, 3. the phase boundary reaction, 4. the removal of the reaction products. The first two steps belong to the field of process engineering and will be discussed from this point of view. The aim of these experiments15 was to find out first of all the limits of efficiency of self-sucking stirrers in solutions of low viscosity with regard to the mass transfer. In addition, the effect of ultrasonics in the same reaction system was studied. The experiments were carried out in a lucite container as shown in Fig. 1. Four baffles of 0.1 d width were in the stirring vessel. The height of these baffles was adjustable. For every experiment one litre of liquid was used. An infinitely variable direct current motor, which was fixed with a hollow shaft, served as the driving power for the stirrer.