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By Wei Sun, Ruolin Wang, Wenjuan Sun, Junhao Fu, Haisheng Han, Zhao Wei

Pb–benzohydroxamic acid (BHA) (lead complexes of benzohydroxamic acid) exhibits high selectivity but low collecting efficiency in scheelite flotation. This paper reports the manner in which BHA and sodium dodecyl sulfate (SDS) were employed as ligands to coordinate with the lead ions to obtain a colloidal lead-group multiple ligand complex, i.e., the Pb–BHA–SDS, for improving the collecting efficiency of Pb–BHA. The flotation mechanism of Pb–BHA–SDS with respect to scheelite was investigated from the viewpoint of interface science based on the pure mineral flotation, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and contact angle measurements. The results showed that the BHA and SDS coordinated with Pb2+ to form novel leadgroup multiple ligand complexes, which are different from the traditional understanding associated with the mixed collectors. Pb–BHA–SDS was a better collector with stronger collecting ability and excellent selectivity in regard to a scheelite flotation than Pb–BHA. The addition of SDS to Pb–BHA enhanced the latter’s adsorption ability on the scheelite surface and improved the hydrophobicity of the collector’s nonpolar groups, rendering Pb–BHA–SDS as a more efficient collector at a low dosage. Keywords: Scheelite; Pb-BHA complexes; sodium dodecyl sulfate; multiple ligands; Pb–BHA–SDS

Jan 1, 2020

By M. J. Nicol, G. Cromberge, C. A. Flemming

A relatively simple rate equation for the kinetics of the absorption of gold from cyanide solutions onto activated carbon was lI5ed as the basis in the development of a model for multistage carbon-in-pulp and carbon-in-Ieach absorption circuits. The model was used in the prediction of both the steady-state and the transient behaviour of the absorption process, and the results were found to be in reasonable agreement with those observed in an extended pilot-plant campaign. A number of practical implications of the model are discussed, and an assessment is made of the economic consequences of the various process options available for the design of a carbon-in-pulp plant.

Jan 1, 1983

By J. Daavittila, P. Jokinen, M. Honkaniemi

In the latter part of the 1980?s Outokumpu Chrome in Tornio, Finland, was in a situation when its twenty-year-old ferrochrome plant was becoming inefficient to sustain economically sound production. The company made extensive studies on the then available processing methods to find out the best possible processing route. As a result the whole plant was practically rebuilt and expanded. When equipment was proven in practical operation an application for FeMn production was developed. Now when Tornio FeCr-plant is considering the expansion the same type of exercise is to be performed with today?s challenges, which will be discussed in the paper. These challenges include increasing costs or decreasing quality of raw materials, increasing energy costs, stricter environmental regulations and demand of better working conditions. The possibilities to respond to these challenges will be discussed in the paper. The future and continuing development with FeCr includes the better utilization of process dusts and a lower consumption of energy. By adapting the latest automation tools to better control of the process even higher efficiencies can be achieved with present technology. New processes are considered for development in the future and some possible technologies will be described.

Jan 1, 2004

By D. Mesa, J. Karvonenb, A. López, P. R. Brito-Parada, R. Grau, D. Davoise

The froth zone in flotation cells plays an important role in determining metallurgical performance. This is even more critical as cell sizes increase, since larger bursting surface areas can easily result in poor froth transport and even stagnant froth zones, which are detrimental to recovery. Generating additional overflowing lip length by adding internal launders and reducing surface area (while also directing the froth to the overflow) by adding crowders are well established design strategies to enhance froth mobility. However, comparative experimental studies of froth zone design modifications at industrial scale are scarce and often lack detailed froth characterisation. In this work, we present the results of two experimental campaigns that were carried out at Atalaya’s Riotinto concentrator in order to determine the effect of a new froth zone design on the flotation performance of a TankCell® e300 cell that operates as the first cell of the rougher bank. These campaigns provided a unique opportunity to assess froth phase phenomena and metallurgical performance before and after changes in design. The original cell design had an internal peripherical launder and a froth cone, while the new concentrate launder technology adds a centre launder and an adjustable froth crowder to the existing launder design. The new concentrate launder arrangement reduces significantly the froth area as well as the froth transport requirements, aiming to improve froth recovery and, consequently, enhance flotation performance, allowing copper recoveries in the TankCell® e300 cell to increase dramatically. In addition, radial profiles of froth height and froth velocity at the surface were determined, which provide valuable insight into the effect of design changes on froth stability and mobility. Keywords: Flotation performance, enhanced recovery, launder, crowder, froth stability

Jan 1, 2020

By S. K. Murphy, K. B. Le Bron, A. K. Ward, S. Hayes, T. Rangasamy

A process for evaluating different options for extraction of mining blocks is presented. The process is described and an example of the application of the process to a case study is presented. Un procédé pour évaluer différentes options pour l’extraction de blocs d’exploitation est présenté. Le procédé est décrit et un exemple de l’application du procédé à un cas particulier est présenté. Ein Prozeß für das Auswerten der unterschiedlichen Optionen für die Extraktion von Abbaublöcken wird dargestellt. Der Prozeß wird beschrieben und ein Beispiel der Anwendung des Prozesses zu einer Fallstudie wird dargestellt.

Jan 1, 2003

By N. Morris

In South Africa, diamonds are mined predominantly in rural areas. Kimberlitic diamonds dominate in Limpopo and the Northern Cape Provinces whereas alluvial diamonds are mainly sourced from the North West and Northern Cape Provinces. There are a few large and medium sized diamond companies (De Beers, Petra Diamonds, Trans Hex, Rockwell and Alexkor). There are many smaller companies involved in diamond mining, mostly alluvial diamond mines. The nature of alluvial diamond deposits is that they are aerially more extensive and thus their surface impacts are more pervasive: The recent downturn in diamond prices has resulted in the sudden cessation of mining at many small and medium diamond operations. The South African Mining Charter requires all mines, including diamond mines, to subscribe' to .the following empowerment objectives:

Jan 1, 2010

By S. Banisi, S. M. Mousavi, S. D. Tafvizi, Gh. A. Parsapour, M. Mahmoudi

Generally, regrind circuits are used to increase the degree of liberation of value minerals which are fed to flotation circuits. At the regrind circuit of the Sarcheshmeh copper complex, four ball mills are in closed circuit with their hydrocyclone clusters. In the initial design of the plant, feed and underflow percent solids, and pressure drop of the hydrocyclones were 39% and 65%, and 15psi, respectively. Over the years, due to a reduction in the feed grade from 1.17% to 0.67% and changes in the operational conditions, the feed rate to each hydrocyclone cluster has decreased from 401 to 70t/h and consequently the pressure drop, feed and underflow percent solids have reduced to 4psi, 17% and 25%, respectively. The main objective of this research was to audit the feed solids concentration and pressure drop of the hydrocyclones and make the necessary modifications based on the Plitt’s model. The results of sampling showed that water recovery to underflow was 59% which was higher than normal values. By reducing the number of operating regrind mills from 4 to 2, the feed rate to each mill increased. After this modification and taking necessary measures in the plant to implement the new operating approach, the pressure drop, feed and underflow percent solids increased to 18psi, 28% and 58%, respectively. The water recovery of the hydrocyclones underflow decreased from 59% to 12%. These changes in addition to increasing the circuit efficiency saved 1000 kWh energy and decreased ball consumption by 925 ton/year because of reduction in the number of operating ball mills. Keywords: Regrind mills, flotation, audit, troubleshooting

Jan 1, 2020

By M. Tang, X. Tong

"SynopsisSlime coating is one of the most common ways for serpentines to contaminate metallic mineral concentrates during traditional flotation of coarse sulphide particles. This could pose quite a complicated and challenging problem in the case of some types of low-grade and finely disseminated Cu-Ni ores bearing high serpentine contents. This is the case for the copper and nickel sulphides from the Yunnan Mine, China. Previous batch flotation tests of this ore resulted in satisfactory recoveries of 86.92% Cu, 54.92% Ni, and 74.73% Pt+Pd, and concentrate grades of 4.02% Cu, 3.24% Ni, and 76.61 g/t Pt+Pd. However, the MgO content in these concentrates was more than 19%. In the current study, microflotation tests and settling rate tests were introduced to investigate the effects of a combination of strong collectors (a 2:1 weight ratio of butyl xanthate and butyl ammonium dithophosphate) on entrainment of serpentines in metallic mineral concentrate, as well as visual observations of the concentrates in suspension using still photography. All test results indicated the presence of serpentines entrapped in the hydrophobic flocs that resulted from these collectors, even with the use of effective gangue depressants. These strong collectors are used to flocculate the ultra-fine sulphides by forming loose and ‘fluffy’ hydrophobic flocs. However, these hydrophobic flocs may also be able to load or entrap some serpentine slimes into the concentrate, and this entrained serpentine could be harder to remove by using depressants or intensified conditioning than serpentine slime coating on the particle surfaces.IntroductionSerpentine minerals, which have the generalized composition (Mg,Fe)3Si2O5(OH)4, can be easy to crush and grind due to their convoluted and bent layered structures. These serpentines can hinder the enrichment of some metallic minerals and dilute their concentrates by entrainment during flotation. The resulting high pulp viscosities, slime coatings, and high content of dissolved ions adversely affect the flotation recoveries of copper and nickel sulphides, and high levels of MgO entrained in the concentrates lead to heavy penalties from smelters. Since the quality of nickel flotation concentrate depends heavily on its MgO content (generally less than 6–7% for No.1 or 2 grade nickel concentrate according to the standard requirement from National Nonferrous Industry), reducing the entrainment of serpentine during flotation is becoming more and more pressing. Previous research has focused on the collectors and depressants that are commonly used in copper-nickel flotation, as well as their interaction mechanisms."

Jan 1, 2015

By A. Lebedev

Application of dynamic simulation for a base metal processing plant is discussed. The plant receives ore of variable quality from two pits and blending had to be applied to maximise recovery. The plant employs multiple stage crushing, screening, dense media separation, two-stage milling, flotation and further filtration. Stockpiles and bunkers are used in the plant to cater for breakdowns and operating delays, the latter being appropriately incorporated in the model. A detail dynamic simulation model was constructed from the rock face to the filtration plant to assist the plant design, notably with definition of the ore blending method, sizing storage capacity and in-plant conveyors. The plant model was broken down to capital equipment items and various feed types and mass balances were tested to ensure that the production target is met. The dynamic simulation tested the proposed blending method, identified bottlenecks, produced risk profiles for all strategic storage facilities and overall helped minimise the project risks and improve confidence in the plant design. Keywords: Dynamic simulation, ore grade, blending, capacity, risk profile, throughput, utilisation

Jan 1, 2020

By G. C. Lindeque

"A downward trend in tyre life on haul trucks at an open pit iron ore mine prompted an investigation into the current tyre management strategy in order to improve tyre life. ‘Best practice’ was compared to the current tyre management strategy at the mine to determine aspects that could be improved. Aspects that showed significant room for improvement included employee tyre awareness, tyre pressure maintenance, and road conditions. For each of these aspects a plausible alternative was suggested.A new tyre management strategy was formulated as a step-by-step guide on how to implement the proposed changes. Each step introduces new initiatives but at the same time builds on the previous step’s success. A sensitivity analyses was performed to determine the impact of the proposed changes, with the variables being the reduction in the percentage of premature tyre failure, and the reduction of the site wear rate.The ‘most likely’ scenario showed an increase in tyre life of 41% for the Komatsu 730 trucks and 105% for the CAT 777 trucks if the entire tyre management model is implemented. This would result in a possible annual saving related to tyre usage of R9.2 million. OverviewThe study focused on the tyre life on the main haul fleet at an open pit iron ore mine. The haul fleet consisted of 17 Komatsu 730 (180 t) haul trucks and 12 CAT 777 (90 t) haul trucks.The haulage operation consists entirely of tyre-based haul trucks. Five per cent of the total mining budget is related to tyre costs. Since 2012 there has been a steady decrease in tyre life as measured in operating hours (Figure 1) due to the high percentage of tyres that fail prematurely. In 2014 a total of 41% of all tyres failed prematurely and 61% were classified as ‘worn out’."

Jan 1, 2016

By M. R. L. Blackwell

Over the period 1964 to 1969 Conzinc Riotinto of Australia undertook and completed an evaluation of a large low-grade copper orebody on Bougainville Island in the Territory of Papua and New Guinea. From the outset it was clear that the geographic, climatic and topographic characteristics of the area would necessitate a heavy capital outlay on production and support facilities. Both the physical problems and the magnitude of the investment amplified the need for a thorough and rigorous evaluation of the various strategies for exploiting the orebody. In view of the number of independent and inter-related variables and the flow of new data, a computer-based evaluation process extended the scope and depth of the analysis considerably. The system used permitted an iterative assessment and re-assessment of the various strategies with the results becoming increasingly refined with time. This process encompassed the modelling of the orebody, the simulation of alternative operating strategies and the determination of the financial profitability of the project,

Jan 1, 2014

By Harushige Kusumi, Yuzuru Ashida, Toshiki Watanabe, Toshifumi Matsuoka

ABSTRACT: The technique of various kinds of numerical analysis offered remarkable results to explication of many rock mechanical phenomena. These techniques regarded a rock stratum as a continuum body and solved the governing equation of continuum mechanics by using finite differ-ence method, finite element method and/or others. Using numerical analysis based on continuum mechanics, however, the simulations of destruction phenomena caused by elastic waves and on the other hand, the elastic wave propagation which generated by fracturing events are quite difficult. In this paper, we express a rock stratum by a granular body model and develop a simulation tech-nique can simulate both wave phenomena and destruction phenomena at once. The DEM (discrete element method) simulation results are compared with finite difference solutions of elastic wave equation. Furthermore, we simulate Hopkinson effect by this proposed method. Hopkinson effect is famous as a destruction phenomenon caused by elastic wave propagation. ABRISS: In dieser Studie drücken wird eine Felsschicht durch ein Granularkörpermodell aus und entwickeln eine Simulationstechnik, die sowohl Wellenphänomene als auch Zerstörungsphänomene simulieren kann. Die Ergebnisse der Simulation mit DEM (Diskrete-Elemente-Methode) werden mit denen der Finit-Differenz-Lösung von Gleichungen elastischer Wellen verglichen. Desweiteren simulierten wir den Hopkinson-Effekt mit dieser vorgeschlagenen Methode. Der Hopkinson-Effekt ist als Zerstörungsphänomen berühmt, verursacht durch Fortpflanzung elastischer Wellen. RESUME: Dans cette étude, nous exprimons un lit de roches par un modèle à corps granulaire et développons une technique, permettant de simuler d'un coup le phénomène des ondes et le phé-nomène de destruction. Les résultats de la simulation DEM (méthode d'éléments discrets) sont comparés aux solutions à différence finie de l'équation d'ondes élastiques. En outre, nous simulons l'effet d'Hopkinson par la méthode proposée. L'effet d'Hopkinson est connu comme phénomène de destruction, causé par la propagation d'ondes élastiques.

Jan 1, 2003

By S. T. L. Harrison, A. Kotsiopoulos, M. D. Maluleke, E. Govender-Opitz

In the extraction of base metals from printed circuit boards (PCBs) using bioleaching, the accumulation of metal ion stress in solution has been shown to inhibit the microbial regeneration of ferric iron. This poses a challenge for the development of this technology for e-waste treatment. The paper explores the application of a microbial immobilisation system in a two-stage bioleaching system consisting of a chemical leaching reactor in series with a microbial ferric iron regenerating reactor to mitigate microbial inhibition and to enhance base metal extraction. A mixed microbial culture dominated by L. ferriphilum, L. ferrooxidans and At. Caldus was maintained over a period of two months in the presence of polyurethane foam which acted as the biomass support particle. Microbial metabolic activity of immobilised cells and their tolerance to inhibitory Cu ions was investigated. Results showed that immobilised microbial cells maintained higher ferrous iron oxidation activity compared to planktonic cells in the presence of increasing Cu2+ concentrations up to 6 g/L. This presents an opportunity for microbial immobilised systems to be adopted in two-stage bioleaching system. Keywords: Bioleaching, microbial immobilisation systems, microbial inhibition and ferrous iron oxidation

Jan 1, 2020

By L. A. Cisternas, A. Lopez-Valdivieso, Y. L. Botero, L. Cortes

In the processing of sulfidic ores, pyrite is usually depressed and ends up in the tailings. However, pyrite is the most common species responsible for acid mine drainage (AMD) due to its spontaneous oxidation. This AMD affects the tailing chemical stability by dissolving some toxic or heavy metals species such as As, Cd, Co, Pb, and Zn, which can migrate into the surrounding ecosystems. Therefore, the strategies to reduce pyrite’s environmental impacts are a crucial point to produce more chemically stable tailings. Consequently, numerous studies have been made to find procedures that could inhibit or restrain AMD. This work aims to develop a procedure for designing conceptual flotation circuits that can produce tailings with low content of pyrite and to assess this type of circuit with traditional flotation circuits. The method consists of applying optimal flotation design where three products are considered: metal concentrate, pyrite concentrate, and tailing with low content of pyrite. Two approaches are considered; in the first, a flotation circuit is designed to generate a concentrate rich in all sulfide minerals and to obtain a tail with low pyrite content. Then, a second flotation circuit is designed for the selective separation of the bulk into metal concentrate and pyrite concentrate. This is called fractional separation design. In the second approach, a flotation circuit design is realised that generate the three products simultaneously. This is called integrated separation design. Both fractional separation design and integrated separation design are assessed in this paper. This methodology is focused on cleaner production (waste prevention and resource minimisation) rather than end-of-pipe technology (treat existing waste). The methodology was applied to a copper sulfide ore from a local company in the Antofagasta region (Chile). This ore contains chalcocite, covellite, iron oxides, and pyrite. Keywords: Flotation, tailing, pyrite, cleaner production

Jan 1, 2020

By V. Sheikhzadeh, S. M. H. Haddad, M. Saghaeian, N. Esmaeili, R. Hejazi

One of the most significant features of iron ore concentrate (pelletising feed) is the specific surface area (SSA) that affects the achievement of desirable pellet properties. There are various methods to determine this parameters and currently, the most common is the Blaine air permeability method. However, due to the simplified assumptions including spherical and identical particles and 50% bed porosity, the Blain test does not provide accurate results. In fact, these two suppositions are far from reality. In this research, comparison of SSA measurement ways are investigated, containing laser diffraction testing and Blaine air permeability, on samples with different SSA, obtained from Ball mill and high pressure grinding rolls (HPGR). The output data showed that the calculated amounts of SSA by means of laser analysis were far greater than any other one. Furthermore, in the same results of Blaine air permeability tests on samples comminuted by different grinding methods, it was observed that the SSA figures from the laser diffraction method for HPGR products were almost 800 units greater than Ball mill ones. Keywords: Pelletising feed, specific surface area, Blaine air permeability, laser diffraction testing

Jan 1, 2020

By F. M. G. Egerton

Mechanisation of mining operations is not a new concept in the world of mining. Machinery has been developed, manufactured and used for many decades in massive orebodies and coal mines, both locally and abroad. Because of their size and the huge tonnages available, massive ore bodies lend themselves very easily to mechanisation. However, little progress in mechanisation has been made in narrow tabular orebodies in South Africa. The equipment available for narrow tabular orebodies requires excavations of a size that introduce large volumes of waste dilution. Nevertheless, it is essential for South African miners to experiment with mechanisation and to find a solution to the problem. This address looks at current conventional mining methods and compares them to bord-and-pillar type mining methods. Off-reef mechanisation is also touched on. It then looks at different hybridised mining methods that are being used, i.e. a mixture of conventional mining and mechanisation. It finally looks at future prospects for mechanisation in narrow tabular orebodies.

Jan 1, 2004

By S. G. Mgenge, J. D. Steenkamp

Tronox Namakwa Sands operates two ilmenite smelters for the production of high-titania slag and low-manganese pig iron. Slag or metal is tapped from one of two product-specific, bi-level tap-holes. In this paper the refractory design specific to the tap-hole refractory layout is described, as well as practices for slag and metal tapping and refractory maintenance. Further developments planned are briefly described.

Jan 1, 2014

By Y. Zhou, G. Chisakuta, P. Bwando, G. Mitshabu

A newly started copper hydrometallurgical plant was confronted with a manganese oxidation issue in electrowinning. This oxidation, in the absence of the amount of iron required to stabilise the electrolyte oxidation-reduction potential, is known to produce oxidants (MnO2, MnO4) that can cause accelerated degradation of the organic phase components in solvent extraction and corrosion of lead anodes in electrowinning. The overpotential required to build up the protection layer on new anodes causes an increased electrolyte potential that creates oxidized species in the electrowinning tankhouse, and these species come back to solventextraction plant with the recycled spent electrolyte. This paper discusses the impacts of manganese oxidants on the health of a plant organic phase. It also outlines the actions taken using iron scraps and sulfur dioxide to mitigate the problem that happened due to the lack of ferrous iron sulfate available on site, as recommended for better control.

Jan 1, 2023

By R. Dehghan, M. Zarei, A. Tohry, S. C. Chelgani

Typical depressants for selective reverse flotation of iron oxides from complex silicates do not generally show high levels of efficiency. Therefore, as a hot topic, there are several ongoing investigations in this area. The main aim of this paper is exploring the potential of using humic acid (HA) as a depressant in reverse cationic flotation of hematite from complex silicates. For such a process, the wettability and flotation behaviour of pure minerals (hematite and silicates) was investigated at pH 10 in the presence of HA and cationic collector. Adsorption mechanism of HA on these minerals was measured by zeta-potential and FTIR. Results of flotation tests showed that at the lower concentrations of HA, selective separation of silicates from hematite is beneficial, where the floatability of amphibole was higher than pyroxene. A higher separation efficiency of hematite through reverse flotation was observed in the presence of amphibole, in comparison with the presence of pyroxene. Wettability studies showed that HA has a significant effect on reducing the hydrophobicity of treated minerals with the collector. The adsorption, ZPC and FTIR test results indicated that HA was adsorbed on both silicates and hematite. However, the absorption intensity onto hematite was much higher than silicates. It was found that the adsorption mechanism of HA on hematite takes place through both strong H-bonding and ligand exchange. Keywords: Reverse cationic flotation, humic acid, iron oxide, complex silicates, surface adsorption

Jan 1, 2020

By F. Bonnet, J. Lehmann, H. Gaye

A review of thermodynamic information and models of slags, including associated software when available, is presented. The pertinence and accuracy of these models is discussed by comparison of their predictions for various slag thermodynamic properties with the available experimental data. Practical industrial applications will be illustrated by a literature review of the dephosphorization process of ferromanganese alloys and by the description of Ti behavior during silico-manganese alloys production. This latter example will show how the thermodynamic models have been used to propose a flotation treatment at low temperature to enhance TiC removal.

Jan 1, 2004