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O.F.S. Branch Proceedings of the Annual General Meeting Held on Wednesday, 4th August, 1976 Mr G. J. C. Young (Chairman) was in the Chair. Also present was Dr R. E. Robinson, President of the South African Institute of Mining and Metallurgy. NlM reports Report no. 175 Copper extraction by leaching magnetites from Palabora Mining Company. (12th Apr., 1967; re-issued Jun. 1976) Report no. 1632 A mineralogical examination of beach-sand concentrates from a pilot plant at Richards Bay. (20th May, 1974; re-issued Jun. 1976.) Report no. 1825 The full automation of a Philips 1220 X -ray spectrometer. A Philips 1220 X-ray spectrometer (semi-automatic) Report no. 1840 The spectrophotometric determination of total uranium in silicate ores and leach liquors by use of bromo-PADAP. Report no. 1841 The determination of aC1;d-soluble uramum in silicate ores and solutions. AS & TS National Award The Associated Scientific and Technical Societies of South Africa has decided to make two National Awards this year. These awards, given in recognition of outstanding contributions to science and the application of science, will be made to Dr T. L. Wadley for his invention of the Tellurometer system of distance measurement and to Mr H. Scheffel for his design of the High Stability Bogie. Treatment of waste water A major international symposium, organized jointly by the Water and Environment Group of the Society of Chemical Industry and the Environment Group of The Chemical Society of London, will be held in London in 1977. Down-the-hole drilling Atlas Copco announces the publication of a revised and enlarged version of one of the booklets in their series 'Mining and Construction Methods'. This 40-page booklet is entitled 'Down-the-hole drilling with COP drills'.

Jan 10, 1976

1. New Publications Tin and its uses no. 140. Greenford (England), International Tin Research Institute, 1984. Catalogue. English translations of German standards 1984. Berlin, Beuth Verlag GmbH, 1984. Mining and mineral processing operations in Canada 1983. Ottawa, Canadian Government Publishing Centre, 1984. $6.00. Canadian mineral deposits not being mined in 1983. Ottawa, Canadian Government Publishing Centre, 1984. $6.00. 2. Mintek Publications Report M42D The recovery of tantalite and cassiterite from a bulk sample of pegmatite supplied by Falconbridge Explorations Limited. (First issued 1982.) Report M46D Tests on the nature and reduction of the chlorine in fluorspar concentrate from the western Transvaal. (First issued 1982.) Report M58D An electrochemical process for the recycling of tungsten carbide scrap. (First issued 1982.) Report M59D Testwork on samples of oxidized ore from the Potgietersrus Prospect. (First issued 1982.) Report M60D The production of electrolytic manganese dioxide from furnace sludge. (First issued 1983.) Report M64D Isotope-source neutron-activation analysis for the determination of manganese in bulk samples. (First issued 1982.) Report M128 The determination of cyanide in hydrometallurgical process solutions and effluents by ion chromatography. Report M132 Mineralogical parameters influencing the acid-bacterial leachability of low-grade nickel ores. Report Ml34 The NIMROC reference materials: revised values for thorium, yttrium, lanthanum, and the rare-earth elements. ReportM140 The effect of physical and chemical factors on the corrosivity of a synthetic mine water. Report Ml44 The development of standard procedures for the evaluation of magnetite for use in heavy-medium separation. Report M145 A preliminary study of the mineralogy of the nickel occurrence at Mabilikwe Hill, northern Transvaal.

Jan 1, 1984

By N. Watson

Historically the insurance industry's involvement in any project has been relatively late in the process. Often it was a case of the last item to be ticked off the checklist has been to ensure that the insurance is in place. However, in more recent times insurers have imposed more restrictions on the cover they are prepared to provide, which has in some cases necessitated a change in the contracting structure to accommodate the insurance policy(ies). In addition, changing contractual practices have changed the allocation of risk between the various parties involved. This calls for a more proactive approach to the design and implementation of an insurance program for both the construction and operational phases of any resource project. This paper explores how a risk managed approach to the design and implementation of an insurance program for a resource project can align itself with current management approaches to project development. From the authors' experience, this approach is best adopted early on in the project (often in conjunction with the bankable feasibility study) and follows AZ/NZS4360 to objectively examine and compare a wide range of risk exposures of the project in a time-effective manner across the following areas: ? personnel; ? environment; ? general management; ? compliance - legislation, systems, protocols; ? asset management; ? change management; ? financial impacts to the organisation; ? products/services; ? service delivery; and ? technology. Having identified and then analysed the risk exposures according to common consequence and likelihood ratings the next step is to develop a risk map of all considered exposures. The true value of this approach lies in the development and implementation of a risk treatment plan for identified exposures where the exposure is unacceptable. The plans will lead to the optimal solution to the appropriate risk prevention, risk mitigation and risk transfer options available. This paper also examines other benefits to the project that may arise from adopting a risk managed approach in addition to the ability to design an insurance program which recognises the exposures and the ability of the organisation (and other project parties) to retain risk.

Jan 1, 2007

By W. F. Nothard, J. R. C. Hill

The Rhodesian approach to the vegetating of slimes dams by J. R. C. HILL, B.Sc.(Agric.) (Visitor) and W. F. NOTHARD (Visitor) To prevent environmental pollution from mine dumps, it is necessary to stabilize them either mechanically or biologically. In the long term biological stabilization is more attractive because of its permanent nature. Initially, the basis of stabilization is in the correct siting and construction of the dump. The main toxic factors influencing plant growth on Rhodesian mine dumps are arsenic, antimony, copper, nickel, a high ratio of magnesium to calcium, excessive soluble salts, high pH, and Iow macronutrient content. Root-growth studies in culture solution and pot experiments are used to supplement information on the suitability of plant material obtained from replicated field trials on mine dumps. In addition to the selection of plants for toxic tolerance, it is advisable to provide multiple-layer protection with trees, shrubs, and grasses. Further, a range of different plant species gives greater biological stability. Protection must be provided for young plants against wind erosion and the abrasive effects of windblown sand. Planted wind breaks are preferred to mechanical forms; windrows of garden refuse make good wind breaks and at the same time introduce organic material to the dump and provide a good environment for seedling establishment. The use of artificial fertilizers and sewage effluent is recommended to hasten the development of a complete and protective plant cover.

Jan 12, 1973

1. Recent publication Iron and steel works of the world. Worcester Park (England), Metal Bulletin PLC, 1987. 9th edition, 728 pp. £94.75 by air mail.2. Canadian publications Mining and mineral processing operations in Canada, 1987. Mineral Bulletin MR 216. $15. (Obtainable from Printing and Publishing, Supply and Services Canada, Hull, Quebec, KIA 059 Canada.) Peat producers in Canada, 1986 directory, by M. Prud'homme. MRI 87/7 Canadian mines: Perspective from 1986. Reserves, production capability, exploration, development. Mineral Buletin MR 215. $9.95. 3. Mintek publications Report M313 The testing of abrasion resistance in pipeline materials, by D.P. Enright. Nov. 1987. 36 pp. Report M328 The installation and commissioning of a Hilger Monospek D500 scanning monochromator, by A.E. Watson. Sep. 1987. 11 pp. Report M331 The design and operation of hot-air dryers for the drying of granular activated carbon. Nov. 1987. 30 pp. Report M338 Ore microscopy, image analysis, and the extractive metallurgy of sulphide minerals-an overview. Nov. 1987. 14 pp. Report M339 The determination, by flow-injection analysis, of sulphate in solutions containing chromium(I/I) and iron(I/I). Nov. 1987. 11 pp. Report M222D The simultaneous determination of common anions by ion chromatography, by A. Cameron and C. Pohlandt. Oct. 1985, reissued May 1987. 10 pp. Report M227D The spectrophotometric determination of silica in metallurgical-grade fluorspar, by M. Solomons. Nov. 1985, reissued Jun. 1987. 9 pp. Report M229D The determination of metalic iron in prereduced iron ores, by R. Lownsbrough. Dec. 1985, reissued Jun. 1987. 7 pp. Report M252D The spectrophotometric determination of bismuth in sulphide materials, by M. Solomons. Mar. 1986, reissued Jun. 1987. 13 pp. Special Publication no. 12 Platinum in South Africa, by A.M. Edwards and Silk. 1987. 64 pp. Illustrated in colour. R30 ( Africa), US$30 (other countries). 4. Journals of interest Industrial Minerals. London, Metal Bulletin Journals Ltd. Tin and its uses no. 154, Nov. 1987.

Jan 1, 1988

Primary roof support represents the first line of defence against rockrelated falls of ground in underground mines, and improper utilization or misunderstanding of the applicability and behaviour of primary support can be costly from a safety standpoint. This is a major concern for underground mines, as roof support is the single most costly expense from a mining operational perspective. This is further backed by the evidence that, in the USA, hundreds of injuries and fatalities still occur each year because of rib, roof, and massive roof falls. Additionally, the fully-grouted passive rebar, fully-grouted tension rebar, and resin-assisted mechanical anchor bolts, which constitute a large portion (89%) of the 68 million bolts installed each year in underground mines in the USA can vary in cost quite dramatically. To mitigate this concern a study was conducted in 2010 by the National Institute of Occupational Safety and Health, in conjunction with Southern Illinois University of Carbondale, to assess the performance of primary roofbolts in underground coal mines for improved safety and cost. This was accomplished using underground roofbolt monitoring solutions, field data, and numerical modelling to better understand the quasi-static behaviour of underground coal mine roofs and the response behaviour of the bolts. In particular, over 170 instrumented extensometers, closure meters, shear meters, fully-grouted passive rebar, fully-grouted tension rebar, and resin-assisted mechanical roofbolts were installed at three coal mines across the USA. Of these three mines, two used the room and pillar extraction method and the other used the longwall extraction method. There was no evidence to indicate a difference in performance of the active primary roofbolts compared with the passive primary roofbolts. Additionally, in the initial loading phase, the active bolts showed no difference in loading, indicating that tension bleed-off is of more of a concern than originally thought. Lastly, for the initial computer modelling studies, challenges still remain in obtaining a good match to the in situ bolt measurements and replicating the discontinuous roof rock and in situ bolt behaviour over time.

Jan 1, 2014

By S. Kamalpour

It has been observed that the productivity of ferromanganese furnaces, and the stability of metal and slag compositions, vary considerably according to the type of coke used as reductant. However, the desired properties of coke for optimum furnace performance are not well understood. In this investigation, the behaviour of four cokes, which exhibited a wide range of performance in ferromanganese production, was investigated by means of laboratory simulations of reducing conditions in the furnace. The Stationary Charge in Controlled Environment (SCICE) technique was used to simulate the conditions in the furnace shaft. Batches of raw materials, mixed in the same proportions as used in practice, were heated at fixed rates to 900, 1100 and 1300°C then cooled. The mass loss was used as a measure of the degree of reduction. Conditions in the lower part of the furnace were simulated by means of melt-reduction experiments in which lumps of coke were drilled out to form crucibles in which enriched ferromanganese slags were reduced at 1500 and 1550°C then cooled. An examination of the raw materials and the cooled, reacted charges using a variety of analytical and characterization techniques enabled the sequence of reaction and changes in morphology of the raw materials to be followed. This enabled an understanding of the behaviour of the cokes during reduction to be developed, which was then used to explain the observed performance of the cokes in practice. By relating the observed behaviour of the cokes in the laboratory tests to measurable properties of the unreacted cokes and to their observed performance in practice, it was shown that to achieve high productivity and good furnace performance, cokes should be selected to have moderately high reactivity towards CO2 (Boudouard reactivity) relative to conventional iron blast furnace cokes.

Jan 1, 2004

By F. L. D. Cloete

he above article by E. Barnea, which appeared in the January 1978 issue of the Journal (vol. 78, no. 6, pp. 143-145), calls for comment in view of the author's claims for the novelty of his proof. He states in his article that its main purpose is to give a mathematically acceptable proof by induction of the 'recently proposed' equation

Jan 1, 1978

By E. Matinde, S. L. Msibi

"The robust nature of alumina refractory materials presents opportunities for their in-process reclaiming and re-use in non-critical applications. Virgin refractories can be substituted with different quantities of reclaimed materials without compromising the quality of the refractory products. In this study, the effect of reclaimed bauxite on andalusite-containing refractory castables for tundish applications was investigated. The recycled bauxite was formulated in different proportions to replace virgin andalusite in the castables. Standard tests were conducted to evaluate the physical, physicochemical, and thermochemical properties of the formulated products. Static corrosion tests were conducted using tundish slag in order to simulate the actual operating conditions. The results show that the standard flow behaviour, open porosity, and bulk density of samples containing up to 22 mass% reclaimed bauxite were comparable to those of the reference castable. However, high-temperature properties such as static corrosion at 1400°C and hot modulus of rupture at 1500°C indicated that there is an upper constraint to the amount of substitution. The study demonstrated direct potential savings of up to 10% when the reclaimed alumina replacement ratio was increased to 22 mass%. IntroductionAlumina-based refractories can be classified into low-alumina, containing less than 50% Al2O3, and high-alumina or bauxite, containing between 50 and 90% Al2O3. High-alumina refractories have widespread applications in high-temperature metal extraction processes due to their outstanding thermochemical and thermomechanical properties and stability (Rebouillat and Rigaud, 2002; Frulli, 2016). The typical chemical composition of refractory-grade bauxite consists of 85–90 wt.% Al2O3, 5–10 wt.% SiO2, 1–2wt.% Fe2O3, 3–4 wt.% TiO2, 0.4–0.8 wt.% CaO + MgO, and 0.20–0.8 wt.% K2O + Na2O (Nyoka et al., 2013). The thermochemical and thermomechanical properties of bauxite-based refractories rely principally on the conversion of the contained silica and alumina to the highly stable corundum (?-Al2O3) and mullite (3Al2O3· 2SiO2) phases (Rebouillat and Rigaud, 2002; Hill and Sehnke, 2006; Garbers-Craig, 2008; Frulli, 2016)."

Jun 1, 2019

By D. Duncanson, R. J. Davidson

The elution of gold from activated carbon using deionized water by R. J. DAVIDSON, M.Sc., Ph.D. (Rhodes) (Visitor) and D. DUNCANSON, H.N.C., B.Sc. Hons. (Strathclyde) (Visitor) The pretreatment of gold-loaded activated carbon with a relatively strong sodium cyanide solution prior to elution with deionized water at 90 to 125°Chas been shown to have a most beneficial effect on the elution of gold. The findings emphasize the important role played by the calcium cation and the hydroxyl anion in effecting efficient elution of gold. The elution of the relatively unstable complexes of silver and base metals with cyanide was also significantly affected by the ratio of the sodium cyanide to sodium hydroxide in the reagents used in the pretreatment stage. It was demonstrated that the use of 0,5 bed volume of a pretreatment reagent comprising 10 per cent sodium cyanide stabilized with I per cent sodium hydroxide for safety reasons resulted in a virtually 100 per cent recovery of adsorbed gold, silver, and base metals on subsequent elution with deionized water. The elution procedure takes a relatively short time, about 14 hours at 90°C (7 bed volumes) or 3 hours if pressure elution at 125°C (4 to 5 bed volumes) is used. Because the mechanism of elution after pretreatment entails the shifting of a physical rather than a chemical equilibrium, the higher the gold loading on the activated carbon, the more efficient is the elution procedure. When compared with other elution procedures, the proposed method appears to have several economic advantages.

Jan 7, 1977

By P. den Hoed, J. Nell

Tests were conducted on samples of rutile, titaniferous slag and ilmenite; each sample was mixed with coke and chlorinated in a bubbling fluidized bed at 1000°C. Profiles of the rates of chlorination of species were constructed from chemical compositions of the bed residues at different durations. From the start FeO and MnO are chlorinated quickly and all but entirely in a fraction of the time it takes to chlorinate all the TiO2. When the level of FeO is significant, as in slag and ilmenite, FeO is chlorinated faster than TiO2is. In these oxides, there is an inverse relationship between the rates of chlorination of FeO and TiO2during this first stage; the relationship, moreover, correlates linearly with the initial percentage of FeO in the oxide. We identify three stages in the chlorination process; a first, in slag and ilmenite, when FeO is being chlorinated; a second, when TiO2is most readily chlorinated; and a third, towards the end, when the levels of TiO2are reduced to those of other species. The rates at which individual species are chlorinated are analysed in terms of their appreciation or depreciation with respect toTiO2

Jan 1, 2003

1. Recent publications Canadian minerals yearbook 1986. Review and outlook. Mineral Report 35. Available from Printing and Publishing, Supply and Services Canada, Hull, Quebec KIAOS9, Canada. $44.70. The 1987 Sigma cataloge. SI. Louis (USA), Sigma Chemical Co., 1986. 1736 pp. Der Maschinenschaden. Munchen(G. rmany), Koningstrasse 28. Metallurgicalworks in Canada primary iron and steel 1987. Mineral Bulletin MR 214. Available from the above address at $6.60 per copy. Annual report 1986. Oxbridge, International Research Institute, 1987. Canadian iron ore industry statistics, 1986, by B.W. Boyd and A. Cadieux. Publication MRI 87/6. Micromedia Limited (Document Delivery, 165 Hotel de Ville, Place du Portage 2, Hull, Quebec J8X 3X2, Canada). Tin and its uses no. 153. Oxbridge (England), International Tin Research Institute, 1987. This issue includes articles on can-making, titanium-tin alloy, coppernickel2. New journal Pergamon are producing a new journal, entitled Minerals Engineering, which they describe as 'an international journal devoted to innovation and developments in mineral processing and extractive metallurgy'. 3. Mintek publications Report M298. The effect of flocculant additions to the leaching solution on the kinetics of the oxidative dissolution of sphalerite, by F.K. Crundwell. Report M304. The smelting of ilmenite in a d.c. transferred-arcplasma furnace with a molten-anode configuration, by AD. Brent. Jut 1987. 17 pp. Report M312. The reactions of some thiol collectors at noble-metal and pyrite electrodes, by D.R. Groot. Jut 1987. 21 pp. Report M321. The determination of molybdenum, arsenic, and uranium in activated carbon by X-rayfluorescence spectrometry,by A.M.E. Balaes and G.J. Wall. Aug. 1987. Report M321. The determination of molybdenum, arsenic, and uranium in activated carbon by X-rayfluorescence pectrometry, by A.M.E. Balaes and G.J. Wall. Aug. 1987.

Jan 1, 1988

By A. A. Angelov

This paper presents a unique method of monitoring the effectiveness of the planning process as well as the execution of mine plans. The method primarily determines the degree of deviation from the original mine plans by comparing actual mined areas to initially planned mining areas. The performance of mining operations is also measured by comparing actual and planned tonnages for a particular period. Once the degree of deviation from mine plans has been established the cause/s of the deviation can be determined through a simple fault tree analysis. Accurate identification of the reasons of deviation can aid the mine in selecting possible methods to correct the deviation. It is, however, beyond the scope of this paper to discuss the methods employed in correcting such deviations, as each mining operation will have unique causes of plan deviation and methods of remedying them. Deviations from the plan greatly affect the yields obtainable, which in turn affects the life of mine, thus having negative economic and financial implications. Accordingly, this paper presents a project management method which aims to reduce risk by improving planning systems to ensure optimum overall extraction of coal reserves.

Jan 1, 2010

Palabora Mining Company is operating a copper block cave mine in the Limpopo Province of South Africa. The mine was developed in the late nineties with a target ore reserve of 220 million tonnes of carbonatite at 0.69% copper. At 30,000 tonnes per day the operation had an estimated life of mine of approximately 23 years. Cave induced open pit side wall failure occurred in late 2004 with 130 million tonnes of waste reporting to the bottom of the open pit. This failure resulted in potential sterilization and dilution of the ore reserve and subsequent reduction in life of mine. Physical and numerical modelling indicated potential losses of up to 30% of the original ore reserves. Cave Management tools based on throughput principles are utilized to manage the failed waste ingress and ensure an optimum life of mine. Extracting the maximum rate possible, as soon as draw points are commissioned, with the view of achieving the highest production in the short term, is any mining operation?s goal as more money is required sooner. This approach, of course, improves the cash flow but presents a risk in the cave propagation profile as overall draw control is compromised. At Palabora it is evident from a Mineral Resource Throughput Management (MRTM) point of view that maximum production in the short term is not the solution. If high production rates are achieved and the profile of the cave is not manage correctly, this results in failed waste reporting to draw points earlier with adverse effects on grade. This would effectively and significantly shorten Palabora?s Life of Mine. The applications of good MRTM principles are required to assist the value chain for sustained profitability. The process commenced with change management paving the way for a better understanding and a holistic view for all role players.

Jan 1, 2007

By R. J. Davidson, V. Veronsee

Some of the parameters affecting the elution of gold from freshly loaded activated carbon using pure water as an eluant were studied. The procedure involved pretreatment of the gold-loaded activated carbon with a strong reagent of sodium cyanide and sodium hydroxide, followed by elution of the gold with water. Gold-loaded carbon obtained from three different sources was studied. It was shown that the elution temperature was the most critical parameter, and column operation at I !OCC (gauge pressure of 50 to 100 kPa) is suggested. The effects of variations in the concentration of sodium cyanide required for the pretreatment of loaded carbon and of variations in elution flowrate were also investigated. Both these parameters were found to have only a marginal effect on the efficiency of gold elution. The investigation also indicated that gold-elution rates were affected to a considerable degree by the particle size of the carbon concerned. Higher elution flowrates could be used when carbons of finer particle size were eluted. A modified eluate-collection procedure was also developed during the course of the investigation. Oven-drying of the loaded carbon was shown to have little or no effect on the efficiency of the subsequent gold elution. The calcium and silica contents of the various carbon samples were also determined. It was immediately evident that the calcium content was very considerable in the case of loaded carbons originating from carbon-in-pulp operations. Calcium concentration was particularly high where air agitation had been employed in the carbon-contacting circuit. To some degree, the calcium build-up explains the serious carbon fouling taking place, resulting in a decreased efficiency of gold adsorption. The fouling problem was found to be less severe when mechanical agitation was used. No poisoning by calcium carbonate was observed where the pregnant solution had been acidified before it was contacted with the carbon.

Jan 1, 1979

By D.W. Gentry

1. Book reviews Mine investment analysis, by D.W. Gentry and T.J. O'Neil. Society of Mining Engineers (Caler No. D, Litleton, CO 80127, U.S.A.). US$50.Finance for the mineral industry, by C.R. Tinsley, M.E. Emerson, and W.D. Eppler. Society of Mining Engineers (Caler No. D, Litleton, CO 80127, U.S.A.). US$50. 2. Mintek reports The folowing reports are available from the Council for Mineral Technology, Private Bag X3015, Randburg, 2125 South Africa. They are free of charge to South African addressees, but there is a handling charge of US$25 per copy for reports sent to overseas destinations. Report M291D Removal of pebbles and pre-crushing of selected feed material in autogenous milling, by D.I. Hoyer. First issued Nov. 1986, reissued Apr. 1988. 16 pp Report M350 A survey of miling and mil-lining practice on South African gold mines, by M.S. Powel. Jun. 1988. 30 pp Report M356 The distribution of cobalt in mineral constituents of the Merensky Reef and UG-2 Chromitite Layer of the Bushveld Complex, by G. Smits. Jut. 1988. 13 pp Report M359 The development of a mobile laboratory for the monitoring of gold and cyanide in alkaline cyanide solutions, by R.V.D. Robert, C. Pohlandt-Watson, H.J. du Plessis, and G.D. Marshal. Aug. 1988. 17 pp. Productivity and technology The Metalurgical Society and Geselschaft Deutscher Metalhuten-und-Bergleute are sponsoring the Symposium on Productivity and Technology in the Metalurgical Industries, which is to be held in Cologne, West Germany, from 17th to 22nd September, 1989.Non-ferrous smelting Commemorating a centenary of lead smelting and refining at Port Pirie, the Conference on Non-ferous smelting wil be held at Port Pirie from 17th to 20thSeptember, 1989. International trade fairs From 20th to 26th May, 1989,4 major international trade fairs wil be held in Disseldorf, West Germany.

Jan 1, 1988

By J. C. van Dyk

The objectives of this study were firstly to characterize and quantify the inorganic material in the Secunda gasification feedstock. Secondly, the effect of washing on coal properties and sulphur content was investigated. Coal from a single source and a coal blend from 6 different mines were tested. Composite samples were visually sorted by a geologist in the groups containing roof, floor, C-shale, pyrite, carbonates and siltstone material. Inorganic mineral types from the single source and coal blends were characterized separately. Characterization results indicate that the average mineral matter distribution (mass %) of the coal tested was as follows: carbonates (6%), carbon-shale (19%), pyrite (12%), roof (18%), floor (46%) and siltstone (22%). The roof, floor, pyrite, carbon-shale, carbonates and siltstone in the single source and coal blend have similar chemical properties and characteristics, except for the ash melting temperatures of pyrite and kaolinite in the siltstone. By implementing selective mining and increasing mining management practices, the percentage discard in the run of mine coal can be significantly reduced, by up to 45%, if the mining of roof and floor material can be avoided. No significant impact of mining practices on sulphur content is expected in this case due to the low concentrations of sulphur in the roof and floor material. In summary, selective mining practices will probably result in almost45% decrease in the discard content in the run of mine to gasification, an increase in the carbon content from 55.0% to 58% (air dry basis) and a decrease in sulphur content from 1.1% to 0.9% (air dry basis). It is clear from this study that the main source of sulphur is not in the high ash-content mineral types (e.g. floor and roof), but in situ in the coal structure. Keywords: inorganic material, effect of washing, roof, floor, pyrite, C-shale, carbonates and siltstone

Jan 1, 2005

By Dr. T. L. F. Muller

INTRODUCTION During the past decade a wealth of knowledge has been acquired about the mechanisms and reactions responsible for the physical properties of metals. In the field of steels, in particular, research of a fundamental nature has enabled us to interpret mechanical properties such as hardness, brittleness, creep strength, etc., in terms of atomic interactions. So rapid has been the development of physical metallurgy in some fields that publications are often outdated by the time they appear in print. The development of new steel products has been rather empirical by nature in the past and only during the past few years have new products been "designed" in terms of known physico-metallurgical phenomena. However, although this is a great stride forward it should be added that the development of a commercially successful product is a far more complicated process. In addition to the physico-metallurgical background this requires consideration of factors such as low production cost, market research and probably most valuable of all, an interested end user to co-operate in the development. This paper deals rather briefly with three of the most recent developments in steels in Britain with which the author has had some association. The main purpose of this is to demonstrate how the improved properties of the new product are based upon established physico-metallurgical phenomena. Generally speaking a commercially successful product of the type described here offers similar properties to that of an existing product at lower cost or has improved properties or features such as greater ease of cold forming, at similar cost. ULTRA-FINE GRAIN STRUCTURAL STEELS The development of higher yield strength structural steels dates back over a considerable number of years and has led to a variety of types. The one described below contains niobium as a grain refiner in an otherwise conventional mild steel matrix. By controlled rolling in a strip mill considerably increased yield strengths are obtained. In Fig. 1 are shown somewhat diagrammatically the relative hardening effects of carbon and manganese on ferrite. It will be seen that strength is enhanced by the solid solution hardening effect of manganese and the pearlite content. An obvious limitation of high pearlite content is a lack of cold workability and weldability. Manganese has to be restricted to low levels for the same reasons. The two other mechanisms which are known to impart higher strength are precipitation hardening and grain refinement. Precipitation hardening is impractical in most cases for structural steels and it is therefore clear that only grain refinement remains as a potentially useful strengthening mechanism.

By J. T. M. Amphlett, C. A. Sharrad, M. D. Ogden, R. I. Foster

"A renewed interest in nuclear power around the world in order to reduce greenhouse gas emissions is going to increase demand for uranium as fuel. This will result in more uranium being mined, which will in turn increase associated environmental pressures, such as fresh water use. A move to lower quality waters containing impurities such as chloride would help alleviate these pressures. In this work, we determined the uptake characteristics of weakly basic anion exchange resin Ps-EDA towards uranium from saline solutions in a dynamic flow column. Breakthrough curves were produced, with suppression of uptake being observed for chloride concentrations above 5 g L-1. Calculated resin saturation capacities at zero and 5 g L-1 chloride are comparable with literature values for strong-base anion exchange resins, and exceed those published for weak-base resins up to 20 g L-1 chloride. Data has been fitted to multiple breakthrough models, with the modified dose-response model most effectively predicting uranium recovery. The results show that the ethylenediamine functionality could be suitable for use in future uranium processing flow sheets where a high-saline lixiviant is used. IntroductionIon exchange (IX) is a key technology in the uranium mining industry and is well established for the extraction of uranium from both acidic and alkaline leach liquors (Edwards and Oliver, 2000). It was first employed in 1952 at the West Rand mine in South Africa (Ford, 1993; Taylor, 2016). H2SO4 and Na2CO3 are the most commonly employed lixiviants used to solubilize uranium in acidic and alkaline leach conditions respectively. The chemistry of these systems causes uranium to form anionic sulphate or carbonate complexes, which can be taken advantage of by anion exchange resins.Another major technology for the extraction and purification of uranium from leach liquors is solvent extraction (SX). This technique involves the extraction of uranium from the aqueous phase into an immiscible organic layer. Although this is a commonly used method, there are major drawbacks to it, including the use of large volumes of flammable solvents, solvent loss, phase disengagement, third phase formation, and the production of problematic degradation products (Veliscek-Carolan, 2016). These problems can be circumvented through the use of IX resins."

Dec 1, 2018

1. Mintek publications The folowing are available from Mintek (Private Bag X3015, Randburg, 2125 South Africa) at R35 (including GST) per copy to purchasers in South Africa and US$30 (including airmail postage) to purchasers elsewhere. Report M402 The preparation of synthetic fusion standards for use in the X-ray-fluorescence analysis of rocks and minerals, by RT. Eddy and J.J. Jacobs. Apr. 1990. 19 pp. Report M405 Slag-metal equilibria in the system Fe-Cr-Si-C-Ca-Mg-AI-O, by R.H. Eric and M. Akyizli. Aug. 1990. 29pp. Application Report no. 8 The development of a process for the recovery of gold from gold-bearing solutions by means of activated carbon or resin in a NIMCIX column. 1990. 19 pp. 2. New publications from Trans Tech The folowing are available from Trans Tech Publications Ltd, Old Post Road, Brookfield VT05036, USA. Efect of iron and silicon in aluminium and its aloys, edited by I. Kovacs. 1990. 450 pp. $124. Martensitic transformations, edited by B'.C. Muddle. 1990. 714 pp. $190. Ferites, edited by C.M. Srivastava. 1989. 2 vols. 1280 pp. $254. Properties and characterization of amorphous carbon films, edited by J.J. Pouch and S.A. Alterovitz. 1990. 714 pp. $152. Synthesis and properties of boron nitride, edited by J.J. Pouch and S.A. Alterovitz. 1990.426 pp. $192. Electronic structure and latice defects in aloys, edited by R. W. Siegel and F .E. Fujita. 1989. 320 pp. $78. 3. A new edition Tomorow's materials, by K.E. Easterling. London, The Institute of Metals (1 Carlton House Terace, London SWIY 5DB, England), 1990. 2nd ed. 170pp. US$29. 4. Books for exploration geologists The folowing books are obtainable from Elsevier Science Publishers, P .0. Box 211, 1000 AE Amsterdam, The Netherlands. Lateritic bauxites, by G. Bardossy and G.J.J. Aleva. 1990. 624 pp. DFL. 295. Platinum-group element exploration, by D.L. Buchanan. 1988. 186pp. DFL 150. Lead isotopes in mineral exploration, by B.L. Gulson. 1986. 246 pp. Dfl. 160. Prospecting and exploration of mineral deposits, by M. Kuzvart and M. B6hmer. DFL. 285. 5. Journal for earth scientists . Ore Geology Reviews, published by Elsevier Science Publishers, P.O. Box 211, 1000 AE Amsterdam, Netherlands. 6 issues per year. Annual subscription DFL 453 including postage.

Jan 1, 1990