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By W. P. C. Duyvesteyn, J. R. Cutland, J. R. L. Russell

In 1970 it was decided to build a large new plant at the Chingola Division of N.C.C.M., Ltd., to treat concentrator tailings and leach residues with a low copper content by a leach-solvent extraction-electrowinning process. In order to assist in the establishment of the design parameters for the new plant, and to study the interaction of this plant with the existing leach-electrowinning plant, mathematical models, formulated as linear programs, have been developed and used extensively. The paper outlines the metallurgy of the plants and describes briefly the way in which the models have been formulated and used. The formulation involved the use of separable programming to form the products of some variables.

Jan 1, 2014

By G. Voiloshnikov, P. Koblova, Ye. Musin

Preg-robbing activity of the carbonaceous matter negatively impacts the process of precious metals recovery from gold-bearing ores and concentrates. In this paper, ore heap leaching (HL) using a blinding agent which inhibits ‘preg-robbing’ is a promising method. A carbonaceous ‘preg-robbing’ gold ore with head gold grade of 1.92 g/t from a Russian deposit was studied. Corg was 1.12%. In accordance with the Irgiredmet technique, preg-robbing activity was 65.3%. Surfactant reagent DN was used as the blinding agent. Column tests on the ore HL were conducted using two options. They were: a conventional flow sheet (Column 1) and a flow sheet with the reagent addition (Column 2). Gold recovery in Column 1 was 55.39% while gold recovery in Column 2 was 68.48%. The test results confirmed the efficiency of reagent DN. Keywords: Carbonaceous ore, organic blanking, preg-robbing, recovery

Jan 1, 2020

By J. Petersen, H. Naderi, M. H. Nikzad, M. Karimi

In this research, the thermodynamic study of sodium persulfate (Na2S2O8) solution in the presence and absence of H2SO4 and Fe3(SO4)3 was done. Eh-pH and equilibrium distribution diagrams were constructed using Outotec HSC Chemistry Software and the main stable ionic species were determined. Also, the mean activity coefficient and Pitzer model coefficients were evaluated. Effects of system composition, sodium persulfate concentration and temperature were investigated. According to the results, HS2O7 -, HS2O8 -, S5O3 2-, S4O3 2-, S3O3 2-, HS- and NaSO4 - are the main stable species in these three systems. Increasing of sodium persulfate concentration resulted in disappearing of SO4 2- and the appearance of NaSO4 -. The main effect of increasing the temperature from 25 to 75oC, is changing the stability regions of HS2O7 -, NaSO4 -, SO4 2- and S2-. From equilibrium studies, it was concluded that at 25 and 50oC, increasing the persulfate concentration results in a 55-60% decrease for HS2O7 - and an 20- 30% increase for HS2O8 -. At 75oC, HS2O8 - becomes the main species and its percentage decreases with increasing the persulfate concentration. Keywords: Thermodynamic, sodium persulfate, activity coefficient

Jan 1, 2020

By F. Hörtkorn, Y. Narainsamy

Rather quietly, a new generation of European norms dealing with earthworks has been developed over the past few years, in particular a part of EN 16907 pertaining to extractive waste. Whereas the majority of the parts deal with routine geotechnical aspects, one part deals specifically with tailings dams. The standard is currently in draft form but if this becomes a European Standard, members of the European Union are bound to comply with the regulations. As such, the standard has the capacity to influence mining in Europe and potentially in South Africa. In this paper we review the standard and compare it to the South African standard on mine residues and the recently published Global Industry Standard on Tailings Management (GISTM). We conclude found that although the European norm makes great strides towards increasing tailings dam safety, there is room for improvement. The current South African standard has served well since its inception, but can be improved by using concepts from the European and global tailings standards.

Jun 2, 2022

By S. Khan, M. Auret

Due to the modernisation of mines, traditional training methods may be supplemented to support the upskilling of supervisors in mines. A project was initiated by the SAMERDI SATCAP programme to demonstrate the “art of possibility” through a modern training methodology. Two exemplar digital supervisory leadership development modules for underground gold and platinum-group metal conventional and modernising mines, were developed for potential uptake by the mining industry. These exemplar modules were exhibited on a digital platform, towards leading and driving mining modernisation. The research adopted a mixed method approach that included a literature review, a review of an existing supervisory leadership development programme, data gathering, a pilot study, and stakeholder validation workshops. The research supported the development of exemplar digitised modules. The two digitised modules were showcased to the industry for potential adoption. Training slides, a facilitator guide, and a training video were developed for ease of use by industry. The training modules are generic and not specific to a particular mine. They may be used by multi-commodity mines, including gold and platinum-group metals, as ‘stand-alone’ modules. They are customisable, through consultation with relevant service providers for specific working environments. The findings indicated that both the traditional classroom training and the new digitised online learning solution offer advantages for supervisory leadership development. Digital learning is not a new concept for supervisors at mines and modern training methods are well-supported by supervisors in the industry. A ‘modernised’ training solution may consider a ‘blended’ learning approach that combines traditional training with digital methods.

Jun 27, 2025

By M. Grozdanovic, D. Marjanovic, M. Ilic

We present a framework for solving the problem of functional compatibility between process control equipment in control centres at underground mines and operator capabilities. The equipment incorporates displays of current ventilation, gas, and fire hazard data, status of alarm and early warning systems, a voice communication subsystem, and facilities for recording and printing ofdata and reports. The layout of the existing control panel is compared with a recommended design. The basic principles of ergonomic design and arrangement of the controls and indicators, as well as ease of use, type of operations carried out with these controls, and operators’ viewing angles are discussed. The objective is to improve the usability of control panels, display boards, and graphic screens so as to enhance the functioning of control centres and optimize control of technological processes in coal mines.

Jun 10, 2024

By C. Bergmann, V. Ross

The concept of underground ore processing, in which valuable ore and waste are separated at a coarse particle size to improve the economics of operations and minimise the environmental impact, seems attractive from a sustainability perspective. Perceived benefits of such an operation include energy and cost savings due to a reduced hoisting load, a reduced footprint of surface operations, and using material for backfill that has not been contaminated by process chemicals. Progress in the South African mining industry in this area has however been below expectation, and opportunities for underground processing in deep, narrow reef operations were therefore explored by an Excel-based simulation with sensor-based sorting (SBS) as concentration technology. Various PGM mining scenarios incorporating factors such as the mining rate, depth of operation, and effects of dilution and particle size on the metallurgical efficiency, were compared. Whilst these initial results can be regarded as indicative only, they have shown that the economics of such an operation are driven by selective mining at significantly higher rates than achievable with conventional methods. Also, the cost of preparing, conveying and placing rock backfill will need to be lower than that of hoisting waste and depositing it on a surface dump. Another aspect to be addressed is whether ore sorting machines would be able to operate under harsh conditions underground and what provision would need to be made to ensure their efficient operation. Further investigations should focus on refining costs, incorporating environmental considerations in the modelling of economics and sustainability, and compare greenfields with brownfield scenarios. Keywords: Ore sorting, hoisting, backfill, mining rate, economics simulation

Jan 1, 2020

By G. L. Dyer, R. D. Alorro, R. E. Browner

A potential new rare earth extraction process has been suggested (Lazo, et al., 2017) (Lazo, et al., 2018) based on converting the rare earth elements to solid phase rare earth oxalates in an oxalic acid leach. Oxalic acid consumption is a significant issue in the process, therefore to improve the viability of this proposed new extraction method, a process to recover oxalate from the leach solution and recycle oxalic acid is required. A review of the literature and confirmation through thermodynamic analysis of the potential options identified precipitation of calcium or ferrous oxalate as the best potential options. The use of metallic iron to both provide ferrous ions as a precipitant and reduce ferric ions in solution would provide the most economical option, however slow kinetics and unreacted iron created significant issues with this process. The direct use of ferrous ions, while faster and more efficient, produced a precipitate with relatively poor solid/liquid handling characteristics and would require an intermediate stage utilising calcium in regenerating the oxalate. Utilising calcium chloride and oxide created very similar precipitates with better physical properties than the ferrous oxalate and that a reasonable proportion of the oxalate could be recovered before neutralisation of the solution induced precipitation of other phases such as iron oxy-hydroxides and calcium phosphate. The produced calcium oxalate was easily converted to oxalic acid and gypsum via immersion in sulphuric acid. It was also found that there is a significant loss of oxalic acid due to factors other than rare earth oxalate precipitation during leaching. This leads to a maximum oxalate recovery in the range of 50 %.

Jan 1, 2020

By R. Asamoah, P. Forson, S. Xu, W. Skinner, M. Zanin

In most auriferous hydrothermal deposits, gold is preferentially associated with pyrite and arsenopyrite minerals, with higher economic gold values noted for the latter and arsenian pyrite minerals. In this paper, surface (Cryo-XPS) and solution (EDTA extraction) analysis were used to characterise pyrite and arsenopyrite minerals under different aqueous conditions involving electrokinetic study and collector interactions to better understand ways of improving the separation of pyrite and arsenopyrite. The evidence showed higher surface oxidation at solution pulp pH values in the range of 4-11 for arsenopyrite relative to pyrite. The observed highest ratio of pyrite to arsenopyrite selectivity was 1.7 at collector concentration of 50 g/t and decreased with an increase in collector concentration. Keywords: EDTA extractable iron, selectivity index, differential flotation, grade engineering

Jan 1, 2020

By T. Mahlangu Mahlangu, T. Fungene, K. C. Sole

"Although oxygen is widely employed as the oxidant of choice in gold leaching by cyanide, its low aqueous solubility presents some drawbacks in practical application; hydrogen peroxide has therefore been considered as a possible alternative. The aim of this investigation was to study the catalytic decomposition of hydrogen peroxide, which generates an oxidizing intermediate species, and to understand its effect on cyanide destruction. Operating conditions that facilitated the effective decomposition of hydrogen peroxide were established by varying the pH and catalyst type and concentration. The oxidizing intermediate, detected using an indirect technique, was found to be the hydroxyl radical (OH?). OH? is commonly generated in acidic solutions, but this work demonstrated that it is also produced at the alkaline pH values necessary for cyanide gold leaching. The effects of free and complexed iron and copper catalysts on the oxidation and consumption of hydrogen peroxide and cyanide were also investigated. It was shown that the cyano complexes of Fe(II) and Cu(I) are also effective as decomposition catalysts. Hydrogen peroxide concentrations above 0.01 M decreased the free cyanide concentration, which was attributed to the probable formation of the cyanate anion (CNO-). Although cyanide consumption increased due to its oxidation in the presence of OH?, excessive cyanide consumption in the presence of copper was attributed primarily to its complexation by the unstable copper(I) cyanide species. Rate constants for the decompositions of H2O2 and cyanide by ferrocyanide and copper cyanide were calculated; the latter was identified as being a better catalyst. IntroductionLeaching of gold from its ores using cyanide has been employed for well over a century (Habashi, 2016). Addition of cyanide converts the gold into a cyanide complex (Au(CN)2 -) that is soluble in water (Wang and Forssberg, 1990). The leaching reaction can be represented as Equation [1]:"

Dec 1, 2018

By K. R. Koch

Although some of the platinum(II/IV) and rhodium(III) chemistry is considered ?old? and well-known, the application of modern multinuclear NMR spectroscopic methods to this chemistry in solution reveals new details about their rich and relevant solution chemistry. In this paper we will briefly illustrate that the highly-sensitive 195Pt NMR shielding is an excellent probe to explore aspects such as solvation, ion-pairing, and the hydrolysis chemistry of inter alia [PtCl6-n(H2O)n]n-2 (n=0-5). Moreover the novel use of 35Cl/37Cl and 18O isotopes effects as unique NMR ?fingerprints? leading to a new and unambiguous method of chemical speciation of the numerous possible PtII/IV and RhIII complexes present in halide-rich aqueous solutions. In the case of Rh(III) chemistry a new, direct speciation distribution diagram has been established for [RhCln(H2O)6-n]3-n complexes (n = 3-6) in HCl solution at 292 K with these methods.

Jan 1, 2012

By J. Petersen, S. W. Robertson

Heap leaching is used extensively for the processing of low-grade copper, gold, and uranium ores. The hydrodynamics is often the most important factor that limits the rate of metal recovery. Over the past decades the author has performed physical and hydraulic testing of a large number of ore samples considered for heap leaching. The data were reviewed to investigate the effect of physical properties such as particle size distribution (PSD) and bulk density on the hydrology. The unsaturated flow through the bed is traditionally modelled with soil science models such as Brooks-Corey (BC) and Van Genuchten-Mualem (VGM), which relate the hydraulic conductivity to the degree of saturation, also known as the hydraulic conductivity function (HCF). However, most authors found a disconnect between the saturated hydraulic conductivity (KS) and the rest of the HCF, which is explained as resulting from a transition from capillary-to gravity-controlled flow. However, the author found no such transition, and found the flow to be governed by capillary flow throughout. Traditional BC or VGM fits were found to be appropriate, however it was necessary to modify the model to include a point of inflection, above which the hydraulic conductivity remains constant while the moisture content keeps on increasing. It was proposed that this is the result of unconnected or poorly connected pores, which fill with solution but do not create additional flow channels. The point of discontinuity was also found to correspond with the air entry point, measured independently from the air conductivity curves. On average, the air entry point corresponds to the experiential rule that the void saturation should remain below 65% for aerated heaps.

Dec 11, 2024

By S. Botes, H. van der Merwe

While the refractory lining contains the process on a steady-state basis, the tap-hole must provide a channel for transport of molten materials at discreet intervals, with thermal cycling as routine. The tap-hole introduces a discontinuity in any lining, and this fact can lead to failure in the region around the tap-hole before general lining failure occurs. Hence there is a need for a rapid and reliable tap-hole repair technique that can be readily implemented in conjunction with all types of linings. The UCAR®V Repair supplied by GrafTech is a durable solution capable of repairing all types of lining designs and has been extensively utilized in the ferroalloy industry. More than 20 UCAR®V Repairs have been successfully performed in South Africa alone. This paper describes the system in general and reviews recent repairs and their unique challenges.

Jan 1, 2014

By D. Chetty

Process mineralogy forms an integral part of geometallurgy, with ore body characterisation being but one piece of the puzzle in optimising value derived from ore. This value is not only financial, but importantly speaks to sustainability from environmental and social standpoints. The reactive approach of traditional process mineralogy is increasingly being replaced by predictive methods in the geometallurgical sphere, for which mineralogical information must be timeously acquired on judiciously selected sample sets to understand ore variability and its impact on orebody processing. Such processes are not only metallurgical, but must incorporate mining and waste management protocols. Dwindling resources like water and energy also demand innovative approaches for lowering consumption and/or promoting recycling along the value chain. Addressing such challenges relies on appropriate characterisation of ore behaviour under different process regimes. Coupled with this, emerging characterisation tools are increasingly applied to understand the mineralogy of unconventionallypresented and difficult-to-process ores to meet societal and technology demands. Such tools are often accompanied by the generation of large, computationally intensive datasets, for which data management and storage are key requirements, particularly when deciphering temporal trends in ore and process variability. This paper will elaborate on these themes with examples that highlight the importance of process mineralogy throughout the minerals value chain. Keywords: Process mineralogy, ore characterisation, geometallurgy

Jan 1, 2020

By D. Pienaar, C. O’Connor, B. McFadzean

Dithiophosphate (DTP) is classically used as a co-collector in sulphide mineral flotation, where xanthate-DTP mixtures have been shown to synergistically improve mineral flotation performance. Notwithstanding the improved recoveries observed, ethyl DTP does not appear to behave as a conventional collector, since it has been shown that it does not adsorb onto certain sulphide mineral surfaces. Recent investigations have nevertheless indicated that when ethyl DTP does not adsorb onto the sulphide mineral surface, the presence of a non-ionic frother can activate a synergistic increase in pulp phase mineral recovery, and bubble-particle attachment probability. A regular solution approach was used to determine the interactions between thiol collectors and non-ionic frothers at the air-water interface. Attractive interactions were observed between longer alkyl chain DTPs and frothers, whereas the activity of xanthates at the air-water interface were too weak to determine if an interaction was occurring. This is the first time that such interactions have been shown for the DTP-frother system and represents an important contribution to our understanding of the role of DTP reagents in the flotation process. Keywords: Collector-frother interaction, dithiophosphate, surfactant synergism

Jan 1, 2020

By T. Grewar

"South Africa is a water-scarce country, rated as one of the 30 driest countries in the world. Worryingly, government expects water demand to outstrip supply as early as 2025. The South African government believes that substantial volumes of water can be made available through the reuse of treated mining-impacted water. Currently, however, large volumes of treated mining-impacted water are produced, often with no end use in mind other than discharge or disposal, when these treated effluents may have further uses in applications which are currently and unnecessarily using high-quality water. Treating the wastewaters to levels that meet ’fitness-for-use’ guidelines for alternative applications such as agriculture, sanitation, or industrial processes will reduce the treatment cost burden compared to potable water production. The primary conclusion of this review is that the most suitable option for re-using treated mine-impacted water is in agriculture, for irrigation of crops (food, forage, or energy crops), which currently and unnecessarily makes use of the majority of South Africa’s high-quality resources or potable water. Other findings include the realization that although guidelines and legislation for water re-use in South Africa exist and are readily available, they tend to be contradictory and confusing in many cases. It is imperative that these ambiguities and incongruities in the available guidelines and legislation for water re-use be clarified and updated swiftly IntroductionSouth Africa is a water-scarce country and is currently rated as one of the 30 driest countries in the world, with an average rainfall of 490 mm/a, approximately half of the global average. As an indicator of the degree of regional variability in South Africa’s water supply, it has been shown that 70% of all runoff is from approximately 20% of the land area. Regardless of the water scarcity faced in South Africa, our water conservation track record is poor, with an average consumption of 280 L/d per person, almost 60% more than the global average of 175 L/d per person. Around 40% of this allocation is utilized in watering lawns and gardens (Zhuwakinyu, 2017).The South African government predicts water demand to outstrip supply as early as 2025. On an international scale, the situation appears just as dire, with the United Nations High Level Panel on Water (HLPW) expecting a 40% water shortfall by 2030, which may affect up to 1.8 billion people based on current water demand trajectories (Zhuwakinyu, 2017)."

Mar 1, 2019

By B. A. Obadele, R. Machaka, M. L. Raganya, M. E. Makhatha, N. A. Moshokoa

The influence of solution treatment on the phase evolution and tensile properties of Ti-Mo alloys was investigated to assess their potential use in biomedical applications. Phase formation and microstructural evolution were studied using X-ray diffraction (XRD), optical microscopy (OM), scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD). The mechanical properties were characterized by means of tensile tests and bending strength. XRD analysis showed that solution treatment increased the volume fraction of β phase and supressed the α" phase. The microstructures of the as-cast alloys consisted of β equiaxed grains with sub-grain structures of different sizes, while the solution treated alloys comprised β equiaxed grains only except for Ti- 10.02Mo, which comprised needle-like α" structures. EBSD showed an increase in the volume fraction of the ω and α" phases in all the alloys after solution treatment. The elastic modulus and UTS of all the alloy significantly decreased after solution treatment, except for Ti-15.05Mo,whereas the elongation significantly increased. The fracture surfaces of all the alloys after solution treatment indicated more ductile behaviour than brittle

Jun 10, 2024

By Jean Michel Marino, Jean-Pierre Slama

"The computer methods used by the French Commissariat a l'Energie Atomique, which are applicable to any type of ore deposits, are:(i) Ore reserve estimation. The data are either the core analyses or gamma leggings. To determine the spatial distribution of the ore, three different methods of interpolation are used. Two of these are based on the least-squares theory and the third one is an application of the regionalized variable theory. The interpretations of the orebody by the geologists are introduced in the computer program as often as possible.(ii) Optimal open pit design. From the spatial distribution of ore, the three-dimensional outlines of the optimal pit are determined by a geometrical algorithm which allows different slopes varying with the azimuth.Finally, the optimization of annual successive plans arc discussed."

Jan 1, 2014

By T. Bruce, R. C. A. Minnitt

Mining operations are generally reluctant to install high-cost sampling systems at operations that have been functioning for many years. The principal objection to installing appropriate equipment to extract correct and representative samples in process flows is the time and costs involved. The Theory of Sampling (TOS) provides a structured framework for identifying and quantifying the errors and bias associated with any sampling event, but this may be insufficient to initiate substantial investment in correctly designed sampling equipment. Financial losses arising from substandard sampling installations are usually disregarded because the value-add from a good quality sampling solution is invisible, but the cost is quite obvious. Depending on the needs, a less-than-perfect or fit-for-purpose sampling solution may be acceptable, provided the magnitude of sampling errors is understood and the assay results are interpreted accordingly. Categorical levels of acceptable accuracy and precision can be established depending on the sampling position in the mining value chain and the nature of the decisions to be made. The objective benefits of proposed fit-for-purpose sampling solutions should be presented to relevant decision-makers in such a way that adverse subjective decisions are countered so that appropriate solutions are implemented. Practical examples of the benefits from motivating the implementation of fit for purpose sampling solutions at sampling facilities around the world are provided.

Jul 2, 2022

By Z. Leng

"After detonation of the explosive, the final blast-induced damage area around the blast-hole falls into three categories, namely crushed zone, fractured zone, and elastic deformation zone. This paper presents a modified model to calculate the size of crushed zone around a blast-hole in drill-and-blast, with the hoop compressive stress and cavity expansion effect taken into account. The material in the crushed zone was assumed to be a granular medium without cohesion, but with internal friction. On this basis, the formula for crushing zone radius was derived. The proposed approach was verified with tests reported in the literature and the simulated results from SPH-FEM coupled models. A full statistical analysis was also carried out, and the predicted values were found to be in better agreement with the test results compared with other models. A sensitivity analysis of the modified model showed that the size of the blast-induced damage area is mainly affected by the following factors: rock mass properties, in situ stress, and borehole pressure. In particular, the roles of borehole pressure and in situ stress are discussed. Finally, suggestions are made on how the size of the crushing zones can be decreased. IntroductionOver the past decades, drill-and-blast has become the most commonly used technology in rock excavation. It is well known that in rock mass fragmentation with explosives, the annular rocks around the blast-hole are converted into fines. The formation of these fines consumes a significant part of the energy of the detonation, which in general is ignored in the determination of the efficiency of detonation (Glatolenkov and Ivanov, 1992; Furtney et al., 2012). Many studies show that only 20–30% of the total explosive energy is effectively used in fragmenting the rock, and up to 50% of the energy generated by conventional charges is wasted in overcrushing of the crushed zone and the inner part of the fractured zone (Ouchterlony et al., 2004; Sanchidrian et al., 2007). How to control the crushed zone to enhance the effective utilization of explosive energy, reducing the unit explosive consumption and the engineering cost, is therefore of great significance."

Jan 1, 2016