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By A. O. Filmer

A study of the dissolution of gold from a pyrite concentrate and from various calcines is reported. The percentage extraction of gold was found to decrease with increasing sulphur content in the material leached because of the porosity of the materials, and particularly because of the passivation of the anodic dissolution of gold when the gold was In contact with other conducting minerals. This is explained in terms of the current-potential curves for the oxidation of gold and the reduction of dissolved oxygen.

Jan 1, 1982

By H. H. McGregor

Introductory remarks by author When Mr R. C. J. Goode suggested preparation of a paper in the area of manpower utilization in South Africa, I was, while keen to accept his invitation, somewhat hesitant for two reasons. Firstly, I recognized the great difficulty of making a factual contribution, because of the lack of really relevant statistical information available, the fact that much of it is out of date, and the difficulty of researching and co-ordinating it and of evaluating a statistically sound resultant viewpoint. Experience in the actual preparation of this paper has done nothing to change my view in this respect. Secondly, it is obvious that a paper presented to a meeting of this Institute, by a member of it, would be expected to devote considerable attention to the subject in the mining industry. I am not directly employed by the mining industry, although my company has carried out extensive assignments for various sectors of it both in this country and in other parts of the world, since the 1939-45 war. I am more conscious than most of the tremendous technical and managerial skills at the disposal of the industry in this country, and consequently am equally conscious of the hazards of publishing facts and figures which might be taken to indicate any criticism of performance. I am aware that some of the information that I am about to present may indeed generate comment, and possibly even critical comment. I would like to be regarded therefore in presenting this information, as a member of the group, rather than an external critic. Under these circumstances, comment can only be constructive, and this is my earnest hope. The contribution of my paper, if contribution there is, will I hope be in the area of assessing labour productivity in mining, and in secondary industry in such a way that the performance of each against its own past results is comparable. This task has not for the present been to my knowledge attempted, and in advance I wish to take out authors' insurance against legitimate criticism from professional economists and others, by stating that I am well aware of possible short-comings in the arguments. Nevertheless I believe that under the circumstances I have, with the important assistance of several people, been able to take the subject further than has been the case in the past. Finally, I have related productivity in the mining industry and in secondary industry to a target of productivity in the Republic of South Africa. I was fortunate recently in being able to attend a series of lectures by a prominent economist in America. He introduced his subject by calling it 'A broad survey of macro-economics'. Perhaps I might be permitted to describe my paper, in the same idiom, as 'The macro-management of labour'.

Jan 6, 1970

By H. Jeram

The ilmenite, rutile and zircon processes of the mineral separation plant generate tailing streams, which still contain valuable mineral. This is due to a combination of factors, which include separator equipment efficiency, particle size effects and inefficient operating practices (equipment overloading, blockage, etc.). Recent developments by metallurgical equipment suppliers have led to increased mineral separator performance enabling recovery of previously lost valuable mineral. Mineralogical studies were conducted using QEM*SEM and MLA techniques to identify and quantify gangue mineral species and determine mineral association. Laboratory and pilot-scale test work was then conducted to develop suitable process flowsheets for the recovery of ilmenite, rutile and zircon from current and stockpiled tailings.

Jan 1, 2007

By D. D. Howat, J. van der Colf

Slags of the system CaO-MgO-AI2O3-TiO2-SiO2at had been reduced in graphite crucibles for selected time Intervals were fully re-oxidized so that an assessment could be made of the rate and extent to which the titanium oxide had been reduced. The derived kinetic parameters were studied as functions of slag composition and temperature. The extent of reduction after selected Intervals of treatment could be correlated with the physical behaviour of the melt (in terms of viscosity and electrical resistivity).

Jan 1, 1979

By G. B. Lundstrom

SYNOPSIS For some time, Vaal Reefs South has operated blindhole borers successfully as an integral part of the mining cycle of operations. To date, over 13 000 m of mechanized boxholing has been completed, and from time to time impressive performances have been achieved. The paper describes the machines, the modus operandi, and the structure of the boring organization at the Mine, with some of the results recorded. The Mine recently took delivery of two new machines with interesting design features. The introduction and early experiences with these two machines are also described.

Jan 1, 1985

Discussion of the previous paper E. N. H. MOLLOY The first 22-foot-diameter Aerofall mill was installed at Mangula in 1957. This was fitted with cast-iron trunnion'! located to the mill shell with 2-inch-diameter mild-steel bolts. O.F .S. Branch Minutes of the General Meeting held at the Welkom Club on Wednesday, 2nd June, 1976, at 4.00 p.m. Mr G. J. C. Young (Chairman of the O.F.S. Branch) was in the Chair. Also present were:

Jan 9, 1976

By C. A. Hunt

The problem of materials balancing is reviewed with particular reference to the minerals industry. A broad statistical framework is established that, besides extending the classical estimation problem, allows questions concerning the value of sample information to be addressed. The following are examples of such questions: How much money should be spent on sampling? Which streams in a plant should be sampled? What should be sampled? The approach adopted makes use of Bayesian analysis. The discussion includes an illustrative example involving a simple flotation circuit.

Jan 1, 1985

Notices EIGHTH WORLD MINING CONGRESS The Eighth World Mining Congress will be held in Lima, Peru, from 3rd to 8th November, 1974. The theme of the Congress is 'Prognosis of mining development up to the year 2000', with the following subthemes: INF ACON 74 Readers are reminded of the International Ferro-alloys Congress being organized by the National Institute for Metallurgy, in conjunction with the Ferro Alloy Producers' Association of South Africa and the South African Institute of Mining and Metallurgy.

By A. W. de Villiers

This paper explores the behaviour of methane in the goaf during longwall mining, together with some methods for the control of methane emissions into the goaf, the working face, and the ventilation system. Experimental work done at Twistdraai Colliery, Sasol Coal, is referred to, as well as the gas-drainage system being practised at West Cliff Colliery in New South Wales, Australia. Gas drainage is discussed briefly, and certain suggestions are made in regard to coal mining in South Africa.

Jan 1, 1989

By J. W. Klokow, S. L. Mulder

Early removal of the shaft reef is usually considered necessary on deep level South African gold mines to avoid damaging stress build-up associated with traditional shaft-protection pillars. In the case of the relatively shallow Beatrix Gold Mine it was largely motivated by early access to ore and the consequent earlier return on invested capital. A number of options were considered to protect the shaft from possible damaging stress changes and to minimise deformations in the shaft-reef area. Numerical modelling was used to evaluate the options and to quantify as accurately as possible the likely deformations to be accommodated by the shaft steelwork designs. The option chosen was a combination of strategically placed satellite pillars and yield pillars, and backfill. Following the mining of a small inner cut during the shaft sinking process, full-scale mining is progressing away from the shaft. Suitable instrumentation has been installed to monitor deformations associated with the shaft reef removal. Enlever rapidement le filon du puits est en général considéré nécessaire dans les galeries de fond des mines d’or sud-africaines pour éviter l’accumulation nuisible de contraintes associée aux piliers de protection de puits traditionnels. Dans le cas de la mine d’or Beatrix, relativement peu profonde, l’enlèvement était motivé en grande partie par l’accès rapide au minerai et par conséquent un profit plus rapide sur l’investissement. Un certain nombre d’options furent considérées pour protéger le puits contre les changements de contraintes potentiellement nuisibles, et pour minimiser la déformation dans l’aire puits/filon. La modélisation numérique fut utilisée pour évaluer les options et pour quantifier aussi précisément que possible les déformations probables que la conceptualisation du puits devrait prendre en compte. L’option choisie fut une combinaison de piliers satellites placés à des points stratégiques avec des piliers de protection, et terre de remblayage. Pendant le fonçage de puits une petite coupure intérieure fut exploitée, et maintenant l’exploitation à grande échelle, au-delà du puits, est en cours. Les instruments nécessaires ont été installés pour surveiller les déformations associées à l’enlèvement du filon du puits. Die frühe Entfernung des Riffschachtes wird normalerweise bei südafrikanischen Tiefbaugoldmienen als notwendig erachtet um den zerstörende Druckaufbau zu vermeiden, welcher mit traditionellen Schachtschutzpfeilern verbunden ist. Im Fall der verhältnismäßig flachen Beatrix Goldmine war es hauptsächlich vom frühen Zugang zum Erz und dem konsequenten frühen Rückfluß des investierten Kapitals motiviert. Eine Anzahl an Optionen wurde erachtet um den Schacht vor möglichen zerstörenden Druckänderungen zu schützen und Deformationen im Riffschachtbereich zu minimieren. Um die Optionen zu bewerten und mögliche Deformationen so genau wie nur möglich quantitativ darzustellen die von den Schachtstahlkonstruktionen aufgenommen werden müssen, wurden numerische Modelle verwendet. Die gewählte Option war eine Kombination aus strategisch plazierten exzentrischen Pfeilern und Schutzpfeilern sowie Hinterfüllungen. Nach dem Vortrieb eines kleinen inneren Einbruches während des Abteufens wird der Vollvortrieb vom Schacht weg vorgenommen. Um die Deformationen, die mit der Riffschachtentfernung verbunden sind zu überwachen, müssen geeignete Instrumentenausrüstungen installiert werden.

Jan 1, 2003

By T. V. Thoms, T. R. Twidle, J. W. Crous

This note describes an investigation into the most cost-effective material for mil-shell liners in large-diameter pebble mils with lifter bars. This is part of a project being conducted at the gold plant of East Driefontein near Carletonvile in the Transvaal. It was found that manganese-steel and chromium-steel liners are more cost-effective than liners of cast mild steel or white iron.

Jan 1, 1990

Introduction to high temperature oxidation of metals, by N. Birks and G. H. Meier, London, Edward Arnold, 1983. 19S pp. R30,25. Reviewers: M. B. Cortie and G. G. Garrett Seam gas drainage with particular reference to the working seam, edited by A. J. Hargraves. Woollongong, The Australasian Institute of Mining and Metallurgy. 370 pp. $A30. Reviewer: C. J. Fauconnier New books Solvent extraction Part I, by G. M. Ritcey and A. Ashbrook. Amsterdam, Elsevier, 1983. Elektronishche Steuerungen und Mikroprozessoren im Bergbau. Sicherheit und Zuverlassigkeit Environmental impact control. Philosophical and procedural guidelines for the planning professions Mineral processing and extractive metallurgy. Reagents in the minerals industry.

Jan 1, 1984

By A. P. W. Briggs

Difficulties with the screening of large volumes of pulp to remove plus 600 /km material before the adsorption circuit and to retain plus 20-mesh carbon in the adsorption contactors have largely been solved, with the result that the plant can now handle its design throughput. The elution and electrowinning processes have been modified to simplify the circuit, but the regeneration of carbon remains unsatisfactory. The production of fine carbon in the plant can lead to increased gold losses, and this carbon must be collected and treated. Collection methods for fine carbon and some indications of the quantity of the carbon and its gold values are given.

Jan 1, 1983

By N. A. Barcza

An investigation was conducted into the reactions between the slag system MnO-CaO-MgO-SiO2(AI2O3) and the alloy system Mn-Fe-Si-(C). Synthetic slags representative of plant melts and a plant alloy were reacted in alumina crucibles at temperatures of 1400°C, 1450°C, 1550°C, and 1600°C. In similar experiments, slags were used that comprised a South African manganese ore with various amounts of lime and several synthetic alloys with various silicon contents and manganese-to-iron ratios. These experiments were conducted in a vertical molybdenum-wound resistance furnace with full temperature control. Slag-to-alloy ratios were also varied during the tests. The rate of reduction of Mn.O3 and the MnO from the slag by the silicon in the alloy was extremely rapid, most of the reaction being completed within five minutes. The strongly exothermic nature of the reaction resulted in considerable generation of heat at the slag-alloy interface, causing convectional stirring of the contents of the crucible and promoting the rate of reaction. Equilibrium was usually attained after fifteen minutes. The major limitation governing the recovery of manganese is the need for the silicon content of the alloy to meet a maximum specification of 2 per cent. Higher concentrations of silicon in the final alloy of between 8 and 12 per cent favour good recoveries of manganese from the slag, but, since such an alloy is not salable, lower recoveries must apparently be tolerated. In alloys of 2 per cent silicon, low activities of the silicon are responsible for poor recoveries of manganese. The activity of MnO in the slag can be increased by moderate additions of CaO and small amounts of MgO, i.e., by an increase in the basicity of the slag.

Jan 1, 1979

By W. Bleloch

Published in the Journal, September 1970, and presented at a colloquium on 'Future of the Steel Industry', 17th March, 1971. Errata (a) The final sentence in the penultimate paragraph, left hand column p. 34 of the text should read: 'In the hot regions of the bosh and stack the C+CO2=2CO reaction proceeds to CO from coke carbon and carbon dioxide generated by reduction of iron oxides by CO (the so-called solution loss of carbon)'. The italicised words have been omitted in the text. (b) Temperature in Fig. 3 is K not C. (c) In Fig. 9, connection from top plate of column 10 to heat exchanger 9 has been omitted. DISCUSSION J. B. BEEDON AND C. J. JONKER* Dr Bleloch's paper has outlined the advantages of recycling stack-gas of low nitrogen content in the blast furnace. In the first instance it would appear to be extremely beneficial in controlling the hearth temperature and allowing a 100 per cent oxygen-blast to be used. On a second point however we have to disagree. It is claimed that heat is liberated in the combustion zones by the oxidation of CO to CO2 near the tuyeres and in the subsequent reduction of the CO2 by CO. The author has hypothesized as follows, and we quote: 'The C+CO2=2 CO reaction in the outer combustion zone at about 1 700°C is no longer endothermic due to loss of stability of CO2 and its consequent dissociation into CO and free oxygen.' This statement requires closer examination. If we consider the individual events occurring with the CO in the recycled topgas, with the oxygen in the blast and with the coke in the burden, as done by Dr Bleloch, the following heat considerations emerge. All heats of reaction are calculated from the enthalpy values of each reactant and product, as well as the temperature dependence of their molar heat capacities. (a) At the tuyeres: CO+1/2 O2-+CO2 . . . . . (1) CO, CO2 at 500°C; O2 at 25°C. ?H reaction = -65 000 cals/mole CO The reaction (1) is exothermic. (b) In the outer combustion zone: CO2+C?2 CO . . . . . . . . (2) C, CO at 1 700°C; CO2 at 500 0C. ?H reaction = -56 000 cals/mole CO Reaction (2) is endothermic. The overall heat gain of reactions (1) and (2) is ?H=+56 000 - 65 000= -9000 cals/mole CO i.e. the overall reaction is slightly exothermic, the amount of heat liberated is however smaller than suggested by Dr Bleloch. (c) The dissociation CO2+CO+1/2 O2 . . . . . (3) is a highly endothermic reaction at 1 700 0C, requiring 82 000 cals/mole CO2 to proceed to completion. Furthermore, this reaction (3) is energetically not favoured to proceed, as can be observed from the free energy-temperature relationship of figure (3), which favours the formation of CO2 at 1 700 0C. Hence direct dissociation of CO2 at 1 700 0C appears to be unlikely.* The concept of recycling topgas is however still intriguing from many other points of view. Apart from providing a very efficient method of hearth temperature control, it will create a much higher CO partial pressure in the stack. Whether the rate of indirect reduction in the stack will be proportional to this partial pressure or not is un-

Jan 9, 1970

Infacon 74 Members are reminded of the International Ferro-Alloys Congress that is to take place in Johannesburg between 22nd April and 1st May, 1974. The Congress is being held jointly by the National Institute for Metallurgy, the Ferro Alloy Producers' Association of South Africa, and the South African Institute of Mining and Metallurgy. Correspondence and enquiries should be addressed to The Secretary, Organizing Committee, INFACON 74, Private Bag 7, Auckland Park 2006. The gold deposits of the farms Lisbon and Berlyn in the Eastern Transvaal by v. c. H. R. BRERETON. Published in the Journal November 1973. AUTHOR'S CORRECTIONS The following amendments should be made.

Jan 2, 1974

Professor R.F. Sandenbergh matriculated at Germiston Afrikaans High School, and then he obtained the degrees of B.Eng. (Chem.) in 1972, M.Eng. (Chem.) in 1975, and D.Eng. (Met.) in 1983-all from the University of Pretoria. Mr J.A.D. Britz matriculated in 1958 at the Roodepoort Hoerskool, and joined the mining industry in 1959 as a student mine official at the Rand Mines Training Centre. Mr J.A. Cruise matriculated at Durban High School and joined Union Corporation as a Learner Official in 1962. He was awarded a scholarship to read for B.Sc. and M.Sc. degrees in mining engineering at the University of the Witwatersrand

Jan 1, 1990

When designing coal mine roof support, it is necessary to account for the uncertainties and variability that inherently exist within the rock mass and support elements. The performance of a support system is affected by these uncertainties, which are not taken into account in the current deterministic design methodologies used in South Africa. The key to the design of a roof support system is a better understanding of roof behaviour and uncertainties that can been countered during extraction. This paper sets out to develop a method that takes all uncertainties that exist within the rock mass and the mining process into account and provides a quantitative risk-based design methodology.

Jan 1, 2009

By M. Coetzee

The susceptibility of experimental low-nickel Cr-Mn-N stainless steels to hot cracking, sensitization, and pitting corrosion in the as-welded condition was investigated. These steels were developed for deep-drawing applications and are similar in composition to type 201 stainless steel. In order to obtain good formability, the rapid rate of work-hardening (characteristic of the 200-series steels) was decreased by the addition of copper. The behaviour of two sets of alloys during fusion welding was investigated: 17Cr-7Mn-4Ni-o.5Cu steels containing 0.001 to 0.27 per cent nitrogen, and 17Cr-7Mn-2Ni-o.1N steels with copper contents varying between 0.01 and 3.11 per cent. Al the steels in these two sets initially solidify as d-ferrite, which transforms partially to austenite during cooling. As the nitrogen level increases, the microstructure of an autogenous-weld metal ranges from large amounts of d -ferrite, martensite, and Widmanstätten austenite, to austenitic structures with small amounts of vermicular d -ferrite. The formation of d -ferrite during solidification and the presence of ferrite retained in the weld metal indicate that the experimental alloys will not be susceptible to hot cracking during welding. Except for the alloy with 0.27 per cent nitrogen, the resistance to pitting corrosion of the experimental steels in the as-welded condition is inferior to that of type 304 stainless steel. None of the experimental steels is susceptible to intergranular attack in the as welded condition. The alloys with 0.19 and 0.27 per cent nitrogen have properties (corrosion and microstructure) similar to those of type 304 stainless steel in the as-welded condition.

Jan 1, 1996

By J. C. Paynter

A review of copper hydrometallurgy by J. C. PAYNTER, B.Sc. (Chem. Eng.) (Visitor) Copper hydrometallurgy is discussed with special reference to the treatment of chalcopyrite concentrates under South African conditions. The following processes are described and illustrated: Sherritt Gordon's ammonia pressure leachilng, the Arbiter Process, sulphuric acid pressure leaching, roasting processes, the Cymet Process, and the ferric chloride process developed at the National Institute for Metallursy. These processes are then compared with respect to the form of sulphur produced (elemental sulphur or sulphate), the character of the iron product and the handling of different types of ore.

Jan 11, 1973