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By L. Tartibu, S. Assuli, P. Nkul, A. Kabimba, W. Elongo, N. Makhotla, D. F. Verwey, F. G. Ndiitwani, J. Bilali, T. Mukongo

The presence of colloidal silica negatively impacts various hydrometallurgy processes. This paper details the nature of colloidal silica, operational issues caused by colloidal silica, as well as various mitigation measures. MMG Kinsevere observed severe phase-continuity instability, increased crud formation, and reagent consumption, and reduced current efficiency in electrowinning with a deterioration in copper quality. Historical mitigation measures were initially implemented but failed to solve the problem. MMG Kinsevere successfully achieved efficient silica removal without adverse effect on the solvent extraction with the use of DEHSCOFIX® SC12 coagulant. A week into the coagulant trial, silica concentration had dropped from > 1500 mg/L to within 500 mg/L. The solventextraction plant recovered its stability and again operated at maximum capacity. Additionally, improvement was observed on current efficiency and copper cathodes quality with use of the coagulant.

Jan 1, 2023

By I. V. Filippova, Y. Foucaud, M. Badawi, O. Barrès, L. O. Filippov, S. Lebègue

Sodium silicate (Na2SiO3) is one of the most common reagents used in the froth flotation process, in which it is an efficient dispersant as well as a powerful gangue minerals depressant. Due to its high affinity with a lot of minerals, mostly silicates, it adsorbs on their surfaces and prevents the adsorption of the collectors, maintaining them hydrophilic. Hence, Na2SiO3 is widely used in the flotation separation of rare earth minerals, zinc minerals, iron minerals, scheelite, fluorite, apatite, and many other minerals. For decades, authors have demonstrated higher efficiency of Na2SiO3 when it is used in combination with sodium carbonate (Na2CO3), a common pH regulator. Among many well-known depressants, this system presented the best efficiency for many ores, including the Tabuaço scheelitebearing skarn studied herein. However, the mechanisms resulting in these strong positive synergistic effects are not well understood at the moment. Hence, the response surface methodology (RSM) was applied to this ore, considered as a case study, to optimize the depressing conditions and to study deeply the flotation behavior of this system. Strong synergistic effects between the two reagents were exhibited by the RSM, mostly affecting the scheelite, fluorite, and calcium-bearing silicates recoveries. This was attributed to surface carbonation of the minerals by Na2CO3, subsequently leading to a better depression by Na2SiO3. Overall, a 1:1 ratio between the two reagents displayed the best results in terms of WO3 grade and recovery. To gain understanding in the molecular mechanisms responsible for the aforementioned synergistic effects, FTIR studies were combined with state-of-the-art molecular modelling (Ab Initio Molecular Dynamics at 300 K) on fluorite, an archetype of calcium minerals. Keywords: Synergistic effects, scheelite, depressants, FTIR, DFT calculations

Jan 1, 2020

By K. Barani, S. M. S. Ganji

Creatine was used as a lixiviant for gold dissolution from gold ore. The effects of creatine concentration, temperature, leach time, and pH were examined for their influence on extent of gold dissolution. The results show that at a temperature of 75°C and pH 11.5, gold dissolution increased from 51% to 88% on increasing creatine concentration from 25 to 50 g/t. Further increase in creatine concentration showed a negative effect on the gold dissolution. Gold dissolution increased from 47% to 87% by increasing the temperature from 25°C to 55°C, and from 61% to 89% by increasing pH from 10 to 11.5. Under the optimum conditions of solids’ content of 30%, pH 11.5, creatine concentration of 100 g/t, temperature of 75°C, and hydrogen peroxide addition of 2%, about 90% of the gold could be dissolved from the ore after 24 h. A comparison between creatine and cyanide leaching showed that 90% gold dissolution was achieved at a cyanide concentration of 300 g/t, which is three times higher than the creatine concentration under optimal conditions.

Apr 14, 2024

By N. Mulaudzi

The use of SO2/air gas mixtures as an oxidant to precipitate Mn from Co(II) leach liquors was investigated. The effects of SO2/air ratio, pH and temperature on Mn precipitation were evaluated. It was found that the use of SO2/air gas mixtures resulted in significantly higher Mn precipitation kinetics compared to using air or pure O2 alone. The SO2/air ratio was varied from 0% to 6% SO2(v/v) in air and similar Mn removals were achieved at 0.75% to 3% SO2 at pH 3. The solution pH was varied from pH 2 to pH 4; Mn precipitation did not increase considerably from pH 2 to pH 3, but increased significantly at pH values higher than pH 3. Cobalt co-precipitation also increased as pH increased, with 1% Co co-precipitation at pH 3. An increase in temperature from 30°C to 60°C also increased Mn precipitation and 100% Mn precipitated at 50°C. Cobalt co-precipitation also increased significantly with an increase in temperature. An activation energy of 25 kJ/mol was calculated from the Arrhenius plot, which is an indication that the precipitation reactions were both chemically and diffusion controlled. XRD analysis showed that Mn precipitated in the form of Mn2O3 instead of MnO2 that was predicted from thermodynamic data. SEM and XRD analysis also revealed that the precipitate consisted mainly of gypsum or bassanite (99%), with the Mn containing phase (< 1%) distributed within the gypsum phase. The co-precipitated Co reported to the Mn phase. Keywords: manganese precipitation; SO2/O2 gas mixtures; cobalt solutions.

Jan 1, 2009

By G. Akdogan, M. Tadie, A. Tapfuma

The Southern African region contains abundant gold tailing heaps that are an environmental concern due to dust pollution and chemical contamination of nearby water bodies. Nevertheless, these heaps contain gold with potential to be extracted for financial gain. In this study, the feasibility of extraction of gold from a Witwatersrand gold tailings using glycine was investigated using a two-level full factorial design. Effects of variables such as glycine concentration at levels of 0.5–1.5 M with a solid–liquid ratio of 50–200 g/L were investigated. Although the solid–liquid ratio used in this study was below the industrial norm, it provides a starting point for investigating the applicability of this technology. To enhance the gold extraction, potassium permanganate pretreatment and copper ion addition were adopted. The results revealed that 91.4% gold extraction was achieved after 24 h pre-treatment of the tailings using 2 g/L potassium permanganate followed by subsequent leaching using 1.5 M glycine at pH 12, with 50 g/L solid–liquid ratio and 2 g/L copper ions. Statistically, the solid–liquid ratio and potassium permanganate pre-treatment of the tailings were found to be significant at 95% confidence interval, whilst interactions of copper ions and glycine concentration were significant factors. The work demonstrates that potassium permanganate pre-treatment prior to glycine leaching of low-grade secondary gold resources, such as tailings, can be beneficial. Furthermore, the methodology developed in this work provides an opportunity for further investigation of the recovery of gold hosted in complex mineralogical matrices.

Apr 14, 2024

By J. O. Claassen

A study was initiated and solutions implemented to address the root causes of a 30%?40% lower than predicted product yield achieved at a Mpumalanga coal mine. A holistic MRTM approach, which focused on improving exploration, geological sampling and analysis, geological modelling, planning, mining, and beneficiation practices, was used. The study indicated that deviations in the planned versus actual yields at the DMS plant were caused mainly by incorrect geological yield predictions, high and variable levels of dilution, and near-dense material, as well as the textural properties of the ore. Keywords MRTM, mining value chain improvement, Witbank coalfields, complex geology.

Oct 1, 2013

By W. Soetaert, P. Dhar, H. R. Kota, M. Thornhill, S. Roelants, I. V. Chernyshova

Yeast-derived bola-amphiphiles have attracted considerable attention for their applications in various industrial sectors in recent years. However, only a few studies on this class of surfactant were reported to be relevant to mineral processing applications. In this paper, one of the novel surfactants, acidic glucolipid obtained from Candida bombicola sophorolipids and modified by using Penicillium decumbens naringinase substrate has been evaluated for its interaction with chalcocite and calcite minerals because of a new Cu-ore Nussir deposit in Norway containing calcite impurity. The interaction of glucolipid biosurfactant with copper sulphide and carbonate minerals was investigated with zeta potential, adsorption and FTIR studies, and also by Hallimond tube and bench scale flotation tests using pure minerals and Nussir copper ore, respectively. The results illustrate collector adsorption and flotation of copper sulfides at neutral pH. The bench-scale flotation results demonstrate that copper sulphides can be selectively floated from carbonate and silicate gangue minerals. This study underlines the glycolipid’s high potential for its use as collector for flotation of valuable copper sulphide minerals. Keywords: Flotation, biosurfactants, adsorption

Jan 1, 2020

By C. Musingwini

The subject of optimal planning of level and raise spacing for inclined narrow reef deposits has received intermittent attention over the years because the subject matter is inherently complex. Previous work has approached the problem as simply that of simultaneously minimizing the total excavation and haulage cost associated with the development workings. However, when level and raise spacing are altered, other factors such as productivity are negatively affected, thus requiring a delicate trade-off of contradicting planning or optimization criteria. The paper concludes that the problem is actually of the multi-criteria decision analysis (MCDA) type, contrary to traditional thinking that the planning problem is achieved solely by minimizing waste development.

Jan 1, 2010

By E. D. Musin, S. S. Gudkov, A. V. Epiforov, S. V. Balikov

The standard technology for processing of gold-bearing sulfide raw material has many problems associated with the use of cyanide as a gold lixiviant. Therefore, many tests to find alternative gold recovery methods are being undertaken. This paper describes some technological solutions, which can become alternatives to cyanide technology in the future. Pressure oxidation (POX) of refractory gold-bearing sulfide concentrates from five different Russian gold deposits were investigated. Concentrate 1 was gold-copper concentrate. Concentrate 2 was gold-pyrite concentrate. Concentrates 3-5 were pyrite-arsenopyrite double refractory concentrates. The POX tests were at temperatures of 110, 200 and 220 °C and oxygen pressures of 1.5, 2.4 and 3.0 MPa were carried out. Gold lixiviants, such as chloride, thiosulfate, sulfite and thiocyanate were tested. The recovery of gold from sulfide gold-bearing concentrates by non-cyanide methods was 97- 99%, and from double refractory concentrates, 86-93%. The tested reagents are less toxic than cyanide, and their use will reduce of the cost of gold production. These methods make it possible to recover gold in acidic media, and eliminate the washing operation and POX slurry neutralisation. In addition, precious metals recovery from POX cakes using lead reduction smelting was investigated. It was shown that the “POX-pyrometallurgical” technology for double refractory concentrates processing could be used with recoveries of gold and silver of 97 and 96%, respectively. Keywords: Recovery of gold, refractory sulfide gold-bearing concentrates, double refractory concentrates, pressure oxidation, non-cyanide lixiviants of gold, chloride autoclave leaching, thiosulfate leaching, thiocyanate leaching, sulfite leaching, reduction smelting, POX-pyrometallurgical technology

Jan 1, 2020

By Z. Tshentu, M. Ngayek, P. Moleko-Boyce

This paper is focused on the development of iridium(IV)-specific quaternary diammonium cations containing electron-donating substituents in the benzyl group of methyl and electron-withdrawing substituents such as triflouromethyl and nitro groups. Quaternary diammonium cations used were tetra- 4-methylbenzyl-1,10-diammonium decane chloride (QuatDMDAMeBnz), tetrabenzyl-1,10- diammoniumdecane chloride (QuatDMDABnz), tetra-3-trifluoromethylbenzyl-1,10- diammoniumdecane chloride (QuatDMDACF3Bnz) and tetra-4-nitrobenzyl-1,10-diammoniumdecane chloride (QuatDMDANO2Bnz). Polyvinylbenzylchloride (PVBC) nanofibres were used as support material, and the functionalised nanofibres were used for separation of Ir(IV) from Rh(III). The sorbent materials were characterised by FTIR and elemental analysis. The efficiency of the quaternary diammonium cations was investigated in a column study under dynamic flow adsorption conditions. Column sorption of [IrCl6]2- and [RhCl5(H2O)]2- on nanofibres functionalised with diammonium cations showed [RhCl5(H2O)]2- was not adsorbed by the sorbent materials while [IrCl6]2- was loaded onto the column. The loading capacities of [IrCl6]2- on the quaternary diammonium sorbent materials increased in the order of F-QuatDMDAMeBnz (3.08 mg/g) < F-QuatDMDABnz (3.39 mg/g) < FQuatDMDACF3Bnz (5.46 mg/g) < F-QuatDMDANO2Bnz (7.10 mg/g). The loading capacity for Ir(IV) with quaternary diammonium cationic nanofibres increased with an increase in the electron-withdrawing nature of the substituent on the quaternising group. The charge delocalising ability of the 4-nitrobenzyl group resulted in the best interaction of the decamethylene diammonium cation with [IrCl6]2-. Keywords: Iridium(IV), rhodium(III), quaternary diammonium, polymer nanofibres, separation

Jan 1, 2020

By S. K. Lahiri, K. C. Ghanta

Design of industrial slurry pipelines is usually performed by applying semi-empirical procedures, requiring a significant experimental study for each project. The mechanisms of suspension flow are not yet completely understood and existing predictive models cover only some aspects of uniform or closely graded particle slurry flows. This paper presents a computational technique for prediction of the velocity and concentration profile in slurry pipelines based on computational fluid dynamics. This model gives numerical solutions for the concentration and velocity distributions in the pipeline cross-section. The model prediction and experimental concentration and velocity profiles were found to be in good agreement. Keywords: pressure drop; concentration profile; particle diffusivity; slurry flow.

Jan 1, 2007

By S. Mohanty, K. Sarangi, S. Dash, P. P. Patra

Industrial effluent from various industries contains heavy metals that are a serious threat to humans, flora and fauna in water bodies, and the environment. The heavy metals are dumped after precipitation, which has serious environmental consequences. In this paper, a 2D axi-symmetry CFD model has been developed to study the extraction of chromium ion from industrial effluent, in a hollow fibre membrane, using Alamine 336 as the carrier and kerosene as the diluent. The Navier Stokes equation was used to predict the velocity profile of the aqueous and organic phases, and species transport equation, which considers both convective and diffusive mass transfer, was used to predict the concentration profile of the chromium ion in the computational domain. The distribution coefficient was experimentally determined at a pH 4, which was found to be the optimum pH. Numerical simulations were performed considering 11.11 mol/m3 of initial feed concentration for chromium ions and extractant concentration of 0.2 M. Simulations were carried out with various aqueous and organic flow rates, and validated with experimental data. Keywords: CFD, metal extraction, hollow fibre membrane, heavy metals

Jan 1, 2020

By John Freer

On 25th November, 1983, nearly forty members of The South African Institute of Mining and Metallurgy, together with Doris Gardner and Judith Money from Kelvin House, travelled by luxury motor coach to Secunda, there to visit the coal-mining and conversion operations of Sasol Limited.

Jan 1, 1984

By T. van Heerden

A range of supported gold catalysts was prepared by ion exchange, varying many of the preparation variables, including concentration in the precursor solution, washing procedure, as well as drying and calcination procedures. These catalysts have been characterized extensively. TEM images show essentially the same crystallite size distributions, between 2?5 nm, for almost all catalysts, the only exception being catalysts not washed in ammonia, which did not show any small crystallites. Additional characterization with SEM yielded an interesting discovery. Catalysts that appear identical on the TEM also contain some large crystallites in the range of 50?500 nm. Differences in dispersion due to the drying procedure not seen on the TEM can now be observed. Oxygen chemisorption is being investigated as an additional method to characterize gold based catalysts to complement the typically used electron microscope techniques.

Jan 1, 2012

"Chairman: Mr R. A. PLUMBRIDGE Rapporteur: Dr D. M. HAWKINSPapers:The relevance of computer methods to the economics of the mineral industry by R: A. PerlmanDynamic control of a mining enterprise by R. G. CoyleAn economic model of the mineral sands industry by G. P. A. HoweMr M. Splaine, in opening the discussion on Mr Perlman&apos;s paper, asked whether the model, as fitted by data up to 1963, predicted the rise in the price of copper in 1967, and whether the model could be used to capitalize on short-term price fluctuations.Answering the second question first, Mr Perlman said that the horizon used is six months to one year. In the very short term the activities of speculators obscured the effect of the fundamental econometric variables. This effect, however, was removed if one moved to a longer term, say, quarterly. In 1963 the model had predicted a price rise in 1964 and 1965 and a drop in price in 1966. The rise in 1967 had been caused by a strike, and imponderables such as large strikes were difficult to include in the model since they were unpredictable. Model simulation can be used to show the effect of strikes on price and the effect of small strikes is small.Mr B. R. van Rooyen said that because models are both calibrated and tested on historical data a bias was introduced which gave rise to an overoptimistic estimate of the accuracy of the forecasts. To this Mr Perlman replied that there seemed to be no alternative to the use of historical data for calibrating and testing models, and thus little hope of avoiding the bias. A second point made by Mr. van Rooyen was that manage¬ment tended to be suspicious of complex models and that frequently more heuristic models were sufficiently accurate and preferable for investment decisions. He added that if management were not involved in the model building the econometrician might easily go astray, Mr Perlman replied that symbiosis between data analysts and users of the model was essential and that the experience of the practitioner must be reflected in the model.Mr M. R. Fuller-Good remarked that a clear understanding of future price trends was essential for effective capital planning, and asked, first, how one went from the compiled data on supply and demand to the determination of their effect on price, record, whether necessary data, for example, capacities, could be obtained timeously, and, third, when strikes restricted supply, whether stockpiling by consumers induced large price fluctuations."

Jan 1, 2014

Council and Standing Committees, 1975-1976 President: Dr R. E. Robinson. Vice-Presidents: Dr M. D. G. Salamon and P. A. von Wielligh. Honorary Treasurer: J. K. E. Douglas. Immediate Past President: Prof. R. P. Plewman. Members of Council: Dr M. G. Atmore, J. D. Austin, C. T. Fenton, J. A. Holmes, P. Holz, Dr P. R. Jochens, Prof. R. P. King, Dr D. G. Krige, Dr D. I. Legge, D. G. Malan, C. T. Shaw, D. A. Viljoen, R. A. von Maltitz, H. M. Wells. Chairman, Witbank-Middelburg Branch: E. J. Jackson. Chairman, Orange Free State Branch : G. J. C. Young. Past Presidents Serving on Council: R. J. Adamson, H. Britten, H. E. Cross, J. K. E. Douglas, R. C. J. Goode, Prof. D. D. Howat, Dr J. P. Hugo, D. M. Jamieson, D. G. Maxwell, Dr J. T. McIntyre, V. C. Robinson, P. W. J. van Rensburg. Seven Council meetings and five Executive Committee meetings were held during the year, and the standing and sub-committees held fifty-five meetings. Standing Committee Chairmen Membership, P. A. von Wielligh ; Technical Programme-Metallurgy, D. A. Viljoen; Technical Programme-Mining, D. G. Malan; Vacation School-Metallurgy, Dr P. R. Jochens ; Vacation School-Mining, H. M. Wells; Awards, Dr R. E. Robinson; Excursions, Dr D. I. Legge; Adjudicating, Dr R. E. Robinson; Constitution, Rules and Policy, Prof. R. P. Plowman; Mines and Works, C. T. Shaw; Education, Prof. R. P. Plewman; Foundry Colloquia, Prof. D. D. Howat. Representatives on Other Bodies Associated Scientific and Technical Societies: Members : Dr R. E. Robinson and Prof. R. P. Plewman. Alternates : P. A. von Wielligh and Dr M. D. G. Salamon. Federation of Societies of Professional Engineers: Members : J. K. E. Douglas and Prof. R. P. Plewman. Alternates: Dr R. E. Robinson and Dr M. D. G. Salamon. FSPE Technicians Committee: Member: D. M. Jamieson. FSPE Rationalziation Committee: Member: Dr M. D. G. Salamon. South African Council for Professional Engineers (Institute Nominees) Member : R. C. J. Goode. Alternate: G. H. Grange. South African National Committee on Tunnelling: Member : D. G. Malan. Alternate: Prof. R. P. Plewman. Engineers&apos; Liaison Committee (Pretoria) Member : Dr J. P. Hugo. Alternate : P. W. J. van Rensburg. Government Certificate of Competency Liaison Committee: Member: Prof. R. P. Plowman. Alternate: D. M. Jamieson. James Moir Memorial Lectures: Member : Prof. D. D. Howat. World Mining Congress-National Committee: Members : Dr M. D. G. Salamon, Prof. R. P. Plewman, and H. M. Wells. I.F.A.C. Symposium: Member: P. W. J. van Rensburg (Chairman-Organising Committee). Alternate : Dr J. P. Hugo. I. U.P.A.C. Symposium: Member: Dr P. R. Jochens. Membership Nine Fellows, twenty Members, six Associate Members, thirteen Graduates, nine Associates, twenty-nine Students, and ten Company Affiliates were elected during the year. One Fellow was elected to Honorary Life Fellowship, eight Members and one Graduate were transferred to Fellows, twelve Graduates and two Students were transferred to Members, three Students were transferred to Graduates, and one Student was transferred to the grade of Associate. Six Fellows, two Members, and two Associates were admitted to retired membership. Nine Fellows, fifteen Members, three Graduates, one Associate, two Students, and one Company Affiliate resigned. A statement of membership as at June 30th, 1976, and the end of the previous year is shown in the following tabulation. 30th June, - 30th June, 1975 1976 Honorary Life Fellows 16 - 17 Honorary Fellows 8 - 8 Life Fellows 171 - 171 Fellows 549 - 547 Members 523 - 517 Associate Members 15 - 21 Graduates 132 - 123 Associates 209 - 205 Students 173 - 179 Company Affiliates 71 - 80 1866 -1878 Obituaries Your Council records with deep regret the death during the year of the following members: P. A. Creewell, Life Fellow; A. S. Davis, J. S. Hay, P. 0. Lange, N.

Jan 10, 1976

By S. Fuchida, Y. O. Zubair, C. Tokoro

Mining of As-bearing minerals had resulted in the release of arsenic species predominantly As(III), which is known to be more toxic, and undue exposure to it is detrimental to human organ systems. Many materials have been examined for As(III) removal, but it is still challenging to advance sustainable materials for effective removal of As(III). In this paper, a more eco-friendly and superparamagnetic Fe0-Fe3O4 composite was synthesised and evaluated for heterogeneous catalytic oxidation and removal of As(III) with peroxymonosulfate (PMS, KHSO5). The kinetic removal studies showed that removal of As(III) was probably through a chemical process and the Elovich model best represented the experimental data. The removal capacity for As(III) on Fe0-Fe3O4 with PMS (1.76 mmol/g) is superior to that without PMS (0.83 mmol/g). Combined results from XPS and ESR showed that As(III) was fully transformed to As(V) through catalytic oxidation by Fe0-Fe3O4/PMS and afterwards enhanced its removal. The removal mechanism of arsenic was ascribed to the formation of outer-sphere (electrostatic attraction) and inner-sphere complexes. The adsorbent can be separated easily from water due to its excellent magnetisation (64.5 emu/g) and also has good reusability potential as more than 85% of the initial concentration of As(III) was immobilised after five consecutive cycles. Keywords: Arsenite, Fe0-Fe3O4 composite, catalytic oxidation, removal mechanism

Jan 1, 2020

By S. M. Spottiswoode

Much as one hopes to predict whether damaging seismicity might occur somewhere in the next shift, this is not possible at present. Recently, an analysis of seismicity at two mines has shown that a small increase in seismicity occasionally occurs before both large and small events. This analysis is extended here to five mines, with the same results. Earthquake seismologists forecast hazard in terms of the average incidence of earthquakes over the last 50 years, adjusted on an hourly basis according to the possibility of aftershocks of events that have happened. The rate of seismicity in any area remains approximately constant when expressed as seismicity per area mined, or better still, per unit of elastic strain energy released. It is suggested that seismic hazard in mines be estimated using historical seismicity and forward modelling, adjusted according to the possibility of aftershocks. In summary, medium-term forecasting of seismicity is viable; short-term prediction of large events is not.

Jan 1, 2010

By N. Mphathiwa

When slope angles are designed during open pit optimization, there is a risk factor applied in steepening the slopes. The steepening of slope angles has implications for the safety and economics of the mining operation. The steeper the slope angles, the greater the probability of slope failure. Although a slope failure will result in added costs, the challenge is to compile an accurate cost-benefit exercise optimizing the economic benefits of the project without exposing mine workers and equipment to unacceptable risk of rockfalls. A balance between the safety of the operation and the economics of the investment is therefore required. The ideal situation is to have a slope monitoring system that will predict slope failure by detecting any ground movement before the actual failure occurs. This early warning will allow the risk factor to be applied with a high degree of confidence, knowing that the risk will be adequately mitigated. The objective of this paper is to provide guidelines on how to design an optimal survey slope monitoring system. It is the authors? view that for a survey monitoring system to yield desirable results, it should adhere to survey principles such as working from the whole to part and consistently cross-checking. The case study used is Jwaneng Mine, and the design strategy outlined can be used as a guideline for developing a new slope monitoring system or to optimize an existing one.

Jan 1, 2014

By A. S. Ratnayake, H. C. S. Subasinghe

In this study, we review the role of mechanical activation in the pyrometallurgical, hydrometallurgical, and electrometallurgical processing of titanium feedstock. Mechanical activation has been shown to decrease the activation energy of chemical reactions, thus enhancing process efficiency and product quality by reducing processing time and energy consumption. Pyrometallurgical processing is energy-intensive and time-consuming. Hydrometallurgy is costly, requires high-grade feed material, and generates toxic waste. Waste generation and process complexity are the major drawbacks of electrometallurgy and solvent extraction. Bioleaching via a mechanically activated pyrometallurgical process can be identified as an alternative method, but the lengthy processing time is the major disadvantage. Mechanically activated titanium concentrate can be used in a finely tuned combined metallurgical process to overcome the challenges and drawbacks in these technologies.

Aug 3, 2023