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By A. R. Barnes, A. F. Newall

Keywords: Pyrometallurgy, furnace, smelting, spinel, PGM, phase diagrams As Merensky reef ores are replaced by UG2 ores, chromium levels in PGM smelting furnace feeds have steadily increased. Increased chromium levels lead to operating problems. Attempts to increase the chromium solubility in the slag by a variety of techniques create other difficulties. The authors have developed a technique for removal of the chromium spinel interface along with the matte for subsequent separation outside the smelting furnace by utilising differential solidification in the ladle. The process has been patented internationally with support from the Innovation Fund.

Jan 1, 2006

By N. Hanief

This research involves the investigation of phase transformations in the platinum-chromium coated system. Single-layer 0.1 µm platinum coatings were deposited via electron beam deposition on 99.98 percent pure chromium substrates. Specimens were subjected to systematic heat treatment in a vacuum furnace at 900°C for up to 20 hours. Phase formation and the changes in surface morphology were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM).Both CrPt and Cr3Pt phases are formed during heat treatment for different times at 900°C. Significant changes in the morphology of this coated system were detected after heat treatment at 900°C for 20 hours.

Jan 1, 2012

By D. Norval, J. J. Dunkley

The process of atomisation is introduced and related to granulation. Some processes applicable to ferroalloys are discussed, along with their limitations and advantages. Examples of applications of atomisation to the processing of ferroalloys, including ferrosilicon and ferromanganese for use in the welding industry and as injectable additions to steel or cast iron are also presented. The economics of the process and the impact of process scale are discussed, along with criteria for process selection and system design.

Jan 1, 2004

The increasing transportation of solids by pipeline, in South Africa and internationally, replacing the conventional transportation methods of rail, road, and conveyors, has resulted in much research into this area of solids transportation. Pipeline wear continues to be an area of specific concern, since it constitutes a major cost during the life of a pipeline installation. Wear data from an accelerated wear test and actual pipeline tests are presented. Trends in the performance of the pipeline materials tested are discussed, and possible solutions to the problem of pipeline wear are presented.

Jan 1, 1992

By P H. Ferreira

The mechanisation of mine development is becoming increasingly important in our South African and Southern African mines with increased emphasis on safe and efficient mining. Raise, blind and shaft boring offer mechanised solutions for excavations such as:- [reef raises stope boxholes and shaft ore passes ventilation passes and shafts chairlifts large vertical hoisting shafts (in excess of 1200 metres in depth) angled hoisting shafts (from small to large diameter bored holes)] These techniques will be discussed with reference to relevant applications and the author?s comparison between conventional drill and blast techniques.

Jan 1, 2005

Notices COMPETITION FOR STUDENT MEMBERS OF THE SOUTH AFRICAN INSTITUTE OF MINING AND METALLURGY Each year the Institute offers a prize (or prizes should the entries warrant it) of up to RlOO for the best paper or dissertation on a topic appropriate to the interests of the Institute. The competition is open to all Student Members of the Institute. APPLICATION AND PRACTICAL OPERATION OF HYDROCYCLONES Dr H. F. Trawinski of Amberger Kaolinwerke, Hirschau, West Germany, gave a very interesting lecture on this subject to an audience of over one hundred, composed largely of members of the Institute, on 15th August, 1973, at the University of the Witwatersrand. ROTARY INTERNATIONAL Applications are invited before 15th March, 1974, for the following awards of The Rotary Foundation: Post-graduate Fellowships Under-graduate Scholarships Awards for Technical Training Awards for Teachers of the Handicapped. NIM REPORTS Report No. 1509 The instrumentation developed for electrochemical studies of the le(Whing of uranium dioxide. Report No. 1550 A fundamental study of the dissolution in (Wid solutions of uranium minerals from South African ores. Report No. 1552 The preparation and analysis of minerals for use as reference material.Progress report No. 2. Report No. 1556 The spectral analysis of solutions.2. The analysis of leach liquors, concentrates, slags, and residues. Report No. 1559 A cost assessment of the production of elemental sulphur by chlorination roasting. Report No. 1562 Application of a flotation model to an industrial plant

Jan 11, 1973

By L. Andrews

Keywords: mineralogy, phase-chemical, chemical-looping combustion, XRD, SEM, EDS, QEMSCAN, PGM, slag, matte, ilmenite Mineralogy, traditionally associated with concentrator studies, is being increasingly applied to problems in pyrometallurgy. Such investigations commonly make use of a number of techniques, and the results are combined for a meaningful interpretation, which can lead to a successful solution. Mineralogical applications are described from pyrometallurgical operations. Examples are given of studies and investigations involving mineralogy in chemical-looping combustion, feed monitoring to platinum-smelting furnaces, and losses to slag in base metal and platinum smelting.

Jan 1, 2011

By M. W. Hildyard

A blast was engineered close to a tunnel in a deep-level mine with the purpose of studying the wave interaction with the tunnel. Numerical modelling of seismic wave propagation was used in both the forward planning and the back-analysis of this experiment. This paper presents the forward analysis. A likely model for a propagating blast was investigated and developed. This model predicts the influence of the velocity of detonation of the blast and the rise-time of the blast on the radiation pattern, and hence on the expected positions of maximum velocity at the tunnel surface. An attempt was made to quantify the parameters of the blast model, using waveform data from two other blast experiments. The blast model caused particle velocities which were an order of magnitude lower than these measured velocities. Large values for blast pressure were required to match the amplitudes of the recorded velocities. An alternative ?effective? source with a similar mechanism but increased diameter was proposed to account for the higher velocities. It was established that distant velocities scale with the square of the borehole diameter. A calibration blast at the experimental site was also modelled. Agreement in the waveforms was not sufficient for conclusive statements to be made about the validity of the source model. However, the modelled waveforms show an encouraging correspondence with some measured waveforms. This gave confidence that the model could be used to examine wave propagation around the tunnel, and allowed a scaled source to be developed for forward analysis of the main experiment.

Jan 1, 2001

By R. C. D. Phillis

Conventional stoping in hard rock mining is largely considered an operational environment. This paper suggests that stoping falls within the realm of a project management environment typified by uncertainty, variation, and large numbers of interdependencies. Stoping was then equated to a micro-project with many simultaneous activities that had to be executed accurately using finite resources within limited shift durations in order to reach specific goals. Critical chain project management (CCPM) principles were applied to the stoping activities, and the results showed that the number of blasts per panel can be significantly increased by successfully moving the distribution of work as close as possible to the start of shift. Critical chain principles also assisted in facilitating re-focusing and teamwork among stoping crews as well as between day- and night-shift crews. The main recorded success was in managing inherent protective capacities/local contingencies/fat/buffers that are found in all projects. The impact on mine health and safety (MHS) was significant as individual operators and crews became convinced that they could perform all stoping tasks (activities) without compromising accuracy or speed.

Jan 1, 2011

By J. Kempken, R. Degel, J. Kunze, R. König

The FeNi technology is currently dominated by high-power submerged arc furnaces, often designed as smelter as "two-inline-solution". To achieve the intended high efficiency, state-of-the-art design in good correlation with ores and reductants and an integrated layout of the whole plant is of great importance. An introduction will be given to general aspects in the production FeNi, plus a detailed overview of design principles for large FeNi smelters and finally some examples of innovations and research projects concerning Fe-Ni.

Jan 1, 2007

By Ravichandar. D., K. B. Nagashanmugam, M. S. Pillai

"Blast furnace performance depends strongly on the coke reactivity index(CRI) and coke strength after reaction (CSR) properties. An innovative and cost-effective method, known as the Salem Box Test, has been developed to prevent the mass production of inferior coke unsuitable for blast furnace use. This method consists of coal carbonization on a micro-scale and involves charging approximately 18 kg of coal blend in a stainless steel box, carbonizing it together with coal cake in the plant coke ovens, and testing the coke produced for CRI and CSR to determine its suitability for blast furnace use. Only coal blends that yield coke with CRI <25% and CSR >64% are permitted for mass production, and other coal blends are either rejected or the blending ratios adjusted in an attempt to upgrade them. The experimental results reveal that, for a given coal blend, the quality of coke produced by the Salem Box Test is comparable with that produced by bulk production, indicating that the test is acceptable as a screening tool for regular use. The present paper describes the methodology and application of Salem Box Test to predict the suitability of coke for blast furnace use at JSW Steel Limited, Salem Works (JSWSL), and illustrates its advantages in adjusting the coal blending ratio to produce superior coke, in detecting coal contamination, and in preventing bulk production of inferior coke."

Jan 1, 2015

By I. Alp

Application of magnetic separation was investigated for the enrichment of colemanite ores by removing the magnetic gangue fraction. The detailed XRD analysis of the ore has indicated that the gangue fraction is composed predominantly of the iron-bearing silicates such as smectite and, to a lesser extent, illite. Magnetic susceptibility measurements of the colemanite and gangue samples have proved that colemanite is diamagnetic in character whereas gangue fraction is weakly paramagnetic to allow the removal of this fraction by magnetic separation. Magnetic separation of the crushed and sized ore samples (-5 mm +75 µm) was performed using a high intensity permanent magnetic separator. Under the test conditions a colemanite concentrate (41.29 wt.% B2O3) was found to be produced from the crushed ore (30.76 wt.% B2O3) at a recovery of 96.76%. These findings suggest that magnetic separation has great potential as an alternative process for the production of a concentrate of commercially sufficient grade.

Jan 1, 2009

By M. Karimi

Artificial neural networks (ANNs) have found their applications in the modelling of unit operations of mineral processing plants. In this research, laboratory-scale tests were conducted, using a three-inch diameter Mozley hydrocyclone. Main parameters included pressure drop at inlet, solid per cent, vortex and apex diameter were adjusted. The corrected cut size (d50c) and the flow rates of underflow and overflow were determined. Multi layers perceptron (MLP) feed forward network architectures were designed to predict the responses. The results showed a good correlation between experimental and network output, for corrected cut size and flow rates. Keywords: hydrocyclone, artificial neural network, corrected cut size, flow rates.

Jan 1, 2010

By H. A. D. Kirsten

Mining-induced seismicity is usually evaluated in terms of continuum elastic analyses, and is quantified in terms of energy release rate as state parameter and excess shear stress along particular features on which failure may be induced. Although both of these quantities are representative measures of potential seismic activity, elastic analyses do not enable the associated stresses and displacements in the rock in which failure occurs to be evaluated reliably. The paper compares the effect of depth, span, support stf1Jhess, field stress ratio, and discontinuity strength on mining induced seismicity determined from elastic analyses and from analyses in which discontinuities in the rock are allowed to fall. It is, accordingly, shown that the incidence and magnitudes of potential seismic events and the net excess shear as representative state parameter cannot be determined reliably from elastic analyses that do not account for the failure of ubiquitous discontinuities. The magnitudes of seismic events in rock in which ubiquitous discontinuities are allowed to fail are very considerably overestimated in elastic analyses. The extent of the seismic source region and the associated seismicity do not increase with depth, which, together with the improved containment of the concomitant rockburst damage by backfill is reassuring for mining at greater depth in future. For conventional support, the magnitude of potential seismicity increases for an increase in span in elastic rock, but remains unaffected in non-elastic rock. For backfill, the magnitude of potential sesmicity decreases substantially in elastic and non-elastic rock for an increase in span. Increases infield stress ratio very significantly reduce potential seismicity irrespective if the type if analysis, but effect the distribution if potential seismic events very differently in elastic and non-elastic rock.

Jan 1, 1994

By O. S. Tinkler, K. C. Sole

"Although the first large-scale application of copper recovery by solvent extraction took place in Zambia in the early 1970s, it is only in the last decade that this technology has become widely employed in this part of the world and is now a mainstay unit operation in copper hydrometallurgical flow sheets. The mineralogy of the ores of the African Copperbelt, and hence the characteristics of African leach liquors, differs significantly from those in Chile and the southwestern USA, where copper solvent extraction has had a long and successful history. These differences provide operators, metallurgists, reagent vendors, and engineers with many challenges: new approaches are needed to adapt solvent-extraction technology for successful implementation in this region. This paper examines typical operating practice in the African Copperbelt, discusses differences compared with other parts of the world, and looks at some of the challenges and opportunities presented by these flow sheets. IntroductionFollowing the success of the Rancher’s Bluebird and Bagdad solvent extraction and electrowinning (SX–EW) operations in Arizona in the late 1960s, the Tailings Leach Plant at Chingola, Zambia, became the first large-scale copper SX plant in the world, commissioned in 1974. Despite the equipment design now being outdated, this plant still continues to operate successfully, indicating the versatility and adaptability of this technology. Today, there are some 75 copper SX operations worldwide with cathode production above 10 kt/a. The top ten producers currently account for about 40% of the global 4.3 Mt/a SX–EW copper production. South America (predominantly Chile and Peru) is the largest copper cathodeproducing region, with annual production of some 2 Mt. The Central African Copperbelt (Zambia and the Democratic Republic of Congo (DRC)) is second, with cathode production of 1.2 Mt/a, and North America (USA and Mexico) third, producing close to 0.8 Mt/a Cu (Solvay Cytec data, 2014). The remaining 0.35 Mt/a comes from all other regions combined (referred to as ‘Rest-of-World’)."

Jan 1, 2016

By L. Andrews

Nickel is recovered as a by-product of the platinum-producing process operated by Anglo Platinum. The metal is mined mainly as sulphide minerals contained in platinum ores. These pass through the concentrating, smelting and converting process route and nickel is finally recovered by electrowinning. Smelting of the concentrated ore in the electric furnace produces a melt with a high slag to matte ratio. The resulting furnace slag is granulated and later milled and floated to recover matte. A project was initiated to investigate the distribution of nickel in the slag in order to improve recovery. Slag samples were examined using a combination of chemical and mineralogical techniques. The granulated slag was found to consist mainly of a silicate glass phase, which reflects the composition of the molten slag in the furnace. Nickel occurs as free matte granules, as matte phases locked inside the glass, and in the glass phase itself. Whereas nickel in the matte is as sulphide, most of the nickel in the glass phase appears to be oxide- bound(i.e. in solid solution). Milled slag as flotation feed showed recovery-limiting features such as free matte with oxidized surfaces and unliberated matte inclusions in the slag. The biggest nickel losses, assuming no tapping problems, are in the glass phase solid solution. Only around 40% of nickel would be recovered from the slag, even under ideal conditions. Spoon and pot slag samples were also examined to see if casting and crushing would improve recovery. Although larger and therefore more easily recovered matte phases formed, nickel partitioned into crystalline silicate phases, limiting the maximum theoretical nickel recovery to 70%.

Jan 1, 2004

By S. Asokan, Ch. V. G. K. Murty, R. Upadhyay

Zircon (ZrSiO4) is the most frequently found zirconium ore occurring in heavy mineral sands, from which it is extracted as a co-product in the production of ilmenite and rutile. Estimated world reserves of zircon are 124 million tonnes, highest in Australia (around 56 million tonnes), followed by Mozambique (15 million tonnes), India (12.6 million tonnes) and South Africa (12million tonnes). Zircon finds its application in ceramics (54%) and refractory industries (14%), which account for 68% of zircon?s total world consumption of 1.20 million tonnes. The rest (32%) is consumed in foundry, TV glass, zirconia chemicals and other applications. It is a long recognized feature of the zircon industry that supply is totally dependent upon the concurrent production of titanium minerals. But in recent years, several new developments such as the discovery of zircon-rich mineral sands in Australia, the continuing trend of higher prices of zircon and increase in trade of lower quality zircon have changed the scenario. These factors have prompted more intensive efforts to increase the recovery of zircon, particularly in the process for separating zircon from alumino-silicate minerals. Tata Steel?s proposed heavy mineral sands deposit contains on an average 10% heavy mineral content and 15% slimes of the size below 63 micron. Mineral assemblages of the resource contain65?70% ilmenite, 4?6% rutile, 4% zircon, 16% sillimanite and other minor minerals. Wide size range and tenacious iron oxide coating are the inherent characteristics of this deposit. High concentration of sillimanite among the non-magnetic heavy minerals and heavy surface coatings on the minerals are challenges for high recoveries and production of premium grade zircon. This paper outlines various process steps that were taken at pilot plant stage to produce zircon of premium grade and subsequently develop the appropriate flow-sheet.

Jan 1, 2007

By A. Tsekov, Stefan Neufeind, T. Angelov, G. Savov

"A complementary ion exchange/solvent extraction process for the recovery of copper from low-grade ores developed by Iontech Engineering Ltd. is described. It has successfully been implemented on a full-scale plant level at the Buchim Copper Mine in Macedonia, yielding a maximum copper cathode production of 2400 tonnes per year. Technical and economic aspects of three years of operational experience are comprehensively compared with the Asarel Medet copper plant in Bulgaria, which is utilizing conventional solvent extraction in the enrichment/purification step. INTRODUCTION The concentration and separation of copper from primary leachates is one of the key operations in the hydrometallurgical processing of oxide ores (Langner, 2011). Conventionally, this basic operation is conducted by submitting the pregnant leach solution (PLS), with a 1–5 g/L Cu content, from the initial sulfuric acid leach to a solvent-extraction (SX) process in which copper reports to the organic phase (see Figure 1). After phase separation, the metal is stripped from the extractant/diluent mixture employing sulfuric acid to furnish a concentrated metal solution, usually containing 40–50 g Cu/L. The final products of the overall process are copper cathodes, which are obtained from a terminal electrowinning step.Although considered as “technology of choice”, SX to date is still suffering from several drawbacks, such as the risk of poor phase disengagement and the high capital costs of solvent-extraction plants. Especially, the processing of leachates with lower copper tenors (< 1 g/L) is often economically less attractive. As a result, tremendous efforts have been dedicated to the evaluation of alternative technologies to address these challenges."

Jan 1, 2015

By A. M. Bauristhene

Ti-64, which accounts for more than 50% of the worldwide titanium tonnage, has found commercial importance in industries requiring components with high specific strength and resistance to corrosion. Investment casting is the preferred production method due to the difficult machinability of the alloy. This study was aimed at investigating the mechanism and the extent of alpha case formation on Ti-64 components cast using the investment casting method with YFSZ (yttria fully-stabilized zirconia) shell moulds after vacuum induction melting. The extent of the reaction between the mould hot face and the molten metal has been studied by varying parameters such as soaking temperature and mould hot face composition, and examining their effects on the reaction with the mould. An increase in the soaking temperature had an effect on the alpha case, both in appearance and hardness, but had no effect on contamination levels by carbon, oxygen, and nitrogen. The depth of alpha case increased with soaking temperature, increasing from 35 µm to 161 µm with an increase in temperature from 1200°C to 1400°C. The micro-hardness profiles provided insight into the effect of the alpha case on the mechanical properties of the Ti-64 alloy by displaying hardness values of 1000 HV0.1 and above, but could not be solely utilized to determine the alpha case penetration depth due to microstructural differences in the unaffected Ti-64, in particular the martensitic microstructure that formed with a fast cooling rate from a higher temperature. Levels of expected contaminants such as Zr, Y, 0, and C were low. The addition of the colloidal zirconia binder affected the interfacial reactions. YFSZ proved to be a thermodynamically stable refractory material, with the alpha case possibly forming as a result of segregation.

Jan 1, 2013

By D. Farrow

Future development of kimberlite mines is now focused on mining at deeper levels. The consequences are increased difficulty and costs of the mining operations. The decisions on investments require accurate resource evaluation and quantification of the risk. In the decision process the first step consists in choosing the number of boreholes sampling the pipe relative to the level of uncertainty that can be accepted. The uncertainty in the volumes of rocks of different types can be assessed as soon as we can estimate these volumes from a given borehole layout and calculate the error by means of its variance for instance. In theory this can be achieved by using geostatistical techniques (‘transitive theory’), but in practice the calculation of the error on volumes can be achieved in very particular cases, assuming some regular sampling patterns. A different approach has been chosen based on simulations, giving maximum flexibility to reproduce the reality of the sampling procedure. The idea is to simulate the geometry of several ‘possible’ pipes with their internal geology and estimate them by kriging. Several experimental errors are obtained on which risk analysis can be performed. The aim is to find a feasible method to perform the simulations with reasonable chance to correctly represent the reality, without data on the pipe extension. The methodology applied is based on some hypotheses that can be assessed by the geologist as well as by the geostatistician. The procedure assumes a geological model based on current knowledge including appropriate geostatistical variation. What make these simulations specific and powerful in this case comes from the fact that the boundaries between the different rock-types can be simulated using a transformation of the real 3D space into a 2D space defined by means of polar coordinates. Ultimate transformations to account for smoother variations with morphological transformations allow the generation of realistic pipe geometries on which sampling pattern can be used to evaluate the estimation errors. By estimating the simulated pipe geometries with different boreholes layouts a risk curve expressing the uncertainty in the volumes of the different rock-types versus the number of holes can be developed.

Jan 1, 2003