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By D. Bessinger

The present paper provides a brief overview of the thermodynamics of titania rich slags, an outline of the Multi-Phase Equilibrium (MPE) package and its application to ilmenite smelting. Through assessment of published experimental data on various systems containing TiOx, it was found that despite considerable scatter in measured phase equilibria data for the binary Ti2O3-TiO2system,the behaviour of binary and higher order titania rich slags and oxide solid solutions phases could be represented by solution models in the MPE package. Results from the applications of the MPE model on the stability of solid phases and slag-refractory interactions will be presented and discussed. Parallels will be drawn between the predictions by the model and observations made during pilot plant tests. Key words: Thermodynamics, titania slags, ilmenite smelting, phase equilibria, refractory.

Jan 1, 2003

By Donald Sir Tebbit

To have been invited to deliver this second CMMI lecture is an honour that I deeply appreciate. But, when I contrast my qualifications for delivering it, with those of Sir Alistair Framet, who delivered the inaugural lecturet in the series, or with those of other members of the Council, I feel rather an imposter. Far from having been a miner al my life, I have been associated with the mining industry on a part-time basis for a mere eight years. However, I encourage myself with two recollections. The first is the admission of the great Sherlock Holmes that he was often guided to the truth by the erroneous opinions expressed to him by Dr Watson. I may be able to perform a similar service for you. Secondly, I recall that, when I was a member of the Diplomatic Service, I was quite often asked to address representative gatherings of such professional people as the police, architects, dress designers, teachers, doctors, funeral directors, bird fanciers, and so on. Since it would have been pointless to pretend that I was expert in any of their businesses, I used to resort to the technique of announcing as my theme' A diplomat looks at the police' or whatever profession it was. They fortunately took it as a compliment that their profession was apparently one that diplomats spent a lot of time brooding over. They could also afford to laugh of any criticism that I might make because it could be ascribed to ignorance rather than informed malice. I hope that you will do the same.

Jan 1, 1988

When a mine decides to construct surface structures close to, or on undermined ground, it is required in terms of the regulations of the Mine Health and Safety Act to obtain permission from the Department of Minerals and Energy (DME). Apart from the legal requirements, the stability of the structures is crucial as damage to the structures due to surface movements could result in loss in life, equipment and/or production. This paper deals with the rock engineering aspects of a study that was conducted on one of the chrome mines in the Bushveld Complex (BC) involving the construction of plant structures on shallow undermined ground. The paper addresses the legal requirements and guidelines regarding ground stability of surface structures placed on undermined ground and the assessment of the undermined area with regard to the following: ?sources of potentially damaging surface movements ?safe mining spans ?stability of the pillars ?effect of the loading of plant structures on underground stability. Due to the irregular layout and geometry of the pillars in conjunction with a changing surface topography, numerical analysis and not the conventional tributary area theory was used to determine the imposed loads on the pillars. In order to subject the plant structures to minimum movement, the plant should be located in areas where the pillars would remain stable, the elastic deformation of the hanging wall is minimized and hanging wall failure extending to surface is unlikely to occur. The study indicates that although the depth of undermining is shallow (between 27 m and 60 m), potential damaging surface movements are not anticipated due to the stability of the pillars, competent nature of the overlying strata and negligible effect of the plant structure loading on the underground stability.

Jan 1, 2004

By P. Gonzalez, C. Ariyo, L. Holappa

Oxidation state of titanium was determined in CaO-SiO2-TiOxslags in the composition range25–53 per cent CaO, 27–46 per cent SiO2, 10–55 per cent TiOxat 1873K using gas equilibration method. In the experiments, slags with different titanium oxide contents were equilibrated with a known carbon monoxide and carbon dioxide ratio. The results were used to determine the Ti3+and Ti4+contents as well as the activity coefficient ratio of corresponding oxides in the slag. The dependency of the activity coefficient ratio as a function of oxygen partial pressure was determined. Keywords: titanium, titanium oxide, activity, activity coefficient, slag iron, carbon monoxide,carbon doixide, gas, equilibrium.

Jan 1, 2004

By H. M. Friede

A short survey is given of the Iron Age smelting sites and smelting furnaces that have been found in South Africa. An attempt is made to classify South African smelting furnaces by the inclusion of functional characteristics such as the numbers and positions of tuyeres. An affinity is suggested between the Venda (eastern Transvaal) type of furnace and an East African type. The principles of the smelting process in South African Iron Age furnaces and the characteristics of the smelting products are discussed. Results of metallographic and chemical analyses of 19 iron specimens found at South African sites are given and compared with those from sites in Zimbabwe-Rhodesia, Mocambique, and Nigeria. The carburization and steeling of iron during primitive smelting and forging are discussed.

Jan 1, 1979

By N. T. Halgreen

The use of coal for combustion, carbonization, and the production of synthetic fuel is discussed briefly, highlighting the effect of certain physical and chemical properties of coal on these processes. The effect of consumer specifications of properties such as calorific value, ash content, moisture content, and size consist on the planning and operation of a mine are discussed, including the influence of coal degradation through time or mechanical means. The effects of various mining methods on these parameters and on the utilization of coal reserves are discussed.

Jan 1, 1984

By P. Kohler, T. D. Sampson, T. H. Tunley

The Metsep Process for the separation and recovery of zinc, iron, and hydrochloric acid from spent pickle liquors by T. H. TUNLEY, B.Sc. (Ch em. Eng.) (Visitor), P. KOHLER (Visitor), and T. D. SAMPSON, Pr. Eng., B.Sc. (Chem. Eng.), B.Econ. (Visitor) A spray roaster has been installed in the Johannesburg area for the treatment of spent liquors from a variety of small pickling operations. A new process was developed for the processing of the liquor that is contaminated with zinc chloride, and a commercial plant was built incorporating this process. An ionexchange plant separates the zinc from the iron chloride, and a liquid-liquid-extraction plant converts the zinc chloride to zinc sulphate and recovers the hydrochloric acid.

Jan 5, 1976

By A. Koursaris, Y. N. Turan

A series of experiments was caried out in a vacuum-induction furnace to investigate the solubility of nitrogen in stainless steel type 3100S. Melts were made under constant and variable partial pressures of nitrogen so that the absorption of nitrogen from the atmosphere could be examined. Additions of nitrogenized ferochromium were made to give high nitrogen contents in the steel. Nitrogen contents of up to 0,16 wt per cent were obtained under gaseous atmospheres. With additions of nitrogenized ferochromium, nitrogen contents of up to 0,525 wt per cent were obtained. Comparisons of the later value with existing data indicate that the equilibrium concentration of nitrogen was reached for the experimental conditions used.

Jan 1, 1992

By D. G. Krige

Using a very large number of chip-sample values from a mined-out area of the Hartebeestfontein mine and accepting these as equivalent to borehole values (also areas of 1 km by 1 km as equivalent to 'mines'), the authors apply a series of borehole-valuation procedures to these 'mines', Large undeveloped sections of existing mines are also regarded as the equivalent of such 'mines'. These procedures start with the orthodox arithmetic mean and then introduce additional information in the form of the Iog normal frequency distribution model for Sichel's 't' estimator. Knowledge of the average log-variance within mines leads to the tH estimator. The mean grade of the 'family' of mines to which a new mine belongs is then introduced via regression or elementary kriging. Next, further information on the macro spatial structure of the grade is used, together with the grades of adjacent existing mines in ordinary and simple macro-kriging procedures; finally, via the distribution model, the grade is seen as a function of the logs of the grades and their variances. These are introduced as spatial variables, and both are estimated by macro-Iog normal ordinary and simple kriging procedures with grades and variances from adjacent mines'. Comparisons are also made between macro-kriging on lognormal transformed values versus untransformed values. Conclusions are drawn on the relative importance of the various items of additional information used, on the procedures followed, and on the significance of the advantages gained

Jan 1, 1992

By M. Ng

As part of a long-term study of titanium minerals processing being undertaken by the Julius Kruttschnitt Mineral Research Centre, techniques have been developed to measure the resistivity of ilmenite, rutile, zircon and other associated minerals. The techniques have proven reproducible and have allowed the measurement of resistivity under conditions of varying temperature, surface condition and surface moisture adsorption. The measured values can be linked to the separability of the minerals in the dry plant, and hence are useful as a diagnostic test for existing plants when performance deteriorates, or for greenfield sites to investigate potential problems. One of the major problems in electrical separation of titanium minerals is surface coating on the mineral grains. Coatings can make normally conductive minerals such as ilmenite and leucoxene behave much more like non-conductors. Electrical separation of surface contaminated ilmenite from non-conductors then becomes extremely difficult unless the surface contaminant is first removed. The resistivity measurement technique was used to evaluate the effect of surface cleaning on the resistivity of ilmenite and zircon from a Western Australian deposit which will shortly be in production. Ten different attritioning methods were evaluated, ranging from simple rinsing inwater to chemical attritioning in sulphuric acid combined with ultrasonic leaching. A roasting and quenching step was also investigated. As would be expected, the gentler treatments, such as rinsing in water or Calgon, had only amoderate effect on the ilmenite surface coatings. Ilmenite resistivity decreased by about 1 order of magnitude from 5.6 x108?m to between 2.5 and 4.4 x107?m. More intense treatments had a much more pronounced effect. The most effective, reduced ilmenite resistivity to 6.5 x105?m or three orders of magnitude. Zircon was relatively unaffected by any of the attritioning methods, with only a small increase in resistivity observed from 8.0 x1012?m to 2 x1013 ?m. The results show that measurement of mineral resistivity allows the effect of surface treatments to be easily quantified in a way that has benefits for greenfield site development where only small samples are available for testing. The effect of surface moisture has also been investigated using resistivity measurements. Measurements were made on zircon in an environmental chamber in which both humidity and temperature could be closely controlled. Zircon resistivity at 60 deg C decreased from 6 x1011?m at 5% relative humidity to 8 x108?m at 95% humidity. Moisture content and moisture re-adsorption from dry of zircon and number of other minerals were measured using a Mettler moisture analyser. Zircon adsorbed the least amount of surface moisture (0.05–0.09%) but re-adsorbed moisture from dry the fastest, reaching 98% of the original level in 10 minutes. Leucoxene adsorbed the most moisture (0.67%), but was much slower re-adsorbing this moisture from the dry state, reaching only 63% of the original level in 10 minutes. The difference was attributed to the surface characteristics of the grains, the leucoxene being much more porous than the zircon examined. The resistivities and differing rates of moisture adsorption can be used to quantify the effects of changes in atmospheric conditions of the performance of electrical separation in dry plants.

Jan 1, 2003

The First International Symposium on Seismicity in Mines, organized by the South African National Group on Rock Mechanics in collaboration with the South African Institute of Mining and Metallurgy, was held in Randburg (near Johannesburg) from 13th to 17th September, 1982. It was the first attempt to provide an international forum for the consideration of seismic problems specifically affecting mines or associated with mining. Numerical mathematics The South African Society for Numerical Mathematics and the Computer Science Department of the University of Natal are organizing the Ninth Symposium on Numerical Mathematics to be held in Durban from 18th to 20th July, 1983.

Jan 1, 1983

By David J. Haddock

On Wednesday, 6th July, 1988, 28 members of the Johannesburg Branch of The South African Institute of Mining and Metallurgy and their guests assembled at the Rand Refinery Sports Club, which is situated within the Refinery complex, to hear Dr Daniel Polnow, General Manager of the Refinery, give a very interesting lecture on the Rand Refinery Complex and its activities. Accounting for gold The South African Institute of Mining and Metallurgy will be holding a 3- or 4-day school in the third week of May 1989 on the topic 'Accounting for Gold'.

Jan 1, 1988

South Africa?s now a member of this body, tailored on the World Bank, and headquartered in Abidjan-Cote d'Ivoire. As a funding agency for capital projects within 59 member countries of the ADB it is to be expected that there are guidelines to the requirements for funding application and for project management and control.

Jan 1, 1996

By J. A. L. Napier

It has been established that significant time-dependent stope convergence may occur over time periods of hours and days in certain hard-rock gold and platinum mines. The source of this time-dependent behaviour appears to be associated with both pre-existing discontinuities and with mining-induced fractures that form near the stope face. These induced fractures may be associated with blasting processes and may also be formed in response to high stress concentrations in the unmined regions immediately ahead of the stope face. In shallower platinum mining operations, time-dependent behaviour is, however, observed to be much less marked unless some form of specific mining-induced fracturing occurs. One particular case of considerable interest is the time-dependent behaviour that is found to be associated with the formation and deployment of crush pillars. The purpose of the paper is to present a simple limit-equilibrium computational model of this behaviour that is sensitive to both the formation sequence and the size of planned crush pillars in a mine layout. This model provides a useful means to optimize the sizing of crush pillars, and at the same time may be used to identify potentially hazardous circumstances in which pillars may not crush in a stable manner.

Jan 1, 2012

By D. G. Davies

Colloquium on the construction of Slimes dams The following contributions to the discussion at the above Colloquium were received for publication. D. G. DAVIES* This contribution is really a follow up on Mr H. E. Cross's paper on the conversion of a uranium plant to the recovery of zinc (published in the Journal, November 1973). Ecological aspects of slimes-dam construction by H. T. CLAUSEN C. M. VAN STADEN* Published in the Journal, December 1973 I should like to thank Mr Clausen for his paper and to congratulate the Research Laboratories and the Vegetation Unit of the Chamber of Mines on the excellent work they have done in the past, are still doing at present, and, we hope, will continue to do in future, on the testing of various methods for the covering of slimes dams and specifically on the vegetation of dams. The impact of slimes-dam formation on water quality and pollution by R. T. RUDD* C. M. VAN STADEN Published in the Journal, December 1973 I should like to congratulate Mr Rudd on the paper he presented. Congratulations are also due to the Department of Water Affairs for the practical attitude they have taken in implementing the Water Act. Slimes-dam construction in the gold mines of the Anglo American Group by W. T. RUHMER W. R. FLOOK* Published in the Journal, February 1973 Methods for the construction and operation of slimes dams in the gold-mining industry do not appear to have changed much for some considerable number of years.

Jan 3, 1974

By A. Whillier

The decisive action taken by mine managements in recent years has been the main factor in bringing about the present downward trend in mine fires. A better understanding of the fundamental factors that govern the ignition and spread of fires. obtained as a result of investigations into mine fires, has provided useful guidance to production personnel. Similar investigations into fire-fighting techniques have assisted the Rescue Training Service and mines to institute more effective fire-fighting techniques. Some of the more important findings of recent investigations in these areas are outlined.

Jan 1, 1981

It is perhaps somewhat unusual for a contributor to comment on the authors' reply to his critique. However, I should like to return to a specific comment made by the authors. Award to Bob Laburn The Federation of Societies of Professional Engineers (FSPE) is pleased to announce that the 1984 FSPE Award for Services to the Engineering Profession was presented to Dr R. J. (Bob) Laburn at a function held on 14th February, 1984.

Jan 1, 1984

By C. -T. Mutale, A. S. Tuling

Titanium can exist in three different oxidation states. Its oxides are numerous and in presence of iron and oxygen, iron-titanium oxide compounds can also form. Some of the oxides are non-stoichiometric, making the determination of the thermodynamic properties of titanium and its oxides in molten steel and in slag difficult. Therefore, for the assessment of titanium activity in molten steel using the electrochemical measurements of oxygen partial pressure, the identification of oxides in equilibrium with titanium is important. This paper reports on an investigation of solid titanium oxide inclusions, which have been identified by combining different methods of analysis on quenched samples. These samples were taken from a Fe-Ti-melt at 1600°C, quenched in cold water then mounted and polished for optical microscopy. The oxide inclusions were analysed using transmission electron microscopy (TEM) with energy dispersive spectroscopy (EDS). Both single crystal and polycrystalline diffraction patterns were used to identify the oxides by comparing the d spacings with those in the ICDD X-Ray Diffraction (XRD) database. XRD was used to analyse the oxide particles on the top of slow cooled samples. It was found in the TEM study that the similarity of the diffraction patterns of the various phases meant that unique identification was difficult to achieve in some of the diffraction patterns. However, TiO, Ti2O3, Ti3O5, Ti4O7were identified in quenched samples, while TiO2, FeO.TiO2and iron oxides were seen in slow cooled samples. It was also confirmed that the type of oxides is related to titanium content of the samples. Keywords: Titanium, Titanium Oxides, Iron, TEM, XRD, thermodynamic.

Jan 1, 2004

By M. Gholinejad

Applying non-explosive expansion material (NEEM) is one of the safest methods for rock fracturing, especially in a hard rock quarry. An experimental study was conducted to determine the pressure exerted by NEEM in a hole, which is necessary for analysing rock fracturing, particularly in a numerical modelling. Stress distribution was developed in a thick-wall cylinder in order to measure the tangential strain on the external boundary. In the experiments, nine pipes of different materials and varying diameters were selected and then loaded internally with a general type of NEEM. Through electrical strain gauges, the tangential strains were recorded on the external boundary of the pipes. The results obtained from these tests and existing data from previous researchers were utilized for the statistical analysis. A new experimentally-derived formula is proposed for determining the pressure exerted by NEEM by multiple parameter regression with a high correlation coefficient. The proposed model has a nonlinear form with three independent parameters i.e. the hole diameter, the time, and the modulus of elasticity of the material.

Jan 1, 2012

By M. Gholinejad

Applying non-explosive expansion material (NEEM) is one of the safest methods for rock fracturing, especially in a hard rock quarry. An experimental study was conducted to determine the pressure exerted by NEEM in a hole, which is necessary for analysing rock fracturing, particularly in a numerical modelling. Stress distribution was developed in a thick-wall cylinder in order to measure the tangential strain on the external boundary. In the experiments, nine pipes of different materials and varying diameters were selected and then loaded internally with a general type of NEEM. Through electrical strain gauges, the tangential strains were recorded on the external boundary of the pipes. The results obtained from these tests and existing data from previous researchers were utilized for the statistical analysis. A new experimentally-derived formula is proposed for determining the pressure exerted by NEEM by multiple parameter regression with a high correlation coefficient. The proposed model has a nonlinear form with three independent parameters i.e. the hole diameter, the time, and the modulus of elasticity of the material.

Jan 1, 2012