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By M. J. Nicol, R. P. Colborn

An investigation into the kinetics and mechanism of the oxidation of iron (11) by oxygen in aqueous chloride solutions By R. P. COLBORN Pr. Eng., Ph.D. (Natal) and M. J. NICOLt B.Sc. Hons., Ph.D. (Rand) A reaction mechanism for the oxidation of ferrous chloride by molecular oxygen is developed. and the appropriate constants are evaluated. The effect of a number of cations and anions on the rate of oxidation has been tested.

By R. H. Matjie, J. R. Bunt, A. C. Collins, J. C. van Dyk, C. A. Strydom

South African discard coal fines and K₂CO₃ blends were heated in a laboratory-scale rotary kiln to produce ashes for H₂SO₄ leaching tests. The optimized H₂SO₄ leaching conditions of 6.12 mol.dm³ (M) H₂SO₄, solid to liquid ratios 1:5 and 1:10, and 80°C for 8 hours were used. K₂CO₃ was added to increase the dissolution efficiency of K. The objective was to determine if the Al present in metakaolinite (Al₂O₃.2SiO₂), the Al, K, and Ti in the alumino-silicate glasses, and the Ti in rutile (TiO₂) in the ashes could be selectively dissolved in H₂SO₄. XRF results show that the ashes formed at 700°C dissolved more efficiently (87% Al, 89% K and 23% Ti) compared to the ashes formed at 1050°C. This can be attributed to the presence of Al₂O₃.2SiO₂, K₂CO₃ melt, K₂CO₃ remnants, KAl(SO₄)₂, and K-aluminosilicate glass in these ashes. XRD results indicate that the ashes prepared at 1050°C contained anorthite (CaAl₂Si₂O₈), microcline (KAlSi₃O₈), pseudomullite (Al₂O₃.SiO₂), and silicon spinel (2Al₂O₃.3SiO₂), which are either insoluble or only sparingly soluble in H₂SO₄. These minerals resulted in the lower dissolution efficiencies of Al and K. Based on the high dissolution efficiencies of Al and K for the ashes produced at 700°C, coal fines blended with K₂CO₃ could possibly be utilized as feedstocks for the production of aluminium(III), potassium(I), and titanium(IV) and a sulphate-containing leach liquor. Furthermore, the environmental issues and costs associated with the handling and disposal of large volumes of coal fines will also be resolved.

Aug 2, 2022

By P. Lundman, L. Rosengren, T. Brandshaug

Tunnel 99’, the Swedish National Road Administration´s (SNRA) general technical specification for road tunnels requires that the load bearing system must be designed to withstand specified design explosion loads. This paper presents the results of an SNRA study to provide a perspective of design analyses tailored to comply with the new requirement. The paper provides an example of a design analysis for assumed tunnel conditions using a numerical model. Dynamic predictions of potential damage to the rock mass and ground support system (rock bolts and shotcrete) from the specified explosion loads are presented including the nonlinear response of the shotcrete. “Tunnel 99”, qui fixe les règles de l’Administration nationale suédoise des Routes (Vägverket) concernant la conception et la construction des tunnels routiers, requiert entre autres que la structure porteuse soit capable de résister à certaines contraintes spécifiques résultant d’explosions. Cette étude présente les résultats d’une étude effectuée par Vägverket en vue d’obtenir une perspective d’analyses de conception spécialement élaborées pour se conformer aux nouvelles règles. Il contient un exemple d’analyse en fonction de conditions déterminées, basée sur un modèle numérique. Des prévisions de’études dynamiques de dommages potentiels subis par la masse rocheuse et les systèmes de soutènement (boulons d’ancrage et béton projeté) du fait des contraintes libérées par la force d’explosion spécifiée sont également présentées, y compris dans le cas d’une réaction non linéaire du revêtement en béton. “Tunnel 99” - die Vorschriften für Strassentunnel der Nationalen Schwedischen Behörde für Straßenwesen - (Vägverket) - fordern vom Tragsystem eine Auslegung in der Form, dass es spezifischen Explosionsbelastungen standhält. Dieser Artikel präsentiert die Ergebnisse einer Studie der Behörde, um einen Ausblick über konstruktive Auslegungen zu geben, die geeignet sind, die neuen Vorschriften zu erfüllen. Der Artikel zeigt ein Beispiel einer konstruktive Auslegung für eine angenommene Tunnelsituation mit Hilfe eines numerischen Modells. Voraussagen unter Beachtung der vollständigen dynamischen Berechnung zu potentiellen Schädigungen des Gebirges und des Ausbaus (Anker und Spritzbetonauskleidung) durch die spezifizierten Explosionsbelastungen, einschließlich des nichtlinearen Verhaltens der Spritzbetonauskleidung, werden gezeigt.

Jan 1, 2003

By A. Koursaris, Y. Turan

The object of this study was to investigate the i1Jfluence of nitrogen on the structure and properties of AISI 310S steel. Experimental ingots of the steel with nitrogen contents of up to 0,525 per cent by weight were prepared, hot-rolled, and tested after various treatments. The rollability of the material was adequate. The yield strength, tensile strength, hardness, and fatigue properties of the new alloys improved with increasing nitrogen content. The impact properties improved slightly. Empirical equations were developed for the calculation of the yield and tensile strengths, as well as the difference between these two properties, with increasing nitrogen content.

Jan 1, 1995

By D. R. Tesarik, F. M. Jones, J. B. Seymour

As part of safety and stability studies at three underground mines in the United States, researchers installed earth pressure cells and embedment strain gauges in cemented rockfill to measure stress and strain changes as mining progressed and the rockfill was loaded. Data from these instruments were used to calculate the in situ modulus of the rockfill for two of the mines. A three-dimensional numerical model of a cemented rockfill cap was validated with data from extensometers anchored in the mine roof and sill; this model was then used to estimate deformation modulus at the third mine because the earth pressure cells and embedment strain gauges recorded negligible changes. Rockfill binder used at these mines ranged from 4 to 8 per cent of the dry components by weight, the water-to-cement ratio was from 0.42 to1.0, and the largest aggregate size in the three mixes ranged from 5 to12 cm (2 to 4.7 in). The range of the calculated in situ deformation modulus values was large, but as expected, it was bracketed by modulus values for cemented tailings and roller-compacted concrete with similar cement contents and water-to-cement ratios. Dans le cadre d’études sur la sécurité et la stabilité de trois mines souterraines situées aux États-Unis, les chercheurs ont installé des palpeurs de pression des terres et des extensomètres d’encastrement dans les remblais cimentés afin de mesurer les variations relatives à l’effort et à la déformation des terrains durant l’exploitation minière et le chargement du remblai. Les données recueillies à l’aide de ces instruments ont servi au calcul du module in situ du remblai dans deux de ces mines. Le modèle numérique tridimensionnel de la semelle d’un remblai cimenté a été validé à partir des données recueillies par les extensomètres ancrés dans la voûte et dans la semelle de ces mines; ce modèle a ensuite été utilisé pour estimer le module de déformation à la troisième mine, étant donné que les palpeurs de pression des terres et les tensiomètres enfouis avaient relevés des variations négligeables. La matière d’agrégation de l’enrochement utilisée dans ces mines comportait entre 4 % et 8 % des composantes sèches par poids; le rapport eau-ciment se situait entre 0,42 et 1,0; et la taille des agrégats les plus gros dans ces trois mélanges était de 5 cm à 12 cm (2 po à 4,7 po). L’écart entre les valeurs calculées des modules de déformation in situ était grand, mais comme on s’y attendait, cet écart a été compensé par les valeurs modulaires des résidus cimentés et du béton tassé au rouleau avec des teneurs en ciment et des rapports eau-ciment semblables. Als Teil der Sicherheits- und Stabilitätsstudien an drei Bergwerken in den Vereinigten Staaten von Amerika installierten Forscher Erddruckgeber und Einbindungsdehnungsmesser in zementierter Steinschüttung, um Spannungs- und Dehnungsveränderungen während der fortlaufenden Bergarbeiten und der Belastung der Steinschüttung zu messen. Daten von diesen Instrumenten wurden dazu verwendet, das In-Situ-Modul der Steinschüt-ung für zwei Gruben zu berechnen. Ein dreidimensionales numerisches Modell einer zementierten Steinschüttungsschwelle wurde mit den Daten von den im Grubendach und in der Schwelle verankerten Extensometern validiert; dieses Modell wurde dann dazu eingesetzt, um das Deformationsmodul in der dritten Grube zu schätzen, da die Erddruckgeber und Einbindungsdehnungsmesser nur geringfügige Messabweichungen feststellten. Das in diesen Gruben verwendete Steinschüttungsbindemittel variierte zwischen vier und acht Prozent an Trockenkomponenten nach Gewicht, der Wasser-Zementfaktor betrug zwischen 0,42 und 1,0 und die größte Zuschlagstoff-größe in den drei Mischungen schwankte zwischen fünf und zwölf Zentimetern. Die Reichweite der berechneten Werte des In-Situ-Deformationsmoduls fiel etwas breit aus, aber es fand erwartungsgemäß eine Klammerung der Modulwerte zwischen den Zemen-trückständen und dem durch Walzen verdichteten Beton mit ähnlichem Zementanteil und Wasser-Zementfaktor statt.

Jan 1, 2003

High pressure grinding roll (HPGR) technology is used in an increasingly diverse range of applications, predominantly iron ore , gold and diamonds. KHD Humboldt Wedag HPGRs are applied world-wide, and consistently prove to be well designed and reliable operating units, with their performance meeting the pre-set standards. This publication summarizes some of the features and experiences for recent applications in treatment of copper ore, coarse iron ore, and gold ore. Summary data of roll surface wear life and operating data are given, together with operational observations. In addition, effects of feed segregation and truncated feed are discussed, as well as the implications of a product recycle flow sheet.

Jan 1, 2012

By D. D. Marsden

This paper discusses the concentrations of sulphides and total sulphur in widely spread regions around mine residue deposits, from which rain-water run-of can enter the Vaal River system. Analyses of borehole samples from several deposits are used to establish typical sulphur head grades. It is shown that a high percentage of al the oxidizable, and hence leachable and pollution-causing, sulphur has already been removed. When the residues were fresh, water that came from the deposits was highly polluted, but the dissolved solids from these residues are today of very minor significance. The data are supported by analyses of the drainage streams.

Jan 1, 1986

By N. F. Dawson

Recovery of a chromite concentrate from UG2 flotation tailings streams, of a grade suitable for further pyrometallurgical treatment for the production of ferrochrome, has certain specific challenges not only by virtue of the decoupled nature of the primary PGM recovery process and secondary gravity based chromite recovery circuits, but also because of intrinsic variations in the nature of the ore and its mineral composition. Variability in the ore, together with upstream process dynamics, creates a challenging environment in which to achieve optimal recovery of a gravity concentrate with accurate grade control. This paper examines certain inter-relational aspects between the ore gangue and chromite mineral types, the influence of the primary PGM extraction circuit and secondary chromite extraction activity as applied specifically to UG2 ore against a background of actual plant experiences and circuit configurations applied in order achieve a suitable quality of chromite concentrate.

Jan 1, 2010

By K. W. Falconer

The Witbank-Middelburg Branch of The South African Institute of Mining and Metallurgy celebrated 100 years of coal mining in the Witbank area with a function held at Douglas Colliery on the 5th December, 1989. Two hundred guests associated with the industry attended the occasion, at which Mr A.A. Sealey, Chairman of Rand Mines, Coal and Base Minerals Division, unveiled a plaque presented to the municipality.

Jan 1, 1990

The International Colloquium on Developments in Froth Flotation, which replaced the Annual University of Cape Town (UCT)/University of Stelenbosch (US) Minerals Processing Symposium, was held at the Van Riebeeck Hotel in Gordon's Bay on 3rd and 4th August, 1989. The Colloquium attracted 150 delegates from the mining, metallurgical, and chemical industries, including 9 from overseas.

Jan 1, 1989

By R. E. Robinson

On 18th November, 1991, the Department of Chemical Engineering at the University of the Witwatersrand, Johannesburg, held a display of posters to review their R & D activities. Although not a new concept, this series of presentations was the first time that the Department of Chemical Engineering at Wits had undertaken as comprehensive a review in this particular format. It turned out to be a most worth-while exercise, and the many visitors must have been impressed with the quality of the presentations.

Jan 1, 1991

By A. Koursaris, Y. N. Turan

This paper reports the results of a literature review carried out on nitrogen-alloyed austenitic stainless steels and their properties. It was found that a large volume of work has been carried out on the subject, particularly with regard to the more common stainless steels such as types 304 and 316. No work appears to have been conducted on the highly alloyed steels such as type 310S. Nitrogen has been found to increase the stability of the austenite in stainless steels and to impart significant improvements in the mechanical and corrosion properties of these alloys. Importantly, nitrogen appears to increase both the ductility and the strength of austenitic stainless steels over a wide range of temperatures.

Jan 1, 1993

By H. V. R. Von Rahden

The expertise of the industrial mineralogist has not always been sufficiently used in decision-making in the minerals industry in South Africa. The mineralogist can make a contribution at al stages of the exploration programme, from the time of discovery of a geological target area, through metallurgical testwork and pilot-plant studies, to the production of a saleable product. This indicates that the activities of the industrial mineralogist should be more closely integrated with those of the exploration geologist and the extraction metallurgist in order to provide management with a meaningful picture of the economic potential of an ore deposit.

Jan 1, 1997

By P. J. Bartlett, H. A. D. Kirsten

A two-dimensional numerical scheme for the simulation of the plastic stress-strain properties of rock, and the various components of rock reinforcement and shotcrete, was used to rigorously determine the characteristics of tunnel support under squeezing conditions. D-shaped tunnels varying in size from 2,8 to 6,5 m in height and width were considered. The four main mining stages in the BAS block cave on Premier Mine were simulated as alternative sets of field stresses. The rock reinforcement comprised 1,8 m long fully grouted rockbolts and 6,0 m long fully grouted cable anchors at various spacings, and of various tensile and bond strengths. Various thicknesses of shotcrete and footwall support configurations were also considered. It was found that shotcrete and rock reinforcement, owing to inherent differences in stiffness, do not function in unison. As monolithic application, shotcrete has an overriding avidity for the imposed loading and destructs itself unless of extraordinary thickness. Under squeezing conditions, it accordingly supports the excavation surface while the rock reinforcement contains on-going convergence. The loads in the various support components can be determined only by simulation of the shotcrete as a stress-relieved medium to represent its broken condition in the field. The loads in the rock reinforcement vary around a tunnel and are the largest in the sidewalls. The loads increase with an increase in tunnel dimensions, the increase in load in the sidewall due to an increase in height being larger than that in the hanging- and footwalls due to an increase in width. Depending on the strength of the rock, the loads in the rock reinforcement become prohibitively large beyond a certain size of tunnel. The reinforcement of footwall rock can be omitted without adversely affecting that in other walls, provided the tensile and bond strengths of the reinforcement are not limited. The resulting footwall heave may, however, result in undermining of the reinforcement in the adjoining walls. A relative depth of anchor of 1,37 provides adequate bond strength in the larger sizes of tunnel, whereas, in smaller tunnels, anchor length is determined by the allowable convergence. The lack of fun column grouting adversely affects the efficiency of rock reinforcement to a major extent. The loads in rock reinforcement are very sensitive to the strength of the rock. Owing to a lack in refinement and calculational rigour, empirical classification systems are an inappropriate means for the design of tunnel support in squeezing conditions and, as a result, grossly unclear-estimate the support requirements.

Jan 1, 1992

By K. O. R. Gebhard

Direct reduction-are we moving in the right direction? by K. o. R. GEBHARD INTRODUCTION Numerous forecasts predict a rapid growth rate for direct-reduction processes. The figures quoted are so impressive that many a top manager must fear that he will fall behind in technical development if he does not base a substantial part of his future steelmaking for mass production on direct reduction.

Jan 2, 1974

By R. Mumbi, M. Peart, E. Arinaitwe, B. Mbao, J. Zulu

Since 1925, xanthates have been widely used in sulfide flotation due to their low cost, ease of manufacture, and ability to float most value species. However, the industry's increasing need for safer and more selective alternatives, driven by low head grades, poor-quality, difficult-to-process ore with complex mineralogy, and stricter environmental regulations, has led to the development of Solvay's AERO® XR series of collectors. These custom-formulated products are based on greener chemistries and offer metallurgical benefits that are similar to or better than those of xanthates, without the safety concerns. Developed through Solvay's Flotation Matrix (FM) 100 approach, the XR series collectors are suitable for a wide range of applications, including the processing of Cu, Zn, and Cu-Ni, as well as the flotation of precious metals. This paper will highlight the differences between xanthates and XR series collectors, and present case studies of their successful commercial application at various global operations.

Jan 1, 2023

By G. L. Smith

[Research and development conducted by CSR.-Mining Technology in the areas of active continuous miner based coal dust/methane explosion suppression systems, passive 'bag based, atone dust barriers systems, din and positioning of refuge bays, integrated escape and rescue strategies, and neural network based coal dust/methane explosion risk assessment is briefly described. It is concluded that effective catastrophic risk management of coal dust/methane explosions is dependent on an integrated, systems approach drat encompasses fundamental understanding of hazard sources, qualitative and quantitative probability of occurrence, magnitude of consequences and efficacy of control and recovery measures.]

Jan 1, 1999

Slake durability of rocks is an important property of rock-mass and rock-materials in geotechnical practice. The slake durability of rocks is closely related to their mechanical properties. In this paper, mechanical properties and slake durability tests for weak and clay-bearing rocks from Beypazari Trona Bed in Ankara, were performed in order to assess the slake durability and mechanical properties (especially rock strength) of these rocks as well as to understand the relationship between mechanical properties and slake durability. In performing this relationship, statistical based correlation has been applied.

Jan 1, 2003

By H. M. Friede

Iron Age metal working in the Magaliesberg area by H. M. FRIEDE, Ph.D. (Visitor) Evidence of smelting and metal working in the Magaliesberg comes mainly from three sites: Broederstroom (Pretoria District). Uitkomst Cave (Krugersdorp District), and Olifantspoort/Olifantshoek \Rustenburg District). The analyses of copper ores found at or near these sites are reported. as are the analyses of twenty-six samples of slag from the Magaliesberg area and other sites in the Transvaal. Iron implements and copper ornaments found at the Magaliesberg sites are described. and the analyses of some of these specimens are reported and discussed. A metallographic report on two iron objects from Broederstroom points to similarities in the smelting and forging techniques that were practised in the Transvaal and Nigeria during the Early Iron Age.

Jan 6, 1977

COLLOQUIUM AND GENERAL MEETING Developments in gold recovery processes A General Meeting and Metallurgical Colloquium on the above topic were held on Wednesday, 14th March, 1973, at Kelvin House, Johannesburg. Dr J. P. Hugo (President) was in the Chair. The colloquium was attended by 170 delegates, and was opened by the President at 9.15 a.m.