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By B. M. Munyungano

Rössing Uranium Mine operates a recovery circuit with continuous ion exchange followed by solvent extraction. Serious organic degradation problems were encountered during 1985/6, 2000 and 2005 in the solvent extraction plant. The preferential loss of the tertiary amine extractant was observed during the above-mentioned period. Previous investigations revealed that the tertiary amine was breaking down to nitrosamine, which cannot take part in the exchange reaction with U3O8. A reduction in the redox potential of the solvent extraction plant feed to below 500 mV halted this preferential loss. A lot of effort has been made to try and understand the actual mechanism for nitrosamine formation. Current understanding for the degradation is that formation is due to high nitrates on the strip side of the circuit emanating from nitrates from the precipitation process using ammonia. It is the current belief that pH lower than 3.7 on the strip side results in loading of nitrates onto the solvent. If oxidizing conditions prevail on the extraction side of the solvent extraction circuit, the tertiary alamine will then degrade into nitrosamine. This phenomenon is yet to be established and verified. It has, however, been established that the above process is brought about the following conditions ?High redox potential greater than 550 mV predominately caused by a high Fe3+/Fe2+ratio (4:1) ?Perception that if Fe2+<0.5 g/lit will contribute to high redox ?High concentrations of NO-3 in the conc eluate (feed to SX)/ammonium sulphate (NO-3> 4 g/l based on historic values) ?Presence of Mo as a catalyst ?Tests also have proved that the presence of nitrous acid in a concentration of 1 g/lat 550 mV leads to formation of nitrosamines from alamine.

Jan 1, 2007

By C. Musingwini

The South African platinum mining industry is using a number of different mining methods, including variations of the same method, to extract the narrow reef tabular platinum deposits of the Bushveld Complex. These mining methods fall into three broad categories, namely conventional, mechanised and hybrid mining. A question sometimes asked in the industry is whether mechanized mining methods are more efficient than conventional mining methods. An objective answer requires the methods to be evaluated against multiple criteria simultaneously, whereby each criterion has a relative degree of importance in the overall decision. The most efficient method is the one that scores highest on each criterion. However, some of the criteria can be conflicting, such as by increasing dilution the shaft head grade decreases. The analytic hierarchy process (AHP) methodology was selected for the study because it is used to solve problems of this nature. A survey was carried out to determine the relative importance of each efficiency criterion by drawing on the knowledge and experience of mine technical services and project management practitioners in the industry. Efficiency data for four different mining methods drawn from the Egerton (2004) study were used as a case study. The conventional mining method ranked as the most efficient mining method from the four methods considered. The exercise indicates potential for the AHP to be used in the South African platinum mining industry as a tool for selecting optimal layout designs, conduct regular evaluation of the performance of production shafts, or objectively evaluate line managers for promotion. The work described in this paper is part of the methodology used in a current PhD research study at the University of the Witwatersrand. Keywords: Analytic hierarchy process (AHP); multiple criteria decision analysis (MCDA); decision-making; conventional mining, hybrid mining, mechanized mining.

Jan 1, 2008

By R. P. King

A class of gravity separation unit operations in ore-dressing relies for its operation on the production of a stratified bed. Heavier material gravitates downwards, and separation is achieved by splitting the ore horizontally, with the recovery of a dense stream and a lighter stream. The important ore-dressing unit operations that fall in this class are the jig, the Reichert cone and the pinched sluice. A new quantitative model based on Mayer&apos;s potential theory is developed here. This model is developed completely for the simple case of binary mono-size particulate materials, but the extension to units operating with feed material distributed over particle size and density is discussed in principle. The model can be used to predict the performance of these units and is very suitable for simulation. The model is tested successfully against experimental data obtained from a batch jig and a Reichert cone.

Jan 1, 1987

By E. Minnaar, P. J. Cilliers, M. Bellino, L. M. Roux, R. Dye

The classic technique to remove impurities in a cobalt stream is selective precipitation. This is usually followed by re-leaching to produce an advanced electrolyte for cobalt electrowinning. Although this technique ensures an adequate cobalt concentration in the electrowinning circuit, some of the consequences include unwanted losses through the numerous selective precipitation steps resulting in lower recoveries. One plant that currently utilizes selective precipitation is the Luilu Metallurgical Plant (Luilu) in the Democratic Republic of the Congo. This paper evaluates the benefits of using solvent extraction technology as a purification step in the Luilu Process with the aim of further increasing the overall cobalt recovery and to ensure that a suitable cobalt concentration in the advanced electrolyte is achieved. The implementation of a solvent extraction-electrowinning process is found to be beneficial in terms of achieving improved recoveries and cobalt cathode quality, however there are many other factors that impact the success of converting from the classic precipitation process used at Luilu.

Jan 1, 2007

By K. I. Afewu, L. C. Woollacott

Little is reported in the literature that is directly useful for the interpolation film coefficients for the in-pulp adsorption circuits used in gold metallurgy. This can create a problem if the design or operation of these circuits is to be optimized by the use of simulation techniques. To address this problem, a study was undertaken on the influence of mixing intensity, scale, and geometry on the film coefficient in adsorption systems typical of the carbon-in pulp plants used for gold extraction. This, the first paper deals with the influence of these factors on the film coefficient and shows that the specific power to just disperse the carbon in the slurry is an important variable. This variable is also strongly dependent on mixing intensity, scale, and geometry-a dependence that is dealt with in the second paper in the series. From the informatlon obtained, practical scale-up procedures were developed. These procedures are considered to be applicable to resin-in-pulp as well as to carbon-In-pulp plants.

Jan 1, 1995

By D. J. de Clerk

Global trends stipulate the need to optimize existing assets while reducing environmental impacts. This paper illustrates the procedure that was followed to achieve such goals at one of the coal burning flash dryer units at an Anglo American smelter. An in-depth study of the process and related literature led to the development and installation of a revised control philosophy. This system includes modifications to the existing regulatory control structure as well as a hybrid rule-based and model-predictive advanced process control (APC) layer. Since commissioning of the APC, this flash dryer?s average throughput has increased by more than 6%, despite higher feed moistures. Furthermore, even though coal consumption has increased slightly, operating efficiency has improved by close to 5%. This was made possible by improving stability of the drying column outlet temperature by approximately 40%, which in turn enabled selection of a more optimal setpoint. Recent data has shown that APC utilization now exceeds 95%. This is indicative of a successful controller installation with good site acceptance. The same philosophy has therefore since been rolled out to most of the other flash dryers in the group.

Jan 1, 2012

Today&apos;s conservation thinking is becoming increasingly polarised-a widening gap that could eventually be to the overall detriment of mankind, one way or the other. In one corner, stand the disciples of the untainted wilderness, moral protectors of the natural world who subscribe to the doctrine that the fragile balance of nature is threatened by man&apos;s very existence. On the opposite side of the ring, stands the relentless developer, with the megalomaniac notion that nature is purely there to serve humanity and civilisation, under the auspices of &apos;progress&apos;,

Jan 1, 1996

By L. Hermansson

Trackless mining at LKAB, Sweden by L HERMANSSON (Visitor) Because the usual means of transporting men and material to the working sites was time-wasting and uneconomical, inclined subways were installed in the Kiirunavaara Mine that permitted the access of rubber-wheeled vehicles to all underground working sites. Men and material could now be transported direct to the working site with no reloading. An increase of 8 to 12 per cent in underground productivity has been obtained by the use of this new transportation system. Rubber-wheeled vehicles are also used in development, production drilling, and loading. In December 1958, the management of the Luossavaara Mine decided to cut the costs of waste-rock haulage. The system of waste transport was the conventional one of shuttle car, rail haulage, and skip hoisting. After consideration of other methods, it was decided to re-equip the mine completely for a system of trackless transport. Results show that mining costs per ton of ore were reduced by 27 per cent, and mining costs per ton of waste were reduced by a spectacular 80 per cent. The new system has proved to be more flexible, and ore grading has been simplified since there is no longer any mixing in ore passes and chutes.

Broken Hill Mines-1968, edited by M. Radmanovich and J. T. Woodcock, published by The Australian Institute of Mining and Metallurgy, Melbourne, 613 pages. Price $A15. This volume, containing some 65 technical papers, was produced for the 1968 annual conference of the Australasian Institute held at Broken Hill to mark the 75th Anniversary of that Institute, founded at Broken Hill in 1893. That conference also coincided with the 85th Anniversary of the discovery of the Broken Hill mining field. This closely reflects the position in this country, where the Witwatersrand gold fields were discovered in 1886, and our South African Institute of Mining and Metallurgy will in March, 1969 be celebrating the 75th Anniversary of the founding of the forerunners of our Institute. There is a comprehensive report of the geology of the Broken Hill area and the mineralogy of the ore body, and there are reports on the mining methods and the metallurgical procedures which have been developed over 85 years of operation of one of the great mining fields of the world. The value of most of the papers is enhanced by a large number of illustrations and photographs. An early section covers the academic and practical aspects of rock mechanics, prospecting, and exploration techniques are described in some detail. A third of the volume is devoted to mining, with papers on 26 aspects. The breadth of the coverage gives an indication of much specialized development, research, and consequent maturity in all departments. The detailed treatment of metallurgical aspects such as sizings of individual mineral particles throughout the milling stages and the development of an on-stream analysis system for lead will commend this volume to the specialist. The committee responsible for the production of this volume, which brings together much information previously only to be found after searching through numerous publications, are to be congratulated on a well produced comprehensive review of many aspects of the mining and metallurgical fields. H.B.

Reviewer: R. Graham The chemistry of gold extraction by John Marsden and lain House. Elis Horwood Series in Metals and Associated Materials. Chichester, Elis Horwood. £80. The chronology has been well researched, and the book defines al the milestones. It is a pity that there is no map of the early gold finds in South Africa, which would have offered a comparison with those shown of Australia and the USA. Nevertheless, the &apos;Pre-cyanidation, Cyanidation and Technical Development&apos; eras fall logically into place, and reflect on the advances in social history and civilization, as well as in technology.

Jan 1, 1992

By M. Reuter

This paper gives an overview of some criteria for the selection of processes for the recovery of lead and zinc from various raw materials and/or intermediate products. A glossary of possible processes and process variants, is presented and discussed, as well as the way in which these are interlinked. Recent developments in metallurgical process synthesis are also discussed, and the results produced by an eco-techno-.economic synthesis procedure for process routes in zinc metallurgy are given briefly. The way in which such a synthesis can complement a life-cycle assessment (LCA) of zinc-producing technologies is also described.

Jan 1, 1997

By R. Guest

Reichert cone concentrators are used successfully in many applications, but have as yet not found favour in the gold mining industry on the Witwatersrand, because, for optimum operation, the cones need to have specially designed feed-preparation and circuit details. In addition, good liberation of the valuable minerals is essential. Gravity tests, in which a pilot plant was used on refractory gold ore, showed that 94 per cent of the gold could be extracted after gravity concentration and preferential grinding, roasting, and cyanidation of the concentrate, whereas 96 per cent could be extracted by flotation followed by the same preferential treatment. However, the capital and operating costs for gravity separation are expected to be considerably lower than those for flotation.

Jan 1, 1982

By D. Moradkhani, S. M. Javad Koleini, M. Abdollahy, F. Soltani

"The objective of the study was to determine the type and distribution of rare earth elements (REEs) in the phosphate flotation concentrate from the Esfordi flotation plant in central Iran, in order to understand their leaching behaviour. Samples of the concentrate were prepared and analysed using XRF, XRD, ICP, and EMPA. The Ce, Nd, La, and Y contents were 5608, 2227, 1959, and 679.7 mg/kg, respectively. The main REEbearing minerals in the concentrate are fluorapatite, monazite, and xenotime. Apatite is the chief mineral of the concentrate and the ratio of apatite to monazite is greater than 60. From EMPA analysis, monazite contains a much higher proportion of REEs than apatite, but more than 50% of the REE content of the concentrate is in apatite, as this is the main mineral constituent of the concentrate. During the leaching of REEs in the phosphoric acid production process, more than 99% of the total rare earth values report to the large amounts of phosphogypsum (CaSO4·2H2O) formed during the dissolution reaction. Accordingly, two process options are suggested for treating the Esfordi concentrate. In the first option, the concentrate is treated with 98% H2SO4 at 200–300°C. After digestion and water leaching, phosphorus and REEs are precipitated out of solution. In the second option, the concentrate is treated in a pre-leach stage. The process residue from the pre-leach stage is then subjected to acid digestion at elevated temperature for phosphoric acid production.IntroductionThe rare earth elements (REEs) comprise a set of 17 chemical elements in the periodic table, specifically the 15 lanthanides plus scandium and yttrium. REEs and alloys that contain them are used in devices such as computer memory, rechargeable batteries, cell phones, catalytic converters, magnets, fluorescent lighting, and many more (Krishnamurthy and Gupta, 2004). China supplies about 94% of the REE demand, with the remaining 6% coming from Russia and Estonia, the USA, India, Malaysia, and Brazil (Zhanheng, 2011). Increased industrial development in China has prompted the Chinese government to limit annual export quotas to approximately 35 kt of rare earth oxides (REOs), while non-Chinese annual demand is expected to reach 80 kt by the year 2015. This constriction of supply is being met by the development of many new rare earth mining projects, each of which has its own unique mining and processing challenges (Jordens, Cheng, and Waters, 2013). One of these projects is the Esfordi phosphate project, which is located in Yazd Province in central Iran. The concentrate from the Esfordi flotation plant contains 1.2–1.5% REEs."

Jan 1, 2017

Notices Competition for Student Members of the South African Institute of Mining and Metallurgy Each year the Institute offers a prize (or prizes should the entries warrant it) of up to Rl00 for the best paper or dissertation on a topic appropriate to the interests of the Institute. The competition is open to all Student Members of the Institute. NEW PUPLICATION Bougainville-the establishment of a copper mine. St. Kilda (Australia), &apos;Foundations&apos;, 1973. The editors of Foundations, Australia&apos;s journal of architecture, engineering, and construction, are preparing the above book for publication late in 1973. The story of Bougainville is told and illustrated NIM REPORTS Report No. 1503 Fast-neutron-activation analysis for the determination of oxygen m rock sam ples. Report No. 1514 The determination by X-ray-fluorescence spectrometry of minor amounts of niobium and tantalum in geological materials. Report No. 1530 AUREOL - an X-ray-absorption analyser for the determination of the uranium on loaded resin in ionexchange plants. Report No. 1534 The determination, by atomicabsorption spectrophotometry, of noble metals in the presence of sodium, barium, or sulphate ions. A comparison of uranium and lanthanum as &apos;releasing agents.

Jan 10, 1973

By D. Duncanson, R. J. Davidson

The elution of gold from activated carbon using deionized water by R. J. DAVIDSON, M.Sc., Ph.D. (Rhodes) (Visitor) and D. DUNCANSON, H.N.C., B.Sc. Hons. (Strathclyde) (Visitor) The pretreatment of gold-loaded activated carbon with a relatively strong sodium cyanide solution prior to elution with deionized water at 90 to 125°Chas been shown to have a most beneficial effect on the elution of gold. The findings emphasize the important role played by the calcium cation and the hydroxyl anion in effecting efficient elution of gold. The elution of the relatively unstable complexes of silver and base metals with cyanide was also significantly affected by the ratio of the sodium cyanide to sodium hydroxide in the reagents used in the pretreatment stage. It was demonstrated that the use of 0,5 bed volume of a pretreatment reagent comprising 10 per cent sodium cyanide stabilized with I per cent sodium hydroxide for safety reasons resulted in a virtually 100 per cent recovery of adsorbed gold, silver, and base metals on subsequent elution with deionized water. The elution procedure takes a relatively short time, about 14 hours at 90°C (7 bed volumes) or 3 hours if pressure elution at 125°C (4 to 5 bed volumes) is used. Because the mechanism of elution after pretreatment entails the shifting of a physical rather than a chemical equilibrium, the higher the gold loading on the activated carbon, the more efficient is the elution procedure. When compared with other elution procedures, the proposed method appears to have several economic advantages.

Jan 7, 1977

By D. F. Malan

Considerable practical knowledge and effective use of empirical evidence is required in the design of tunnel support systems. In many instances, it is unclear how individual support elements interact with fractured rock and which elements of the support system are critical in controlling and containing the movement of material proximate to the excavation. The present paper outlines a displacement discontinuity approach that allows the coupling of surface constraints, in the form of liner or mesh material, to an explicit representation of time-dependent rock discontinuity creep movements. The method is illustrated for a simple square-shaped tunnel profile in which the fracture zone is mobilized by an imposed stress field. A crucial aspect of the model is the computational treatment of the coupling between the liner material and there presentation of the fractured rock mass. This allows the response of the liner material to be assessed quantitatively in terms of the possible reduction of movement in the rock mass. The importance of installing the liner timeously after the excavation is formed is illustrated in a specific example. A number of computational difficulties in simulating liner-rock interaction mechanisms are identified.

Jan 1, 2008

By L. Woollacott, R. P. King

This paper presents data collected from full-scale plants in order to verify the predictions of a new simulator of CIP or CL operations. Good agreement was found between the experimental data and the simulator predictions. The simulator is able to predict the effects of many of the complex operating phenomena in GIP and CL plants that previous simulation techniques could not describe. This is illustrated by predictions of how factors, such as the manner of carbon transfer, concurrent leaching, and gold loading on eluted carbon, can affect the performance of an adsorption plant.

Jan 1, 1990

The inherent weakness of the Zincor and similar iron removal processes is the relatively high undissolved zinc loss associated with the iron residue. High soluble zinc losses also occur due to poor filterability of the iron residue even though it may be limited to intermittent events. This work focussed on defining the optimum operating window for the Zincor iron removal process where iron is mainly removed in the form of amorphous, intermediate iron phases such as schwertmannite and ferrihydrite. In terms of the main operating conditions, optimum filterability was achieved under the following conditions: pH of 3.0, temperature as high as practically possible (70C), at least 25 kg/m3 seeding, and a retention time of at least 4 hours. When increasing the temperature from 60C to 70C, the required residence time decreased by almost 50%. Undissolved zinc loss was also reduced from 8% to between 2% and 3% by using a basic zinc sulphate/zinc oxide mixture as neutralising agent to effect iron removal.

Jan 1, 2003

By L. Dison

This technical note is issued in two parts, as follows: Part I, after a brief introduction, discusses the value of patents and the law of patents, including patent applications and the exploitation of inventions. This is followed by some comments for the benefit of would-be inventors and potential users of patents. Part II, which will appear in the February issue of this Journal, focuses on the mining industry and then discusses views on patents that were Quoted in Part I. The last section makes recommendations as to how II1ventors and users (including mining authorities) should handle patents.

Jan 1, 1992

By V. M. Lovell, N. P. Finkelstein

Fundamental studies of the flotation process: The work of the National I nstitute of Metallurgy N. P. Flnkelsteln and V. M. Love Presented at the Colloquim on Flotation, March 1972, and published in the Journal, July, 1972. AUTHORS&apos; REPLY TO DISCUSSION In his contribution to our paper Dr Lloyd makes two criticisms: The first criticism, as we interpret it, is that the agglomerate flotation process that we described is not really necessary because previously described processes effect almost the same results or could be made to give the same results by including sufficient paraffin in the reagent combination.