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H. W. Glen (ed.). Proceedings of Asbestos Symposium, Johannesburg, South, Africa, 3rd-7th, October, 1977. Randburg, National Institute for Metallurgy, 1978. 158 pp. (Copies obtainable from the Department of Mines, P.O. Box 4584, Johannesburg, 2000 South Africa.) This Symposium, which concentrated on the theme of dose-response relationships for asbestos-related diseases, was attended by an internationally representative group of experts in this field. Bulk solids The Powder Advisory Centre announces its third annual International Conference on Bulk Solids Swrage, Handling and Flow, to be held at the Holiday Inn, Liverpool, on 7th to 9th November, 1978. This sequel to the extremely successful November '76 Stratford and November '77 Nottingham Conferences is again to be co-sponsored by a number of internationally acknowledged professional societies, including the Institute of Materials Handling (through its Bulk Solids Panel), the Institution of Production Engineers, and the American Society of Mechanical Engineers (through its Materials Handling Engineering Division). NIM reports Report no. 1943 A review of the literature on the separation and determination of rare-earth elements. (23rd Mar., 1978.) Report no. 1947 The cation- and anion-exchange behaviour of various base-metal chlorides in polar organic solvents. (lOth Mar., 1978.) Report no. 1948 The measurement of trace amounts of gold in solution by atomic-absorption spectrophotometry and carbon-rod atomization. (28th Feb., 1978.) Report no. 1949 The kinetics of the leaching of zinc sulphide concentrates in acidic solutions containing ferric sulphate. (23rd Mar., 1978.) Report no. 1950 Factors affecting the carbon contents of alloys formed during the prereduction of chromite ores. (31st Mar., 1978.) Report no. 1952 The effect of slag composition on copper losses to silicasaturated iron silicate slags. (31st Mar., 1978.) Report no. 1953 A fundamental investigation into the depression of copper-activated sphalerite. (28th Apr., 1978.) Report no. 1956 An improved ion-exchange separation of rare-earth elements for spectrographic analysis. (10th Mar., 1978.) Report no. 1960 The recovery of ferrochromium from furnace slags and related products. (20th Aug., 1976; declassified 31st Mar., 1978.) Process instrumentation The National Institute for Metallurgy and the South African Institute of Measurement and Control are organizing a symposium that will draw the attention of researchers and industrial workers to the importance of metallurgical process instrumentation.

Jan 1, 1978

By Q. Lui, J. Oxenford

The occurrence of heavy minerals in the oil sands of Alberta has long been known and has been well documented in the literature. Unfortunately most of the researchers working on this resource have been unable to produce products that meet acceptable market specifications. This has resulted in many misconceptions about this resource. Recent efforts have shown that with some innovative approaches, marketable material can be produced and as a result it might finally be possible to realize the potential of this immense resource that, some have estimated, could contain in excess of 20% of the world demand by 2010. This paper highlights the uniqueness of this mineral assemblage and the mineral processing challenges it presents. It shows the most recent work that has resulted in the production of marketable titanium and zircon products. This paper also focuses on some of the special problems resulting from the variability in the heavy mineral suite. Of special interest is the occurrence and removal of bitumen and pyrite without adding to the sulphur dioxide loading in the regional airshed. The trend by the mining industry to develop various positions on ‘sustainable mining’ has some significance for the heavy mineral industry. Although the industry generally has an excellent track record of eventually rehabilitating disturbed ground in an acceptable manner, heavy mineral mining operations tend to have a relatively large footprint of disturbance and the industry is under considerable pressure to develop options that are more environmentally acceptable. In addition, as operators move to exploit deposits that are lower grade and/or are further from a port site, the emissions per unit of sold product will also rise and the industry will be under pressure to address this issue as well. Because heavy minerals from oil sands are by-products of existing operations, there are virtually no incremental disturbances or emissions that would be associated with heavy mineral production. All mining and tailings remediation issues are accounted for by the oil sand operation. The only incremental emissions would be those associated with the mineral processing operations and transport of finished products to a port site. This paper discusses the environmental and cost implications of this situation.

Jan 1, 2003

By M. M. Valenta

A number of challenges face platinum concentrator plant operators. These challenges include the increase in operating costs, the increase in smelter cost for the processing of concentrate, the shortage and cost of power, and the tightening of specifications on concentrate quality by the toll-smelting operations. Over the years the focus has moved from extracting the platinum group metals (PGM) from the Merensky Reef to the UG2 reef. This has a number of advantages, including the higher ?basket price? for UG2 concentrate, reduced mining cost per unit volume as a result of the higher density of UG2, and the reduction in overall concentrate tonnage to be smelted. In many cases the Merensky ore has been fully exploited and it makes sense for the focus to shift to the UG2 ore that can be accessed through the Merensky shaft infrastructure. The presence of relatively high levels of chromite in UG2 concentrate is, however, a major disadvantage due to the problems associated with smelting such a concentrate in conventional submerged arc furnaces. In addition to increasing the specification on the minimum PGM grade of concentrates, smelters have had to impose strict specifications on the levels of chromite in the concentrate. The threat of high penalties has forced concentrators to change their modus operandi, often resulting in a significant loss in recovery. The final concentrate grades and PGM recoveries are shown to vary significantly throughout the industry. The reasons for this include varying ore mineralogy and different operating philosophies. This would therefore imply that the opportunity exists to optimize the operations by considering fundamental aspects such as the PGM mineralogy and the application of appropriate technologies. By returning to the fundamentals of flotation and applying the findings of detailed process reviews, it has been possible to increase the concentrate PGM grade, reduce the concentrate chromite grade, and in some cases increase the recovery of PGM to concentrate. This paper presents case studies where this approach has been used to successfully optimize concentrator performance, resulting in lower operating cost and higher PGM production. Keywords Process optimization, platinum concentrator, milling, flotation, grade, recovery

Jan 1, 2011

By K. Goshtasbi

The mechanical behaviour of schistose sedimentary rocks such as slate show a great amount of anisotropy. Hence, the schistocity plane is essential when investigating the mechanical behaviour of such rocks. The presence of such rocks in civil projects causes non-symmetric deformation and their behaviour is unpredictable. In this research, the anisotropic strength behaviour of slates is studied. Uniaxial and triaxial tests were conducted on specimens having orientation angles (ß) of 0, 30, 45, 60, 75 and 90 degrees. The triaxial tests were done at confining pressures of 3, 5 and 10 MPa. The effect of anisotropy on uniaxial and triaxial strength, cohesion, angle of internal friction and Hoek and Brown's m and s constants were investigated. The results indicate that the strength of slates in uniaxial and triaxial compression exhibit a U-shaped anisotropic behaviour. In-order to evaluate the most suitable criterion for predicting the anisotropic strength of rocks in uniaxial and triaxial compression, an investigation was carried out on various criteria. In uniaxial compression, the Liao and Huong and Ramamurthy criteria had good agreements with the test results. In triaxial compression the Hoek and Brown and Mc Lamore criteria had better agreements with the test results. It should be noted that in-order to utilize these criteria, a large number of tests must be carried out. However, as the Ramamurthy criterion needs fewer test results, it can be the most suitable for investigating the behaviour of anisotropic rocks in triaxial compression. Keywords: Slate, anisotropy, schistose, failure criteria

Jan 1, 2006

By D. J. Bosman

The impoved densification of sludge from neutralized acid mine drainage. by D. J. BOSMAN, B.Sc., (Member) The paper describes an investigation aimed at finding a solution to the accumulation of acid mine drainage in the old workings at Coronation Collieries, Kromdraai. The problem involved the neutralization of the acid in the water, without the large volumes of sludge and the large amounts of dissolved solids that usually result from neutralization. Pilot-plant work on the site using a limeneutralization process developed at Bethlehem Steel Corporation (U.S.A.) showed this to be a feasible method. A sludge of 22 per cent density was obtained under optimum operating parameters. The amount of suspended solids in the overflow water was very high, but this does not give rise to concern because the full-scale plant at Kromdraai will practise secondary sedimentation by running the thickener overflow through large dams with a theoretical retention time of 25 days. An analysis of the theory underlying the process is also made.

Jan 4, 1974

By M. Bwalya, L. Mabokela, L. C. Woollacott

This paper presents a study on the ability of the King stratification modelto describe density stratification patterns that are achieved under idealizedconditions. Tests were conducted in a batch jig using artificial particles inseven density classes. All particles in a density class had essentially thesame density, size, and shape. Tests were conducted for particle systemsinvolving from two to seven components. Good agreement was obtainedbetween measured and modelled data to an extent that gave strongendorsement of the mathematical appropriateness of the core equation inthe King model. Somewhat ambiguous results were found with regard toclaims about the independencies of the single experimentally-determinedparameter required by the model.

Jan 1, 2015

By W. Carter, P. Chaubal, K. Spaleck, M. Schoeman, J. Bobek, W. Seegers

Keywords: Pyrometallurgy, steel, hearth, blast furnace The Mittal Steel Company operates about 36 blast furnaces on four continents. Furnaces range from 1100 m3 to 4800 m3 inner volume. The focus of the group is to push for increasing productivity and increasing campaign life. This has been especially challenging, as many of these furnaces were not equipped for long campaigns during their prior rebuilds. Monitoring and operating practices have to be modified to match the new philosophy. Mid-campaign hearth repair strategies and hearth design philosophies have had to be reconsidered. The paper describes experiences with the current hearth designs and measures taken for hearth life extension. Additionally, the philosophy of recent hearth re-designs is discussed.

Jan 1, 2006

By M. M. D. S. Vemba

Paper written on project work carried out in partial fulfilment of B.Sc. Eng (Mining Engineering) degree Engineering refers to the application of mathematics and other sciences to logically develop solutions to problems. However, in opencast mining, due to the randomness of operations, the use of mathematics is often neglected. Instead, practices that have proven successful elsewhere tend to apply. At the other end of the scale, mathematical models have been developed to identify and quantify all the operational parameters involved in the loading and haulage of ore. These are then used to optimize the operation. Optimization in this context, refers to the reduction of cost through effective utilization of the available time and resources. Considering these mathematical models, the loading and transport system at SMC (Catoca Mining Society) will be assessed with a view to its optimization. The discussion will be introduced by considering the mine background and other general information, which will highlight the main operational variables.

Jan 1, 2004

By E. Wolmarans

Dowding, Reynard and Associates Mineral Projects (DRAMP) was approached by the ARM/Lion Ore JV during July 2006 to conduct a feasibility study and control budget estimate for a new greenfield project for their NKOMATI Nickel mine 45 km east of Machadadorp. The scope included the evaluation and review of previous studies as well as a techno-economic trade-off on four possible comminution circuits ranging from conventional crushing and ball milling to fully autogenous milling. The following document encapsulates the thought process, decisions and the references used in selecting the final comminution route for the new 375 ktpm MMZ concentrator. Apart from the pilot test work performed, design simulations from a number of sources, performance results from a recently commissioned 100 ktpm MMZ concentrator, together with an understanding of the geology and mineralogy of the orebody and possible variations in the characteristics of the orebody over the life of mine were assessed. The results from all the above-mentioned work indicated that it would be possible to treat the MMZ ore at the desired throughputs to the desired grind sizes in a fully autogenous grinding (ABC-type) circuit. Autogenous milling is generally considered to be one of the higher risk milling circuits. This is mainly due to the fact that the ore, which is utilized as the grinding media, could be variable in terms of hardness and mineralogy/geology. Nevertheless, it is a very popular route as the cost benefits, more specifically the operating cost, are normally very attractive. This is especially the case when large low grade orebodies are evaluated. In North/South America, autogenous and semi-autogenous grinding circuits have been successfully employed during the past 20 years on large scale low grade operations. Taking all the above factors into account, the DRA/Nkomati project team recommended an autogenous circuit with the option to add steel to both the primary and secondary mills (if required) for the new operation in order to create the opportunity for significant operating cost savings. One has to bear in mind that all the new design simulations and decisions are based on previous work and potential unknown variations within the orebody will never be fully understood until the pit is operational for some time.

Jan 1, 2009

By T. P. Katakwa

The utilization of software is now inherent to virtually every activity along the mining value chain. However, apart from the software survey done by Gibbs in the 1990s and work on the extent of diffusion of information and communication technology (ICT) in the South African platinum sector by Mugodi and Fleming in 2003, the nature and extent of software utilization in the South African mining industry has never been evaluated. The Mine Planning, Optimisation and Valuation (MPOV) Research Group in the School of Mining Engineering, University of Witwatersrand, therefore initiated a project to collate and analyse the current utilization of software in the South African mining industry. This was done through the development of a web-based database of the relevant software. Snowball sampling was used to collect the data because the South African mining industry is diverse and software utilization is fragmented across and within the sectors of the industry. The data was then organized into distinct categories so that the information from a variety of sources could be evaluated on the same basis. A beta version of the database can be accessed online through a user-friendly front-end platform at http://db.mining.wits.ac.za. The database is expected to help at least 13 educational institutions with decisions on facilities and training that are vital to the education of mining and mining-related professionals. Exploration, mining, and consulting companies will also benefit from information in the database relating to availability and useful combinations of software solutions. The database is also strategic to software providers by providing a better understanding of their respective relative market share along the mining value chain. An analysis of the data collated in this research shows that about 77% of the software users are mining companies, 17% are consulting companies, 3% are mineral exploration companies, and the rest are software providers and educational institutions. The software used in the South African mining industry is largely provided by Gemcom Software International, MineRP Solutions, and MRM Mining Services. CAE Mining, who in 2010 acquired the Datamine Group providing Datamine software, is also widely acknowledged as a major software supplier in South Africa, but data from them had not been obtained at the time of producing the beta version of the database due to proprietary constraints. The work reported in this paper is part of an MSc research study in the School of Mining Engineering at the University of the Witwatersrand. Keywords mine planning, mining, value chain, software, database, South African mining industry, utilization.

Jun 1, 2013

By W. R. Matizamhuka

"The consolidation of nano-sized composite materials presents a challenge using conventional hot pressing methods. Spark plasma sintering (SPS) technology has shown great promise in the successful sintering of nanoreinforced composite materials. This qualitative review seeks to impart knowledge gathered, and progress made over the years on the consolidation of nanocomposite materials using SPS technology. The review is aimed at introducing this technology to the South African science and engineering community. Emphasis is on improving the mechanical properties of structural ceramic nanocomposite materials, which over the years have shown great promise in a wide range of applications, including transport, energy, mining, and the environment. Although success has been achieved within the laboratory for research purposes, there are still great opportunities to commercialize the technology for the production of larger components with more complex shapes.IntroductionSince the pioneering work of Niihara and Nakahira (1991) over a decade ago there have been extensive attempts to harness the potential of nanostructural metals, ceramics, and composites in a number of applications (Niihara and Nakahira, 1991; Selaho et al., 1997; Sekino and Niihara, 1995; Khalil, 2012; Aalund, 2008). It is generally realized that reducing the grain size of materials to nanoscale offers a significant improvement in properties. Attempts to synthesize nanostructured compacts by conventional sintering methods have not succeeded owing to the uncontrollable high rates of grain growth driven by long dwelling times at the sintering temperatures and large powder surface areas (Sergueeva et al., 2009; Gua, Khora, and Chieng, 2004; Tang et al., 2009). Following the development of spark plasma sintering (SPS) technology, it is now possible to process nanocrystalline materials with controlled grain growth. SPS, also referred to as the field-assisted sintering technique (FAST) or pulsed electric current sintering (PECS), was developed with the aim of improving on the well-established hot pressing (HP) technology (Kessel and Hennicke, 2007;"

Jan 1, 2016

By Y. Sagawa

The Hishikari Gold Mine consists of epithermal vein type Au-Ag deposits, each of which has several veins standing almost in parallel each other and inclining 70 to 90 degrees. The veins have 1 to 3m widths and are extracted mainly by drifting and bench stoping with waste rock fill. The Hishikari has tried to optimise the stope dimensions by the Potvin’s Stability Graph Method, which is well known as an easy and effective tool to design appropriate stope dimensions. The method, however, has some limitations of application due to its simplicity so that it has been used only in limited cases. The authors developed a new numerical approach, based on 2D FEM solu-tion for the stability analysis. As a result, it has been possible to solve the Hishikari situation. The authors also introduce the concept of the design approach and compare the results obtained by us-ing the approach with the database of the Stability Graph Method for validation. La mine d’or Hishikari se compose de gisements d'Au-AG avec des types de filons épither-maux dont chacun a plusieurs veines qui sont presque parallèle les unes par rapport aux autres et sont inclinées de 70 à 90 degrés. Les veines ont de 1 à 3 m de largueur et elles sont principalement extraites en creusant et en abattant des bancs de roches encaissantes. Hishikari a essayé d’optimiser les dimensions du chantier d’exploitation avec la méthode de graphique de stabilité de Potvin, bien connue comme un outil facile et efficace pour avoir des dimensions de chantier d’exploitation appropriées. Toutefois, la méthode a certaines limites d’application dues à sa sim-plicité de sorte qu’elle a été utilisée seulement dans des cas limités. Les auteurs ont développé une nouvelle approche numérique, basée sur la solution 2D FEM, pour l’analyse de stabilité. Par conséquent, il a été possible d'expliquer la situation de Hishikari. Les auteurs présentent le concept de l'approche et ils comparent les résultats donnés en l'employant avec la base de données de la méthode de graphique de stabilité pour la validation. Die Hishikari-Goldmine besteht aus Au-Ag-Ablagerungen mit epithermalen Adern, die jeweils mehrere Adern aufweisen, die mit einer Neigung zwischen 70 und 90 Grad nahezu parallel zueinander verlaufen. Die Adern haben eine Breite von 1 bis 3 Metern und werden überwiegend durch Vortrieb von Stollen und Bergversatz abgebaut. Hishikari hat versucht, die Abmessungen des Abbauorts durch das Potvins Stabilitätskurvenverfahren zu optimieren, das als einfaches und effizientes Mittel für die Erzielung angemessener Abmessungen des Abbauorts bekannt ist. Das Verfahren weist jedoch aufgrund seiner Einfachheit einige Anwendungsbeschränkungen auf, so dass es nur in einigen Fällen benutzt worden ist. Vor diesem Hintergrund haben die Autoren einen neuen numerischen Ansatz entwickelt, der hinsichtlich der Stabilitätsanalyse auf der 2D-FEM-Lösung beruht. Dadurch wurde es möglich, das Problem von Hishikari zu lösen. In diesem Dokument stellen die Autoren die Grundlagen des Ansatzes vor und vergleichen die erzielten Resultate durch Benutzung der Datenbank des Stabilitätskurvenverfahrens zur Validierung.

Jan 1, 2003

Published experimental data on thermodynamic behaviour of cobalt-containing slags have been reviewed and used in validating a recently developed thermodynamic model. The results from the exercise show that the model provides a reasonably good description of behaviour of cobalt in multi-component slag systems. The models for cobalt containing slags, matte and oxide solid solution phases were incorporated into CSIRO?s multi-phase equilibrium (MPE) package, which was used to calculate the equilibrium distribution of cobalt between matte and slag phases under various conditions. The results agreed well with the experimental data. Furthermore, the good agreement between the calculation and the plant data indicates that the operating conditions of industrial smelting and converting processes are close to equilibrium. Two diagrams showing the effects of slag chemistry and SO2and O2partial pressures on the distribution of cobalt between phases were generated for conditions similar to smelting and converting processes. These diagrams provide some useful guidelines for developing new strategies to improve cobalt recovery.

Jan 1, 2004

By T. G. Maepa

"The creation of mine excavations alters the stress distribution in the surrounding rock mass. In modern mining, resin-grouted rockbolts are used as a means of support in order to redistribute stresses and reestablish equilibrium in the rock mass. The success of resin-grouted rockbolting depends on the design of the system and the correct installation of the support units.The support design and rockbolt installation procedure at a platinum mine in the Bushveld Complex were investigated. A number of issues that resulted in poor installation were identified, including resin admixture, incorrect length and orientation of support holes, over- or under-spinning of the resin, and incorrect rockbolt tensioning. The support design used at the mine was reviewed and its limitations identified. A number of recommendations were made for optimizing the support design by reducing the diameter of the drill bit and reducing the length of the support holes. These changes will enable the mine to use different combinations of resin capsules. Implementation of the proposed changes will lead to a significant reduction in the cost of installation per support hole, as well as improve productivity and safety.IntroductionThe creation of any mine excavation disturbs the virgin state of stress in the Earth’s crust. This results in stress concentrations that interfere with the stability of the rock mass surrounding the excavation. It is essential to modify the internal behaviour of the rock mass surrounding excavations in order to reinforce the ground and stabilize excavations. Resin-grouted rockbolts are extensively used for this purpose. Esterhuizen (2014) stated that when effectively installed, the rockbolt exerts a clamping force and a bonding strength that keeps the rock mass together. This increases the cohesive strength of all discontinuities in the rock mass and enhances the stability of the excavation. Poorly designed and installed ground support is ineffective and constitutes a safety hazard. It is therefore crucial for every mine to ensure that any form of ground support is designed and installed correctly. This research evaluates the installation of resign-grouted rockbolts and identifies challenges and solutions for improved safety as observed at an operating hard rock mine. The support design used at the mine was reviewed and the design parameters optimized. The outcomes will enhance the efficiency of support and minimize the costs associated with the installation of resingrouted rockbolts."

Jan 1, 2017

By J. J. Stacey

Large mining companies generally follow the distributed ownership corporate model, with a board of directors responsible for decisions that affect both shareholder value and stakeholders of the company. The board is simultaneously responsible for setting the culture and values of the corporation, which drive performance and priorities. Companies listed on the Johannesburg Securities Exchange (JSE) commit to sustainable development in various ways, either by virtue of implementing the King Code of Governance 2009 (King III) and/or through their own public reporting on social and environmental matters. Many mining companies make public statements regarding their support for environmental stewardship, ethical behaviour, and fair treatment of communities. It is a local, regional, and indeed, global phenomenon that companies fail to deliver on these statements. Research was carried out through the Institute of Directors of Southern Africa in 2007, and followed up in 2012, regarding directors? understanding of sustainable development issues, the relative priorities, what is needed for ?radical change? to effect sustainable development, and what enables or constrains the latter. Pertinent findings of both surveys are presented in this paper, and it is suggested that ?on-the-ground? performance may be indicative of the nature of leadership and decisions in the topmost ranks of the company. The results indicated that environmental concerns fall consistently below social issues. Financial capital ranked most important, and while environmental issues are recognized as being of strategic concern for the long-term, they ranked as being the lowest importance of all ?Five Capitals? (Financial, Manufactured, Social, Human, and Natural). Social capital ranked second lowest, with black economic empowerment being the only high-priority social issue. There is also evidence that certain companies within the mining sector fail to recognize their absolute dependence on natural resources. Much is made in academic and popular literature of the need for a new type of leadership for the radical shift to sustainable development: at company level this implies therefore a new type of director. The research found that only 14 per cent of directors felt that board decisions are consistent with their personal values; while intentions are strong to behave ethically and serve sustainable development, actions to give effect to these intentions lag significantly. Respondents indicated that the top impediments to courageous leadership for sustainable development related to personal issues of maintaining the image of being a director, fear of appearing weak, fear of being a lone voice, and bowing to board-colleague peer pressure.

Jan 1, 2014

By E de Villiers

Several methods exist by which the capacity of a dense media separation (DMS) plant can be improved: 1) Increase the feed rate in spite of efficiency 2) Replace with bigger equipment 3) Add whole new module 4) Replace total plant 5) Change over to four shift/ seven days per week roster 6) Replace with alternative process 7) Increase the availability and utilization Options 1 ? 6 have varying degrees of cost implications. The seventh option would seem to be the easiest. Normally it is also the function of the plant operating and maintenance team to maximize this. Usually higher operating and maintenance cost are associated with an increase in these parameters. A general principle that is applicable to plants and systems is that as the complexity increases, the total availability decreases. By simplifying the flow line it may be possible to reduce cost while at the same time increase the availability and utilization. The typical standard DMS flow line contains components that compensate for the variance in pump performance or for the inefficient recovery of ferrosilicon with additional equipment. Things have changed though: 1) Advanced electronic control and monitoring is possible 2) More efficient magnetic separators are available 3) New more user friendly densifiers are available ORIGINAL FLOW LINE In principle the process consists of four flow lines or streams 1) Ore flow ? the feed is divided into a waste and product stream by means of the separating vessel

Jan 1, 2006

By M. Matema

Paper written on project work carried out in partial fulfilment of BSc (Eng.) Metallurgy and Materials Engineering Small and large welded aluminium specimens were tested in fatigue and the results compared with design curves for aluminium in specification BS8118. Metallurgical tests were also performed on the specimens in order to correlate microscopic and macroscopic phenomena. The small-scale fatigue test results were in reasonable agreement with results in BS8118, whereas the large-scale fatigue tests showed that BS8118 is conservative.

Jan 1, 2005

By A. McLean, M. Iwase, K. Wakimoto, K. Katogi, Y. Kikuchi

One of the greatest obstacles to the application of physical chemistry principles to the elucidation of slag-metal reactions is a lack of knowledge of activities of the reacting species. To a large extent, oxygen potential of the slag phase governs iron and steelmaking practice. Without oxygen control by means of appropriate sensors, the behaviour of the other elements cannot be managed. In this paper, measurements of the FeO activity with various types of electrochemical FeO sensors will be described together with examples of their applications for improved strategies toward better practice for ladle metallurgy and sulphur and manganese distributions between slag and metal phases during steelmaking. Measurements of FeO activity have also been made in order to improve dephosphorization reactions. This type of work has led to significant reduction in volume of slag generated within the steelmaking vessel, which in turn has important implications for refractory wear, metal yield, alloy recovery and improved productivity. Finally, an on-line sensor is described that permits the oxygen potential to be determined for both the metal phase and the slag phase during steelmaking in the BOF.

Jan 1, 2004

By D. Diering

Having agreed to perform this task, I naturally started to wonder what on earth I was going to talk about, and on reviewing the literature I was surprised at how little I knew and how much I?d forgotten about the origins of this industry. For example: ?I?d forgotten that the Chinese invented black powder at least 1 000 years ago, back in the 10th century (although some say this invention occurred 2 000years ago). ?I didn?t know that Roger Bacon was the first person in the Western World to give exact directions for the making of gunpowder in 1242 and to understand its potential. Pepper?s Playbook of Metals quotes:?...above all, he is named as the discoverer of gun-powder, a material which has brought more wonderful changes in the great family of man than the most potent elixir that could have been devised to prolong life?.

Jan 1, 2000

By K. Saito, Y. Miyauchi, T. Nishi, Y. Kizu

At Tokushima Plant of Nippon Denko Co., Ltd. high-carbon ferromanganese is produced by the electric furnace method using lump manganese ores and sintered manganese ores manufactured from fine manganese ores. However, the distribution of manganese ores is significantly uneven on earth, and their characteristics considerably vary by ore type. It is known from experience that the production of high-carbon ferromanganese by the electric furnace method depends greatly on material ores. Therefore, to maintain stable operation in the electric furnace-smelting field, it is important to identify the characteristics of each type of material ores in advance. Thus, we evaluated the high-temperature electric characteristics of manganese ores using the electrical conductivity measuring system developed by ourselves and provided the standards for determining ores and blending ratio necessary for stable operation of the electric furnace based on the evaluation results. This time we worked for optimisation of the high-temperature electric characteristics of sintered manganese ores through modification of the characteristics because the blending ratio of sintered manganese ores in the electric furnace is high. The electrical conductivity of sintered ores having various chemical components in a high-temperature region (up to 1 550°C) was measured using our electrical conductivity measuring system and high-temperature electric characteristics evaluating method reported at INFACON 9. As the result of the measurement, we revealed that the high-temperature electric characteristics of the sintered ores depend on their chemical contents and the sintered ores can be modified to those having excellent high-temperature electric characteristics by controlling their chemical contents, so that the resources can be effectively used.

Jan 1, 2004