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Mixed integer programming (MIP) has been used for optimizing production schedules of mines since the 1960s. The major problem in the long-term production scheduling for an entire orebody is that the number of integer variables needed to formulate an MIP model is too large to solve the formulation. This number may reach well over one hundred thousand. To overcome this difficulty, this paper presents two new algorithms to reduce the size of the problem. These algorithms assign an earliest and latest possible start date for each machine placement, eliminating the integer variables that correspond to machine placement before its early start date and after its late start date. A case study based on Kiruna Mine, the second largest underground mine in the world, is summarized in the paper. It shows substantial improvement in the solution time required using the new algorithms. This increased efficiency in the solution time of the MIP model allows it to be applied to Kiruna Mine, with the potential to increase substantially the net present value (NPV) of the project.

Jan 1, 2008

By J. P. Hoffman

In 1988 the Japan Iron and Steel Federation started a research-and-development programme known as DIOS (direct iron-ore smelting). Eight Japanese integrated steel producers and the Coal Mining Research Centre, subsidized by the Ministry of International Trade and Industry, are involved in the project. The aim of the programme is to have a 500 v/d pilot plant for the production of iron via an oxygen-coal in-bath smelting converter in operation by mid 1993. The three main components of the DIOS process are as follows: ?a fluidized bed for the pre-reduction of iron-ore fumes ?in-bath smelting reduction in a converter ?off-gas reforming by the addition of coal fines. The main drive is to provide a smelting process that is more energy-effective, using coal instead of coke and/or electricity. The advantages claimed include inter alia ?direct use of fine iron ore ?direct use of non-coking coals-low coal consumption ?low capital expenditure-replaces costly coke ovens, agglomeration plants, and the blast furnace ?economical production on mini-plant scale ?less of an impact on the environment. This concept of 'direct steel has been carried over to the production of stainless steel direct from the ores, again bypassing such energy-intensive units as the submerged-arc furnace for the production of ferrochromium. A number of Japanese companies have indicated a certain amount of success. Several interacting elements are recognized that could have a productivity-limiting aspect. The possibility of the direct production of stainless steel from chromite is discussed briefly with reference to the Highveld of the eastern Transvaal as a possible site for such a plant

Jan 1, 1992

Notices COMPETITION FOR STUDENT MEMBERS OF THE SOUTH AFRICAN INSTITUTE OF MINING AND METALLURGY Each year the Institute offers a prize (or prizes should the entries warrant it) of up to RlOO for the best paper or dissertation on a topic appropriate to the interests of the Institute. The competition is open to all Student Members of the Institute. APPLICATION AND PRACTICAL OPERATION OF HYDROCYCLONES Dr H. F. Trawinski of Amberger Kaolinwerke, Hirschau, West Germany, gave a very interesting lecture on this subject to an audience of over one hundred, composed largely of members of the Institute, on 15th August, 1973, at the University of the Witwatersrand. ROTARY INTERNATIONAL Applications are invited before 15th March, 1974, for the following awards of The Rotary Foundation: Post-graduate Fellowships Under-graduate Scholarships Awards for Technical Training Awards for Teachers of the Handicapped. NIM REPORTS Report No. 1509 The instrumentation developed for electrochemical studies of the le(Whing of uranium dioxide. Report No. 1550 A fundamental study of the dissolution in (Wid solutions of uranium minerals from South African ores. Report No. 1552 The preparation and analysis of minerals for use as reference material.Progress report No. 2. Report No. 1556 The spectral analysis of solutions.2. The analysis of leach liquors, concentrates, slags, and residues. Report No. 1559 A cost assessment of the production of elemental sulphur by chlorination roasting. Report No. 1562 Application of a flotation model to an industrial plant

Jan 11, 1973

By B. Genc, P. Malepfane

This study proposes a new approach to reduce the environmental impact during surface mining by improving environmental factors through the incorporation of carbon footprint into strategic mine planning. Two key variables were analysed by contrasting and comparing the baseline and optimised models generated. These variables include net present value, which helps determine the financial feasibility of the mining models and their carbon emissions. The variables were analysed by using linear regression, Spearman’s correlation, a P-value hypothesis, and an exponential decay test. Results show that at Mine A the projected net present value was 62% higher than when running a baseline model. Furthermore, the net present value from the baseline model portrayed a high rate of decay at 0.667 versus 0.118 from the optimised model. This indicates the baseline model’s sensitivity to long-term project timelines and fluctuating markets. The optimised method presents an opportunity to manage emissions during the high operational costs phases. It is represented by a 31% improvement in carbon emissions during the periods of high operational costs, whilst maintaining a positive net present value when compared with the baseline model. It was shown that the optimised model presents a better chance of achieving financial feasibility and balancing environmental impact, thereby ensuring that Mine A can align with the environmental aspect of economic, social, and governance principles through lowering the carbon footprint resulting from its hauling operations.

Jan 30, 2026

By T. Nesane, S. S. Mnyakeni-Moleele, L. C. Murulana

The effectiveness of two synthesized ionic liquids, 1-(benzyloxy)-1-oxopropan-2-aminium 4-methylbenzenesulfonate (1-BOPAMS) and 4-(benzyloxy)-4-oxobutan-1-aminium 4-methylbenzenesulfonate (4-BOBAMS), were evaluated for mild steel corrosion inhibition in 1.0 M hydro-chloric acid solution, using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), and gravimetric techniques. Organic moieties responsible for the adsorption process on mild steel surface were investigated using Fourier transform infrared spectroscopy (FTIR). Gravimetric analysis revealed that the inhibition efficiency of 1-BOPAMS and 4-BOBAMS increased with concentration, with maximum inhibition values of 90.32% and 97.91%, respectively, at the highest concentration of the inhibitors. Gibbs free energy (ΔG°ads) values indicated a strong interaction between the mild steel surface and the molecules of the ionic liquids, and that the adsorption process was spontaneous. These values also show that the inhibitive nature of ionic liquids against mild steel corrosion is caused by a mixedtype of adsorption film formed on the steel surface. The Langmuir adsorption isotherm was used to describe the adsorption of ionic liquid molecules onto the mild steel surface. Polarization curves showed that 1-BOPAMS and 4-BOBAMS have a similar effect on both the anodic and cathodic half-reactions, indicating that they prevent the dissolution of mild steel through both physical and chemical process. Nyquist plots were defined by incomplete semicircle capacitive loops, showing that the charge transfer mechanism controls the corrosion of mild steel in acidic solution.

Apr 1, 2021

By D. D. Howat, J. van der Colf

Selected members of the slag system were reduced in graphite crucibles in an argon atmosphere, and the physicochemical properties of the reduced derivatives of the slags were determined in inert crucibles. It was found that slags having magnesium aluminium titanate as the primary phase before reduction underwent an increase in liquidus temperature, accompanied by a change in the primary phase. No analogous behaviour could be detected for the slags having perovskite as the initial primary crystallization product. In most instances, the viscosity of the melt passed through an initial minimum, followed by an increase as the reduction time was extended. Increased MgO/CaO ratio. basicity, titania content, and reduction temperature all served to accelerate thickening. During reduction, the electrical conductivity of the slags tended to rise relative to the value for the unreduced melt.

Jan 1, 1979

By K. Böde

Hochtief AG Germany has developed a comprehensive management and information system for the construction industry named Aristoteles. This system is an efficient supporting tool to manage a variety of construction sites as well as operating business units with required economic targets. As such, Aristoteles offers wide-ranging control of complex economic processes in construction in a consistent manner. In this paper the process oriented functions of the system will be described with special emphasis on finance accounting and cost control. The basic elements in this respect are tender estimation, creation of initial project budgets and running budgets, regular determination of work done and result forecast to the end of the project. Further, cost accounting, monthly reporting, and all balance-related postings are included. On the basis of the extensive reporting (targeted/actual cost comparison, cost manager, project report, actual/targeted hours worked comparison, overhead cost report, amendment report or project (result) lists of all projects realized by one business unit), the responsible managers can make justified project evaluations, project controls and variance analyses during the project period and derive appropriate management measures. Thus, Aristoteles includes all substantial elements for the risk management of the operational business. In big construction joint-stock companies it is of crucial importance to satisfy the information requirements of the investors. In this respect the system provides a transparent presentation of the financial, investment and profitability situation of the company. In the international construction industry the balancing rules according to IAS (International Accounting Standards) have already been used to a larger extent. In accordance with these rules the partial profits of the work during execution can be shown as realized even before completion of a long-term contract. The validity of Aristoteles will be outlined briefly. Major advantages using the system are highly enhanced accuracy of project controlling, systematic overhead allocation to projects, change of attitude of the project personnel due to increased cost consciousness and improved flow of information within the company.

Jan 1, 2003

By J. C. Vreugdenburg, B. A. Dippenaar, J. Muller, T. L. de Vries

Iron ore fines are agglomerated in the sintering process to produce sinter: an important feed material for blast furnaces worldwide. A model of the iron ore sintering process has been developed with the objective of being representative of the sinter pot test, the standard laboratory process in which the behaviour of specific sinter feed mixtures is evaluated. The model aims to predict sinter quality, including chemical quality and physical strength, as well as key sinter process performance parameters such as production rate and fuel consumption rate. The model uses the finite difference method (FDM) to solve heat and mass distributions within the sinter pot over the sinter bed height and time dimensions. This method can further be used for establishing empirical relationships with measured sinter properties. Inputs into the model include the feed material physical properties, chemical compositions, and boundary conditions that vary over time. Sub-models describe relationships between applied pressure differential and gas flow rate through the bed of granulated fine ore particles, combustion of carbonaceous material, calcination of fluxes, evaporation and condensation of water, and melting and solidification. Four sinter pot tests were performed and the model predictions validated against temperatures measured at depths of 100, 230, and 420 mm. Differences between predicted and measured temperatures indicated the need for optimization of some model parameters that are uncertain. Optimization resulted in an improvement in the correlation between the predicted and measured temperatures for all tests, although an acceptable level of agreement was not achieved in all cases. Using these parameter values, reasonable agreement was found in terms of typical performance parameters for three out of the four tests.

Jan 1, 2014

By G. A. Bezuidenhout

Lonmin Platinum installed a concentrated mode dual-alkali scrubber at the smelter in Marikana in 2002. The dual-alkali scrubber was the technology of choice at that time as a sulphur fixation plant, due to the perceived benefits of handling both the high SO2 concentrations of converter off-gas and the swings in SO2 concentration that are linked to Peirce-Smith operation. Owing to current and impending legislative requirements for air quality and waste, Lonmin is currently considering additions to the dual-alkali plant, but is also evaluating alternative technologies for sulphur fixation. This paper reviews the decision of Lonmin to install a concentrated mode dual-alkali scrubber and presents plant performance achieved. It also describes the important control variables and sensitivities of the plant, and the final product that is produced by the operation of the plant. The legislative requirement that drives the Lonmin technology evaluation is also discussed.

Jan 1, 2012

By X. H. Li, Q. Zhang, X. Fei

Bauxite residue known as red mud (RM) is a by-product produced in massive quantities during alumina production by the Bayer process with a utilisation rate of less than 5%. A large amount of RM accumulated and produced continuously has had a seriously adverse impact on the surrounding ecological environment. The application of RM in building materials is considered to be the most effective and thorough way to make RM harmless and recycle resources for the reason that adding RM to concrete as a mineral admixture could not only consume a lot of RM, but also save cement and other energy-consuming industrial products. In this paper, the adaptability to cement and aggregate of RM was studied. The results showed that the compressive strength and flexural strength of concrete using ordinary Portland cement, slag Portland cement or fly ash Portland cement as cementing material showed different trends with the increase of the amount of RM. The influence rules of RM on the compressive strength of Portland cement, slag Portland cement and fly ash Portland cement concrete were similar, whether for silicate aggregate or carbonate aggregate. RM has a negative correlation to the flexural strength of silicate aggregate-ordinary Portland cement concrete, but a positive correlation to silicate aggregate-slag Portland cement, silicate aggregate-fly ash Portland Cement. RM promoted the formation of calcium carbonate crystals and inhibited the formation of ettringite and calcium hydroxide crystals in the matrix while ordinary Portland cement, Portland cement and fly ash Portland cement were used as cementing materials. This study provided support for the use of RM in concrete, the reduction of solid waste storage, and the saving of high energy consumption cement as well. Keywords: Red mud, cement, aggregate, adaptability, mechanical properties, mineral composition

Jan 1, 2020

By M. J. U. T. Van Wijngaarden, R. J. Dippenaar, J. M. A. Geldenhuis

The successful application of solid electrolytes in electrochemical cells for high-temperature thermodynamic studies depends to a large extent on an accurate knowledge of the P. value of the electrolyte (the oxygen partial pressure at which the ionic conductivity and n-type electronic conductivity of the electrolyte are equal). Consequently, the P. value of an electrolyte must be determined prior to its use in electrochemical cells. This paper describes the successful application of a coulometric titration technique in the quantitative assessment of the P. values of a commercially available ytria-stabilized zirconia electrolyte that has been used extensively by local investigators. The experimentally determined P. values of the electrolyte are reported and compared with P. values reported in the literature for a similar electrolyte.

Jan 1, 1988

Metso Minerals Process Technology Asia-Pacific (MMPT-AP) has been working with many mining companies worldwide performing `Mine to Mill' or Process Integration and Optimisation (PIO) studies. MMPT-AP has developed a proven methodology to improve the efficiency of the mine-mill interface and gain maximum benefit. The PIO methodology involves rock characterisation, mathematical modelling and simulation to generate a list of operational and control changes for both the mine and concentrator. Following the methodology, the list of recommendations is developed relatively easily; the more challenging part depends on the company. Success of a PIO project relies on the ability of an organisation to implement change - both operationally and culturally: the human element. When a PIO project is started, there is initial interest and commitment from the company. But how can this be maintained? How does an operation know if the benefit continues? MMPT AP is now developing long-term relationships with clients to ensure that the increased production and improved efficiency continues. Direct and indirect measurements are used to determine the key factors involved and to understand the cause/effect relationships. Simulation tools also can be used to compare current with recommended practices - so when material properties vary over time, the benefits can still be quantified. PIO is about empowerment: by measuring and understanding what parameters affect concentrator performance, the site personnel now have the knowledge to make a difference. Rather than simply reporting variable or poor concentrator performance, operations can predict when production will be affected and put controls in place to prevent it from happening. This requires support and commitment from the company or `buy in'. Ensuring this buy in continues is the challenge facing every company involved in PIO work - but the benefits are well worth it. This paper will review MMPT-AP's experiences in implementing PIO projects in the long term: from both the consulting and operational viewpoints. MMPT-AP's involvement with a number of companies will be discussed as examples of what works and what does not.

Jan 1, 2007

By C. A. Snyders

This paper investigates the recovery of platinum group metals (PGMs) from a dilute cyanide leach solution containing base metals, in a manner similar to that used for gold extraction in a typical CIP process, and focuses on both the adsorption and elution stages. The carrier-phase extraction of precious metals using activated carbon offers significant advantages over other processes in terms of simplicity, the high pre-concentration factor, rapid phase separation, and relatively low capital and operating costs. As a sorbent, activated carbon is still by far the most important material because of its large surface area, high adsorption capacity, porous structure, negligible environmental toxicity, low cost, and high purity standards. Adsorption tests were performed on a pregnant alkaline leach solution (0.15 ppm Pt, 0.38 ppm Pd, 0.1 ppm Au) resulting from cyanide extraction performed in column leach tests. The initial adsorption rates of platinum, palladium, and gold were very fast and recoveries of these three metals were approximately 90 per cent after 2 hours and 100 per cent, 97.4 per cent, and 99.9 per cent respectively after 72 hours. The parameters that influence the extraction of PGMs and Au were examined to assess their relative importance during the adsorption process in order to provide the basis for process optimization. The concentration of thiocyanate was not identified as significant factor for PGMs adsorption, while nickel concentration was the most significant extraction process parameter. Base metal cyanide complexes adsorb and compete with the PGM complexes for sites on activated carbon, and while copper adsorption can be minimized by adjusting the residence time, nickel adsorbs at approximately the same rate as that of the PGMs, influencing the loading capacity and adsorption kinetics of the PGMs. The feasibility of eluting platinum and palladium cyanide complexes from activated carbon using an analogue of the AARL process was investigated. Platinum and palladium elute from activated carbon almost to completion in 4 to 5 bed volumes at 80°C, while the elution of gold at this temperature is slow, with a significant amount of gold still to be eluted after 16 bed volumes. Cyanide pre-treatment was found to have a significant influence on PGM elution. Higher cyanide concentration in the pre-treatment step results in more efficient elution up to a point, and experiments suggest the possibility of an optimum cyanide concentration, beyond which elution efficiency starts decreasing.

Jan 1, 2012

By A. S. Geldenhuys, L. S. Leal Filho, D. A. Deglon, T. C. Souza Pinto

The Brucutu iron ore mine (Minas Gerais, Brazil), is Vale`s largest iron producing operation achieving around 21 million tons by flotation of iron ore pellet feed per annum. The run of mine is mainly composed of hematite (70%) and quartz (30%). After preparation (comminution and sizing), the slurry is submitted to reverse cationic flotation of quartz under basic conditions (pH=10.5). Corn starch (500g/t) is used to depress Fe-bearing minerals and alkyl (C10) ether amine is the collector for quartz. The flotation circuit is arranged in a “coarse” section utilizing dated 28m3 square Wemco cells, and a “fine” section utilizing modern 160m3 tank cells. The “coarse” flotation circuit treats material from the deslime cyclone underflow while the “fine” circuit treats material from the deslime cyclone overflow and the pulp product from the “coarse” circuit scavenger 2 bank. Evaluation of process performance is of high importance as even small gains can lead to large improvements for this high throughput plant. Cell-by-cell samples of the froth products, selected feed and pulp-products were analyzed for flow-rate, overall chemical composition, and particle size distribution. Bank-by-bank samples of the feed, froth and pulp products were analyzed on an assay-by-size basis. In addition, the flotation cells were hydrodynamically characterized and gas dispersion parameters assessed. The detailed experimental program resulted in a thorough characterization of the process and enough information to produce a calibrated floatability component model. Longer mainline residence time results in significant Fe2O3 losses while yielding little benefit in terms of SiO2 grade. Scavenger 2 has twice the residence time of scavenger 1 while having to treat only 10% of the SiO2; resulting in high Fe2O3 recoveries to the froth and poor separation. In addition, it is shown that the Fe2O3 exhibits true flotation behavior resulting in increased Fe2O3 losses. The detailed data collection campaign coupled with in depth data analysis and modelling gives unprecedented information and highlights avenues for optimization that was previously unknown. Keywords: Froth Flotation, Process modelling, Process evaluation, Metallurgical survey

Jan 1, 2020

By M. Nyoka

Consideration of the economic, environmental, and social impacts associated with the life-cycle of a technology is of increasing importance for decision-making in industry. It has been suggested that economic assessment of technology deployment projects requires the translation of associated environmental effects into monetary values. This paper introduces an approach for identifying and evaluating environmental damage in monetary terms. The approach groups the environmental impacts associated with a technology life-cycle system into four main criteria: air, water, land, and mined abiotic resources. The valuation of the impacts on the resources consists of an economic cost benefit analysis (CBA) procedure that comprises four steps: the compiling of an impact inventory, a monetary valuation of the inventory, discounting, and a risk/uncertainty analysis. The monetary valuation step for impacts on air resources is primarily based on published externality costs for Europe and the United States, which are adopted and converted to reflect the South African context. Local opportunity costs are utilized for the other resource criteria. The damage costs are transformed into South African Rand at 2005 prices. The paper demonstrates how the approach may be applied in the assessment of projects in the metallurgical industry. Shortcomings in the approach are identified. For example, not all of the aspects that are considered necessary to assess environmental performances comprehensively can be valued in monetary terms. Also, certain values, specifically those pertaining to opportunity costs, need to be determined on a case-by-case basis. Furthermore, the uncertainties associated with the indicators obtained may strongly influence the usability of the results of an environmental performance assessment, e.g. future damage costs will change with fluctuations in the markets. It is concluded that although such an approach has merit in increasing the understanding of the potential financial implications of a technology?s environmental performance, further research is required to improve the approach described if it is to be used further in the South African metallurgical industry. Damage cost estimates that are specific to South Africa need to be developed to reduce uncertainty, and the combination of both quantitative and qualitative approaches is recommended for comprehensive sustain-ability decision-making.

Jan 1, 2007

By T. Käyhköa, J. Liipoa, S. Khizanishvilic, M. Sinche-Gonzalezb

The use of geometallurgical modelling is becoming more common in concentrator plant design and during the operational phase. Predictive modelling aims to define optimised process parameters for the concentrator plant to accommodate variability within the ore feed. The main objective of this study is to show how the metallurgical response of different types of ore blends can be simulated using kinetic models derived from experimental flotation tests with different geometallurgical end-member ore types and their blends. For these validation tests, four different end-member ore types containing different ratios of chalcopyrite, chalcocite and oxidised copper minerals from Rich Metal Group’s Madneuli copper-gold mine, Georgia, were tested. Kinetic flotation tests, including both rougher and cleaner flotation tests, were carried out. The simulations were performed using HSC Chemistry software based on mineral compositions of the ores and kinetic models using rectangular distribution equations and flowsheet model. Simulated and experimental results of copper grade, copper recovery and concentrate mass pull correlated well with R2 values of >0.95. Based on these results, the metallurgical response of different ore blends can be simulated based on the flotation kinetics of end-member ore types. The use of this kind of simulation will create savings during the test work phase and increase the flexibility and predictability in the processing stage. Keywords: Ore body characterisation, geometallurgy, process mineralogy

Jan 1, 2020

By S. T. Johansen, C. Colomb, B. Ravary

Combustion and thermal NOx formation have been modelled using the Computational Fluid Dynamics (CFD) commercial code Fluent 6.1. The aim was to predict and give a better understanding of the combustion in electric arc furnaces for the production of ferro-silicon and silicon metal. Another important objective was to assess the impact of a number of operating parameters on the NOx formation. The CFD tools used are de-scribed with a special focus on models for species and turbulence transport. Sensitivity studies have been carried out to study the influence of several parameters: sub-models, process gas composition and distribution at the charge surface and influence of the presence of SiO. The main conclusions are: ?Using the combination of a realistic design, boundary conditions and models, the simulated NOx level is in quantitative agreement with measurements. The presence of water vapor is particularly important because of its influence on the specific heat of the mixture and resulting temperature. ?Release of significant amounts of SiO from the charge surface results in an important increase of NOx, even if we applied a simplified combustion model for SiO gas. However, because of lack of thermal and compositional data for blowing situations (when SiO flows directly from the arc cavity through open channels to the charge surface), no quantitative validation is possible. The way SiO is distributed (uniformly or as a jet) has a limited impact on the result in our computations.

Jan 1, 2007

By D. N. Esfahani, K. Khazen, M. Mohammadi

Electrowinning is one of the nickel recovery processes from solutions obtained from the leaching of nickel sources. Every year significant amounts of nickel products are used in various industrial processes and daily life, such as catalysts or batteries, which are a valuable source of nickel for recovery. Nickel purity is also very important in the electrowinning process, because the amount of impurities in nickel such as sulphur, if greater than 100 ppm, make it unsuitable for use in catalysts and plating. Because sulfur is intrinsic to the sulphate electrowinning system, we needed to investigate parameters that can affect the quality and purity of nickel. In this regard, experiments were performed in static and circulating electrowinning processes. A monitoring and circulation system was designed and built to measure voltage, current and temperature as well as to circulate the solution in the system at a specified rate. It was then observed that nickel ion concentration, pH, using the circulation system and additives, were factors affecting the purity and quality of nickel, and in the best case the amount of sulphur in nickel was below 100 ppm. Keywords: Nickel, electrowinning, sulphur impurity

Jan 1, 2020

By S. Durapraj, R. T. Masethe, U. Maqina, A. C. Adoko

This study investigates seismicity and rockburst control within the Merensky Reef and UG2 orebody of an intermediate-depth platinum mine located in South Africa's Bushveld Complex. Utilising a mine-wide seismic monitoring system, over 1,900 seismic events were recorded between April 2023 and May 2024, revealing complex seismic patterns driven by mining-induced stress changes. The largest event, with a magnitude of ML 2.0, underscores the seismic risks associated with mining at increasing depths. Key findings include the spatial and temporal variability of seismic events, with high seismic activity observed near pillars and geological structures. A significant portion of events correlated with pillar and foundation failures. Moment tensor analysis identified dominant failure modes, such as stress-driven fracture closures and dynamic pillar failures. To mitigate risks, the study emphasises advanced support system redesign and rockburst risk assessment using the rockburst damage potential (RDP) method. The research highlights the importance of monitoring, geotechnical compliance, and adaptive designs in enhancing safety and reducing seismic hazards in underground mining operations. The study applied the RDP framework, classifying damage across R1 to R5 scales, where most instances fell into low-risk categories (R1 and R3), indicating minor to moderate damage. However, data limitations and the tabular stoping method's complexity led to inconclusive results, highlighting the need for more robust data and customised risk assessment tools. Despite these challenges, the RDP approach provided valuable insights into rockburst mechanisms and the effectiveness of existing support systems.

Jan 12, 2025

By C. J. Pretorius

More than 30 percent of the global demand for zircon (ZrSi04) is supplied by South Africa. A significant amount of the zircon is exported, and beneficiated products are then imported for industrial applications locally. Beneficiating the zircon locally could have a positive impact on the local market, since zircon is only one of many such cases. Ammonium acid fluoride serves as an alternative anhydrous fluorinating agent for zircon in the synthesis of several metal fluorides1,2. It provides an effective dry fluorinating method and is easier to handle than hydrogen fluoride or fluorine gas. Zircon exposed to extreme plasma temperatures dissociates and becomes more reactive. The reaction of the plasma-dissociated zircon (Zr02.SiO2) with the ammonium acid fluoride (NH4F.XHF, where x= 1 to 5) forms two main intermediate compounds (NH4)3ZrFr(s) and (NH4) 2SiF6(s), the latter decomposing to form volatile products at relatively low temperatures, providing easy separation of the silicon and zirconium compounds. The ammonium zirconate compound decomposes to form zirconium tetrafluoride (ZrF4), which can be further manufactured into zirconium metal, to name but one product. Data on the kinetics of the reaction of ammonium acid fluoride with zircon and plasma-dissociated zircon, combined with the thermo¬dynamic parameters of the reaction, is essential for the development of an industrial process for the production of a precursor for the manufacturing of zirconium metal, namely anhydrous ZrF4. Both the reaction kinetics and reaction parameters will be included in this study, as well as some proof that the reaction proceeds to ZrF4 on a small batch scale. If the exact reaction parameters can be pinned down, a wide spectrum of anhydrous metal fluorides can be synthesized through this fluorination route.

Jan 1, 2012